CN103891764A - Fipronil compound pesticide - Google Patents

Fipronil compound pesticide Download PDF

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Publication number
CN103891764A
CN103891764A CN201210583862.2A CN201210583862A CN103891764A CN 103891764 A CN103891764 A CN 103891764A CN 201210583862 A CN201210583862 A CN 201210583862A CN 103891764 A CN103891764 A CN 103891764A
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CN
China
Prior art keywords
solvent
emulsifier
polyoxyethylene
percentage
pesticide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201210583862.2A
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Chinese (zh)
Inventor
黄艳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Jinlianxin Trading Co Ltd
Original Assignee
Qingdao Jinlianxin Trading Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Qingdao Jinlianxin Trading Co Ltd filed Critical Qingdao Jinlianxin Trading Co Ltd
Priority to CN201210583862.2A priority Critical patent/CN103891764A/en
Publication of CN103891764A publication Critical patent/CN103891764A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a fipronil compound pesticide which is characterized by comprising the following components in percentage by weight: 5-10% of fipronil, 40-50% of trichlorfon, 5% of emamectin benzoate, 5% of emulsifier and the balance of solvent. The solvent is selected from xylene, water or dichloromethane. The assistant comprises an emulsifier selected from one or more of nonylphenol polyethenoxy ether, calcium alkylphenylsulfate and phenethylphenyl polyoxyethylene-polyoxypropylene ether. The composition has obvious synergistic effect and widens the pesticidal spectrum, and pests can not easily generate drug resistance.

Description

A kind of Firponil compounded pesticide
Technical field
The present invention relates to a kind of Firponil compounded pesticide, belong to technical field of pesticide.
Background technology
Ethiprole (Frontline, Fipronil), chemical name: 5-amino-1-(2,6-dichlor-4-trifluoromethyl phenyl)-4-trifluoromethyl sulfinyl pyrazole-3-nitrile, Insecticidal pyrazolines, is broad spectrum insecticide, and rice borer insects, plant hopper are all had to preventive effect.It has concurrently and tags and certain systemic action take stomach poison function as main, and the lasting period is long, lower toxicity agricultural chemicals in genus, but easily make pest develop immunity to drugs.In use procedure, there is slow (and quick-acting is poor) of drug effect, in the medicament of control rice borer insects, bad to paddy stem borer effect, and price is higher.
Practice shows, by heterogeneous agricultural chemicals phase mixture, make built agent, can effect complementation, multimachine reason desinsection, expands desinsection scope, reduce pesticide resistance, improve integrated control benefit, built agent is better compared with single dose pesticides application prospect, especially has the built agent of the advantages such as consumption is few, insecticidal spectrum is wide, residual quantity is low, use is safe.Research and develop the insecticidal compound agent of high-efficiency environment friendly of new generation, for preventing and treating paddy rice, vegetables and other piercing mouth parts class insect, can reach expection insecticidal effect, environmental protection again, health, be the problem that current people extensively study.
Summary of the invention
For the deficiencies in the prior art, technical problem to be solved by this invention is, a kind of Firponil compounded pesticide is provided, and the deficiency using to overcome ethiprole agricultural chemicals single dose expands desinsection scope, reduces pesticide resistance, improves integrated control benefit.
For solving the problems of the technologies described above, the technical solution adopted in the present invention is: a kind of Firponil compounded pesticide, and its percentage by weight consists of:
Ethiprole: 5-10%, Dipterex: 40-50%; First dimension salt 5%, emulsifier 5%, surplus is solvent;
Described solvent is selected from dimethylbenzene, water or carrene;
Described auxiliary agent comprises emulsifier, is selected from one or more in polyoxyethylene nonylphenol ether, alkylbenzene calcium sulphate, phenethyl phenyl polyoxyethylene-polyethenoxy ether.
Preferred above-mentioned Firponil compounded pesticide, its percentage by weight consists of:
Ethiprole: 5%, Dipterex: 45%; First dimension salt 5%, the mixture 5% of alkylbenzene calcium sulphate and polyoxyethylene nonylphenol ether, phenethyl phenyl polyoxyethylene-polyethenoxy ether, surplus is water.
Equipment involved in the present invention is pesticide industry conventional equipment.Various former medicine involved in the present invention is commercially available prod, the current domestic production that all has, and the content of described various components is pure effective ingredient consumption.Wherein: chlorophos formal name used at school O, O-dimethyl-(the chloro-1-hydroxyethyl of 2,2,2-tri-) phosphonate ester, is a kind of organophosphorus insecticide.Industrial products are white solid, 83~84 ℃ of sterling fusing points, and the water-soluble and organic solvent of energy, character is more stable, is hydrolyzed into dichlorvos, acute toxicity LD50 value: big white mouse per os is 560~630mg/kg but meet alkali.
Present composition insecticide, belongs to low-toxin farm chemicals, is applicable to silkworm and mulberry area.Its each component mode of action has very strong complementarity, does not have antagonism, and its synergy is obvious, has expanded insecticidal spectrum, and insect is difficult for developing immunity to drugs.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described.
Embodiment 1
The equipment that the present embodiment uses is pesticide industry conventional equipment, and compound process is: by proportioning, Dipterex is put into container and adds ethiprole, first dimension salt, solvent, emulsifier, stir full and uniform after, carry out effective substance, last packing.
The Firponil compounded pesticide of the present embodiment, its percentage by weight consists of:
Ethiprole: 10%; Dipterex: 40%; First dimension salt 5%, polyoxyethylene nonylphenol ether 5%, surplus is dimethylbenzene; The product forms of the present embodiment is missible oil.
Embodiment 2
Mode of operation is with embodiment 1, and its difference is, this Firponil compounded pesticide, and its percentage by weight consists of:
Ethiprole: 5%; Dipterex: 50%; First dimension salt 5%, the mixture 5% of alkylbenzene calcium sulphate and phenethyl phenyl polyoxyethylene-polyethenoxy ether, surplus is water; The product forms of the present embodiment is aqueous emulsion.
Embodiment 3
Mode of operation is with embodiment 1, and its difference is, this Firponil compounded pesticide, and its percentage by weight consists of:
Ethiprole: 5%, Dipterex: 45%; First dimension salt 5%, the mixture 5% of alkylbenzene calcium sulphate and polyoxyethylene nonylphenol ether, phenethyl phenyl polyoxyethylene-polyethenoxy ether, surplus is water.The product forms of the present embodiment is aqueous emulsion.
Above-mentioned pesticide control rice-stem borer effect reaches more than 95%, prevents and treats paddy stem borer effect 85-90%, the control efficiency such as cabbage caterpillar on control Chinese cabbage, radish, muskmelon, eggplant, beet armyworm, diamond-back moth, daikon leaf beetle, striped flea-beetle, sulphur thrips all, more than 95%, also have good control efficiency to the insect on fruit tree, tealeaves.

Claims (2)

1. a Firponil compounded pesticide, is characterized in that: its percentage by weight consists of:
Ethiprole: 5-10%, Dipterex: 40-50%; First dimension salt 5%, emulsifier 5%, surplus is solvent;
Described solvent is selected from dimethylbenzene, water or carrene;
Described auxiliary agent comprises emulsifier, is selected from one or more in polyoxyethylene nonylphenol ether, alkylbenzene calcium sulphate, phenethyl phenyl polyoxyethylene-polyethenoxy ether.
2. Firponil compounded pesticide according to claim 1, is characterized in that: its percentage by weight consists of:
Ethiprole: 5%, Dipterex: 45%; First dimension salt 5%, the mixture 5% of alkylbenzene calcium sulphate and polyoxyethylene nonylphenol ether, phenethyl phenyl polyoxyethylene-polyethenoxy ether, surplus is water.
CN201210583862.2A 2012-12-30 2012-12-30 Fipronil compound pesticide Pending CN103891764A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210583862.2A CN103891764A (en) 2012-12-30 2012-12-30 Fipronil compound pesticide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210583862.2A CN103891764A (en) 2012-12-30 2012-12-30 Fipronil compound pesticide

Publications (1)

Publication Number Publication Date
CN103891764A true CN103891764A (en) 2014-07-02

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201210583862.2A Pending CN103891764A (en) 2012-12-30 2012-12-30 Fipronil compound pesticide

Country Status (1)

Country Link
CN (1) CN103891764A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101019550A (en) * 2006-08-16 2007-08-22 通州正大农药化工有限公司 Pesticide composition of trichlorfon and fipronil
CN101151970A (en) * 2006-09-25 2008-04-02 山东京博控股发展有限公司 Fipronil insecticidal composition

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101019550A (en) * 2006-08-16 2007-08-22 通州正大农药化工有限公司 Pesticide composition of trichlorfon and fipronil
CN101151970A (en) * 2006-09-25 2008-04-02 山东京博控股发展有限公司 Fipronil insecticidal composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
程英 等: "杀虫剂复配对小菜蛾幼虫的室内毒力测定", 《贵州农业科学》, vol. 39, no. 12, 31 December 2011 (2011-12-31), pages 139 - 141 *

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Application publication date: 20140702