CN103938491A - Water and oil resistant oil filter paper added with nano-titanium dioxide and preparation method thereof - Google Patents

Water and oil resistant oil filter paper added with nano-titanium dioxide and preparation method thereof Download PDF

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Publication number
CN103938491A
CN103938491A CN201410099682.6A CN201410099682A CN103938491A CN 103938491 A CN103938491 A CN 103938491A CN 201410099682 A CN201410099682 A CN 201410099682A CN 103938491 A CN103938491 A CN 103938491A
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oil
filter paper
water
powder
oil filter
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CN201410099682.6A
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CN103938491B (en
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薛卉慧
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Hebei Amusen Filter Paper Co ltd
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Bengbu Feng Chi Cleaner Co Ltd
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Abstract

The invention discloses a water and oil resistant oil filter paper added with nano-titanium dioxide. The oil filter paper is characterized by being prepared from the following raw materials by weight part: 36-41 of poplar bark pulp, 60-63 of waste hemp rope pulp, 2-3 of nano-titanium dioxide, 2-3 of heavy calcium carbonate, 2-4 of zeolite, 1-2 of magnet powder, 1-2 of chopped glass fiber, 0.5-1 of a silane coupling agent WD-10, 0.3-0.5 of sesbania gum, 0.4-0.5 of guar gum, 5-7 of polyamide epichlorohydrin resin, 2-4 of carboxymethyl cellulose, 0.3-0.5 of octanol, 0.2-0.4 of castor oil, and 1-2 of an assistant. According to the invention, the added nano-titanium dioxide and the like can enhance the adsorption effect, the magnet powder can adsorb metal impurities blended into engine oil during engine combustion; by adding the assistant, the oil filter paper is safe and environment-friendly, and has good water resistance and oil resistance; and through organic combination of a ceramic material and a filter paper, the water and oil resistant oil filter paper is solid and durable, and has good filtration adsorption effect.

Description

A kind of Waterproofing/oilproofing oil filter filter paper that adds nano titanium oxide and preparation method thereof
Technical field
The present invention relates to automobile filter field, particularly a kind of Waterproofing/oilproofing oil filter filter paper that adds nano titanium oxide and preparation method thereof.
Background technology
Oil filter is the one of cleaner, can remove the impurity such as dust, metallic particles, carbon precipitates and coal soot in machine oil, protection engine.Oil filter paper is the crucial building block in oil filter, determining the performance of oil strainer, oil filter paper he generally include with common wood pulp be a kind of papery filter course that main component is made, because normal wood pulp fibres is thin, hold the shortcomings such as ash amount is low, the life-span is short, and oil filter paper made of paper also ubiquity resistance to water and oil resistivity is poor, the characteristics such as not environmental protection of non-refractory, soak easily distortion when fuel oil is long-time, and then affect filter effect.
Summary of the invention
The object of this invention is to provide a kind of Waterproofing/oilproofing oil filter filter paper that adds nano titanium oxide and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
Add a Waterproofing/oilproofing oil filter filter paper for nano titanium oxide, made by the raw material of following weight portion: willow latex 36-41, the useless rope made of hemp slurry 60-63, nano titanium oxide 2-3, powdered whiting 2-3, zeolite 2-4, magnet powder 1-2, short glass fiber 1-2, silane coupler WD-10 0.5-1, sesbania gum 0.3-0.5, guar gum 0.4-0.5, polyamine epichlorohydrin resin 5-7, carboxymethyl cellulose 2-4, octanol 0.3-0.5, castor oil 0.2-0.4, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight portion: kaolin 7-9, clay 5-8, zirconium English powder 4-6, barium monoxide 2-3, aluminium hydroxide 2-3, nylon 12 14-16, triethyl citrate 2-3, acetic acid 1-2; First preparation method puts into ball mill by kaolin, clay, zirconium English powder, barium monoxide, aluminium hydroxide, wears into 100-140 object powder, mixes; Then nylon 12 is heated to soften, adds all the other residual componentss to stir after 15-25 minute and add mixed-powder, send into double screw extruder granulation, obtain particulate material; Finally particulate material is put into flour mill and pulverize, to obtain final product.
A kind of Waterproofing/oilproofing oil filter filter paper that adds nano titanium oxide of the present invention, made by following concrete steps:
(1) nano titanium oxide, powdered whiting, zeolite, magnet powder, short glass fiber are mixed, grind to form 50-100 object powder, add silane coupler WD-10, with the speed of 850-950 rev/min, stir 25-30 minute, then 110-120 DEG C dry 1.5-2.5 hour stand-by;
(2) willow latex, useless rope made of hemp slurry are put into hydrabrusher size degradation, then through beater, beating consistency is controlled at 5.8-6.5%, makes slurry;
(3) compound of step (1) is added in slurry, add octanol, castor oil, be heated to 65-75 DEG C, stir, add appropriate water size mixing to solid content be 2.5-3.5%, the slurry mixing up, after forming web moulding, aspirates dehydration to the l Water Paper after moulding under the vacuum condition of 0.05-0.08Mpa;
(4) all the other residual componentss are mixed, dilute with water, then heating, temperature is controlled at 60-70 DEG C, boils 50-60 minute, and insulation 25-30 minute, is warming up to 70-75 DEG C, stirs and makes dipping emulsion; (5) make the even dipping emulsion of paper after step (3) dehydration with spreader, then will in paper electric drying oven with forced convection flood, dry 4-5min, finally on polisher, be dried 6-9min, after taking-up and get final product.
The invention has the beneficial effects as follows: the present invention adds nano titanium oxide, powdered whiting etc. and increases adsorption effect, when magnet powder can adsorb engine combustion, sneak into the metal impurities of machine oil; Add auxiliary agent, safety and environmental protection, has good resistance to water and oil resistivity; By the combination of ceramic material and filter paper, durable, filter effective, advantages of good adsorption effect.
Specific embodiments
Below by instantiation, the present invention is described in detail.
Add a Waterproofing/oilproofing oil filter filter paper for nano titanium oxide, by following weight portion (kilogram) raw material make: willow latex 36, useless rope made of hemp slurry 60, nano titanium oxide 2, powdered whiting 2, zeolite 2, magnet powder 1, short glass fiber 1, silane coupler WD-10 0.5, sesbania gum 0.3, guar gum 0.4, polyamine epichlorohydrin resin 5, carboxymethyl cellulose 2, octanol 0.3, castor oil 0.2, auxiliary agent 1;
Described auxiliary agent by following weight portion (kilogram) raw material make: kaolin 7, clay 5, zirconium English powder 4, barium monoxide 2, aluminium hydroxide 2, nylon 12 14, triethyl citrate 2, acetic acid 1; First preparation method puts into ball mill by kaolin, clay, zirconium English powder, barium monoxide, aluminium hydroxide, wears into 100-140 object powder, mixes; Then nylon 12 is heated to soften, adds all the other residual componentss to stir after 15-25 minute and add mixed-powder, send into double screw extruder granulation, obtain particulate material; Finally particulate material is put into flour mill and pulverize, to obtain final product.
A kind of Waterproofing/oilproofing oil filter filter paper that adds nano titanium oxide of the present invention, made by following concrete steps:
(1) nano titanium oxide, powdered whiting, zeolite, magnet powder, short glass fiber are mixed, grind to form 50-100 object powder, add silane coupler WD-10, with the speed of 850-950 rev/min, stir 25-30 minute, then 110-120 DEG C dry 1.5-2.5 hour stand-by;
(2) willow latex, useless rope made of hemp slurry are put into hydrabrusher size degradation, then through beater, beating consistency is controlled at 5.8-6.5%, makes slurry;
(3) compound of step (1) is added in slurry, add octanol, castor oil, be heated to 65-75 DEG C, stir, add appropriate water size mixing to solid content be 2.5-3.5%, the slurry mixing up, after forming web moulding, aspirates dehydration to the l Water Paper after moulding under the vacuum condition of 0.05-0.08Mpa;
(4) all the other residual componentss are mixed, dilute with water, then heating, temperature is controlled at 60-70 DEG C, boils 50-60 minute, and insulation 25-30 minute, is warming up to 70-75 DEG C, stirs and makes dipping emulsion; (5) make the even dipping emulsion of paper after step (3) dehydration with spreader, repeated multiple times, use up to dipping emulsion, then will in paper electric drying oven with forced convection flood, dry 4-5min, finally on polisher, be dried 6-9min, after taking-up and get final product.
After testing, bursting strength 350 KPa of the filter paper that the present invention makes, Air permenbility 85-89 L/m 2between s, maximum diameter of hole is 75 μ m, and average pore size is 55 μ m, filter efficiency 92.0%.

Claims (2)

1. one kind is added the Waterproofing/oilproofing oil filter filter paper of nano titanium oxide, it is characterized in that, made by the raw material of following weight portion: willow latex 36-41, the useless rope made of hemp slurry 60-63, nano titanium oxide 2-3, powdered whiting 2-3, zeolite 2-4, magnet powder 1-2, short glass fiber 1-2, silane coupler WD-10 0.5-1, sesbania gum 0.3-0.5, guar gum 0.4-0.5, polyamine epichlorohydrin resin 5-7, carboxymethyl cellulose 2-4, octanol 0.3-0.5, castor oil 0.2-0.4, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight portion: kaolin 7-9, clay 5-8, zirconium English powder 4-6, barium monoxide 2-3, aluminium hydroxide 2-3, nylon 12 14-16, triethyl citrate 2-3, acetic acid 1-2; First preparation method puts into ball mill by kaolin, clay, zirconium English powder, barium monoxide, aluminium hydroxide, wears into 100-140 object powder, mixes; Then nylon 12 is heated to soften, adds all the other residual componentss to stir after 15-25 minute and add mixed-powder, send into double screw extruder granulation, obtain particulate material; Finally particulate material is put into flour mill and pulverize, to obtain final product.
2. a kind of Waterproofing/oilproofing oil filter filter paper that adds nano titanium oxide according to claim 1, is characterized in that, is made up of following concrete steps:
(1) nano titanium oxide, powdered whiting, zeolite, magnet powder, short glass fiber are mixed, grind to form 50-100 object powder, add silane coupler WD-10, with the speed of 850-950 rev/min, stir 25-30 minute, then 110-120 DEG C dry 1.5-2.5 hour stand-by;
(2) willow latex, useless rope made of hemp slurry are put into hydrabrusher size degradation, then through beater, beating consistency is controlled at 5.8-6.5%, makes slurry;
(3) compound of step (1) is added in slurry, add octanol, castor oil, be heated to 65-75 DEG C, stir, add appropriate water size mixing to solid content be 2.5-3.5%, the slurry mixing up, after forming web moulding, aspirates dehydration to the l Water Paper after moulding under the vacuum condition of 0.05-0.08Mpa;
(4) all the other residual componentss are mixed, dilute with water, then heating, temperature is controlled at 60-70 DEG C, boils 50-60 minute, and insulation 25-30 minute, is warming up to 70-75 DEG C, stirs and makes dipping emulsion; (5) make the even dipping emulsion of paper after step (3) dehydration with spreader, then will in paper electric drying oven with forced convection flood, dry 4-5min, finally on polisher, be dried 6-9min, after taking-up and get final product.
CN201410099682.6A 2014-03-18 2014-03-18 A kind of Waterproofing/oilproofing oil filter filter paper adding nano titanium oxide and preparation method thereof Active CN103938491B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106245417A (en) * 2016-08-05 2016-12-21 蚌埠威尔特滤清器有限公司 A kind of high-stiffness filter paper for gasoline filter
CN106283832A (en) * 2016-08-05 2017-01-04 蚌埠威尔特滤清器有限公司 A kind of high intensity filter paper for gasoline filter
CN108103849A (en) * 2017-12-18 2018-06-01 安徽新立滤清器有限公司 A kind of high-strength water-resistance oil filter filter paper

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB911995A (en) * 1959-06-09 1962-12-05 Shell Int Research Paper substitutes
JP2007007586A (en) * 2005-06-30 2007-01-18 Nippon Muki Co Ltd Filter medium for air filter, and air filter
CN102872651A (en) * 2012-09-25 2013-01-16 蚌埠凤凰滤清器有限责任公司 High-filtering precision filter paper of filter for hemp pulp
CN102912680A (en) * 2012-09-20 2013-02-06 蚌埠凤凰滤清器有限责任公司 High-temperature resistant fiber filter paper for engine oil filter and preparation method of high-temperature resistant fiber filter paper
CN102912682A (en) * 2012-09-20 2013-02-06 蚌埠凤凰滤清器有限责任公司 Filter paper doped with viscose-based activated carbon fiber for automobile filter and preparation method of filter paper

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB911995A (en) * 1959-06-09 1962-12-05 Shell Int Research Paper substitutes
JP2007007586A (en) * 2005-06-30 2007-01-18 Nippon Muki Co Ltd Filter medium for air filter, and air filter
CN102912680A (en) * 2012-09-20 2013-02-06 蚌埠凤凰滤清器有限责任公司 High-temperature resistant fiber filter paper for engine oil filter and preparation method of high-temperature resistant fiber filter paper
CN102912682A (en) * 2012-09-20 2013-02-06 蚌埠凤凰滤清器有限责任公司 Filter paper doped with viscose-based activated carbon fiber for automobile filter and preparation method of filter paper
CN102872651A (en) * 2012-09-25 2013-01-16 蚌埠凤凰滤清器有限责任公司 High-filtering precision filter paper of filter for hemp pulp

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106245417A (en) * 2016-08-05 2016-12-21 蚌埠威尔特滤清器有限公司 A kind of high-stiffness filter paper for gasoline filter
CN106283832A (en) * 2016-08-05 2017-01-04 蚌埠威尔特滤清器有限公司 A kind of high intensity filter paper for gasoline filter
CN108103849A (en) * 2017-12-18 2018-06-01 安徽新立滤清器有限公司 A kind of high-strength water-resistance oil filter filter paper

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Effective date of registration: 20181015

Address after: 230088 Room 303, innovation building, Anhui University science and Technology Park, 2 Tianda Road, Hefei high tech Zone, Anhui

Patentee after: Hefei gather HowNet Information Technology Co., Ltd.

Address before: 233000 Tao Shan Road West, Yanshan Township, Yanshan suburb, Anhui

Patentee before: Bengbu Feng Chi cleaner Co., Ltd

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Effective date of registration: 20181129

Address after: 313000 room 1020, science and Technology Pioneer Park, 666 Chaoyang Road, Nanxun Town, Nanxun District, Huzhou, Zhejiang.

Patentee after: Huzhou You Yan Intellectual Property Service Co., Ltd.

Address before: 230088 Room 303, innovation building, Anhui University science and Technology Park, 2 Tianda Road, Hefei high tech Zone, Anhui

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Effective date of registration: 20190424

Address after: 065000 Wanzhuang Town, Guangyang District, Langfang City, Hebei Province

Patentee after: Langfang City Branch crown filter Co., Ltd.

Address before: 313000 room 1020, science and Technology Pioneer Park, 666 Chaoyang Road, Nanxun Town, Nanxun District, Huzhou, Zhejiang.

Patentee before: Huzhou You Yan Intellectual Property Service Co., Ltd.

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Effective date of registration: 20220608

Address after: 052300 south of 400m eastbound road at the intersection of Anxin line and Weibo Gongye Road, Xinji City, Shijiazhuang City, Hebei Province

Patentee after: HEBEI AMUSEN FILTER PAPER Co.,Ltd.

Address before: 065000 Wanzhuang Town, Guangyang District, Langfang City, Hebei Province

Patentee before: Langfang City Branch crown filter Co.,Ltd.

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