CN103917493B - 使用n,n‑二甲基有机模板合成沸石材料 - Google Patents

使用n,n‑二甲基有机模板合成沸石材料 Download PDF

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Publication number
CN103917493B
CN103917493B CN201280054309.8A CN201280054309A CN103917493B CN 103917493 B CN103917493 B CN 103917493B CN 201280054309 A CN201280054309 A CN 201280054309A CN 103917493 B CN103917493 B CN 103917493B
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zeolitic material
mixture
present
preferred
zeolitic
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Chinese (zh)
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CN103917493A (zh
Inventor
B·耶尔马兹
U·伯伦斯
V·N·斯瓦米纳坦
U·米勒
G·伊夫兰德
L·绍尔沃什
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BASF SE
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7015—CHA-type, e.g. Chabazite, LZ-218
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/85—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by XPS, EDX or EDAX data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
CN201280054309.8A 2011-09-06 2012-09-06 使用n,n‑二甲基有机模板合成沸石材料 Active CN103917493B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710324626.1A CN107021508B (zh) 2011-09-06 2012-09-06 使用n,n-二甲基有机模板合成沸石材料

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11180148.6 2011-09-06
EP11180148 2011-09-06
PCT/IB2012/054596 WO2013035054A1 (en) 2011-09-06 2012-09-06 Synthesis of zeolitic materials using n,n-dimethyl organotemplates

Related Child Applications (1)

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CN201710324626.1A Division CN107021508B (zh) 2011-09-06 2012-09-06 使用n,n-二甲基有机模板合成沸石材料

Publications (2)

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CN103917493A CN103917493A (zh) 2014-07-09
CN103917493B true CN103917493B (zh) 2017-06-06

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CN201280054309.8A Active CN103917493B (zh) 2011-09-06 2012-09-06 使用n,n‑二甲基有机模板合成沸石材料
CN201710324626.1A Active CN107021508B (zh) 2011-09-06 2012-09-06 使用n,n-二甲基有机模板合成沸石材料

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EP (1) EP2753579B1 (https=)
JP (1) JP6081460B2 (https=)
CN (2) CN103917493B (https=)
WO (1) WO2013035054A1 (https=)
ZA (1) ZA201402467B (https=)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6081460B2 (ja) * 2011-09-06 2017-02-15 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Ｎ，ｎ−ジメチル有機テンプレートを用いるゼオライト系材料の合成
US9108856B2 (en) * 2013-09-18 2015-08-18 Chevron U.S.A. Inc. Method for preparing CHA-type molecular sieves using colloidal aluminosilicate and novel structure directing agents
ES2574500B1 (es) 2014-12-17 2017-03-31 Consejo Superior De Investigaciones Científicas (Csic) Síntesis de la zeolita con la estructura cristalina CHA, procedimiento de síntesis y su uso en aplicaciones catalíticas
US9663379B2 (en) * 2015-09-25 2017-05-30 Chevron U.S.A. Inc. Method for preparing zeolite SSZ-98
CN108137333B (zh) * 2015-10-16 2021-04-16 雪佛龙美国公司 分子筛ssz-105、其合成及用途
US10272423B2 (en) * 2015-10-16 2019-04-30 Chevron U.S.A. Inc. Processes using molecular sieve SSZ-105
BR112018010271A2 (pt) * 2015-12-04 2018-11-27 Exxonmobil Research And Engineering Company material cristalino sintético emm-28, sua preparação e uso
US9663377B1 (en) * 2015-12-09 2017-05-30 Chevron U.S.A. Inc. Synthesis of molecular sieve SSZ-105
GB2551871A (en) * 2016-04-22 2018-01-03 Johnson Matthey Plc STA-18, A new member of the SFW family of molecular sieve zeotypes, methods of preparation and use
CN109195911B (zh) 2016-05-23 2023-04-07 东曹株式会社 Cha型沸石和其制造方法
JP2018079428A (ja) * 2016-11-17 2018-05-24 東ソー株式会社 炭化水素吸着剤及び炭化水素の吸着除去方法
WO2019082004A1 (en) * 2017-10-27 2019-05-02 Chevron U.S.A. Inc. MOLECULAR SIEVES SSZ-112, SA SYNTHESIS AND ITS USE
US11667536B2 (en) 2018-08-24 2023-06-06 Umicore Ag & Co. Kg Method for the preparation of a molecular sieve of the CHA-type
CN111099610B (zh) * 2018-10-25 2021-11-30 中国石油化工股份有限公司 Stf沸石分子筛的制备方法
EP3947284A1 (en) * 2019-03-28 2022-02-09 Johnson Matthey Public Limited Company Molecular sieve intergrowths ofcha
JP2022536736A (ja) 2019-06-13 2022-08-18 エコヴィスト・カタリスト・テクノロジーズ・リミテッド・ライアビリティ・カンパニー 有機テンプレートを用いたチャバザイトゼオライト合成
JP7624430B2 (ja) * 2019-07-09 2025-01-30 中国石油化工股▲ふん▼有限公司 ケイ素およびゲルマニウムに基づくｓｃｍ－２５モレキュラーシーブ、その製造方法、およびその使用
CN112573534B (zh) * 2019-09-29 2022-07-12 中国石油化工股份有限公司 一种non型分子筛及其制备方法和应用
JP7647063B2 (ja) * 2020-10-21 2025-03-18 東ソー株式会社 ４－アンモニオピぺリジニウム塩及びその用途
EP4247758A1 (en) 2020-11-20 2023-09-27 Ecovyst Catalyst Technologies LLC Chabazite zeolite synthesis with combined organic templates
CN114538461B (zh) * 2020-11-26 2023-08-08 中国科学院大连化学物理研究所 一种ssz-13硅铝分子筛及其制备方法与应用
CN114057208B (zh) * 2021-11-26 2023-06-30 中触媒新材料股份有限公司 一种双模板剂合成的cha型分子筛及应用其制备scr催化剂的方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070244341A1 (en) * 2006-04-17 2007-10-18 Kremer Sebastien P B Molecular sieves having micro and mesoporosity, their synthesis and their use in the organic conversion reactions
US20080045767A1 (en) * 2005-10-31 2008-02-21 Guang Cao Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
JP4596116B2 (ja) * 2002-05-24 2010-12-08 三菱瓦斯化学株式会社 ８酸素員環細孔を持つ結晶質シリコアルミノリン酸塩モレキュラーシーブ及びその製造方法、並びにそれを触媒とするメチルアミン類の製造方法
ITMI20061231A1 (it) * 2006-06-26 2007-12-27 Eni Spa Proxcesso e materiali zeolitici per la separazione di gas
US20090196812A1 (en) * 2008-01-31 2009-08-06 Basf Catalysts Llc Catalysts, Systems and Methods Utilizing Non-Zeolitic Metal-Containing Molecular Sieves Having the CHA Crystal Structure
EP2161243A1 (en) * 2008-08-29 2010-03-10 Total Petrochemicals Research Feluy Method for preparing metalloaluminophosphate (MeAPO) molecular sieves
JP6081460B2 (ja) * 2011-09-06 2017-02-15 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Ｎ，ｎ−ジメチル有機テンプレートを用いるゼオライト系材料の合成

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080045767A1 (en) * 2005-10-31 2008-02-21 Guang Cao Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins
US20070244341A1 (en) * 2006-04-17 2007-10-18 Kremer Sebastien P B Molecular sieves having micro and mesoporosity, their synthesis and their use in the organic conversion reactions

Also Published As

Publication number Publication date
ZA201402467B (en) 2016-06-29
EP2753579B1 (en) 2020-12-16
CN107021508B (zh) 2019-08-27
EP2753579A1 (en) 2014-07-16
WO2013035054A1 (en) 2013-03-14
CN107021508A (zh) 2017-08-08
CN103917493A (zh) 2014-07-09
JP2014530797A (ja) 2014-11-20
EP2753579A4 (en) 2015-08-19
JP6081460B2 (ja) 2017-02-15

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