CN103966835A - Method for preparing ultraviolet shielding textile composite fabric with graphene nanoplatelets - Google Patents
Method for preparing ultraviolet shielding textile composite fabric with graphene nanoplatelets Download PDFInfo
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Abstract
The invention provides a method for preparing an ultraviolet shielding textile composite fabric with graphene nanoplatelets. The method is characterized by comprising the following steps: performing shock dispersion on a graphene nanoplatelet solution and a nano titanium dioxide solution and adding into a certain quantity of adhesive solution, and fully stirring the mixed solution, wherein the composite fabric is prepared from the following raw materials in percentage by weight: 30-60 percent of graphene solution, 10-30 percent of nano titanium dioxide solution and 30-60 percent of adhesive solution; performing coating with a transfer coating method; performing high-temperature ultraviolet curing on a graphene coating fabric for 5-30 minutes and drying at 75-95 DEG C; and after the fabric is cooled, stripping the graphene coating fabric from transfer coating paper, thereby obtaining the composite material with the ultraviolet shielding function. The method is simple and reasonable in process, easy to operate and high in yield; the using amount of the graphene nanoplatelets is less, and the composite fabric has the high ultraviolet shielding function and can be used in functional textile products such as ultraviolet shielding sun umbrellas and protective clothing.
Description
Technical field
Textile product manufacturing technology of the present invention field, is specifically related to the weaving face fabric process technology of safeguard function, is the preparation method of the ultraviolet shielded textile composite fabric of a kind of nano-graphene microplate specifically.
Background technology
Along with the industrialized fast development in the whole world, air is subject to severe contamination, atmospheric ozone layer is destroyed, ozone thickness reduces, the short wavelength ultraviolet that is radiated the earth in sunshine partly increases, appropriate ultraviolet ray can make the interior synthetic vitamin of human body and kill some microorganisms and virus, but after ultraviolet excessive absorption and shortwave, people is known from experience and produces great harm and impact; Long-term irradiation ultraviolet ray can make people's skin produce melanin, occurs tanned and sunburn, if tanned, repeatedly occurs with sunburn, can increase and suffer from melanomatous danger.So exploitation has the weaving face fabric of anti-ultraviolet function and goods are significant to the damage of skin to effectively covering ultraviolet ray, market prospects are wide.
At present, screening uv-ray agent can be divided into two kinds, and a kind of is the agent of mineral-type ultraviolet reflection, the mechanism of action be mainly to ultraviolet ray absorb, reflection and scattering, to stop it to enter human body skin, the reflective agent that ultraviolet transmittance is lower is titanium dioxide, zinc oxide, comparatively conventional; Another kind is organic ultra-violet absorber, mainly that ultraviolet ray is had to absorption, the common ground of this type of absorbent is structurally all to contain hydroxyl, in the processes such as hydrogen bond, hydrogen bond chelate ring are stablized in formation, can absorb ultraviolet energy and be transformed into heat energy dissipation, on domestic market, conventional organic ultra-violet absorber is benzophenone and benzotriazole.Above-mentioned two class smoke agents for shielding are prepared Uvr Protective Fabric by co-blended spinning and afterfinish method, for mineral-type reflective agent, its larger specific area can produce diffuse reflection to ultraviolet ray, and to reach preventing ultraviolet effect, but the stability of its preventing ultraviolet effect and efficiency have much room for improvement; For part organic absorbent, there is certain toxicity, be not suitable for and human body skin Long contact time.
Meanwhile, above-mentioned anti-ultraviolet textile is the protection effect in Ultraviolet Protection Factor (UPF) 50, UVB transmitance 0.5% all, can stop most ultra-violet radiations, but shielding ultraviolet rays completely.Under some specific environment, require " ultraviolet shielded ", Ultraviolet Protection Factor (UPF) is much larger than 50, UVB transmitance much smaller than 0.5%, so developing a kind of ultraviolet shielded textile composite fabric is current technical task urgently to be resolved hurrily.
Nano-graphene microplate is a kind of New Type of Carbon nanometer light material, there is unique monoatomic layer two dimensional crystal structure, huge specific area, because the characteristics such as the intensity of its superelevation, electrical conductivity, thermal conductivity, reflectivity obtain broad research, the thickness of nano-graphene microplate (1-3nm), much smaller than ultraviolet wavelength (100-400nm), easily promotes ultraviolet scattering; Nano-graphene at 270nm, easily produces electron-hole pair at the absworption peak of ultraviolet band, has the ultraviolet function of absorption; In addition, two-dimension plane structure is high to the reflection efficiency of each lightlike line, screening effect is desirable.Based on above-mentioned characteristic, nano-graphene microplate should have desirable ultraviolet shielded effect, can be applicable to the preparation of ultraviolet shielded textile composite fabric.
Summary of the invention
The problem that the present invention exists for solving prior art, the preparation method of the ultraviolet shielded textile composite fabric of a kind of nano-graphene microplate is provided, technique is simple, reasonable, easy operating, and output is higher, nano-graphene microplate content is less, and the weaving face fabric of production has excellent ultraviolet shielding function, is applicable to functional ultraviolet shielded textiles.
For achieving the above object, the present invention adopts following technical scheme:
A preparation method for the ultraviolet shielded textile composite fabric of nano-graphene microplate, is characterized in that, comprises nano-graphene microplate screener mixed processes, coating operation and the ultra-violet curing operation of carrying out successively; Described nano-graphene microplate screener mixed processes is: will after nano-graphene microplate solution and nanometer titanium dioxide titanium solution concussion dispersion, join in a certain amount of binder solution, mixed solution fully stirs; The percentage by weight of its raw material is: nano-graphene microplate solution 30%-60%, nanometer titanium dioxide titanium solution 10%-30%, binder solution 30%-60%; Described coating operation is: the coating process of employing is transfer coated method; Described ultra-violet curing operation is: by nano-graphene microplate coated fabric ultra-violet curing, wherein bake out temperature is 75-95 ℃, be 5-30 minute hardening time, after cooling, nano-graphene microplate coated fabric and transfer coated paper are peeled off, finally, make the composite material with ultraviolet shielding function characteristic.
Preferably, in described nano-graphene microplate solution, nano-graphene microplate solid content is 1%-5%, and nanometer titanium dioxide titanium solution solid content is 5%-10%, and adhesive solid content is 30%-50%; On described composite material, the Gram Mass of coating nano-graphene microplate is 0.1-2g/m
2.
Preferably, described adhesive is selected from one or more in polyurethane, polyvinyl alcohol, polyacrylate, epoxy resin.
Preferably, described ultraviolet light polymerization operation is used high-voltage mercury lamp, and irradiation power is 100-500W, and irradiation distance is 30-60cm.
Further, the concrete technology of described coating operation is: on transfer laminator, fabric base cloth is carried out to top finish, first, nano-graphene microplate screener is coated on transfer coated paper, coating layer thickness is 0.05-0.5mm; Selected fabric base cloth and coating are carried out bonding, with pressure roller, pressurize, pressure roller spaces for 0.15-0.5mm.
The present invention compared with prior art has many advantages and good effect:
Preparation method of the present invention production technology simple, easy operating, output is higher, nano-graphene microplate content is less; The uv transmittance (UVA)≤0.5% of nano-graphene microplate coated fabric prepared by the inventive method, Ultraviolet Protection Factor (UPF) ranges up to 500+, there is superpower ultraviolet shielding function (according to standard GB/T 18830-2002, UPF50+ reaches antiultraviolet product standard), can be used for the functional ultraviolet shielded textiless such as ultraviolet shielded parasol, sunbonnet, protective clothing, tent, sunshade.
Accompanying drawing explanation
Fig. 1 is the terylene parasol composite material ultraviolet ray transmissivity curvilinear coordinate figure with ultraviolet shielding function through the embodiment of the present invention 1 preparation;
Fig. 2 is the anti-flaming viscose plural tent fabric ultraviolet ray transmissivity curvilinear coordinate figure with ultraviolet shielding function through the embodiment of the present invention 2 preparations.
Fig. 3 is the Polyamide Filament Fabrics ultraviolet ray transmissivity curvilinear coordinate figure with ultraviolet shielding function through the embodiment of the present invention 3 preparations.
The specific embodiment
Below in conjunction with concrete embodiment, the present invention is described further.
The preparation method's of the ultraviolet shielded textile composite fabric of a kind of nano-graphene microplate of the present invention the specific embodiment, comprises nano-graphene microplate screener mixed processes, coating operation and the high temperature set operation of carrying out successively, wherein:
Described nano-graphene microplate screener mixed processes is: will after nano-graphene microplate solution and nano titanium oxide concussion dispersion, join in a certain amount of binder solution, mixed solution fully stirs; The percentage by weight of its raw material is: nano-graphene microplate solution 30%-60%, nanometer titanium dioxide titanium solution 10%-30%, binder solution 30%-60%.Described coating operation is: the coating process of employing is transfer coated method.Described ultra-violet curing operation is: by nano-graphene microplate coated fabric ultra-violet curing, wherein bake out temperature is 75-95 ℃, be 5-30 minute hardening time, after cooling, nano-graphene microplate coated fabric and transfer coated paper are peeled off, finally, make the composite material with ultraviolet shielding function characteristic.
Specific embodiments of the invention are as follows:
Embodiment 1: the preparation method of the ultraviolet shielded terylene parasol of a kind of nano-graphene microplate composite material, comprises following operation:
(1) nano-graphene microplate screener mixed processes: will join in soluble polyurethane solution after nano-graphene microplate solution and nanometer titanium dioxide titanium solution concussion dispersion, mixed solution fully stirs; The percentage by weight of its raw material is: nano-graphene microplate solution 30%, nanometer titanium dioxide titanium solution 10%, soluble polyurethane solution 60%; Wherein, in nano-graphene microplate solution, nano-graphene microplate solid content is 2%, nano titanium oxide solid content 5%, and in soluble polyurethane solution, polyurethane solid content is 50%.
(2) coating operation: on transfer laminator, it is carried out to top finish, first nano-graphene microplate screener is coated on transfer coated paper, coating layer thickness is 0.05mm; Selected terylene parasol fabric base cloth and coating are carried out bonding, with pressure roller, pressurize, pressure roller spaces for 0.15mm.
(3) ultra-violet curing operation: nano-graphene microplate coated fabric is placed under ultra-violet curing device and is dried, and wherein uviol lamp power is 200W, and irradiation temperature is 80 ℃, and irradiation distance is 30cm, and the hot setting time is 20 minutes.After cooling, terylene parasol coated fabric and transfer coated paper are peeled off, obtained the ultraviolet shielded terylene composite solar of nano-graphene microplate umbrella cover material, wherein, on composite material, the Gram Mass of coating nano-graphene microplate is 0.2g/m
2.
After tested, without coating, process the uv transmittance UVA=14.38% of terylene parasol fabric, UVB=2.70%, Ultraviolet Protection Factor (UPF)=18.44.The uv transmittance UVA=2.14% of gained nano-graphene microplate terylene composite solar umbrella cover material, UVB=0.30%, ultraviolet ray transmissivity curve as shown in Figure 1, Ultraviolet Protection Factor (UPF)=155.96.
Embodiment 2: the preparation method of the ultraviolet shielded anti-flaming viscose plural tent of a kind of nano-graphene microplate fabric, comprises following operation:
(1) nano-graphene microplate screener mixed processes: will join in polyacrylate solution after nano-graphene microplate solution and nanometer titanium dioxide titanium solution concussion dispersion, mixed solution fully stirs; The percentage by weight of its raw material is: nano-graphene microplate solution 40%, nanometer titanium dioxide titanium solution 10%, polyacrylate solution 50%; Wherein, in nano-graphene microplate solution, nano-graphene microplate solid content is 2%, and nano titanium oxide solid content is 10%, and in polyacrylate solution, polyacrylate solid content is 50%.
(2) coating operation: on transfer laminator, it is carried out to top finish, first nano-graphene microplate screener is coated on transfer coated paper, coating layer thickness is 0.1mm; Selected anti-flaming viscose fabric base cloth and coating are carried out bonding, with pressure roller, pressurize, pressure roller spaces for 0.2mm.
(3) ultra-violet curing operation: nano-graphene microplate coated fabric is placed under ultra-violet curing device and is dried, and wherein uviol lamp power is 300W, and irradiation temperature is 95 ℃, and irradiation distance is 30cm, and the hot setting time is 30 minutes.After cooling, anti-flaming viscose fabric coating fabric and transfer coated paper are peeled off, obtained the ultraviolet shielded anti-flaming viscose plural tent of nano-graphene microplate fabric, wherein, on composite material, the Gram Mass of coating nano-graphene microplate is 1g/m
2.
After tested, process the uv transmittance UVA=29.30% of anti-flaming viscose fabric without coating, UVB=21.29%, Ultraviolet Protection Factor (UPF)=4.26.The uv transmittance UVA=0.45% of gained nano-graphene microplate anti-flaming viscose plural tent fabric, UVB=0.07%, ultraviolet ray transmissivity curve as shown in Figure 2, Ultraviolet Protection Factor (UPF)=500.
Embodiment 3: the preparation method of the ultraviolet shielded chinlon filament of a kind of nano-graphene microplate and composite material thereof, comprises following operation:
(1) nano-graphene microplate screener mixed processes: will join in soluble polyurethane solution after nano-graphene microplate solution and nanometer titanium dioxide titanium solution concussion dispersion, mixed solution fully stirs; The percentage by weight of its raw material is: nano-graphene microplate solution 50%, nanometer titanium dioxide titanium solution 10%, polyacrylate solution 40%; Wherein, in nano-graphene microplate solution, nano-graphene microplate solid content is 1%, and nano titanium oxide solid content is 10%, and in soluble polyurethane solution, soluble polyurethane solid content is 50%.
(2) coating operation: on transfer laminator, it is carried out to top finish, first nano-graphene microplate screener is coated on transfer coated paper, coating layer thickness is 0.05mm; Selected chinlon filament arranged in a uniform and coating are carried out bonding, with pressure roller, pressurize, pressure roller spaces for 0.1mm.
(3) ultra-violet curing operation: nano-graphene microplate coated fabric is placed under ultra-violet curing device and is dried, and wherein uviol lamp power is 250W, and irradiation temperature is 85 ℃, and irradiation distance is 50cm, and the hot setting time is 45 minutes.After cooling, coating chinlon filament and transfer coated paper are peeled off, obtained the ultraviolet shielded chinlon filament of nano-graphene microplate, wherein, on chinlon filament, the Gram Mass of coating nano-graphene microplate is 0.5 g/m
2.
(4) weaving operation: take nano-graphene microplate polyamide fibre bicomponent filament yarn as through weft yarn, by air-jet loom weaving nano-graphene microplate polyamide fibre composite material, fabric structure is plain weave.
After tested, process the uv transmittance UVA=27.73% of nylon fibre without coating, UVB=13.42%, Ultraviolet Protection Factor (UPF)=6.63.The uv transmittance UVA=0.75% of gained nano-graphene microplate Polyamide Filament Fabrics, UVB=0.27%, ultraviolet ray transmissivity curve as shown in Figure 3, Ultraviolet Protection Factor (UPF)=375.
Above embodiment is only in order to technical scheme of the present invention to be described, but not is limited; Although the present invention is had been described in detail with reference to previous embodiment, for the person of ordinary skill of the art, the technical scheme that still can record previous embodiment is modified, or part technical characterictic is wherein equal to replacement; And these modifications or replacement do not make the essence of appropriate technical solution depart from the spirit and scope of the present invention's technical scheme required for protection.
Claims (7)
1. a preparation method for the ultraviolet shielded textile composite fabric of nano-graphene microplate, is characterized in that, comprises nano-graphene microplate screener mixed processes, coating operation and the ultra-violet curing operation of carrying out successively;
Described nano-graphene microplate screener mixed processes is: will after nano-graphene microplate solution and nanometer titanium dioxide titanium solution concussion dispersion, join in a certain amount of binder solution, mixed solution fully stirs; The percentage by weight of its raw material is: nano-graphene microplate solution 30%-60%, nanometer titanium dioxide titanium solution 10%-30%, binder solution 30%-60%; Described coating operation is: the coating process of employing is transfer coated method; Described ultra-violet curing operation is: by nano-graphene microplate coated fabric ultra-violet curing, wherein bake out temperature is 75-95 ℃, be 5-30 minute hardening time, after cooling, nano-graphene microplate coated fabric and transfer coated paper are peeled off, finally, make the composite material with ultraviolet shielding function characteristic.
2. according to the preparation method of the ultraviolet shielded textile composite fabric of a kind of nano-graphene microplate claimed in claim 1, it is characterized in that, in described nano-graphene microplate solution, nano-graphene microplate solid content is 1%-5%, nanometer titanium dioxide titanium solution solid content is 5%-10%, and adhesive solid content is 30%-50%; On described composite material, the Gram Mass of coating nano-graphene microplate is 0.1-2g/m
2.
3. according to the preparation method of the ultraviolet shielded textile composite fabric of a kind of nano-graphene microplate described in claim 1 or 2, it is characterized in that, described adhesive is selected from one or more in polyurethane, polyvinyl alcohol, polyacrylate, epoxy resin.
4. according to the preparation method of the ultraviolet shielded textile composite fabric of a kind of nano-graphene microplate described in claim 1 or 2, it is characterized in that, described ultraviolet light polymerization operation is used high-voltage mercury lamp, and irradiation power is 100-500W, and irradiation distance is 30-60cm.
5. according to the preparation method of the ultraviolet shielded textile composite fabric of a kind of nano-graphene microplate claimed in claim 3, it is characterized in that, described ultraviolet light polymerization operation is used high-voltage mercury lamp, and irradiation power is 100-500W, and irradiation distance is 30-60cm.
6. according to the preparation method of the ultraviolet shielded textile composite fabric of a kind of nano-graphene microplate described in claim 1 or 2, it is characterized in that, the concrete technology of described coating operation is: on transfer laminator, fabric base cloth is carried out to top finish, first, nano-graphene microplate screener is coated on transfer coated paper, and coating layer thickness is 0.05-0.5mm; Selected fabric base cloth and coating are carried out bonding, with pressure roller, pressurize, pressure roller spaces for 0.15-0.5mm.
7. according to the preparation method of the ultraviolet shielded textile composite fabric of a kind of nano-graphene microplate claimed in claim 5, it is characterized in that, the concrete technology of described coating operation is: on transfer laminator, fabric base cloth is carried out to top finish, first, nano-graphene microplate screener is coated on transfer coated paper, and coating layer thickness is 0.05-0.5mm; Selected fabric base cloth and coating are carried out bonding, with pressure roller, pressurize, pressure roller spaces for 0.15-0.5mm.
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| CN104562682A (en) * | 2015-01-16 | 2015-04-29 | 浙江大学 | Wash-wear nonwoven fabric capable of selectively blocking ultraviolet rays |
| CN105088793A (en) * | 2015-08-25 | 2015-11-25 | 无锡市长安曙光手套厂 | Non-woven fabric, and preparation method and application thereof |
| CN106283609A (en) * | 2016-07-27 | 2017-01-04 | 江苏新凯盛企业发展有限公司 | A kind of preparation technology of Graphene coating fabric |
| CN106811967A (en) * | 2016-04-01 | 2017-06-09 | 青岛大学 | A kind of preparation method of graphene oxide antimicrobial coating fabric |
| CN106832883A (en) * | 2017-01-17 | 2017-06-13 | 南通强生安全防护科技股份有限公司 | Aqueous PU composite mortars of Graphene and its production and use |
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| CN107142741A (en) * | 2017-06-25 | 2017-09-08 | 长沙善道新材料科技有限公司 | A kind of ultraviolet-resistant fabric and preparation method thereof |
| CN107348580A (en) * | 2017-06-23 | 2017-11-17 | 宁波高新区达康工业科技有限公司 | A kind of antiultraviolet farinfrared health-care material |
| CN108624203A (en) * | 2017-03-16 | 2018-10-09 | 青岛大学 | A kind of preparation method of graphene oxide/titanium dioxide composite coating |
| CN109232927A (en) * | 2018-08-13 | 2019-01-18 | 晋江佰晟新材料科技有限公司 | A kind of preparation method of the antistatic antibiotic far-infrared ray warming textile of containing graphene |
| CN109457499A (en) * | 2018-11-07 | 2019-03-12 | 昆山联盛达纺织品有限公司 | A kind of graphene coating fabric and its preparation process |
| CN110644243A (en) * | 2019-08-27 | 2020-01-03 | 徐州华通手套有限公司 | Processing technology of cutting-resistant gloves |
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| CN113774654A (en) * | 2021-09-09 | 2021-12-10 | 广东职业技术学院 | Ultraviolet-proof composition and application thereof |
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| CN104562682A (en) * | 2015-01-16 | 2015-04-29 | 浙江大学 | Wash-wear nonwoven fabric capable of selectively blocking ultraviolet rays |
| CN105088793A (en) * | 2015-08-25 | 2015-11-25 | 无锡市长安曙光手套厂 | Non-woven fabric, and preparation method and application thereof |
| CN106811967A (en) * | 2016-04-01 | 2017-06-09 | 青岛大学 | A kind of preparation method of graphene oxide antimicrobial coating fabric |
| CN106283609A (en) * | 2016-07-27 | 2017-01-04 | 江苏新凯盛企业发展有限公司 | A kind of preparation technology of Graphene coating fabric |
| CN106832883A (en) * | 2017-01-17 | 2017-06-13 | 南通强生安全防护科技股份有限公司 | Aqueous PU composite mortars of Graphene and its production and use |
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| CN107059415A (en) * | 2017-04-12 | 2017-08-18 | 三元控股集团有限公司 | A kind of preparation method of the multifunctional conductive fabric based on photocuring technology |
| CN107348580A (en) * | 2017-06-23 | 2017-11-17 | 宁波高新区达康工业科技有限公司 | A kind of antiultraviolet farinfrared health-care material |
| CN107348580B (en) * | 2017-06-23 | 2019-01-29 | 宁波高新区达康工业科技有限公司 | A kind of antiultraviolet farinfrared health-care material |
| CN107142741A (en) * | 2017-06-25 | 2017-09-08 | 长沙善道新材料科技有限公司 | A kind of ultraviolet-resistant fabric and preparation method thereof |
| CN109232927A (en) * | 2018-08-13 | 2019-01-18 | 晋江佰晟新材料科技有限公司 | A kind of preparation method of the antistatic antibiotic far-infrared ray warming textile of containing graphene |
| CN109457499A (en) * | 2018-11-07 | 2019-03-12 | 昆山联盛达纺织品有限公司 | A kind of graphene coating fabric and its preparation process |
| CN110644243A (en) * | 2019-08-27 | 2020-01-03 | 徐州华通手套有限公司 | Processing technology of cutting-resistant gloves |
| CN110777541A (en) * | 2019-11-05 | 2020-02-11 | 宁波故乡行雨具有限公司 | Anti-aging and antibacterial raincoat fabric |
| CN112663343A (en) * | 2020-12-29 | 2021-04-16 | 诸暨市申嘉机械科技有限公司 | Pearl graphene fiber and production method thereof |
| CN113774654A (en) * | 2021-09-09 | 2021-12-10 | 广东职业技术学院 | Ultraviolet-proof composition and application thereof |
| CN113774654B (en) * | 2021-09-09 | 2023-09-12 | 广东职业技术学院 | Ultraviolet-proof composition and application thereof |
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