CN103928547A - Floating type solar cell panel and forming method thereof - Google Patents

Floating type solar cell panel and forming method thereof Download PDF

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Publication number
CN103928547A
CN103928547A CN201410173430.3A CN201410173430A CN103928547A CN 103928547 A CN103928547 A CN 103928547A CN 201410173430 A CN201410173430 A CN 201410173430A CN 103928547 A CN103928547 A CN 103928547A
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China
Prior art keywords
floating type
type solar
solar cell
solar panel
antioxidant
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CN201410173430.3A
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Chinese (zh)
Inventor
徐松炎
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HANHZHOU YONGDIAN ILLUMINATION CO Ltd
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HANHZHOU YONGDIAN ILLUMINATION CO Ltd
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Priority to CN201410173430.3A priority Critical patent/CN103928547A/en
Publication of CN103928547A publication Critical patent/CN103928547A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/0481Encapsulation of modules characterised by the composition of the encapsulation material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Photovoltaic Devices (AREA)

Abstract

The invention relates to a floating type solar cell panel and a forming method of the floating type solar cell panel. The floating type solar cell panel is formed by connecting a plurality of solar cell modules in series or in parallel or in series and in parallel. The floating type solar cell panel has the advantages that firstly, PVC paste is used as a sealing forming material of a solar chip mold core and is good in ultraviolet resistance, low-temperature resistance and weather resistance, and the inflaming retarding level ranges from the V-1 level to the V-0 level; secondly, the shape of a needed solar panel can be formed by the floating type solar cell panels according to different demands of users, the technology prejudice that technicians of the field think that the PVC paste cannot be used as the sealing forming material of a solar cell for a long time is eliminated fundamentally, and the technology prejudice that solar chips can only be distributed in a rectangle mode and cannot be distributed according to shape design is eliminated fundamentally; thirdly, due to the fact that the floating type solar cell panel can not only be coiled to be carried but also be spread according to the met landform to collect light and generate electivity, the floating type solar cell panel can be not only carried with people to be used on land for collecting light and generating electricity but also carried with a ship to be used in a lake or on the sea to generate electricity.

Description

Floating type solar panel and forming method
Technical field
The present invention relates to a kind of installation that had both been easy to carry, use, can draw in and deposit at any time again, there is again floating type solar panel and the forming method of excellent weatherability, sealing and floatability simultaneously, belong to solar panel and manufacture field.
Background technology
1, CN 102694043A, title " solar panel ", it comprises solar battery sheet, its upper surface and lower surface are all equipped with one deck ethylene-vinyl acetate copolymer.Be characterized on the ethylene-vinyl acetate copolymer of described solar battery sheet upper surface, there is perfluoroethylene-propylene film, under the ethylene-vinyl acetate copolymer of described solar battery sheet lower surface, have fiberglass reinforced panel.Described solar panel edge adopts sealing joint strip sealing.This solar panel is lightweight, easily carries and installs.
2, CN102376791A, title " solar panel ", this solar panel comprises: a plurality of solar cells, each solar cell comprises substrate and is positioned at the lip-deep electrode part of described substrate; Connectors, it is constituted as at least one solar cell in described a plurality of solar cells is electrically connected to another solar cell in described a plurality of solar cell; And electroconductive adhesive films, it comprises resin and is dispersed in a plurality of conductive particles in described resin, between the described electrode part and described connectors of described at least one solar cell of described electroconductive adhesive films in described a plurality of solar cells, so that the described electrode part of described at least one solar cell in described a plurality of solar cells is electrically connected to described connectors, wherein, the width of described connectors is equal to or greater than the width of described electroconductive adhesive films.
3, CN102760787A, title " solar panel ", it comprises: glass plate, film plating layer, cell panel and shell, is characterized in that: the glass plate that surface is fixed with antireflection film is positioned at top; Periphery is shell; Be fixed with the inner casing of reflective membrane at middle part; Cell panel below; The space forming at glass plate, inner casing and cell panel is sealing, inside has protective gas.
4, CN103280478A, title " solar panel ", the square framework (1) that comprises aluminium alloy system, fixing in described square framework (1) too can cell panel body, described square framework (1) is fixedly formed by four sheths (10) amalgamation, it is characterized in that: described sheth (10) comprises that cross section is L shaped frame body, the long side edge side of described frame body is provided with the cell panel holddown groove (11) of U-shaped, between the frame body of adjacent and docking by the latch structure amalgamation of socket (13) and cutting (12), cutting simultaneously and socket are provided with fixing hole, pin inserts fixing hole and fixes by injecting glue.
The weak point that above-mentioned background technology exists: solar panel all adopts monoblock solar battery sheet to form, thereby can not carry by reel, also cannot make the best of things and lay solar panel.
Summary of the invention
Purpose of design: design a kind of installation that had both been easy to carry, use, can draw in and deposit at any time again, there is again floating type solar panel and the forming method of excellent weatherability, sealing and floatability simultaneously.
Design: in order to realize above-mentioned purpose of design.1, the present invention adopts PVC thickener as the design of solar energy module encapsulant, is one of technical characterictic of the present invention.The object of design is like this: it changes the PVC that those skilled in the art think for a long time and sticks with paste due to good dispersion property, can only use for soft material field, as artificial leather, vinyl toy, soft trade mark, wallpaper, paint, foamed plastic etc., can not be as the technology prejudice of solar cell sealing moulding material.The application Fan Qi road it, adopt PVC to stick with paste as solar cell sealing moulding material, not only can make solar panels may need to be formed in various shapes according to user, and the solar cell of formed thereby is easy to cast, good, heat-resisting, the shock resistance of translucent effect, tear-proof, and can realize a small amount of, many kindizations and produce, the more important thing is that this material realized long-term hermetically sealed, the round-the-clock weather-proof use out of doors of solar cell sealing.2, polylith solar module serial or parallel connection or connection in series-parallel being formed to the design of floating type solar panel, is two of technical characterictic of the present invention.The object of design is like this: because solar chip adopts monocrystalline silicon or polysilicon manufacture, and monocrystalline silicon or polysilicon monocrystalline silicon have diamond lattice, crystal is hard and crisp, therefore in the making of existing solar cell, need to be by the positive EVA that adopts the high degree of cross linking of solar battery sheet, the encapsulation agent of high bond strength (neutral silicone resin glue), the high-intensity toughened glass of high transmission rate etc., the back side adopts rigid back to support, surrounding adopts rigid frame sealing, not only manufacturing cost is high, body weight, frangible, and can not portable use, make the use of solar cell only be confined to the use under fixed environment state.
The application adds and is used for absorbing ultraviolet absorbent in PVC sticks with paste; because ultra-violet absorber can absorb sunlight or fluorescence source middle-ultraviolet lamp part; and this body structure does not change; it can discharge high-octane ultraviolet luminous energy energy transform into heat energy or nondestructive longer light wave; thereby protection is added with the material of ultra-violet absorber and exempts from ultraviolet ray destruction; in PVC sticks with paste, add ultra-violet absorber and can effectively stop ultraviolet ray in the sunlight destruction to solar cell sealing module, extend the useful life of floating type solar panel.
The object that the application adds antioxidant in PVC sticks with paste is: because the PVC paste plastics after plasticizing are easily aging under the factor effects such as light, heat, oxygen, solvent, auxiliary agent, HCl, i.e. degraded or crosslinked, degenerates its physical and mechanical properties, reduction of service life.The application PVC adds antioxidant effectively to suppress or reduces the macromolecular thermal oxidation of plastics, photooxidation reaction speed in sticking with paste, improve significantly heat-resisting, the light fastness of the PVC paste plastics after plasticizing, delay degraded, ageing process that the PVC after plasticizing sticks with paste plastics, improve the weather resisteant that PVC sticks with paste made floating type solar panel, extend the PVC paste plastic products useful life after plasticizing.
The object that the application adds low temperature plasticizer in PVC sticks with paste is: because low temperature plasticizer and PVC paste resin have good compatibility, plasticization effect is good, be difficult for segregation, be difficult for oozing out, and low temperature plasticizer can reduce the vitrification point that the PVC after plasticizing sticks with paste plastics, make its pliability good, the cold tolerance that can improve the PVC paste plastics after plasticizing, makes it in cold district, still have good serviceability.
The object that the application adds stabilizer in PVC sticks with paste is: PVC thickener at high temperature plastify or high temperature under use, very easily emit HCL, form unsettled polyene structure.Meanwhile, HCL has autocatalysis, can make PVC further degrade.In addition, if aerobic exists or have iron, aluminium, zinc, tin, copper and cadmium plasma to exist, all can be to the PVC catalytic action of having degraded, accelerate that it is aging.Therefore will there are various bad phenomenon in plastics, as variable color, distortion, be full of cracks, mechanical strength decline, edge hydraulic performance decline, embrittlement etc.In order to address these problems, PVC sticks with paste in plastics must add different cultivars, the stabilizer of different numbers.
Technical scheme 1: a kind of floating type solar panel, floating type solar panel consists of polylith solar module serial or parallel connection or connection in series-parallel.
Technical scheme 2: a kind of floating type solar cell board manufacturing method, solar module is made: solar chip is unsettled in the die cavity of floating type solar cell plate forming die, then PVC thickener is injected in the die cavity of floating type solar cell plate forming die, 15-30 minute heats, after PVC thickener in floating type solar panel shaping mold cavity is solidified, floating type solar panel after solidifying is deviate from from the die cavity of floating type solar cell plate forming die and obtained solar module, last according to the size of client's power demand, to between polylith solar module, adopt connector to connect, and adopt serial or parallel connection or series-parallel system to connect polylith solar module power output end.
The present invention compares with background technology, and the one, adopt PVC to stick with paste the moulding material as the sealing of solar chip core rod, not only there is good UV resistant, low temperature resistant, good weatherability, and fire-retardant V-1 to the V-0 level that reaches; The 2nd, can be according to the be shaped profile of required solar panels of floating type solar panel for user's different demands, not only fundamentally changed those skilled in the art and since the normal phase, thought that PVC thickener can not be as the technology prejudice of solar cell sealing moulding material, and change fundamentally changed solar chip can only distributed rectangular and the technology prejudice that can not distribute with appearance; The 3rd, because the floating type solar panel of the application can carry in rolling, can launch daylighting generating according to met topography and geomorphology again, so it can, with people for land daylighting generating, also can float on the face of Zhong Huo ocean, lake and generate electricity with ship.
Accompanying drawing explanation
Fig. 1 is the plan structure schematic diagram of floating type solar panel.
Fig. 2 is the sectional structure schematic diagram of floating type solar panel.
Embodiment
Embodiment 1: with reference to attached Fig. 1 and 2.A floating type solar panel, floating type solar panel 5 forms (connection in series-parallel is connected after referring to the rear parallel connection of first series connection or first parallel connection) by polylith solar module 4 serial or parallel connections or connection in series-parallel.Described solar module 4 consists of solar chip 1 and the PVC thickener 2 being sealed and coated on solar chip 1.Described solar chip 1 power line hermetically passing PVC thickener 2 sealants.Between described polylith solar module 4, adopt flexible connecting member to connect, as elastic sheet rubber or elastic caoutchouc rope etc.The said PVC thickener of the application refers to the PVC thickener that contains plasticizer.
Embodiment 2: on the basis of embodiment 1, described solar chip 1 is monolithic encapsulation, i.e. monolithic solar cell (module).
Embodiment 3: on the basis of embodiment 1, described solar chip 1 is multi-disc encapsulation, be that multi-disc solar chip 1 is coated and forms floating type solar panel by 2 sealings of PVC thickener, the connection in series-parallel between multi-disc solar chip 1 is prior art, at this, is not described herein.
Embodiment 4: on the basis of embodiment 1, described PVC contains ultra-violet absorber in sticking with paste, and ultra-violet absorber addition is that 100 parts of PVC stick with paste 0.1 part to 0.8 part ultra-violet absorber of resin interpolation.Described ultra-violet absorber is one or more the combination of ultraviolet absorbent UV-531, ultra-violet absorber UV-327, ultraviolet absorbent uv-326, ultra-violet absorber UV-74, ultra-violet absorber UV-9, Ultraviolet Absorber UV-P.
Embodiment 5: on the basis of embodiment 1, described PVC contains antioxidant in sticking with paste.Antioxidant addition is that 100 parts of PVC stick with paste every kind of 0.5 part to 1 part antioxidant of resin interpolation.Described antioxidant is antioxidant 2246, antioxidant 1520, antioxidant 1098, antioxidant 1076, antioxidant 1010, antioxidant 300, antioxidant 264, one or more combinations of irgasfos 168.
Embodiment 6: on the basis of embodiment 1, described PVC contains low temperature resistant additive in sticking with paste.Low temperature resistant additive addition is that 100 parts of PVC stick with paste 5 parts to 20 parts low temperature plasticizer of resin interpolation.Described low temperature resistant additive is diisodecyl adipate (being called for short DIDA), dioctyl adipate (being called for short DOA), dioctyl azelate (being called for short DOZ), decanedioic acid two butyric acid (being called for short DBS), di-n-octyl sebacate (being called for short DOS), one or more combinations of Plexol 201 (being called for short DIOS).
Embodiment 7: on the basis of embodiment 1, described PVC contains stabilizer in sticking with paste.Stabilizer addition is that 100 parts of PVC stick with paste every kind of 0.5 part to 5 parts stabilizer of resin interpolation.Described stabilizer is octyl mercaptan tin, octyl group tin oxide, Bis(lauroyloxy)dioctyltin, maleic acid dioctyltin, butanethiol tin, maleic acid dibutyl tin, laurate maleic acid dibutyl tin, laurate maleic acid dibutyl tin, two butyl tin oxide, dimethyl tin oxide, epoxidized soybean oil, epoxy siritch, phosphite.
Embodiment 8: on the basis of embodiment 1, during described PVC sticks with paste, contain flame-retardant plasticizer.Flame-retardant plasticizer addition is that 100 parts of PVC stick with paste 5 parts to 15 parts flame-retardant plasticizers of resin interpolation.Described flame-retardant plasticizer is DP-45, tricresyl phosphate (TCP), triphenyl phosphate (TPP), tributyl phosphate (TBP), trioctyl phosphate (TOP), one or more combinations of diphenyl octyl phosphate (DPOP).
Embodiment 9: on the basis of above-described embodiment, a kind of floating type solar cell board manufacturing method, solar module 4 is made: solar chip 1 is unsettled in the die cavity of floating type solar cell plate forming die, then PVC thickener is injected in the die cavity of floating type solar cell plate forming die, 15-30 minute heats, after PVC thickener in floating type solar panel shaping mold cavity is solidified, floating type solar panel after solidifying is deviate from from the die cavity of floating type solar cell plate forming die and obtained solar module 4, last according to the size of client's power demand, to between polylith solar module 4, adopt connector to connect, and adopt serial or parallel connection or series-parallel system to connect polylith solar module 4 power output ends.Described heating heated or drying tunnel is heated for baking oven.
It is to be understood that: although above-described embodiment is to the mentality of designing of the present invention detailed text description of contrasting; but these text descriptions; just the simple text of mentality of designing of the present invention is described; rather than the restriction to mentality of designing of the present invention; any combination, increase or modification that does not exceed mentality of designing of the present invention, all falls within the scope of protection of the present invention.

Claims (18)

1. a floating type solar panel, is characterized in that: floating type solar panel (5) consists of polylith solar module (4) serial or parallel connection or connection in series-parallel.
2. floating type solar panel according to claim 1, is characterized in that: described solar module (4) is by solar chip (1) and be sealed and coated on PVC thickener (2) formation on solar chip (1).
3. floating type solar panel according to claim 2, is characterized in that: described solar chip (1) power line hermetically passing PVC thickener (2) sealant.
4. according to the floating type solar panel described in claim 2 or 3, it is characterized in that: described solar chip (1) is monolithic encapsulation.
5. according to the floating type solar panel described in claim 2 or 3, it is characterized in that: described solar chip (1) is multi-disc encapsulation.
6. floating type solar panel according to claim 1, is characterized in that: between described polylith solar module (4), adopt flexible connecting member to connect.
7. floating type solar panel according to claim 2, is characterized in that: in described PVC thickener, contain ultra-violet absorber.
8. floating type solar panel according to claim 7, is characterized in that: described ultra-violet absorber is ultraviolet absorbent UV-531, ultra-violet absorber UV-327, ultraviolet absorbent uv-326, ultra-violet absorber UV-74, ultra-violet absorber UV-9, Ultraviolet Absorber UV-P.
9. floating type solar panel according to claim 2, is characterized in that: in described PVC thickener, contain antioxidant.
10. floating type solar panel according to claim 9, is characterized in that: described antioxidant is antioxidant 2246, antioxidant 1520, antioxidant 1098, antioxidant 1076, antioxidant 1010, antioxidant 300, antioxidant 264, irgasfos 168.
11. floating type solar panels according to claim 2, is characterized in that: in described PVC thickener, contain low temperature resistant additive.
12. floating type solar panels according to claim 11, is characterized in that: described low temperature resistant additive is diisodecyl adipate (being called for short DIDA), dioctyl adipate (being called for short DOA), dioctyl azelate (being called for short DOZ), decanedioic acid two butyric acid (being called for short DBS), di-n-octyl sebacate (being called for short DOS), Plexol 201 (being called for short DIOS).
13. floating type solar panels according to claim 2, is characterized in that: in described PVC thickener, contain stabilizer.
14. floating type solar panels according to claim 13, is characterized in that: described stabilizer is octyl mercaptan tin, octyl group tin oxide, Bis(lauroyloxy)dioctyltin, maleic acid dioctyltin, butanethiol tin, maleic acid dibutyl tin, laurate maleic acid dibutyl tin, laurate maleic acid dibutyl tin, two butyl tin oxide, dimethyl tin oxide, epoxidized soybean oil, epoxy siritch, phosphite.
15. floating type solar panels according to claim 2, is characterized in that: in described PVC thickener, contain flame-retardant plasticizer.
16. floating type solar panels according to claim 15, is characterized in that: described flame-retardant plasticizer is DP-45, tricresyl phosphate (TCP), triphenyl phosphate (TPP), tributyl phosphate (TBP), trioctyl phosphate (TOP), diphenyl octyl phosphate (DPOP).
17. 1 kinds of floating type solar cell board manufacturing methods, it is characterized in that: solar module (4) is made: solar chip (1) is unsettled in the die cavity of floating type solar cell plate forming die, then PVC thickener is injected in the die cavity of floating type solar cell plate forming die, 15-30 minute heats, after PVC thickener in floating type solar panel shaping mold cavity is solidified, floating type solar panel after solidifying is deviate from from the die cavity of floating type solar cell plate forming die and obtained solar module (4), last according to the size of client's power demand, to between polylith solar module (4), adopt connector to connect, and adopt serial or parallel connection or series-parallel system to connect polylith solar module (4) power output end.
18. floating type solar panels according to claim 17, is characterized in that: described in heat and heat or drying tunnel is heated for baking oven.
CN201410173430.3A 2014-04-28 2014-04-28 Floating type solar cell panel and forming method thereof Pending CN103928547A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108963022A (en) * 2018-08-21 2018-12-07 深圳市远达明反光器材有限公司 Flexible solar panel encapsulating structure and solar energy spike
CN109257897A (en) * 2017-07-14 2019-01-22 杭州勇电照明有限公司 Round-the-clock Switching Power Supply and forming method

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CN101588149A (en) * 2009-06-25 2009-11-25 中电电气集团有限公司 Flexible foldable solar mobile electric power and manufacturing method thereof
CN101635536A (en) * 2009-06-25 2010-01-27 中电电气集团有限公司 Foldable solar energy movable power supply and manufacture method thereof
CN103107206A (en) * 2011-11-15 2013-05-15 聚日(苏州)科技有限公司 Packaged solar cell wafer and manufacturing method thereof
CN103221461A (en) * 2010-11-18 2013-07-24 可隆科技特(株) Flexible transparent film and manufacturing method thereof
US20130240015A1 (en) * 2010-11-08 2013-09-19 Dan Chaimovski Portable folding solar panels
CN204088331U (en) * 2014-04-28 2015-01-07 杭州勇电照明有限公司 Floating type solar panel

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Publication number Priority date Publication date Assignee Title
CN101588149A (en) * 2009-06-25 2009-11-25 中电电气集团有限公司 Flexible foldable solar mobile electric power and manufacturing method thereof
CN101635536A (en) * 2009-06-25 2010-01-27 中电电气集团有限公司 Foldable solar energy movable power supply and manufacture method thereof
US20130240015A1 (en) * 2010-11-08 2013-09-19 Dan Chaimovski Portable folding solar panels
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Publication number Priority date Publication date Assignee Title
CN109257897A (en) * 2017-07-14 2019-01-22 杭州勇电照明有限公司 Round-the-clock Switching Power Supply and forming method
CN108963022A (en) * 2018-08-21 2018-12-07 深圳市远达明反光器材有限公司 Flexible solar panel encapsulating structure and solar energy spike
CN108963022B (en) * 2018-08-21 2024-06-25 深圳市远达明反光器材有限公司 Flexible solar panel packaging structure and solar spike

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Application publication date: 20140716