CN103907649B - A kind of soil sterilization agricultural chemical compositions - Google Patents
A kind of soil sterilization agricultural chemical compositions Download PDFInfo
- Publication number
- CN103907649B CN103907649B CN201410153468.4A CN201410153468A CN103907649B CN 103907649 B CN103907649 B CN 103907649B CN 201410153468 A CN201410153468 A CN 201410153468A CN 103907649 B CN103907649 B CN 103907649B
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- China
- Prior art keywords
- carbendazim
- garlic oil
- filler
- soil
- mould spirit
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- 239000000203 mixture Substances 0.000 title claims abstract description 31
- 239000002689 soil Substances 0.000 title claims abstract description 21
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 12
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 11
- 239000003905 agrochemical Substances 0.000 title claims abstract description 8
- 239000010647 garlic oil Substances 0.000 claims abstract description 54
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000006013 carbendazim Substances 0.000 claims abstract description 43
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000000945 filler Substances 0.000 claims abstract description 29
- 239000000575 pesticide Substances 0.000 claims abstract description 11
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 4
- 239000004480 active ingredient Substances 0.000 claims abstract description 3
- 239000004562 water dispersible granule Substances 0.000 claims description 27
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 26
- 239000000080 wetting agent Substances 0.000 claims description 25
- 239000005995 Aluminium silicate Substances 0.000 claims description 13
- 235000012211 aluminium silicate Nutrition 0.000 claims description 13
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 13
- 239000004927 clay Substances 0.000 claims description 3
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical group OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 2
- 229960000892 attapulgite Drugs 0.000 claims description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims description 2
- 229910052625 palygorskite Inorganic materials 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 239000003921 oil Substances 0.000 claims 1
- 240000008067 Cucumis sativus Species 0.000 abstract description 11
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 abstract description 11
- 235000013311 vegetables Nutrition 0.000 abstract description 10
- 239000003814 drug Substances 0.000 abstract description 6
- 230000001018 virulence Effects 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 230000002265 prevention Effects 0.000 abstract description 4
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 2
- 230000001934 delay Effects 0.000 abstract description 2
- 229940079593 drug Drugs 0.000 abstract description 2
- 244000052769 pathogen Species 0.000 abstract description 2
- 230000001717 pathogenic effect Effects 0.000 abstract description 2
- 238000003786 synthesis reaction Methods 0.000 abstract description 2
- 239000004563 wettable powder Substances 0.000 description 37
- 239000000470 constituent Substances 0.000 description 11
- 238000002360 preparation method Methods 0.000 description 11
- 239000002994 raw material Substances 0.000 description 11
- -1 dislike mould spirit Substances 0.000 description 10
- 238000005469 granulation Methods 0.000 description 10
- 230000003179 granulation Effects 0.000 description 10
- 241000227653 Lycopersicon Species 0.000 description 5
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 5
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 4
- 241000223218 Fusarium Species 0.000 description 4
- 244000241257 Cucumis melo Species 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 235000002566 Capsicum Nutrition 0.000 description 2
- 240000008574 Capsicum frutescens Species 0.000 description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 2
- 244000061458 Solanum melongena Species 0.000 description 2
- 235000002597 Solanum melongena Nutrition 0.000 description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000001390 capsicum minimum Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 231100000989 no adverse effect Toxicity 0.000 description 2
- 240000002234 Allium sativum Species 0.000 description 1
- 244000036905 Benincasa cerifera Species 0.000 description 1
- 235000011274 Benincasa cerifera Nutrition 0.000 description 1
- 241000123650 Botrytis cinerea Species 0.000 description 1
- 244000241235 Citrullus lanatus Species 0.000 description 1
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 1
- 235000009847 Cucumis melo var cantalupensis Nutrition 0.000 description 1
- 244000302544 Luffa aegyptiaca Species 0.000 description 1
- 235000009814 Luffa aegyptiaca Nutrition 0.000 description 1
- 241000918585 Pythium aphanidermatum Species 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 235000004611 garlic Nutrition 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000009335 monocropping Methods 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of soil sterilization agricultural chemical compositions, the active ingredient of described composition pesticide by carbendazim, dislike mould spirit and garlic oil forms, described carbendazim, the weight percentage of disliking mould spirit and garlic oil be respectively carbendazim 5～30%, dislike mould clever 5～20% and garlic oil 5～20%, and all the other are auxiliary agent and filler. Soil sterilization agricultural chemical compositions provided by the invention, by carbendazim, to dislike mould spirit mixed with garlic oil, not only improve sterilization virulence, synergy, delay the resistance to the action of a drug, reduce chemical synthesis medicament consumption, also because garlic oil has higher sterilization virulence, in soil stifling bactericidal action strong, thereby synergy is more remarkable. The composition pesticide of the vegetables droops such as the control cucumber that the present invention proposes, can improve the prevention effect to droop, delays the resistance of pathogen to medicament, reduces cost accounting.
Description
Technical field
The present invention relates to pesticide field, particularly relate to a kind of soil sterilization agricultural chemical compositions and uses thereof.
Background technology
Cucumber fusarium axysporum [Fusariumosysporum (Schl.) f.sp.cucumerinumOwen] main harm HuangThe ground family crops such as melon, sponge gourd, watermelon, muskmelon, cucurbit, wax gourd, are caused by Botrytis cinerea how after cucumber blooms, to send out successivelyDisease, wilt sagging lateral lobe sheet noon that killed strain shows as partial blade or plant at first, like lack of water shape, wilting blade laterBe on the increase, spread all over gradually complete stool, and withered very soon, cause the underproduction. Along with the development of the facilities vegetable such as greenhouse, booth, especiallyThe generation that is the RADIX RAPHANI of continuous cropping protection for many years disease is day by day serious.
Summary of the invention
The object of the invention is to propose a kind of composition pesticide of preventing and treating the vegetables droops such as cucumber, to improve witheredSick prevention effect, delays the resistance of pathogen to medicament, reduces cost accounting.
Based on above-mentioned purpose, the active ingredient of a kind of soil sterilization agricultural chemical compositions provided by the invention by carbendazim,Dislike mould spirit and garlic oil composition, described carbendazim, the weight percentage of disliking mould spirit and garlic oil be respectively carbendazim 5～30%, dislike mould clever 5～20% and garlic oil 5～20%, all the other are auxiliary agent and filler.
Optionally, described carbendazim, the weight ratio of disliking mould spirit and garlic oil are 5 ~ 30:5～20:5～20.
Preferably, described carbendazim, the weight ratio of disliking mould spirit and garlic oil are 10 ~ 30:10～20:10～20.
Preferably, described carbendazim, the weight ratio of disliking mould spirit and garlic oil are 20:10:10.
Optionally, the processing formulation of described composition pesticide is wettable powder or water dispersible granules.
The present invention also provides a kind of purposes of soil sterilization agricultural chemical compositions, and described composition pesticide is harnessed the Yellow River for anti-The droop of the various vegetables such as melon, tomato.
As can be seen from above, composition pesticide provided by the invention, by carbendazim, to dislike mould spirit and garlic oil mixedWith, not only improve sterilization virulence, synergy, delay the resistance to the action of a drug, reduce chemical synthesis medicament consumption, also because garlic oil has higherSterilization virulence, in soil stifling bactericidal action strong, thereby Synergistic sterilizing effect is more remarkable.
Detailed description of the invention
For making the object, technical solutions and advantages of the present invention clearer, below in conjunction with specific embodiment 1 ~ 10 HeComparative example 1, the present invention is described in more detail.
It is 30% wettable powder or water dispersible granules that embodiment 1 is prepared with effective component content
Concrete proportioning is:
Raw material consumption (weight portion)
Carbendazim 10
Dislike mould clever 10
Garlic oil 10
Wetting agent 7
Filler complements to 100
Preparation method comprises: take carbendazim, dislike mould spirit, garlic oil, wetting agent, filler (white carbon, kaolin, siliconAlgae soil), first with white carbon, garlic oil is adsorbed, mix, then through air-flow crushing, be prepared into described active constituent content and be30% wettable powder. Wettable powder can be prepared into water dispersible granules through granulation.
It is 40% wettable powder or water dispersible granules that embodiment 2 is prepared with effective component content
Concrete proportioning is:
Raw material consumption (weight portion)
Carbendazim 20
Dislike mould clever 10
Garlic oil 10
Wetting agent 7
Filler complements to 100
Preparation method comprises: take carbendazim, dislike mould spirit, garlic oil, wetting agent, filler (white carbon, kaolin, siliconAlgae soil), first with white carbon, garlic oil is adsorbed, mix, then through air-flow crushing, be prepared into described active constituent content and be40% wettable powder. Wettable powder can be prepared into water dispersible granules through granulation.
It is 50% wettable powder or water dispersible granules that embodiment 3 is prepared with effective component content
Concrete proportioning is:
Raw material consumption (weight portion)
Carbendazim 20
Dislike mould clever 20
Garlic oil 10
Wetting agent 7
Filler complements to 100
Preparation method comprises: take carbendazim, dislike mould spirit, garlic oil, wetting agent, filler (white carbon, kaolin, siliconAlgae soil), first with white carbon, garlic oil is adsorbed, mix, then through air-flow crushing, be prepared into described active constituent content and be50% wettable powder. Wettable powder can be prepared into water dispersible granules through granulation.
It is 50% wettable powder or water dispersible granules that embodiment 4 is prepared with effective component content
Concrete proportioning is:
Raw material consumption (weight portion)
Carbendazim 20
Dislike mould clever 10
Garlic oil 20
Wetting agent 7
Filler complements to 100
Preparation method comprises: take carbendazim, dislike mould spirit, garlic oil, wetting agent, filler (white carbon, kaolin, siliconAlgae soil), first with white carbon, garlic oil is adsorbed, mix, then through air-flow crushing, be prepared into described active constituent content and be50% wettable powder. Wettable powder can be prepared into water dispersible granules through granulation.
It is 60% wettable powder or water dispersible granules that embodiment 5 is prepared with effective component content
Concrete proportioning is:
Raw material consumption (weight portion)
Carbendazim 20
Dislike mould clever 20
Garlic oil 20
Wetting agent 7
Filler complements to 100
Preparation method comprises: take carbendazim, dislike mould spirit, garlic oil, wetting agent, filler (white carbon, kaolin, siliconAlgae soil), first with white carbon, garlic oil is adsorbed, mix, then through air-flow crushing, be prepared into described active constituent content and be60% wettable powder. Wettable powder can be prepared into water dispersible granules through granulation.
It is 60% wettable powder or water dispersible granules that embodiment 6 is prepared with effective component content
Concrete proportioning is:
Raw material consumption (weight portion)
Carbendazim 30
Dislike mould clever 20
Garlic oil 10
Wetting agent 7
Filler complements to 100
Preparation method comprises: take carbendazim, dislike mould spirit, garlic oil, wetting agent, filler (white carbon, kaolin, siliconAlgae soil), first with white carbon, garlic oil is adsorbed, mix, then through air-flow crushing, be prepared into described active constituent content and be60% wettable powder. Wettable powder can be prepared into water dispersible granules through granulation.
It is 60% wettable powder or water dispersible granules that embodiment 7 is prepared with effective component content
Concrete proportioning is:
Raw material consumption (weight portion)
Carbendazim 30
Dislike mould clever 10
Garlic oil 20
Wetting agent 7
Filler complements to 100
Preparation method comprises: take carbendazim, dislike mould spirit, garlic oil, wetting agent, filler (white carbon, kaolin, siliconAlgae soil), first with white carbon, garlic oil is adsorbed, mix, then through air-flow crushing, be prepared into described active constituent content and be60% wettable powder. Wettable powder can be prepared into water dispersible granules through granulation.
It is 35% wettable powder or water dispersible granules that embodiment 8 is prepared with effective component content
Concrete proportioning is:
Raw material consumption (weight portion)
Carbendazim 20
Dislike mould clever 5
Garlic oil 10
Wetting agent 7
Filler complements to 100
Preparation method comprises: take carbendazim, dislike mould spirit, garlic oil, wetting agent, filler (white carbon, kaolin, siliconAlgae soil), first with white carbon, garlic oil is adsorbed, mix, then through air-flow crushing, be prepared into described active constituent content and be35% wettable powder. Wettable powder can be prepared into water dispersible granules through granulation.
It is 45% wettable powder or water dispersible granules that embodiment 9 is prepared with effective component content
Concrete proportioning is:
Raw material consumption (weight portion)
Carbendazim 30
Dislike mould clever 5
Garlic oil 10
Wetting agent 7
Filler complements to 100
Preparation method comprises: take carbendazim, dislike mould spirit, garlic oil, wetting agent, filler (white carbon, kaolin, siliconAlgae soil), first with white carbon, garlic oil is adsorbed, mix, then through air-flow crushing, be prepared into described active constituent content and be45% wettable powder. Wettable powder can be prepared into water dispersible granules through granulation.
It is 45% wettable powder or water dispersible granules that embodiment 10 is prepared with effective component content
Concrete proportioning is:
Raw material consumption (weight portion)
Carbendazim 30
Dislike mould clever 10
Garlic oil 5
Wetting agent 7
Filler complements to 100
Preparation method comprises: take carbendazim, dislike mould spirit, garlic oil, wetting agent, filler (white carbon, kaolin, siliconAlgae soil), first with white carbon, garlic oil is adsorbed, mix, then through air-flow crushing, be prepared into described active constituent content and be45% wettable powder. Wettable powder can be prepared into water dispersible granules through granulation.
It is 40.5% wettable powder or water dispersible granules that comparative example 1 is prepared with effective component content
Concrete proportioning is: (taking embodiment 2 carbendazim, dislike mould spirit and garlic oil preferred weight ratio 20:10:10 as reference,Not with garlic oil)
Raw material consumption (weight portion)
Carbendazim 27
Dislike mould clever 13.5
Garlic oil 0
Wetting agent 7
Filler complements to 100
Preparation method comprises: takes carbendazim, dislikes mould spirit, wetting agent, filler (white carbon, kaolin, diatomite), and mixedClose evenly, then through air-flow crushing, be prepared into described active constituent content and be 40.5% wettable powder. Wettable powder is through makingGrain can be prepared into water dispersible granules.
Optionally, described filler is selected from white carbon, kaolin, diatomite, attapulgite, potter's clay and clay at leastA kind of.
Alternatively, described wetting agent is selected from lauryl sodium sulfate, sodium lignin sulfonate, pulls open at least one in powder.
Field test proves, prevents and treats the vegetables droops such as booth vegetable or open country cucumber, tomato, capsicum, eggplant, with thisBright 40% carbendazim of making. dislike mould spirit. garlic oil wettable powder or water dispersible granules, consumption is 500g ~ 750g/667m2, effective ingredient consumption 250g ~ 375g/667m2, in the time of the vegetable transplanting such as cucumber, tomato, spread fertilizer over the fields in transplanting cave (ditch), rightThe prevention effect of droop reaches 83.8 ~ 92.4%, and survival rate of seedlings 100% can be controlled droop harm completely; Also can prevent and treat root rot,The multiple sprout term disease such as damping-off, has no adverse effect to vegetable growth. And under the same terms, in comparative example 1 not with garlic oilCarbendazim. dislike mould clever wettable powder or water dispersible granules, to the prevention effect of droop only 72 ~ 80%.
Above-mentioned composition pesticide for the using method of preventing and treating the vegetables such as cucumber, tomato droop is: cucumber, tomato,The planting season such as capsicum, eggplant, use 40% carbendazim. dislike mould spirit. garlic oil wettable powder or water dispersible granules, consumption is500g~750g/667m2, effective ingredient consumption 250g ~ 375g/667m2, impose on plantation ditch or plant in plant hole, then transplant or broadcastKind, vegetable growth is had no adverse effect, economic and social benefit is remarkable.
In order to further illustrate the feasibility of composition pesticide provided by the invention, below in conjunction with concrete test, to be total toPoison coefficient describes.
Table 1 carbendazim, dislike mould spirit co-toxicity to cucumber fusarium axysporum mixed with garlic oil.
Known by table 1, carbendazim, dislike that mould spirit is mixed with garlic oil has very high virulence to cucumber fusarium axysporum, eachProportioning synergistic effect is remarkable. When carbendazim, dislike mould spirit and garlic oil when composite with 4:2:1～2:2:4, to cucumber fusarium axysporumCo-toxicity coefficient reaches 128.1～155.5, and apparently higher than 120, synergistic effect is remarkable.
The foregoing is only specific embodiments of the invention, be not limited to the present invention, all in essence of the present inventionWithin god and principle, any amendment of making, be equal to replacement, improvement etc., within protection scope of the present invention all should be included in.
Claims (2)
1. a soil sterilization agricultural chemical compositions, is characterized in that: active ingredient by carbendazim, dislike mould spirit and garlic oil groupBecome, described carbendazim, the weight percentage of disliking mould spirit and garlic oil are respectively carbendazim 5～30%, dislike mould clever 5～20% andGarlic oil 5～20%, all the other are auxiliary agent and filler; Described carbendazim, the weight ratio of disliking mould spirit and garlic oil are 20:10:10; InstituteStating auxiliary agent and filler is filler and wetting agent, and described filler is selected from white carbon, kaolin, diatomite, attapulgite, potteryAt least one in soil and clay, described wetting agent is selected from lauryl sodium sulfate, sodium lignin sulfonate and pulls open in powder extremelyFew a kind of.
2. composition pesticide according to claim 1, is characterized in that: the processing formulation of described composition pesticide is particleAgent or water dispersible granules.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410153468.4A CN103907649B (en) | 2014-04-14 | 2014-04-14 | A kind of soil sterilization agricultural chemical compositions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410153468.4A CN103907649B (en) | 2014-04-14 | 2014-04-14 | A kind of soil sterilization agricultural chemical compositions |
Publications (2)
| Publication Number | Publication Date |
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| CN103907649A CN103907649A (en) | 2014-07-09 |
| CN103907649B true CN103907649B (en) | 2016-05-04 |
Family
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| CN201410153468.4A Active CN103907649B (en) | 2014-04-14 | 2014-04-14 | A kind of soil sterilization agricultural chemical compositions |
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Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107410373A (en) * | 2017-06-08 | 2017-12-01 | 合肥龙滨化工科技有限公司 | A kind of medicine for preventing and treating cucumber fusarium axysporum and preparation method thereof |
| CN107027824B (en) * | 2017-06-12 | 2019-09-10 | 福建省农业科学院植物保护研究所 | A kind of banana blight bacteria synergy composition containing Chinese medical extract and pesticide |
| CN107041389A (en) * | 2017-06-15 | 2017-08-15 | 程艳秋 | A kind of composition pesticide of promotion agro based economic development |
| CN107372671A (en) * | 2017-07-31 | 2017-11-24 | 句容市锦鸿家庭农场 | A kind of succulent soil fungicides and preparation method thereof |
| CN107372625A (en) * | 2017-08-11 | 2017-11-24 | 潍坊华诺生物科技有限公司 | A kind of soil fungicides of Han hymexazos and its application in planting lawn |
| CN108174876A (en) * | 2018-01-30 | 2018-06-19 | 安徽省厚博生态农业有限公司 | A kind of booth vegetable slow-release compound disinfectant and its preparation |
| CN108124716A (en) * | 2018-01-30 | 2018-06-08 | 安徽省厚博生态农业有限公司 | A kind of efficient implantation methods of ternip |
| CN109673405B (en) * | 2018-11-29 | 2021-04-02 | 青川县农村产业技术服务中心 | Planting management method of epimedium |
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|---|---|---|---|---|
| EP0945066A1 (en) * | 1998-03-26 | 1999-09-29 | Safergro Laboratories, Inc. | Natural pesticide containing garlic |
| CN102726415A (en) * | 2012-06-19 | 2012-10-17 | 河南省大地农化有限责任公司 | Allicin-containing prevention and treatment pesticide for crop plant diseases |
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|---|---|---|---|---|
| EP0945066A1 (en) * | 1998-03-26 | 1999-09-29 | Safergro Laboratories, Inc. | Natural pesticide containing garlic |
| CN102726415A (en) * | 2012-06-19 | 2012-10-17 | 河南省大地农化有限责任公司 | Allicin-containing prevention and treatment pesticide for crop plant diseases |
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| Title |
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| CN103907649A (en) | 2014-07-09 |
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