CN103938471B - A kind of dyeing and printing process of COTTON FABRIC - Google Patents

A kind of dyeing and printing process of COTTON FABRIC Download PDF

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CN103938471B
CN103938471B CN201410157385.2A CN201410157385A CN103938471B CN 103938471 B CN103938471 B CN 103938471B CN 201410157385 A CN201410157385 A CN 201410157385A CN 103938471 B CN103938471 B CN 103938471B
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dyeing
fabric
printing process
agent
cotton fabric
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CN103938471A (en
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张伟峰
袁淦堂
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Zhejiang Hongfeng Science and Technology Co., Ltd.
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Changxing Hongfeng Printing & Dyeing Co Ltd
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Abstract

The invention discloses a kind of dyeing and printing process of COTTON FABRIC, it comprises fabric pretreatment, dyeing process: wherein, dyeing is treated to dyes in the fabric immersion staining bath after pre-treatment, controlling bath raio in staining bath is 1:12 ~ 15, contaminate 8 ~ 10min at 25 ~ 30 DEG C, be then warming up to 58 ~ 60 DEG C and contaminate 15 ~ 25min; Dye liquor in staining bath comprises dyestuff, N hydroxymethyl acrylamide, alpha-alkene sulfonate, methyl diphenyl oxide disulfonates, polyquaternary amine class color-fixing agent, the components such as waterglass, easy and simple to handle in such scheme, operation is few, energy consumption is low, and printing and dyeing efficiency is high, and the waste liquid produced in dyeing process is easy to process.

Description

A kind of dyeing and printing process of COTTON FABRIC
Technical field
The present invention relates to textile manufacturing field, be specifically related to a kind of dyeing and printing process of COTTON FABRIC.
Background technology
Textile industry is the traditional pillar industry of China, comprises five parts such as weaving, printing and dyeing, chemical fibre, clothing and textile equipment.Fabric refers to the textiles made with natural fabric or synthetic fiber, can be divided into woven fabric, knitted fabric and non-weaving cloth by different processing methods, is to make the conventional raw material of the articles for daily use such as clothing, curtain.Printing and dyeing refer to and make fabric present shades of colour required for people by dyeing, make it more attractive in appearance.Traditional dyeing and finishing technique comprises destarch, kiering, bleaching, mercerising, dyeing, stamp, the operations such as arrangement, wherein destarch, kiering, bleaching three operations is fabric pretreatment, the object of COTTON FABRIC and BLENDED FABRIC pre-treatment thereof removes the finish on fabric, slurry and natural impurity are as cotton wax etc., to reduce the impurity content on fabric, improve water imbibition and the whiteness of fabric, but this three operation is independently carried out, its operating time is long, require that the temperature for the treatment of fluid is high, energy consumption is large, large to fabric fibre infringement, and containing a large amount of bleaching agents in the treatment fluid used, stabilizing agent, seriously polluted to environment after discharge.
Textile finishing refers to and apply a kind of finishing agent on fabric, and it can change the surface property of fabric, thus gives fabric special function.Such as hydrophobic and oil repellent arranges is the finishing agent process fabric with low surface tension, changes the surface characteristic of fiber, makes fabric face not easily by water or oily wetting and spreading, thus reach the object of hydrophobic and oil repellent.But in traditional dyeing and finishing technique, dyeing and arrangement are two separate operations, make at the bottom of dyeing and printing process complexity, production efficiency.
In addition, in the dye liquor used in traditional dyeing and finishing technique containing cannot degrade in a large number, harmful printing and dyeing assistant, cause waste liquid to be difficult to process, harm environmental and human health impacts.
Summary of the invention
For solving the problem, the invention provides a kind of dyeing and printing process of COTTON FABRIC, its whole printing and dyeing are easy and simple to handle, and operation is few, and energy consumption is low, and printing and dyeing efficiency is high, and the waste liquid produced in dyeing process is easy to process.
For achieving the above object, the technical scheme that the present invention takes is:
A dyeing and printing process for COTTON FABRIC, it comprises fabric pretreatment, dyeing process:
Wherein, dyeing is treated to dyes in the fabric immersion staining bath after pre-treatment, and controlling bath raio in staining bath is 1:12 ~ 15, contaminates 8 ~ 10min at 25 ~ 30 DEG C, is then warming up to 58 ~ 60 DEG C and contaminates 15 ~ 25min; Dye liquor in staining bath comprises following component: dyestuff 15 ~ 20g/L, N hydroxymethyl acrylamide 5 ~ 8g/L, alpha-alkene sulfonate 2 ~ 5g/L, methyl diphenyl oxide disulfonates 5 ~ 8g/L, polyquaternary amine class color-fixing agent 2 ~ 5g/L, waterglass 5 ~ 10g/L, dimethyl dihydroxy cyclic ethylene carbamide resin 2 ~ 5g/L, isopropyl alcohol 0.65 ~ 0.85g/L, naphthalene oxyethylene sulfate 0.05 ~ 0.25g/L, diethylene-triamine pentaacetic acid 0.35 ~ 0.55g/L, wet friction fastness improving agent DM-2588 are 8 ~ 10g/L, finishing agent 1 ~ 5g/L, antiseptic 5 ~ 7g/L;
Finishing agent is sodium sulfonate, alundum (Al2O3), silica, sodium onitrophenol obtain according to the weight ratio mixed preparing of 1 ~ 1.2:3 ~ 3.5:2 ~ 2.2:1.2 ~ 1.5;
Antiseptic is that dimethyl stearyl [3-(trimethoxy is silica-based) propyl group] ammonium chloride, 4-isopropyl-2-hydroxyl-2,4,6-cycloheptatriene-1-ketone and nanometer titanium dioxide titanium valve obtain according to the weight ratio mixed preparing of 1 ~ 1.5:1:2 ~ 3;
Polyquaternary amine class color-fixing agent is that diallyidimethylammonium chloride ammonia is polymerized.
Further scheme is:
Fabric pretreatment is for immerse in pre-treatment groove by fabric, controlling bath raio in pre-treatment groove is 1:4 ~ 5, pad process 35 ~ 40min at 35 DEG C ~ 40 DEG C, in pre-treatment groove, pretreatment liquid comprises cellulase 0.5 ~ 2g/l, pectase 4 ~ 6g/l, proteinase-10 .5 ~ 0.8g/l, HAc 0.1 ~ 1g/l, NaAc 0.5 ~ 2g/l, hydrogen peroxide 20 ~ 25g/l, chelated dispersants 1 ~ 1.5g/l, nonanoyloxybenzene sulfonate 1 ~ 1.2g/l;
Chelated dispersants is that gluconic acid sodium salt and acrylic acid-maleic anhydride copolymer are formulated.
Be provided with ultrasonic transmitter in pre-treatment groove, the ultrasonic frequency that ultrasonic transmitter is launched is 40kHz.
Preferred version is:
Dye liquor in staining bath comprises following component: dyestuff 18g/L, N hydroxymethyl acrylamide 7g/L, alpha-alkene sulfonate 3g/L, methyl diphenyl oxide disulfonates 6g/L, polyquaternary amine class color-fixing agent 4g/L, waterglass 8g/L, dimethyl dihydroxy cyclic ethylene carbamide resin 3g/L, isopropyl alcohol 0.7g/L, naphthalene oxyethylene sulfate 0.2g/L, diethylene-triamine pentaacetic acid 0.4g/L, wet friction fastness improving agent DM-2588 are 9g/L, finishing agent 3g/L, antiseptic 6g/L;
Finishing agent is sodium sulfonate, alundum (Al2O3), silica, sodium onitrophenol obtain according to the weight ratio mixed preparing of 1.2:3:2:1.2;
Antiseptic is that dimethyl stearyl [3-(trimethoxy is silica-based) propyl group] ammonium chloride, 4-isopropyl-2-hydroxyl-2,4,6-cycloheptatriene-1-ketone and nanometer titanium dioxide titanium valve obtain according to the weight ratio mixed preparing of 1.5:1:2.
Pretreatment liquid comprises cellulase 1g/L, pectase 5g/L, proteinase-10 .6g/L, HAc 0.5g/L, NaAc 1g/L, hydrogen peroxide 22g/L, chelated dispersants 1.2g/L, nonanoyloxybenzene sulfonate 1g/L.
Reaction is interfered for avoiding between coloring agent and finishing agent in traditional cotton fabric printing process, therefore dye and arrange and carry out in two steps, in the present invention, by screening the formation component of coloring agent and finishing agent, avoid the reaction between component, when ensureing to add finishing agent and coloring agent, the effect dyeing and arrange can be realized simultaneously effectively simultaneously, also add some allotment equilibrium compositions simultaneously in coloring agent, the better equilibrium of effect of dyeing and arranging can be made.
In addition, in such scheme, in the dye liquor adopted, the biological degradability of each auxiliary agent is good, and help dye effective, can dye to fabric fast, the destarch of pre-treatment, kiering, bleaching three operation are combined into an operation process simultaneously, reduce the operation of whole dyeing and printing process, improve the cycle of whole technique, enhance productivity and reduce production cost.
Detailed description of the invention
In order to make objects and advantages of the present invention clearly understand, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.Wet friction fastness improving agent DM-2588 used in embodiment 1 ~ 3, chelated dispersants, polyquaternary amine class color-fixing agent are for commercially to obtain, and chelated dispersants is that gluconic acid sodium salt and acrylic acid-maleic anhydride copolymer are formulated; Polyquaternary amine class color-fixing agent is that diallyidimethylammonium chloride ammonia is polymerized, and its concrete composition can refer to the record of relevant technical document, product manual.
Embodiment 1
Be formulated as follows the pretreatment liquid of component:
Cellulase 0.5g/l, pectase 6g/l, proteinase-10 .5g/l, HAc 1g/l, NaAc 0.5g/l, hydrogen peroxide 25g/l, chelated dispersants 1g/l, nonanoyloxybenzene sulfonate 1.2g/l;
Immersed by fabric in pre-treatment groove, controlling bath raio in pre-treatment groove is 1:4, starts the ultrasonic generator that pre-treatment groove is arranged, and launches the ultrasonic wave of 40kHz, pads process 35min at 40 DEG C;
Be formulated as follows the dyeing liquor of component:
Dyestuff 20g/L, N hydroxymethyl acrylamide 5g/L, alpha-alkene sulfonate 2g/L, methyl diphenyl oxide disulfonates 8g/L, polyquaternary amine class color-fixing agent 2g/L, waterglass 5g/L, dimethyl dihydroxy cyclic ethylene carbamide resin 5g/L, isopropyl alcohol 0.65g/L, naphthalene oxyethylene sulfate 0.25g/L, diethylene-triamine pentaacetic acid 0.35g/L, wet friction fastness improving agent DM-2588 are 10g/L, finishing agent 1g/L, antiseptic 7g/L;
Finishing agent is sodium sulfonate, alundum (Al2O3), silica, sodium onitrophenol obtain according to the weight ratio mixed preparing of 1:3.5:2:1.5;
Antiseptic is that dimethyl stearyl [3-(trimethoxy is silica-based) propyl group] ammonium chloride, 4-isopropyl-2-hydroxyl-2,4,6-cycloheptatriene-1-ketone and nanometer titanium dioxide titanium valve obtain according to the weight ratio mixed preparing of 1:1:3;
Immersed in staining bath by fabric after pre-treatment and dye, controlling bath raio in staining bath is 1:12, contaminates 8min at 30 DEG C, is then warming up to 60 DEG C and contaminates 15min;
Fabric after above-mentioned dyeing process is carried out wash, dry after can obtain finished textile product.
Embodiment 2
Be formulated as follows the pretreatment liquid of component:
Cellulase 2g/L, pectase 4g/L, proteinase-10 .8g/L, HAc 0.1g/L, NaAc 2g/L, hydrogen peroxide 20g/L, chelated dispersants 1.5g/L, nonanoyloxybenzene sulfonate 1g/L;
Immersed by fabric in pre-treatment groove, controlling bath raio in pre-treatment groove is 1:5, starts the ultrasonic generator that pre-treatment groove is arranged, and launches the ultrasonic wave of 40kHz, pads process 40min at 35 DEG C;
Be formulated as follows the dyeing liquor of component:
Dyestuff 15g/L, N hydroxymethyl acrylamide 8g/L, alpha-alkene sulfonate 5g/L, methyl diphenyl oxide disulfonates 5g/L, polyquaternary amine class color-fixing agent 5g/L, waterglass 10g/L, dimethyl dihydroxy cyclic ethylene carbamide resin 2g/L, isopropyl alcohol 0.85g/L, naphthalene oxyethylene sulfate 0.05g/L, diethylene-triamine pentaacetic acid 0.55g/L, wet friction fastness improving agent DM-2588 is 8g/L, finishing agent 5g/L, antiseptic 5g/L;
Finishing agent is sodium sulfonate, alundum (Al2O3), silica, sodium onitrophenol obtain according to the weight ratio mixed preparing of 1.2:3:2.2:1.2;
Antiseptic is that dimethyl stearyl [3-(trimethoxy is silica-based) propyl group] ammonium chloride, 4-isopropyl-2-hydroxyl-2,4,6-cycloheptatriene-1-ketone and nanometer titanium dioxide titanium valve obtain according to the weight ratio mixed preparing of 1.5:1:2;
Immersed in staining bath by fabric after pre-treatment and dye, controlling bath raio in staining bath is 1:15, contaminates 10min at 25 DEG C, is then warming up to 58 DEG C and contaminates 25min;
Fabric after above-mentioned dyeing process is carried out wash, dry after can obtain finished textile product.
Embodiment 3
Be formulated as follows the pretreatment liquid of component:
Treatment fluid comprises cellulase 1g/L, pectase 5g/L, proteinase-10 .6g/L, HAc 0.5g/L, NaAc 1g/L, hydrogen peroxide 22g/L, chelated dispersants 1.2g/L, nonanoyloxybenzene sulfonate 1g/L;
Immersed by fabric in pre-treatment groove, controlling bath raio in pre-treatment groove is 1:4.5, starts the ultrasonic generator that pre-treatment groove is arranged, and launches the ultrasonic wave of 40kHz, pads process 35min at 35 DEG C;
Be formulated as follows the dyeing liquor of component:
Dyestuff 18g/L, N hydroxymethyl acrylamide 7g/L, alpha-alkene sulfonate 3g/L, methyl diphenyl oxide disulfonates 6g/L, polyquaternary amine class color-fixing agent 4g/L, waterglass 8g/L, dimethyl dihydroxy cyclic ethylene carbamide resin 3g/L, isopropyl alcohol 0.7g/L, naphthalene oxyethylene sulfate 0.2g/L, diethylene-triamine pentaacetic acid 0.4g/L, wet friction fastness improving agent DM-2588 are 9g/L, finishing agent 3g/L, antiseptic 6g/L;
Finishing agent is sodium sulfonate, alundum (Al2O3), silica, sodium onitrophenol obtain according to the weight ratio mixed preparing of 1.2:3:2:1.2;
Antiseptic is that dimethyl stearyl [3-(trimethoxy is silica-based) propyl group] ammonium chloride, 4-isopropyl-2-hydroxyl-2,4,6-cycloheptatriene-1-ketone and nanometer titanium dioxide titanium valve obtain according to the weight ratio mixed preparing of 1.5:1:2.
Immersed in staining bath by fabric after pre-treatment and dye, controlling bath raio in staining bath is 1:13, contaminates 9min at 30 DEG C, is then warming up to 60 DEG C and contaminates 15min;
Fabric after above-mentioned dyeing process is carried out wash, dry after can obtain finished textile product.
Embodiment 4
By COTTON FABRIC traditionally dyeing and printing process carry out destarch, kiering, bleaching, mercerising, dyeing, stamp, arrangement process successively, by the dyeing of the COTTON FABRIC obtained in the COTTON FABRIC obtained and embodiment 1,2 and 3, arrange performance and compare.Comparative result is that present invention process dyeing and the effect and the traditional handicraft that arrange are basically identical, but on average at least saves the production cycle 1/5, reduction production cost.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (5)

1. the dyeing and printing process of a COTTON FABRIC, it comprises fabric pretreatment and dyeing process, it is characterized in that, described dyeing is treated to dyes in the fabric immersion staining bath after pre-treatment, controlling bath raio in staining bath is 1:12 ~ 15, contaminate 8 ~ 10min at 25 ~ 30 DEG C, be then warming up to 58 ~ 60 DEG C and contaminate 15 ~ 25min;
Dye liquor in described staining bath comprises following component: dyestuff 15 ~ 20 g/L, N hydroxymethyl acrylamide 5 ~ 8g/L, alpha-alkene sulfonate 2 ~ 5g/L, methyl diphenyl oxide disulfonates 5 ~ 8 g/L, polyquaternary amine class color-fixing agent 2 ~ 5g/L, waterglass 5 ~ 10g/L, dimethyl dihydroxy cyclic ethylene carbamide resin 2 ~ 5g/L, isopropyl alcohol 0.65 ~ 0.85g/L, naphthalene oxyethylene sulfate 0.05 ~ 0.25g/L, diethylene-triamine pentaacetic acid 0.35 ~ 0.55g/L, wet friction fastness improving agent DM-2588 are 8 ~ 10g/L, finishing agent 1 ~ 5g/L, antiseptic 5 ~ 7g/L;
Finishing agent is sodium sulfonate, alundum (Al2O3), silica, sodium onitrophenol obtain according to the weight ratio mixed preparing of 1 ~ 1.2:3 ~ 3.5:2 ~ 2.2:1.2 ~ 1.5;
Antiseptic is that dimethyl stearyl [3-(trimethoxy is silica-based) propyl group] ammonium chloride, 4-isopropyl-2-hydroxyl-2,4,6-cycloheptatriene-1-ketone and nanometer titanium dioxide titanium valve obtain according to the weight ratio mixed preparing of 1 ~ 1.5:1:2 ~ 3;
Polyquaternary amine class color-fixing agent is that diallyidimethylammonium chloride ammonia is polymerized.
2. the dyeing and printing process of COTTON FABRIC as claimed in claim 1, it is characterized in that, described fabric pretreatment is for immerse in pre-treatment groove by fabric, controlling bath raio in pre-treatment groove is 1:4 ~ 5, process 35 ~ 40min is padded at 35 DEG C ~ 40 DEG C, in pre-treatment groove, pretreatment liquid comprises cellulase 0.5 ~ 2g/l, pectase 4 ~ 6 g/l, proteinase-10 .5 ~ 0.8 g/l, HAc 0.1 ~ 1g/l, NaAc 0.5 ~ 2g/l, hydrogen peroxide 20 ~ 25g/l, chelated dispersants 1 ~ 1.5g/l, nonanoyloxybenzene sulfonate 1 ~ 1.2g/l;
Chelated dispersants is that gluconic acid sodium salt and acrylic acid-maleic anhydride copolymer are formulated.
3. the dyeing and printing process of COTTON FABRIC as claimed in claim 2, is characterized in that: be provided with ultrasonic transmitter in pre-treatment groove, and the ultrasonic frequency that ultrasonic transmitter is launched is 40kHz.
4. the dyeing and printing process of COTTON FABRIC as claimed in claim 1, it is characterized in that, dye liquor in described staining bath comprises following component: dyestuff 18 g/L, N hydroxymethyl acrylamide 7g/L, alpha-alkene sulfonate 3g/L, methyl diphenyl oxide disulfonates 6g/L, polyquaternary amine class color-fixing agent 4g/L, waterglass 8g/L, dimethyl dihydroxy cyclic ethylene carbamide resin 3g/L, isopropyl alcohol 0.7 g/L, naphthalene oxyethylene sulfate 0.2 g/L, diethylene-triamine pentaacetic acid 0.4 g/L, wet friction fastness improving agent DM-2588 are 9g/L, finishing agent 3g/L, antiseptic 6g/L;
Finishing agent is sodium sulfonate, alundum (Al2O3), silica, sodium onitrophenol obtain according to the weight ratio mixed preparing of 1.2:3:2:1.2;
Antiseptic is that dimethyl stearyl [3-(trimethoxy is silica-based) propyl group] ammonium chloride, 4-isopropyl-2-hydroxyl-2,4,6-cycloheptatriene-1-ketone and nanometer titanium dioxide titanium valve obtain according to the weight ratio mixed preparing of 1.5:1:2.
5. the dyeing and printing process of COTTON FABRIC as claimed in claim 2, it is characterized in that, pretreatment liquid comprises cellulase 1g/L, pectase 5g/L, proteinase-10 .6g/L, HAc 0.5g/L, NaAc 1g/L, hydrogen peroxide 22 g/L, chelated dispersants 1.2g/L, nonanoyloxybenzene sulfonate 1g/L.
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Denomination of invention: Printing and dyeing process of a kind of cotton fabric

Effective date of registration: 20210625

Granted publication date: 20151104

Pledgee: Changxin Zhejiang rural commercial bank Limited by Share Ltd.

Pledgor: Zhejiang Hongfeng Science and Technology Co.,Ltd.

Registration number: Y2021330000674