CN102792952B - Bactericide composition for preventing and controlling cotton disease - Google Patents
Bactericide composition for preventing and controlling cotton disease Download PDFInfo
- Publication number
- CN102792952B CN102792952B CN201210335438.6A CN201210335438A CN102792952B CN 102792952 B CN102792952 B CN 102792952B CN 201210335438 A CN201210335438 A CN 201210335438A CN 102792952 B CN102792952 B CN 102792952B
- Authority
- CN
- China
- Prior art keywords
- cotton
- composition
- agent
- bactericide composition
- preventing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920000742 Cotton Polymers 0.000 title claims abstract description 47
- 239000000203 mixture Substances 0.000 title claims abstract description 31
- 201000010099 disease Diseases 0.000 title abstract description 16
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 title abstract description 16
- 230000000844 anti-bacterial effect Effects 0.000 title abstract description 11
- 239000003899 bactericide agent Substances 0.000 title abstract description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 46
- 241000894006 Bacteria Species 0.000 claims abstract description 23
- 150000001408 amides Chemical class 0.000 claims abstract description 23
- 229910052731 fluorine Inorganic materials 0.000 claims description 21
- 239000011737 fluorine Substances 0.000 claims description 21
- 230000003641 microbiacidal effect Effects 0.000 claims description 10
- 229940124561 microbicide Drugs 0.000 claims description 10
- 239000002855 microbicide agent Substances 0.000 claims description 10
- 239000004480 active ingredient Substances 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 125000001153 fluoro group Chemical group F* 0.000 claims description 2
- 239000000945 filler Substances 0.000 abstract description 16
- 239000000080 wetting agent Substances 0.000 abstract description 16
- 239000002270 dispersing agent Substances 0.000 abstract description 9
- 208000031888 Mycoses Diseases 0.000 abstract description 8
- 241000918585 Pythium aphanidermatum Species 0.000 abstract description 7
- 235000013311 vegetables Nutrition 0.000 abstract description 5
- 239000005843 Thiram Substances 0.000 abstract description 4
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 abstract description 4
- 229960002447 thiram Drugs 0.000 abstract description 4
- 239000000375 suspending agent Substances 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 239000004562 water dispersible granule Substances 0.000 abstract description 2
- 239000004563 wettable powder Substances 0.000 abstract description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 2
- 235000004391 Chenopodium capitatum Nutrition 0.000 abstract 1
- 244000038022 Chenopodium capitatum Species 0.000 abstract 1
- 206010059866 Drug resistance Diseases 0.000 abstract 1
- 244000052616 bacterial pathogen Species 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 230000007246 mechanism Effects 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 241000219146 Gossypium Species 0.000 description 40
- 239000000843 powder Substances 0.000 description 21
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
- 238000009736 wetting Methods 0.000 description 14
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 7
- 241000223218 Fusarium Species 0.000 description 7
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical group OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 7
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical group [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 238000009472 formulation Methods 0.000 description 5
- 238000010298 pulverizing process Methods 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 241000220223 Fragaria Species 0.000 description 4
- 235000016623 Fragaria vesca Nutrition 0.000 description 4
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- 244000052769 pathogen Species 0.000 description 2
- 230000001717 pathogenic effect Effects 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- MKVUDWRGFJUDQZ-UHFFFAOYSA-N C(C1=CC=CC=C1)(=O)N.[F] Chemical class C(C1=CC=CC=C1)(=O)N.[F] MKVUDWRGFJUDQZ-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241000233654 Oomycetes Species 0.000 description 1
- 241000082085 Verticillium <Phyllachorales> Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- DNJKFZQFTZJKDK-UHFFFAOYSA-N fluopimomide Chemical compound FC1=C(F)C(OC)=C(F)C(F)=C1C(=O)NCC1=NC=C(C(F)(F)F)C=C1Cl DNJKFZQFTZJKDK-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
Images
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a bactericide composition for preventing and controlling cotton disease. The bactericide composition is a composition of wettable powder, suspending agent, water dispersible granule or seed coating, which is prepared from fluoride ether bacteria amide, thiram and auxiliaries of wetting agent, dispersing agent, filling agent and the like. The fluoride ether bacteria amide and the thiram are mixed by the proportion of 1:4 to 4:1 and the combination of two bactericides with different bactericidal action mechanisms not only plays an obvious synergistic effect for cotton blight, but also is helpful for postponing the drug resistance of pathogenic bacteria. The bactericidal range is wide. The bactericide composition provided by the invention is applicable to prevention and control of various fungal diseases of crops, such as cotton blight, cotton damping off, cotton anthracnose, vegetable root rot and damping off and strawberry blight.
Description
Technical field
The present invention relates to a kind of bactericide, specifically the microbicide compositions of a kind of control cotton disease (especially fusarium wilt).It is suitable for preventing and treating the multiple fungal diseases such as cotton wilt, cotton seedling blight, cotton anthracnose, vegetable root rot and damping off, strawberry fusarium wilt.
Background technology
Fluorine ether bacterium acid amides (LH-2010A), that Shandong United Pesticide Industry Co., Ltd. cooperates with Shandong Agricultural University, in the synthetic a kind of novel fluorine benzamide series bactericidal agent of innovation in 2010, chemical name: N-(the chloro-5-(trifluoromethyl of 3-) pyridine-2-methyl)-2,3,5,6-tetrafluoro-4-methoxy benzamide.It has very high biologically active to Oomycete fungi germ, has protection and therapeutic action.Fluorine ether bacterium acid amides has stronger interior absorption.Can absorb by cauline leaf, by plant bottom, to upper direction, be conducted, along plant xylem, to whole strain crop, distribute.Its structural formula is:
The organosulfureous fungicide of a kind of broad spectrum protection of tmtd (Thiram), has good control efficiency to various crop damping off, anthracnose and fusarium wilt.
Cotton is the important economic crops of China, in the whole growing process of cotton, multiple diseases usually occurs, as cotton wilt, cotton verticillium wilt, cotton seedling blight, cotton anthracnose etc.The disease of cotton is perplexing the development of cotton planting industry, particularly cotton wilt always and spread rapidly in recent years and developed for many years, and the output of cotton and quality have been caused to great impact.The medicine that has on the market at present multiple control cotton disease, have not been reported but fluorine ether bacterium acid amides and tmtd are carried out to composite control cotton disease.
Summary of the invention
The object of this invention is to provide a kind of microbicide compositions of preventing and treating cotton disease, said composition is suitable for preventing and treating the multiple fungal diseases such as cotton wilt, cotton seedling blight, cotton anthracnose, vegetable root rot and damping off, strawberry fusarium wilt, bactericidal action wide spectrum, using value is large, and economic and social benefit is very remarkable.
Technical scheme of the present invention is: a kind of microbicide compositions of preventing and treating cotton disease, it is characterized in that, and comprise active ingredient and auxiliary agent, active ingredient is fluorine ether bacterium acid amides and tmtd, and its mass ratio is 1:4 ~ 4:1, and the total content of active ingredient is 10%-60%.
The present invention can use the auxiliary agents such as wetting agent, filler, by conventional method, above-mentioned microbicide compositions is processed into suspending agent, water dispersible granules, wetting powder and seed coat agent.Wherein applying more is wetting powder.The component of described wetting powder is: fluorine ether bacterium acid amides, tmtd, filler, wetting agent and dispersant; Wherein wetting agent is lauryl sodium sulfate and pulls open powder, and dispersant is sodium lignin sulfonate, and filler is white carbon and diatomite.
The optimum ratio of above-mentioned wetting powder is (weight ratio): fluorine ether bacterium acid amides 25%, and tmtd 25%, filler white carbon 15%, filler diatomite 23%, wetting agent lauryl sodium sulfate 4%, wetting agent pulls open powder 3%, dispersant sodium lignin sulfonate 5%.
The present invention also provides a kind of method of using above-mentioned microbicide compositions control cotton wilt and various plants fungal disease.The method is in cotton's seeding time seed dressing, seed coat agent dressing, soil treatment, or when crop growth period disease just occurs, adds water and be made into suspension liquid irrigating root and use.
The invention has the beneficial effects as follows: the present invention is mixed by 1: 4～4: 1 with tmtd by fluorine ether bacterium acid amides; systemic fungicide and protectant combine; not only cotton-wilt fusarium is had to remarkable synergistic effect; also can be efficient to the multiple fungal disease on cotton, and can delay the resistance of pathogen to medicament.The present invention is suitable for preventing and treating the multiple fungal diseases such as cotton wilt, cotton seedling blight, cotton anthracnose, vegetable root rot and damping off, strawberry fusarium wilt, bactericidal action wide spectrum, and using value is large, and economic and social benefit is very remarkable.Said composition of the present invention is as shown in table 1 below to the control efficiency of cotton wilt.
Table 1 fluorine ether bacterium acid amides and tmtd composition are filled with the effect of root field control cotton wilt
* in table, data are added up through duncan's new multiple range method, containing same letter person, are that difference is not remarkable
The present invention be take fluorine ether bacterium acid amides and tmtd and when cotton growing stage disease just occurs, is prevented and treated as 50% fluorine ether bacterium acid amides wetting powder, 50% thiram wettable powder, 50% fluorine ether bacterium acid amides+tmtd (1:4) wetting powder and 50% fluorine ether bacterium acid amides+tmtd (1:1) wetting powder of active ingredient processing.Two single doses are compared with two mixed composite preparations, composition is under the working concentration of 4000 times of dilutions, the effect of field control cotton wilt is all significantly greater than the preventive effect of 1000 times of tmtd in intermixture dilutions, and higher than the preventive effect (table 1) of 4000 times of alone 50% fluorine ether bacterium acid amides wetting powders, show that fluorine ether bacterium acid amides and tmtd composition are more suitable for field control cotton wilt, and can doublely control other diseases, also can delay pathogen the resistance of fluorine ether bacterium acid amides is occurred.
Accompanying drawing explanation
Fig. 1 is the microbicide compositions processing process figure that the present invention prevents and treats cotton disease.
Embodiment
The wetting powder of the microbicide compositions of the control cotton disease the present invention relates to can be by example 1, example 2 and example 3, be specifically described, but is not limited to this.
Embodiment 1:
Proportioning (weight ratio): fluorine ether bacterium acid amides 10%, tmtd 40%, filler white carbon 15%, filler diatomite 23%, wetting agent lauryl sodium sulfate 4%, wetting agent pulls open powder 3%, dispersant sodium lignin sulfonate 5%.
Preparation method: above composition is all weighed by weight, mixed and pulverizing is prepared into wetting powder formulation.Above raw material is commercially available qualified products.
Embodiment 2:
Proportioning (weight ratio): fluorine ether bacterium acid amides 15%, tmtd 35%, filler white carbon 15%, filler diatomite 23%, wetting agent lauryl sodium sulfate 4%, wetting agent pulls open powder 3%, dispersant sodium lignin sulfonate 5%.
Preparation method: above composition is all weighed by weight, mixed and pulverizing is prepared into wetting powder formulation.Above raw material is commercially available qualified products.
Embodiment 3:
Proportioning (weight ratio): fluorine ether bacterium acid amides 20%, tmtd 30%, filler white carbon 15%, filler diatomite 23%, wetting agent lauryl sodium sulfate 4%, wetting agent pulls open powder 3%, dispersant sodium lignin sulfonate 5%.
Preparation method: above composition is all weighed by weight, mixed and pulverizing is prepared into wetting powder formulation.Above raw material is commercially available qualified products.
Embodiment 4:
Proportioning (weight ratio): fluorine ether bacterium acid amides 25%, tmtd 25%, filler white carbon 15%, filler diatomite 23%, wetting agent lauryl sodium sulfate 4%, wetting agent pulls open powder 3%, dispersant sodium lignin sulfonate 5%.
Preparation method: above composition is all weighed by weight, mixed and pulverizing is prepared into wetting powder formulation.Above raw material is commercially available qualified products.
Embodiment 5:
Proportioning (weight ratio): fluorine ether bacterium acid amides 40%, tmtd 10%, filler white carbon 15%, filler diatomite 23%, wetting agent lauryl sodium sulfate 4%, wetting agent pulls open powder 3%, dispersant sodium lignin sulfonate 5%.
Preparation method: above composition is all weighed by weight, mixed and pulverizing is prepared into wetting powder formulation.Above raw material is commercially available qualified products.
Use the method for above-mentioned composition pesticide control cotton wilt and other fungal diseases to be, in cotton's seeding time seed dressing, seed coat agent dressing, soil treatment, or when crop growth period disease just occurs, add water and be made into suspension liquid irrigating root and use, be used for preventing and treating the multiple kinds of crops fungal diseases such as cotton wilt, cotton seedling blight, cotton anthracnose, vegetable root rot and damping off, strawberry fusarium wilt, bactericidal action wide spectrum, using value is large, and economic and social benefit is very remarkable.
Claims (1)
1. the microbicide compositions application in control cotton wilt, it is characterized in that, described microbicide compositions comprises active ingredient and auxiliary agent, and active ingredient is fluorine ether bacterium acid amides and tmtd, its mass ratio is 1:1 ~ 4, and the total content of active ingredient is 10%-60%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210335438.6A CN102792952B (en) | 2012-09-12 | 2012-09-12 | Bactericide composition for preventing and controlling cotton disease |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210335438.6A CN102792952B (en) | 2012-09-12 | 2012-09-12 | Bactericide composition for preventing and controlling cotton disease |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102792952A CN102792952A (en) | 2012-11-28 |
| CN102792952B true CN102792952B (en) | 2014-02-12 |
Family
ID=47192459
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210335438.6A Expired - Fee Related CN102792952B (en) | 2012-09-12 | 2012-09-12 | Bactericide composition for preventing and controlling cotton disease |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102792952B (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103070196A (en) * | 2012-12-12 | 2013-05-01 | 丹东天祥农药有限公司 | Ternary efficient bactericide for rice in seedling stage |
| CN104413019B (en) * | 2013-09-02 | 2018-08-03 | 张通 | A kind of pesticide composition containing fluoxetrol |
| CN104412998B (en) * | 2013-09-02 | 2018-08-03 | 张通 | A kind of efficient bactericidal composite of fluorine-containing ether bacterium amide |
| CN104413031B (en) * | 2013-09-02 | 2018-08-03 | 张通 | A kind of compound pesticide composition containing fluorobactam |
| CN108849906A (en) * | 2013-09-02 | 2018-11-23 | 张通 | A kind of combination sterilization composition of fluorine-containing ether bacterium amide |
| CN104412990B (en) * | 2013-09-03 | 2018-10-26 | 张通 | A kind of bactericidal composition of fluorine-containing ether bacterium amide |
| CN104413047A (en) * | 2013-09-03 | 2015-03-18 | 张通 | Pesticide composition containing fluoride ether bacterium amide and triazoles |
| CN105660648B (en) * | 2014-11-19 | 2018-06-01 | 山东棉花研究中心 | A kind of microbicide compositions for preventing cotton bell disease |
| CN104655782B (en) * | 2015-03-12 | 2016-07-06 | 崔淑华 | The assay method of fluorine ether bacterium amide residual quantity in a kind of vegetable and fruit |
| CN105028528B (en) * | 2015-09-02 | 2017-10-13 | 刘淑静 | A kind of agricultural chemicals for preventing and treating cotton anthracnose |
| CN106973927A (en) * | 2017-04-12 | 2017-07-25 | 江苏金凤凰农化有限公司 | A kind of composition and application process that cotton boll rot disease is treated based on guaiacol |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101637169A (en) * | 2009-09-08 | 2010-02-03 | 陕西先农生物科技有限公司 | Tebuconazole-thiram sterilizer composition |
| CN102086173A (en) * | 2010-09-07 | 2011-06-08 | 唐剑峰 | Tetrafluorophenoxy nicotinamide compound as well as preparation method and application thereof for sterilizing |
-
2012
- 2012-09-12 CN CN201210335438.6A patent/CN102792952B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101637169A (en) * | 2009-09-08 | 2010-02-03 | 陕西先农生物科技有限公司 | Tebuconazole-thiram sterilizer composition |
| CN102086173A (en) * | 2010-09-07 | 2011-06-08 | 唐剑峰 | Tetrafluorophenoxy nicotinamide compound as well as preparation method and application thereof for sterilizing |
Non-Patent Citations (2)
| Title |
|---|
| 宋国春等.福美双在棉花及土壤中残留量分析方法.《农药科学与管理》.2000,第21卷(第05期),13-14，23. |
| 福美双在棉花及土壤中残留量分析方法;宋国春等;《农药科学与管理》;20001015;第21卷(第05期);13-14，23 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102792952A (en) | 2012-11-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102792952B (en) | Bactericide composition for preventing and controlling cotton disease | |
| CN103907649A (en) | Soil bactericide pesticide composite | |
| CN101347116A (en) | Complex pesticide of osthole and agricultural antibiotic and uses thereof | |
| WO2019012541A1 (en) | Microbial composition and methods of use thereof | |
| CN105145640A (en) | Sterilizing composite containing trichoderma harzianum | |
| CN104186524B (en) | Containing the bactericidal composition of poly hexamethylene biguanide or its salt | |
| CN103988856B (en) | A kind of soil fungicides composition of fluorine-containing ether bacterium acid amides | |
| CN108812673A (en) | A kind of composition pesticide of fluorine-containing ether bacterium amide | |
| CN107372548A (en) | Composition pesticide containing captan and fluorine azoles ring bacterium amine and application thereof | |
| CN104145961B (en) | Containing the composition of S-Ethyl ethylthio sulfonate and dithianon | |
| CN103931626B (en) | Bactericidal composition containing chitosan oligosaccharide | |
| CN103988847B (en) | Bactericidal composition containing chitosan oligosaccharide and dithiocyano-methane | |
| CN102177900A (en) | Formula and using method of novel bactericide for preventing and treating rice blast | |
| CN103081920A (en) | Sterilizing composition containing penconazole | |
| CN106614587A (en) | Bactericidal composition containing trifloxystrobin and dithianon | |
| CN108990992B (en) | Sterilization composition containing pyraoxystrobin and mancozeb | |
| CN107318865A (en) | The composition pesticide of captan and furametpyr compounding | |
| CN107047563A (en) | A kind of bactericidal composition for preventing and treating Zizyphus maurtiana powdery mildew | |
| CN107372505A (en) | A kind of bactericidal composition and application containing bromothalonil and S-Ethyl ethylthio sulfonate | |
| CN104472507B (en) | A kind of Bactericide composition preventing and treating soil-borne disease | |
| CN106689131A (en) | Fungicidal composition containing chitin substance and bromothalonil | |
| CN104082296B (en) | Bactericidal composition containing chitosan oligosaccharide and mandipropamid | |
| CN105638686B (en) | A kind of combination sterilization composition containing tiger glue adipic acid copper | |
| CN103975923B (en) | A kind of agricultural bactericidal composition | |
| CN104996445A (en) | Fenpyrazamine-containing sterilization composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140212 Termination date: 20200912 |