CN103938818A - Noise reducing and heat insulating decoration integrated plate and preparing method thereof - Google Patents

Noise reducing and heat insulating decoration integrated plate and preparing method thereof Download PDF

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Publication number
CN103938818A
CN103938818A CN201410108530.8A CN201410108530A CN103938818A CN 103938818 A CN103938818 A CN 103938818A CN 201410108530 A CN201410108530 A CN 201410108530A CN 103938818 A CN103938818 A CN 103938818A
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parts
paint
agent
defoamer
heat
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CN201410108530.8A
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CN103938818B (en
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李晓军
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Shandong Lumeng low carbon technology research Co., Ltd
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YANTAI SITANPU FINE CONSTRUCTION Co Ltd
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Abstract

The invention discloses a noise reducing and heat insulating decoration integrated plate and a preparing method thereof. The integrated plate comprises a noise reducing layer (1) and a light reflecting heat insulating decoration layer (2). The noise reducing layer (1) is a foam microcrystal ceramic plate. The light reflecting heat insulating decoration layer (2) is a solar heat reflection decoration coating, and comprises three layers of coating film systems including bottom paint (3), middle paint (4) and surface paint (5). The noise reducing and heat insulating decoration integrated plate is fireproof, flame retardant, good in durability and capable of insulating sound, reducing noise, insulating heat and decorating and conforming to the energy conservation, emission reduction, circular economy and other ideas of environmental-friendly buildings, and the service life of the integrated plate is same as the service life of the building.

Description

A kind of noise abatement heat-insulating decorative integrated board and preparation method thereof
Technical field
The present invention relates to building energy conservation and photoelectricity building field, be specifically related to a kind of noise abatement heat-insulating decorative integrated board and preparation method thereof.
Background technology
Show according to interrelated data, China all will build 2,000,000,000 square metres of new buildings every year, is equivalent to 40% left and right of the annual all new buildings in the world, is the country of annual new building amount maximum in the world.The existing area of residence of China exceedes 40,000,000,000 square metres in addition, and wherein great majority are high energy consumption houses, and its energy input is 3 times of developed country.Eleventh Five-Year Plan end, Building Trade in China energy consumption accounts for 30% left and right of national total energy consumption, occupies first of national all kinds of energy consumption, has become energy consumption rich and influential family.In builing industry high speed development, the high problem of industry energy consumption is also more and more outstanding.Therefore, Sustainable Construction Industry energy-saving and emission-reduction are crucial.In the last thirty years, the Building Energy-saving Work of China mainly concentrates on the external wall outer insulation of northern area, to solve the high energy consumption problem of winter heating phase.Along with the power cuts to limit consumption that the air conditioning energy consumption of the warm hot Area during Summer of summer of continuous high temperature, particularly winter of China most areas in summer causes in recent years happens occasionally, thermal isolation is put in the agenda of China's Building Energy-saving Work.
The earth is subject to the irradiation of the sun all the time.The sun is per second 1.765 × 1017(subscript) J energy arrives the earth, huge energy provides necessary requirement to the mankind's existence and life, but the intense radiation of the sun, serve inconvenience also to people's life band, much harm is brought in the space that the high-heating radiation meeting of the sun is depended on for existence to the mankind.Summer, sun lights was on building roof, and the interior temperature of loft exceeds 3~5 DEG C than room downstairs.In many developed countries, the energy that the cooling refrigeration equipment such as spray equipment, air-conditioning, air conditioner and electric fan consume, accounts for the more than 20% of annual total energy consumption.In China, the energy of these devices consume is more.
From last century the seventies, abroad propose and begin one's study a kind of taking near-infrared in reflected sunlight as main infrared reflection coating, compared with traditional cool-down method, it is consumed energy but also can effectively reduce and be exposed to the surface temperature that shines upon lower object not only, stop the transmission of heat to interior of articles from source, reached the object of energy-saving cool-down.
At present, domestic the research of solar heat reflecting and heat insulating coating is also in to the development phase, research work mainly concentrates on the adjustment of film forming matter modification and formulation for coating material.The patent No. is 99114454.6 radioresistant insulating water paint, taking antiradiation as main, so owing to being that single layer coating effect of heat insulation is poor.The patent No. is the aqueous epoxy modified acrylic heat-reflecting thermo that 02109969.3 nanometer acrylic acid microemulsion, water-thinned heat reflecting coating and the patent No. are 03111863.1, and all, to be reflected into master, its reflectivity only reaches 50~80%.All there is problem, the preparation means complexity that effect of heat insulation channel is single in these patents above.And current reflection and heat insulation coating patented technology for building all needs post coat, there are the following problems: (1) industrialization degree is low, all need to be in building-site manual operations, construction link is many, complex procedures, is subject to climate and weather restriction, affects programming; (2) site operation, human factor is more, comparatively difficulty of workmanship and reflection and heat insulation Properties Control; (3) manual operations of post coat very easily causes waste and the environment pollution of material, does not meet and economizes on resources and the demand of the sustainable development of protection of the environment.
Summary of the invention
For improving industrialization and the industrialization level of building heat preservation heat-insulating technique, guarantee Energy Conservation Project in Construction quality, realize the intensive manufacture of green building component, by a large amount of investigation and research work, the technical problem that the present invention solves is to provide a kind of noise abatement heat-insulating decorative integrated board with function of heat reflection.
A kind of noise abatement heat-insulating decorative integrated board, it is characterized in that: described integrated board comprises noise abatement layer and reflection and heat insulation decorative layer, described noise abatement layer is foam micro-crystalline ceramic plate, described reflection and heat insulation decorative layer is solar heat reflection decorative paint, it is divided into three-layer coated system, is made up of priming paint, middle paint and finish paint.
Noise abatement heat-insulating decorative integrated board of the present invention, the thickness of wherein said foam micro-crystalline ceramic plate is 20~500mm; The thickness of described priming paint is that the thickness of 100~200 μ m, middle paint is that the thickness of 5~20mm, finish paint is 300~500 μ m; The specification of described noise abatement heat-insulating decorative integrated board is for long: 2000mm, 2440mm, 3000mm or 3200mm; Wide: 1220mm, 1250mm or 1500mm.
Noise abatement heat-insulating decorative integrated board of the present invention, wherein said priming paint is silicon third or acrylic emulsion.
Noise abatement heat-insulating decorative integrated board of the present invention, wherein said priming paint is made up of the material of following weight portion:
Deionized water: 200~300 parts;
Solid content is 49% silicon third or pure-acrylic emulsion: 320~400 parts;
80~140 parts of coarse whitings;
Wollastonite in powder: 40~60 parts;
Anionic wetting agent: 2~5 parts;
Thickener: 4~6 parts;
Plasticizing agent: 3~5 parts;
Dispersing agent: 7~10 parts;
Coalescents: 30~40 parts;
Defoamer: 6~8 parts;
Antisepticize and mildew preventive: 4~5 parts;
Ethylene glycol: 3~6 parts;
Propane diols: 3~5 parts;
PH adjusting agent: 8~10 parts;
Wherein, the pH value of described anionic wetting agent is 5.5~7.5, and described thickener is carboxymethyl cellulose, and described plasticizing agent is synthetic vegetable esters fluidizer; Described dispersing agent is cithrol 200 or 400, and described coalescents is Lauryl Alcohol ester, and described defoamer is PPG, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described pH adjusting agent is methane-siliconic acid aqueous solutions of potassium.
Noise abatement heat-insulating decorative integrated board of the present invention, wherein said middle paint is prepared from by the raw material of following weight portion:
Solid content is 49% emulsion type synthetic polymer emulsion: 380~450 parts;
Deionized water: 245~300 parts;
Sunshine reflecting material: 50~60 parts;
Color stuffing: 34~40 parts;
Nano material: 45~50 parts;
Anionic wetting agent: 5~7 parts;
Thickener: 4~5 parts;
Plasticizing agent: 2.5~4 parts;
Dispersing agent: 12~14 parts;
Coalescents: 25~40 parts;
Defoamer: 4~7 parts;
Antisepticize and mildew preventive: 3~5 parts;
Ethylene glycol: 3.5~5 parts;
Propane diols: 2~3 parts;
PH adjusting agent: 7~10 parts;
Wherein, the pH value of described anionic wetting agent is 5.5~7.5, described thickener is carboxymethyl cellulose, described plasticizing agent is synthetic vegetable esters fluidizer, described dispersing agent is cithrol 200 or 400, and described coalescents is Lauryl Alcohol ester, and described defoamer is PPG, described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described pH adjusting agent is methane-siliconic acid aqueous solutions of potassium.
Noise abatement heat-insulating decorative integrated board of the present invention, what wherein said emulsion type synthetic polymer emulsion adopted is the one in organic siliconresin emulsion, styrene-acrylic emulsion, acrylate copolymer emulsion, organosilicon-acrylic emulsion, aqueous epoxy resin emulsion, aqueous polyurethane emulsion;
The mixture of one or more in pearl mica, aluminium powder that described sunshine reflecting material is refractive index is 2.03 zinc oxide, refractive index is 2.74 titanium oxide, refractive index is 2.3;
Described color stuffing is one or more the mixture in French chalk, dicalcium powder, glass microballoon, titanium dioxide, iron oxide red, iron oxide zinc, iron oxide yellow, pearl mica, lithopone;
Described nano material is one or more the mixture in nano-calcium carbonate, nano titanium oxide, nano zine oxide, nanometer scale ceramics bubble, nano silicon, nano far infrared ceramic powder.
Noise abatement heat-insulating decorative integrated board of the present invention, wherein said finish paint is applied and is formed by anti-fouling and self-cleaning coating, and described anti-fouling and self-cleaning coating is that particle diameter is nano level organosilicon-modified acrylic coating, and thickness is 300~500 μ m.
Noise abatement heat-insulating decorative integrated board of the present invention, wherein said organosilicon-modified acrylic coating is made up of the material of following weight portion:
Deionized water: 500~560 parts;
Activity substance content is 42% organosilicon-acrylic resin emulsion: 30~60 parts;
Coalescents: 32~40 parts;
Antisepticize and mildew preventive: 8~10 parts;
Defoamer: 6~10 parts;
Ethylene glycol: 40~50 parts;
Plasticizing agent: 0.3~0.5 part;
PH adjusting agent: 8~10 parts;
Wherein, described coalescents is Lauryl Alcohol ester, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, synthetic vegetable esters fluidizer, and described defoamer is PPG, described pH adjusting agent is methane-siliconic acid aqueous solutions of potassium.
One is prepared noise abatement heat-insulating decorative integrated board method of the present invention, comprises the steps:
The preparation of step 1, noise abatement layer: manufactured foam micro-crystalline ceramic is cut into the sheet material that thickness is 30~500mm, to described plate surface and corner polishing, deburring and cleaning, guarantee that upper surface is smooth, horizontal error ± 2mm, facade vertical error ± 1mm, the upright error under ±2 mm of external corner, removes the floating ash of plate surface and waits attachment;
The preparation of step 2, reflection and heat insulation decorative layer: prepare respectively priming paint, middle paint and finish paint, first at foam micro-crystalline ceramic warming plate upper surface primer coating, then at the water-fast flexible putty of surperficial blade coating, finally use spray gun that middle paint is coated on to putty surface, spray paint again after surface is fully dry;
The preparation of step 3, final products: it is 2000mm, 2440mm, 3000mm or 3200mm that the described plate cutting that passes through application is become to length; Width is the integrated board of 1220mm, 1250mm or 1500mm, obtains product.
The preparation method of noise abatement heat-insulating decorative integrated board of the present invention, is characterized in that:
The preparation method of described priming paint is: by load weighted wetting agent, dispersing agent, ethylene glycol, propane diols and fungusproof anti-corrosion agent join respectively pure third or Silicone acrylic emulsion in, fully disperse 20~30min with the rotating speeds of 800 revs/min; Add again coarse whiting and wollastonite in powder, fully disperse 10~15min with the rotating speeds of 1500 revs/min, in the process stirring, add defoamer and the plasticizing agent of 1/3 weight, fully disperse 15~20min with the rotating speed of 800 revs/min again, add the deionized water mixing with coalescents, thickener, then add defoamer, the pH adjusting agent of 2/3 weight, be uniformly mixed, be mixed with solar heat reflection paint priming paint;
The preparation method of described middle paint is: load weighted wetting agent, dispersing agent, ethylene glycol, propane diols and fungusproof anti-corrosion agent are added respectively in emulsion type synthetic polymer emulsion, fully disperse 20~30min with the rotating speeds of 800 revs/min; Add again sunshine reflecting material, nano material and color stuffing, fully disperse 10~15min with the rotating speeds of 1500 revs/min; In the process stirring, add defoamer and the thickener of 1/3 weight, fully disperse 15~20min with the rotating speed of 800 revs/min again, add the deionized water having mixed with coalescents, plasticizing agent, add again defoamer, the pH adjusting agent of 2/3 remaining weight, be uniformly mixed, be mixed with in heat reflection coatings and paint;
The preparation method of described finish paint is: by load weighted fungusproof anti-corrosion agent and ethylene glycol, pH adjusting agent adds in organosilicon-acrylic resin emulsion, with the rotating speed premix of 800 revs/min, fully stir about 20~30min, disperse 10~15min with the rotating speeds of 1500 revs/min, in the process stirring, add the defoamer of 1/3 weight, fully disperse 15~20min with the rotating speed of 800 revs/min again, and add and coalescents, the deionized water that plasticizing agent mixes, add again the defoamer of 2/3 weight, be uniformly mixed, be mixed with sunshine reflective coating finish paint.
The present invention and existing insulation and decoration integrated plate technology difference are:
The present invention has adopted the foam micro-crystalline ceramic warming plate and the mode that sun reflective coating combines with fire prevention noise reduction function, has advantages of the multi-functional Composites such as factory's component, construction assemblingization, high temperature of fire fire-retardant fireproof, sound insulation noise abatement, reflection and heat insulation, decoration; The noise abatement layer material of integrated board of the present invention uses foam micro-crystalline ceramic, this material belongs to inorganic mineral heat insulating material, the characteristic such as have lightweight, coefficient of thermal conductivity is low, thermal property good, environmental protection, durability are strong, fire-retardant, has become one of outer heat preservation fireproofing material first-selection of external wall;
Described noise abatement heat-insulating decorative integrated board is processed into by foam micro-crystalline ceramic, foam micro-crystalline ceramic is taking industrial tailings waste residues such as cullet, flyash, gangues as raw material, add blowing agent, nucleator and Admixture etc., mix after crushed formation batch, then batch is put in special grinding tool, put into electric furnace and heat, the novel porous micro-crystalline ceramic materials for wall of making through techniques such as preheating, melting, foaming, crystallization, annealing.Described foam micro-crystalline ceramic proportion: 0.1~0.6, unit weight: 767~1076kg/m 3coefficient of thermal conductivity :≤0.029w/mk, water absorption rate: 5~20Vol%, compressive strength: 9~18MPa, rupture strength: 5.6~19MPa, high-temperature capability: 740~800MPa, degree of fire resistance: >100, fireproof performance reaches country's " A " grade standard, energy acid resistance: 0.08~5.0, alkali resistance: 0.05~0.8, frost resistance: 0.03~0.38, not fluorine-containing chlorination charcoal and hydrogen fluorine chloric acid.
The present invention takes prefabricate way, efficient sunlight reflective coating is sprayed on crystallite foamed ceramics integrated board, prepare a kind of for external wall enclosed structure there is sound insulation noise abatement, fire-proof and water-proof and reflection and heat insulation several functions and with building with the noise abatement heat-insulating decorative integrated board in life-span; Wherein, noise abatement layer is processed into by foam micro-crystalline ceramic, foam micro-crystalline ceramic is taking industrial tailings waste residues such as cullet, flyash, gangues as raw material, add blowing agent, nucleator and Admixture etc., mix after crushed formation batch, then batch is put in special grinding tool, puts into electric furnace and heat, make through techniques such as preheating, melting, foaming, crystallization, annealing.
In the present invention, solar heat reflection paint is divided into three-layer coated system, i.e. priming paint, middle paint and finish paint; Priming paint is taking alkali resistant and increase base layer exterior surface adhesive power as object; Middle paint is sunshine transmitting coating, is main reflecting layer, the energy of visible ray and near-infrared region in reflected sunlight; Finish paint rises self-cleaning, the effect that protection and opposing external substance corrode; Sunshine reflective coating has adhesive power, pliability and the impact resistance of high-quality to foam micro-crystalline ceramic plate, acid and alkali-resistance, salt spray resistance, stain resistant, impermeable, super-weathering resistance and good self-cleaning property, between 10 years, need not safeguard artificially, realize that heat reflection thermal insulation decorative panel is high-effect, low cost, instant effect and non-maintaining feature.
Below in conjunction with accompanying drawing, noise abatement heat-insulating decorative integrated board of the present invention is described further.
Brief description of the drawings
Fig. 1 is the layer structure schematic diagram of noise abatement heat-insulating decorative integrated board of the present invention.
Detailed description of the invention
Embodiment 1
As shown in Figure 1, a kind of noise abatement heat-insulating decorative integrated board, described integrated board comprises noise abatement layer 1 and reflection and heat insulation decorative layer 2, described noise abatement layer 1 is foam micro-crystalline ceramic plate, described reflection and heat insulation decorative layer 2 is solar heat reflection decorative paint, it is divided into three-layer coated system, is made up of priming paint 3, middle paint 4 and finish paint 5.
The thickness of described foam micro-crystalline ceramic plate is 20mm; The thickness of described priming paint 3 is that the thickness of 100 μ m, middle paint 4 is that the thickness of 5mm, finish paint 5 is 300 μ m; The specification of described noise abatement heat-insulating decorative integrated board is for long: 2000mm; Wide: 1220mm.
Described priming paint 3 is made up of the material of following weight portion:
Deionized water: 200 parts;
Solid content is 49% silicon third or pure-acrylic emulsion: 400 parts;
80 parts of coarse whitings;
Wollastonite in powder: 60 parts;
Anionic wetting agent: 2 parts;
Thickener: 6 parts;
Plasticizing agent: 3 parts;
Dispersing agent: 10 parts;
Coalescents: 30 parts;
Defoamer: 8 parts;
Antisepticize and mildew preventive: 4 parts;
Ethylene glycol: 6 parts;
Propane diols: 3 parts;
PH adjusting agent: 10 parts;
Wherein, the pH value of described anionic wetting agent is 5.5, and described thickener is carboxymethyl cellulose, and described plasticizing agent is synthetic vegetable esters fluidizer; Described dispersing agent is cithrol 400, and described coalescents is Lauryl Alcohol ester, and described defoamer is PPG, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described pH adjusting agent is methane-siliconic acid aqueous solutions of potassium.
Described middle paint 4 is prepared from by the raw material of following weight portion:
Solid content is 49% emulsion type synthetic polymer emulsion: 380 parts;
Deionized water: 300 parts;
Sunshine reflecting material: 50 parts;
Color stuffing: 40 parts;
Nano material: 45 parts;
Anionic wetting agent: 7 parts;
Thickener: 4 parts;
Plasticizing agent: 4 parts;
Dispersing agent: 12 parts;
Coalescents: 40 parts;
Defoamer: 4 parts;
Antisepticize and mildew preventive: 5 parts;
Ethylene glycol: 3.5 parts;
Propane diols: 3 parts;
PH adjusting agent: 7 parts;
Wherein, the pH value of described anionic wetting agent is 7.5, described thickener is carboxymethyl cellulose, described plasticizing agent is synthetic vegetable esters fluidizer, described dispersing agent is cithrol 200, and described coalescents is Lauryl Alcohol ester, and described defoamer is PPG, described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described pH adjusting agent is methane-siliconic acid aqueous solutions of potassium.
What described emulsion type synthetic polymer emulsion adopted is organic siliconresin emulsion;
Described sunshine reflecting material is that refractive index is 2.03 zinc oxide;
Described color stuffing is French chalk;
Described nano material is nano-calcium carbonate.
Described finish paint 5 is applied and is formed by anti-fouling and self-cleaning coating, and described anti-fouling and self-cleaning coating is that particle diameter is nano level organosilicon-modified acrylic coating, and thickness is 300 μ m.
Described organosilicon-modified acrylic coating is made up of the material of following weight portion:
Deionized water: 500 parts;
Activity substance content is 42% organosilicon-acrylic resin emulsion: 60 parts;
Coalescents: 32 parts;
Antisepticize and mildew preventive: 10 parts;
Defoamer: 6 parts;
Ethylene glycol: 50 parts;
Plasticizing agent: 0.3 part;
PH adjusting agent: 10 parts;
Wherein, described coalescents is Lauryl Alcohol ester, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, synthetic vegetable esters fluidizer, and described defoamer is PPG, described pH adjusting agent is methane-siliconic acid aqueous solutions of potassium.
Prepare a described noise abatement heat-insulating decorative integrated board method, comprise the steps:
The preparation of step 1, noise abatement layer 1: manufactured foam micro-crystalline ceramic is cut into the sheet material that thickness is 30mm, to described plate surface and corner polishing, deburring and cleaning, guarantee that upper surface is smooth, horizontal error ± 2mm, facade vertical error ± 1mm, the upright error under ±2 mm of external corner, removes the floating ash of plate surface and waits attachment;
The preparation of step 2, reflection and heat insulation decorative layer 2: prepare respectively priming paint 3, middle paint 4 and finish paint 5, first at foam micro-crystalline ceramic warming plate upper surface primer coating 3, then at the water-fast flexible putty of surperficial blade coating, finally use spray gun that middle paint 4 is coated on to putty surface, spray paint 5 again after surface is fully dry;
The preparation of step 3, final products: it is 2000mm that the described plate cutting that passes through application is become to length; Width is the integrated board of 1220mm, obtains product.
The preparation method of described priming paint 3 is: by load weighted wetting agent, dispersing agent, ethylene glycol, propane diols and fungusproof anti-corrosion agent join respectively pure third or Silicone acrylic emulsion in, fully disperse 20min with the rotating speeds of 800 revs/min; Add again coarse whiting and wollastonite in powder, fully disperse 15min with the rotating speeds of 1500 revs/min, in the process stirring, add defoamer and the plasticizing agent of 1/3 weight, fully disperse 15min with the rotating speed of 800 revs/min again, add the deionized water mixing with coalescents, thickener, then add defoamer, the pH adjusting agent of 2/3 weight, be uniformly mixed, be mixed with solar heat reflection paint priming paint 3;
The preparation method of described middle paint 4 is: load weighted wetting agent, dispersing agent, ethylene glycol, propane diols and fungusproof anti-corrosion agent are added respectively in emulsion type synthetic polymer emulsion, fully disperse 30min with the rotating speeds of 800 revs/min; Add again sunshine reflecting material, nano material and color stuffing, fully disperse 10min with the rotating speeds of 1500 revs/min; In the process stirring, add defoamer and the thickener of 1/3 weight, fully disperse 20min with the rotating speed of 800 revs/min again, add the deionized water having mixed with coalescents, plasticizing agent, add again defoamer, the pH adjusting agent of 2/3 remaining weight, be uniformly mixed, be mixed with in heat reflection coatings and paint 4;
The preparation method of described finish paint 5 is: load weighted fungusproof anti-corrosion agent and ethylene glycol, pH adjusting agent are added in organosilicon-acrylic resin emulsion, with the rotating speed premix of 800 revs/min, fully stir about 20min, disperse 15min with the rotating speeds of 1500 revs/min, in the process stirring, add the defoamer of 1/3 weight, fully disperse 15min with the rotating speed of 800 revs/min again, and add the deionized water having mixed with coalescents, plasticizing agent, add again the defoamer of 2/3 weight, be uniformly mixed, be mixed with sunshine reflective coating finish paint 5.
Embodiment 2
As shown in Figure 1, a kind of noise abatement heat-insulating decorative integrated board, described integrated board comprises noise abatement layer 1 and reflection and heat insulation decorative layer 2, described noise abatement layer 1 is foam micro-crystalline ceramic plate, described reflection and heat insulation decorative layer 2 is solar heat reflection decorative paint, it is divided into three-layer coated system, is made up of priming paint 3, middle paint 4 and finish paint 5.
The thickness of described foam micro-crystalline ceramic plate is 500mm; The thickness of described priming paint 3 is that the thickness of 100 μ m, middle paint 4 is that the thickness of 20mm, finish paint 5 is 300 μ m; The specification of described noise abatement heat-insulating decorative integrated board is for long: 3200mm; Wide: 1500mm.
Described priming paint 3 is made up of the material of following weight portion:
Deionized water: 300 parts;
Solid content is 49% silicon third or pure-acrylic emulsion: 320 parts;
140 parts of coarse whitings;
Wollastonite in powder: 40 parts;
Anionic wetting agent: 5 parts;
Thickener: 4 parts;
Plasticizing agent: 5 parts;
Dispersing agent: 7 parts;
Coalescents: 40 parts;
Defoamer: 6 parts;
Antisepticize and mildew preventive: 5 parts;
Ethylene glycol: 3 parts;
Propane diols: 5 parts;
PH adjusting agent: 8 parts;
Wherein, the pH value of described anionic wetting agent is 7.5, and described thickener is carboxymethyl cellulose, and described plasticizing agent is synthetic vegetable esters fluidizer; Described dispersing agent is cithrol 400, and described coalescents is Lauryl Alcohol ester, and described defoamer is PPG, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described pH adjusting agent is methane-siliconic acid aqueous solutions of potassium.
Described middle paint 4 is prepared from by the raw material of following weight portion:
Solid content is 49% emulsion type synthetic polymer emulsion: 450 parts;
Deionized water: 245 parts;
Sunshine reflecting material: 60 parts;
Color stuffing: 34 parts;
Nano material: 50 parts;
Anionic wetting agent: 5 parts;
Thickener: 5 parts;
Plasticizing agent: 2.5 parts;
Dispersing agent: 14 parts;
Coalescents: 25 parts;
Defoamer: 7 parts;
Antisepticize and mildew preventive: 3 parts;
Ethylene glycol: 5 parts;
Propane diols: 2 parts;
PH adjusting agent: 10 parts;
Wherein, the pH value of described anionic wetting agent is 5.5, described thickener is carboxymethyl cellulose, described plasticizing agent is synthetic vegetable esters fluidizer, described dispersing agent is cithrol 400, and described coalescents is Lauryl Alcohol ester, and described defoamer is PPG, described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described pH adjusting agent is methane-siliconic acid aqueous solutions of potassium.
What described emulsion type synthetic polymer emulsion adopted is styrene-acrylic emulsion;
Described sunshine reflecting material is that refractive index is 2.74 titanium oxide;
Described color stuffing is dicalcium powder;
Described nano material is nano titanium oxide.
Described finish paint 5 is applied and is formed by anti-fouling and self-cleaning coating, and described anti-fouling and self-cleaning coating is that particle diameter is nano level organosilicon-modified acrylic coating, and thickness is 500 μ m.
Described organosilicon-modified acrylic coating is made up of the material of following weight portion:
Deionized water: 560 parts;
Activity substance content is 42% organosilicon-acrylic resin emulsion: 30 parts;
Coalescents: 40 parts;
Antisepticize and mildew preventive: 8 parts;
Defoamer: 10 parts;
Ethylene glycol: 40 parts;
Plasticizing agent: 0.5 part;
PH adjusting agent: 8 parts;
Wherein, described coalescents is Lauryl Alcohol ester, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, synthetic vegetable esters fluidizer, and described defoamer is PPG, described pH adjusting agent is methane-siliconic acid aqueous solutions of potassium.
Prepare a described noise abatement heat-insulating decorative integrated board method, comprise the steps:
The preparation of step 1, noise abatement layer 1: manufactured foam micro-crystalline ceramic is cut into the sheet material that thickness is 500mm, to described plate surface and corner polishing, deburring and cleaning, guarantee that upper surface is smooth, horizontal error ± 2mm, facade vertical error ± 1mm, the upright error under ±2 mm of external corner, removes the floating ash of plate surface and waits attachment;
The preparation of step 2, reflection and heat insulation decorative layer 2: prepare respectively priming paint 3, middle paint 4 and finish paint 5, first at foam micro-crystalline ceramic warming plate upper surface primer coating 3, then at the water-fast flexible putty of surperficial blade coating, finally use spray gun that middle paint 4 is coated on to putty surface, spray paint 5 again after surface is fully dry;
The preparation of step 3, final products: it is 3200mm that the described plate cutting that passes through application is become to length; Width is the integrated board of 1500mm, obtains product.
The preparation method of described priming paint 3 is: by load weighted wetting agent, dispersing agent, ethylene glycol, propane diols and fungusproof anti-corrosion agent join respectively pure third or Silicone acrylic emulsion in, fully disperse 30min with the rotating speeds of 800 revs/min; Add again coarse whiting and wollastonite in powder, fully disperse 10min with the rotating speeds of 1500 revs/min, in the process stirring, add defoamer and the plasticizing agent of 1/3 weight, fully disperse 20min with the rotating speed of 800 revs/min again, add the deionized water mixing with coalescents, thickener, then add defoamer, the pH adjusting agent of 2/3 weight, be uniformly mixed, be mixed with solar heat reflection paint priming paint 3;
The preparation method of described middle paint 4 is: load weighted wetting agent, dispersing agent, ethylene glycol, propane diols and fungusproof anti-corrosion agent are added respectively in emulsion type synthetic polymer emulsion, fully disperse 20min with the rotating speeds of 800 revs/min; Add again sunshine reflecting material, nano material and color stuffing, fully disperse 15min with the rotating speeds of 1500 revs/min; In the process stirring, add defoamer and the thickener of 1/3 weight, fully disperse 15min with the rotating speed of 800 revs/min again, add the deionized water having mixed with coalescents, plasticizing agent, add again defoamer, the pH adjusting agent of 2/3 remaining weight, be uniformly mixed, be mixed with in heat reflection coatings and paint 4;
The preparation method of described finish paint 5 is: load weighted fungusproof anti-corrosion agent and ethylene glycol, pH adjusting agent are added in organosilicon-acrylic resin emulsion, with the rotating speed premix of 800 revs/min, fully stir about 30min, disperse 10min with the rotating speeds of 1500 revs/min, in the process stirring, add the defoamer of 1/3 weight, fully disperse 20min with the rotating speed of 800 revs/min again, and add the deionized water having mixed with coalescents, plasticizing agent, add again the defoamer of 2/3 weight, be uniformly mixed, be mixed with sunshine reflective coating finish paint 5.
Embodiment 3
As shown in Figure 1, a kind of noise abatement heat-insulating decorative integrated board, described integrated board comprises noise abatement layer 1 and reflection and heat insulation decorative layer 2, described noise abatement layer 1 is foam micro-crystalline ceramic plate, described reflection and heat insulation decorative layer 2 is solar heat reflection decorative paint, it is divided into three-layer coated system, is made up of priming paint 3, middle paint 4 and finish paint 5.
The thickness of described foam micro-crystalline ceramic plate is 200mm; The thickness of described priming paint 3 is that the thickness of 150 μ m, middle paint 4 is that the thickness of 10mm, finish paint 5 is 400 μ m; The specification of described noise abatement heat-insulating decorative integrated board is for long: 2440mm; Wide: 1250mm.
Described priming paint 3 is made up of the material of following weight portion:
Deionized water: 250 parts;
Solid content is 49% silicon third or pure-acrylic emulsion: 350 parts;
100 parts of coarse whitings;
Wollastonite in powder: 50 parts;
Anionic wetting agent: 4 parts;
Thickener: 5 parts;
Plasticizing agent: 4 parts;
Dispersing agent: 8 parts;
Coalescents: 35 parts;
Defoamer: 7 parts;
Antisepticize and mildew preventive: 4.5 parts;
Ethylene glycol: 4 parts;
Propane diols: 4 parts;
PH adjusting agent: 9 parts;
Wherein, the pH value of described anionic wetting agent is 6.5, and described thickener is carboxymethyl cellulose, and described plasticizing agent is synthetic vegetable esters fluidizer; Described dispersing agent is cithrol 200, and described coalescents is Lauryl Alcohol ester, and described defoamer is PPG, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described pH adjusting agent is methane-siliconic acid aqueous solutions of potassium.
Described middle paint 4 is prepared from by the raw material of following weight portion:
Solid content is 49% emulsion type synthetic polymer emulsion: 400 parts;
Deionized water: 280 parts;
Sunshine reflecting material: 55 parts;
Color stuffing: 36 parts;
Nano material: 47 parts;
Anionic wetting agent: 6 parts;
Thickener: 4.5 parts;
Plasticizing agent: 3 parts;
Dispersing agent: 13 parts;
Coalescents: 35 parts;
Defoamer: 6 parts;
Antisepticize and mildew preventive: 4 parts;
Ethylene glycol: 4 parts;
Propane diols: 2.5 parts;
PH adjusting agent: 8 parts;
Wherein, the pH value of described anionic wetting agent is 7, described thickener is carboxymethyl cellulose, described plasticizing agent is synthetic vegetable esters fluidizer, described dispersing agent is cithrol 400, and described coalescents is Lauryl Alcohol ester, and described defoamer is PPG, described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described pH adjusting agent is methane-siliconic acid aqueous solutions of potassium.
What described emulsion type synthetic polymer emulsion adopted is acrylate copolymer emulsion;
Described sunshine reflecting material is that refractive index is the mixture that 2.3 pearl mica and aluminium powder mix taking weight ratio as 2:1;
Described color stuffing is the mixture that glass microballoon, titanium dioxide and iron oxide red are mixed taking weight ratio as 3:4:1;
Described nano material is the mixture that nano zine oxide, nanometer scale ceramics bubble, nano silicon, nano far infrared ceramic powder mix taking weight ratio as 6:3:5:1.
Described finish paint 5 is applied and is formed by anti-fouling and self-cleaning coating, and described anti-fouling and self-cleaning coating is that particle diameter is nano level organosilicon-modified acrylic coating, and thickness is 400 μ m.
Described organosilicon-modified acrylic coating is made up of the material of following weight portion:
Deionized water: 540 parts;
Activity substance content is 42% organosilicon-acrylic resin emulsion: 40 parts;
Coalescents: 35 parts;
Antisepticize and mildew preventive: 9 parts;
Defoamer: 8 parts;
Ethylene glycol: 45 parts;
Plasticizing agent: 0.4 part;
PH adjusting agent: 9 parts;
Wherein, described coalescents is Lauryl Alcohol ester, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, synthetic vegetable esters fluidizer, and described defoamer is PPG, described pH adjusting agent is methane-siliconic acid aqueous solutions of potassium.
Prepare a described noise abatement heat-insulating decorative integrated board method, comprise the steps:
The preparation of step 1, noise abatement layer 1: manufactured foam micro-crystalline ceramic is cut into the sheet material that thickness is 200mm, to described plate surface and corner polishing, deburring and cleaning, guarantee that upper surface is smooth, horizontal error ± 2mm, facade vertical error ± 1mm, the upright error under ±2 mm of external corner, removes the floating ash of plate surface and waits attachment;
The preparation of step 2, reflection and heat insulation decorative layer 2: prepare respectively priming paint 3, middle paint 4 and finish paint 5, first at foam micro-crystalline ceramic warming plate upper surface primer coating 3, then at the water-fast flexible putty of surperficial blade coating, finally use spray gun that middle paint 4 is coated on to putty surface, spray paint 5 again after surface is fully dry;
The preparation of step 3, final products: it is 2440mm that the described plate cutting that passes through application is become to length; Width is the integrated board of 1250mm, obtains product.
The preparation method of described priming paint 3 is: by load weighted wetting agent, dispersing agent, ethylene glycol, propane diols and fungusproof anti-corrosion agent join respectively pure third or Silicone acrylic emulsion in, fully disperse 25min with the rotating speeds of 800 revs/min; Add again coarse whiting and wollastonite in powder, fully disperse 12min with the rotating speeds of 1500 revs/min, in the process stirring, add defoamer and the plasticizing agent of 1/3 weight, fully disperse 16min with the rotating speed of 800 revs/min again, add the deionized water mixing with coalescents, thickener, then add defoamer, the pH adjusting agent of 2/3 weight, be uniformly mixed, be mixed with solar heat reflection paint priming paint 3;
The preparation method of described middle paint 4 is: load weighted wetting agent, dispersing agent, ethylene glycol, propane diols and fungusproof anti-corrosion agent are added respectively in emulsion type synthetic polymer emulsion, fully disperse 22min with the rotating speeds of 800 revs/min; Add again sunshine reflecting material, nano material and color stuffing, fully disperse 12min with the rotating speeds of 1500 revs/min; In the process stirring, add defoamer and the thickener of 1/3 weight, fully disperse 18min with the rotating speed of 800 revs/min again, add the deionized water having mixed with coalescents, plasticizing agent, add again defoamer, the pH adjusting agent of 2/3 remaining weight, be uniformly mixed, be mixed with in heat reflection coatings and paint 4;
The preparation method of described finish paint 5 is: load weighted fungusproof anti-corrosion agent and ethylene glycol, pH adjusting agent are added in organosilicon-acrylic resin emulsion, with the rotating speed premix of 800 revs/min, fully stir about 28min, disperse 11min with the rotating speeds of 1500 revs/min, in the process stirring, add the defoamer of 1/3 weight, fully disperse 19min with the rotating speed of 800 revs/min again, and add the deionized water having mixed with coalescents, plasticizing agent, add again the defoamer of 2/3 weight, be uniformly mixed, be mixed with sunshine reflective coating finish paint 5.
Embodiment 4
Be with the difference of embodiment 1: the specification of described noise abatement heat-insulating decorative integrated board is the long 3000mm of being; Described priming paint 3 is Silicone acrylic emulsion.
What described emulsion type synthetic polymer emulsion adopted is organosilicon-acrylic emulsion; Described sunshine reflecting material is that refractive index is 2.3 pearl mica; Described color stuffing is the mixture that iron oxide yellow, pearl mica, lithopone mix with any proportioning; Described nano material is nano far infrared ceramic powder.
Embodiment 5
Be with the difference of embodiment 1:
Described priming paint 3 is acrylic emulsion, and what described emulsion type synthetic polymer emulsion adopted is aqueous epoxy resin emulsion; Described sunshine reflecting material is aluminium powder; Described color stuffing is iron oxide yellow; Described nano material is nanometer scale ceramics bubble.
Embodiment 6
Be with the difference of embodiment 1:
What described emulsion type synthetic polymer emulsion adopted is aqueous polyurethane emulsion; Described sunshine reflecting material is that refractive index is 2.03 zinc oxide, the titanium oxide that refractive index is 2.74, the pearl mica that refractive index is 2.3, the mixture that aluminium powder mixes taking weight ratio as 8:3:5:1; Described color stuffing is the mixture that French chalk, iron oxide red, iron oxide zinc mix taking weight ratio as 6:5:2;
Described nano material is nano zine oxide.
Product of the present invention combines with external wall with bonding mode.
Above-described embodiment is described the preferred embodiment of the present invention; not scope of the present invention is limited; design under the prerequisite of spirit not departing from the present invention; various distortion and improvement that those of ordinary skill in the art make technical scheme of the present invention, all should fall in the definite protection domain of the claims in the present invention book.

Claims (10)

1. a noise abatement heat-insulating decorative integrated board, it is characterized in that: described integrated board comprises noise abatement layer (1) and reflection and heat insulation decorative layer (2), described noise abatement layer (1) is foam micro-crystalline ceramic plate, described reflection and heat insulation decorative layer (2) is solar heat reflection decorative paint, it is divided into three-layer coated system, is made up of priming paint (3), middle paint (4) and finish paint (5).
2. noise abatement heat-insulating decorative integrated board according to claim 1, is characterized in that: the thickness of described foam micro-crystalline ceramic plate is 20~500mm; The thickness of described priming paint (3) is that the thickness of 100~200 μ m, middle paint (4) is that the thickness of 5~20mm, finish paint (5) is 300~500 μ m; The specification of described noise abatement heat-insulating decorative integrated board is for long: 2000mm, 2440mm, 3000mm or 3200mm; Wide: 1220mm, 1250mm or 1500mm.
3. noise abatement heat-insulating decorative integrated board according to claim 2, is characterized in that: described priming paint (3) is silicon third or acrylic emulsion.
4. noise abatement heat-insulating decorative integrated board according to claim 2, is characterized in that: described priming paint (3) is made up of the material of following weight portion:
Deionized water: 200~300 parts;
Solid content is 49% silicon third or pure-acrylic emulsion: 320~400 parts;
80~140 parts of coarse whitings;
Wollastonite in powder: 40~60 parts;
Anionic wetting agent: 2~5 parts;
Thickener: 4~6 parts;
Plasticizing agent: 3~5 parts;
Dispersing agent: 7~10 parts;
Coalescents: 30~40 parts;
Defoamer: 6~8 parts;
Antisepticize and mildew preventive: 4~5 parts;
Ethylene glycol: 3~6 parts;
Propane diols: 3~5 parts;
PH adjusting agent: 8~10 parts;
Wherein, the pH value of described anionic wetting agent is 5.5~7.5, and described thickener is carboxymethyl cellulose, and described plasticizing agent is synthetic vegetable esters fluidizer; Described dispersing agent is cithrol 200 or 400, and described coalescents is Lauryl Alcohol ester, and described defoamer is PPG, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described pH adjusting agent is methane-siliconic acid aqueous solutions of potassium.
5. according to the noise abatement heat-insulating decorative integrated board described in claim 3 or 4, it is characterized in that: described middle paint (4) is prepared from by the raw material of following weight portion:
Solid content is 49% emulsion type synthetic polymer emulsion: 380~450 parts;
Deionized water: 245~300 parts;
Sunshine reflecting material: 50~60 parts;
Color stuffing: 34~40 parts;
Nano material: 45~50 parts;
Anionic wetting agent: 5~7 parts;
Thickener: 4~5 parts;
Plasticizing agent: 2.5~4 parts;
Dispersing agent: 12~14 parts;
Coalescents: 25~40 parts;
Defoamer: 4~7 parts;
Antisepticize and mildew preventive: 3~5 parts;
Ethylene glycol: 3.5~5 parts;
Propane diols: 2~3 parts;
PH adjusting agent: 7~10 parts;
Wherein, the pH value of described anionic wetting agent is 5.5~7.5, described thickener is carboxymethyl cellulose, described plasticizing agent is synthetic vegetable esters fluidizer, described dispersing agent is cithrol 200 or 400, and described coalescents is Lauryl Alcohol ester, and described defoamer is PPG, described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described pH adjusting agent is methane-siliconic acid aqueous solutions of potassium.
6. noise abatement heat-insulating decorative integrated board according to claim 5, is characterized in that:
What described emulsion type synthetic polymer emulsion adopted is the one in organic siliconresin emulsion, styrene-acrylic emulsion, acrylate copolymer emulsion, organosilicon-acrylic emulsion, aqueous epoxy resin emulsion, aqueous polyurethane emulsion;
The mixture of one or more in pearl mica, aluminium powder that described sunshine reflecting material is refractive index is 2.03 zinc oxide, refractive index is 2.74 titanium oxide, refractive index is 2.3;
Described color stuffing is one or more the mixture in French chalk, dicalcium powder, glass microballoon, titanium dioxide, iron oxide red, iron oxide zinc, iron oxide yellow, pearl mica, lithopone;
Described nano material is one or more the mixture in nano-calcium carbonate, nano titanium oxide, nano zine oxide, nanometer scale ceramics bubble, nano silicon, nano far infrared ceramic powder.
7. noise abatement heat-insulating decorative integrated board according to claim 6, it is characterized in that: described finish paint (5) is applied and formed by anti-fouling and self-cleaning coating, described anti-fouling and self-cleaning coating is that particle diameter is nano level organosilicon-modified acrylic coating, and thickness is 300~500 μ m.
8. noise abatement heat-insulating decorative integrated board according to claim 7, is characterized in that: described organosilicon-modified acrylic coating is made up of the material of following weight portion:
Deionized water: 500~560 parts;
Activity substance content is 42% organosilicon-acrylic resin emulsion: 30~60 parts;
Coalescents: 32~40 parts;
Antisepticize and mildew preventive: 8~10 parts;
Defoamer: 6~10 parts;
Ethylene glycol: 40~50 parts;
Plasticizing agent: 0.3~0.5 part;
PH adjusting agent: 8~10 parts;
Wherein, described coalescents is Lauryl Alcohol ester, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, synthetic vegetable esters fluidizer, and described defoamer is PPG, described pH adjusting agent is methane-siliconic acid aqueous solutions of potassium.
9. a method of preparing noise abatement heat-insulating decorative integrated board described in above-mentioned any claim, is characterized in that: comprise the steps:
The preparation of step 1, noise abatement layer (1): manufactured foam micro-crystalline ceramic is cut into the sheet material that thickness is 30~500mm, to described plate surface and corner polishing, deburring and cleaning, guarantee that upper surface is smooth, horizontal error ± 2mm, facade vertical error ± 1mm, the upright error under ±2 mm of external corner, removes the floating ash of plate surface and waits attachment;
The preparation of step 2, reflection and heat insulation decorative layer (2): prepare respectively priming paint (3), middle paint (4) and finish paint (5), first at foam micro-crystalline ceramic warming plate upper surface primer coating (3), then at the water-fast flexible putty of surperficial blade coating, finally use spray gun that middle paint (4) is coated on to putty surface, spray paint (5) again after surface is fully dry;
The preparation of step 3, final products: it is 2000mm, 2440mm, 3000mm or 3200mm that the described plate cutting that passes through application is become to length; Width is the integrated board of 1220mm, 1250mm or 1500mm, obtains product.
10. the preparation method of noise abatement heat-insulating decorative integrated board according to claim 9, is characterized in that:
The preparation method of described priming paint (3) is: by load weighted wetting agent, dispersing agent, ethylene glycol, propane diols and fungusproof anti-corrosion agent join respectively pure third or Silicone acrylic emulsion in, fully disperse 20~30min with the rotating speeds of 800 revs/min; Add again coarse whiting and wollastonite in powder, fully disperse 10~15min with the rotating speeds of 1500 revs/min, in the process stirring, add defoamer and the plasticizing agent of 1/3 weight, fully disperse 15~20min with the rotating speed of 800 revs/min again, add the deionized water mixing with coalescents, thickener, then add defoamer, the pH adjusting agent of 2/3 weight, be uniformly mixed, be mixed with solar heat reflection paint priming paint (3);
The preparation method of described middle paint (4) is: load weighted wetting agent, dispersing agent, ethylene glycol, propane diols and fungusproof anti-corrosion agent are added respectively in emulsion type synthetic polymer emulsion, fully disperse 20~30min with the rotating speeds of 800 revs/min; Add again sunshine reflecting material, nano material and color stuffing, fully disperse 10~15min with the rotating speeds of 1500 revs/min; In the process stirring, add defoamer and the thickener of 1/3 weight, fully disperse 15~20min with the rotating speed of 800 revs/min again, add the deionized water having mixed with coalescents, plasticizing agent, add again defoamer, the pH adjusting agent of 2/3 remaining weight, be uniformly mixed, be mixed with paint (4) in heat reflection coatings;
The preparation method of described finish paint (5) is: by load weighted fungusproof anti-corrosion agent and ethylene glycol, pH adjusting agent adds in organosilicon-acrylic resin emulsion, with the rotating speed premix of 800 revs/min, fully stir about 20~30min, disperse 10~15min with the rotating speeds of 1500 revs/min, in the process stirring, add the defoamer of 1/3 weight, fully disperse 15~20min with the rotating speed of 800 revs/min again, and add and coalescents, the deionized water that plasticizing agent mixes, add again the defoamer of 2/3 weight, be uniformly mixed, be mixed with sunshine reflective coating finish paint (5).
CN201410108530.8A 2014-03-22 2014-03-22 A kind of noise abatement heat-insulating decorative integrated board and preparation method thereof Expired - Fee Related CN103938818B (en)

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CN114163900A (en) * 2022-02-11 2022-03-11 蓝彬尚科(天津)新材料科技有限公司 Manufacturing process of heat-radiation-reflecting heat-insulating coating for communication power
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CN105442782A (en) * 2015-08-26 2016-03-30 马玉新 Integrated plate
CN105239746A (en) * 2015-10-28 2016-01-13 江苏卧牛山保温防水技术有限公司 Reflective insulation and phase-change thermal-insulation integrated board and preparation method thereof
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CN106634350B (en) * 2016-12-23 2019-01-15 煤科集团杭州环保研究院有限公司 Aqueous low viscosity background color showering paint and its full aqueous insulation decoration integrated board facing production technology
CN106634350A (en) * 2016-12-23 2017-05-10 浙江德尔福新型建材有限公司 Aqueous low-viscosity base color curtain coating paint and production process of facings of fully-aqueous heat insulation and decoration integrated boards thereof
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CN109423184A (en) * 2017-07-18 2019-03-05 北京泽马新技术有限公司 A kind of self-cleaning composite coating of the transparent heat-insulated hydrophobic oleophobic of outdoor fabric and preparation process
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CN109988475A (en) * 2019-04-04 2019-07-09 李萌 A kind of skin texture wall film and preparation method thereof
CN114274597A (en) * 2021-02-18 2022-04-05 湖北平安电工科技股份公司 Mica special-shaped piece for lithium battery assembly and processing method
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