GB911995A - Paper substitutes - Google Patents

Paper substitutes

Info

Publication number
GB911995A
GB911995A GB1993060A GB1993060A GB911995A GB 911995 A GB911995 A GB 911995A GB 1993060 A GB1993060 A GB 1993060A GB 1993060 A GB1993060 A GB 1993060A GB 911995 A GB911995 A GB 911995A
Authority
GB
United Kingdom
Prior art keywords
foamed
fibres
paper
sheet
coated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1993060A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB911995A publication Critical patent/GB911995A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/36After-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)
  • Laminated Bodies (AREA)

Abstract

A paper substitute, which may be coated, comprises a thin compressed sheet of foamed, substantially closed cellular plastic material. Before, during or after compression the sheet may be (1) treated with a filler, e.g. clay, titanium dioxide, talc, lignocellulosic materials, calcium sulphate and mixtures of calcium sulphate and alumina; (2) coated with a casein solution of clay, satin white, titanium dioxide or pigment followed by treatment with alkali to render the casein insoluble; or (3) treated with wax. After compression the paper substitutes may be (1) heat glazed; (2) bleached; (3) impregnated with resins, asphalts, tars and pitches and (4) surface conditioned as by staining and application of sizing, e.g. glue, gelatin, rosin, starch or dextrin. In the examples, the paper substitutes are (12) coated with a mixture of straight run asphalt, a diglycidyl ether of 2,2-bis-(4-hydroxyphenyl) propane and diethylene triamine as curing agent (13) coated with paraffin wax, coal tar, coal tar pitch, alkyd resin or pine tar coating and (15) coated with a mixture of a diglycidyl ether of 2,2-bis-(4-hydroxyphenyl) propane and m-phenylene diamine to give sheets which are subsequently laminated.ALSO:A paper substitute comprises a thin compressed sheet of foamed, substantially closed cellular plastic material, the material before compression having a Young's modulous at room temperature of at least 105 degrees per cm.2 and the compression being such as to effect a permanent change in the material, the pores in the compressed sheet having an average thickness which is less than the thickness of the sheet. Numerous plastic materials are specified of the following main types:-polyolefins and other polymers of ethylenically unsaturated monomers (including homopolymers, copolymers, graft copolymers and block copolymers), alkyd resins, polyurethanes, epoxy materials, polycarbonates, phenolic resins, urea-formaldehyde resins and cellulose derivatives. Before, during or after pressing the sheet may be (1) treated with a filler, e.g. clay, titanium dioxide, talc, ligno-cellulosic materials, calcium sulphate and mixtures of calcium sulphate and alumina; (2) coated with a casein solution of clay, satin white or titanium dioxide followed by treatment with alkali to render the casein insoluble; and (3) treated with wax, or heat glazed (after pressing). Fibres such as seed hairs, e.g. cotton; stem fibres, e.g. linen, jute or manilla; leaf fibres, e.g. straw, pineapple or esparto; fruit fibres; wood fibres; nylon or glass fibres may be incorporated into the foamed materials during or after preparation. The paper substitutes may be impregnated with resins, asphalts, tars and pitches or may be bleached, e.g. with hydrogen peroxide, or surface conditioned such as by staining and application of sizing, e.g. glue, gelatin, rosin, starch or dextrin. In the examples, paper substitutes are prepared from (1) expanded cellulose acetate (2) rigid polyurethane foam prepared from hexamethylene diisocyanate and a long chain polyol or from toluene diisocyanate and a long chain polyester of adipic acid and ethylene glycol (3) foamed polystyrene (9) a foamed glycidyl polyether of 2,2-bis(4-hydroxy-phenyl)propane (10) a foamed polycarbonate obtained by reacting phosgene and 2,2-bis-(4-hydroxy-phenyl)propane (11) a foamed polyvinyl chloride, foamed polyethylene, a foamed alkyd obtained by reacting glycerol with phthalic anhydride and t-butyl benzoic acid, and a foamed urea-formaldehyde resin. In Example 12 paper substitutes prepared in the earlier examples are coated with a mixture of a straight run asphalt, a diglycidyl ether of 2,2-bis-(4-hydroxy-phenyl)propane and diethylene triamine as curing agent.ALSO:A paper substitute which may be a filter paper comprises a thin compressed sheet of foamed, substantially closed-cellular plastic material, the material before compression having a Young's modulus at room temperature of at least 105 dynes per cm2 and the compression being such as to effect a permanent change in the material, the pores in the compressed sheet having an average thickness which is less than the thickness of the sheet. For use as a filter paper the compressed foamed plastic is preferably leached with a solvent such as a mixture of benzene and isopropyl alcohol. After filtration, the paper can be removed by dissolving in a suitable solvent and the filtered material recovered. "Thickness" is explained in the Specification.ALSO:A paper substitute comprises a thin compressed sheet of foamed, substantially closed cellular plastic material, the material before compression having a Young's modulus at room temperature of at least 105 degrees per cm2 and the compression being such as to effect a permanent change in the material, the pores in the compressed sheets having an average thickness which is less than the thickness of the sheet. Numerous plastic materials are specified of the following main types: polyolefins and other polymers of ethylenically unsaturated monomers (including homopolymers, copolymers, graft copolymers and block copolymers), alkyd resins, polyurethanes, epoxy materials, polycarbonates, phenolic resins, urea-formaldehyde resins and cellulose derivatives. Before, during or after pressing the sheet may be (1) treated with a filler, e.g. clay, titanium dioxide, talc, ligro-cellulosic materials, calcium sulphate and mixtures of calcium sulphate and alumina; (2) coated with a casein solution of clay, satin white or titanium dioxide followed by treatment with alkali to render the casein insoluble; and (3) treated with wax, or heat glazed (after pressing). Fibres such as seed hairs, e.g. cotton; stem fibres, e.g. linen, jute or manila; leaf fibres, e.g. straw, pineapple or esparto; fruit fibres; wood fibres; nylon or glass fibres may be incorporated into the foamed material during or after its preparation. The paper substitutes may be impregnated with resins, asphalts, tars and pitches; they may also be bleached, e.g. with hydrogen peroxide, or surface conditioned such as by staining and application of sizing, e.g. glue, gelatin, rosin, starch or dextrin. In the examples, paper substitutes are prepared from (1) expanded cellulose acetate (2) rigid polyurethane foam prepared from hexamethylene diisocyanate and a long chain polyol or from toluene diisocyanate and a long chain polyester of adipic acid and ethylene glycol (3) foamed polystyrene (9) a foamed glydidyl polyether of 2, 2-bis (4-hydroxyphenyl) propane (10) a foamed polycarbonate obtained by reacting phosgene and 2, 2-bis-(40hydroxyphenol) propane (11) foamed polyvinyl chloride, foamed polyethylene, a foamed alkyd obtained by reacting glycerol with phthalic anhydride and tert-butyl benzoic acid, and a foamed ureaformaldehyde resin.
GB1993060A 1959-06-09 1960-06-07 Paper substitutes Expired GB911995A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US81911059A 1959-06-09 1959-06-09

Publications (1)

Publication Number Publication Date
GB911995A true GB911995A (en) 1962-12-05

Family

ID=25227226

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1993060A Expired GB911995A (en) 1959-06-09 1960-06-07 Paper substitutes

Country Status (1)

Country Link
GB (1) GB911995A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3384531A (en) * 1961-12-07 1968-05-21 Du Pont Flattened ultra-microcellular structure and method for making same
US3425890A (en) * 1966-12-30 1969-02-04 Scott Paper Co Stretched-set reticulated polyurethane foam and method of making same
US3480507A (en) * 1965-09-02 1969-11-25 Shell Oil Co Process for the preparation of fibrous,filamentous products and the resultant product
WO2007045456A1 (en) * 2005-10-21 2007-04-26 Ccs Technology, Inc. Optic cable and method for producing an optic cable
CN103938491A (en) * 2014-03-18 2014-07-23 蚌埠市风驰滤清器有限公司 Water and oil resistant oil filter paper added with nano-titanium dioxide and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3384531A (en) * 1961-12-07 1968-05-21 Du Pont Flattened ultra-microcellular structure and method for making same
US3480507A (en) * 1965-09-02 1969-11-25 Shell Oil Co Process for the preparation of fibrous,filamentous products and the resultant product
US3425890A (en) * 1966-12-30 1969-02-04 Scott Paper Co Stretched-set reticulated polyurethane foam and method of making same
WO2007045456A1 (en) * 2005-10-21 2007-04-26 Ccs Technology, Inc. Optic cable and method for producing an optic cable
CN103938491A (en) * 2014-03-18 2014-07-23 蚌埠市风驰滤清器有限公司 Water and oil resistant oil filter paper added with nano-titanium dioxide and preparation method thereof
CN103938491B (en) * 2014-03-18 2015-10-28 蚌埠市风驰滤清器有限公司 A kind of Waterproofing/oilproofing oil filter filter paper adding nano titanium oxide and preparation method thereof

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