CN103503903A - High-efficiency insecticidal composition containing dicyclanil - Google Patents

High-efficiency insecticidal composition containing dicyclanil Download PDF

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Publication number
CN103503903A
CN103503903A CN201210199143.0A CN201210199143A CN103503903A CN 103503903 A CN103503903 A CN 103503903A CN 201210199143 A CN201210199143 A CN 201210199143A CN 103503903 A CN103503903 A CN 103503903A
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cga
active component
weight ratio
composition containing
tolfenpyrad
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张秋芳
赵娇
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Shanxi Thompson Biological Technology Co Ltd
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Shanxi Thompson Biological Technology Co Ltd
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Priority to CN201210199143.0A priority Critical patent/CN103503903A/en
Priority to CN201610289243.0A priority patent/CN105941409B/en
Publication of CN103503903A publication Critical patent/CN103503903A/en
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10—Sulfones; Sulfoxides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a high-efficiency insecticidal composition containing dicyclanil. The high-efficiency insecticidal composition contains an active component A and an active component B, wherein the active component A is selected from dicyclanil, and the active component B is selective from any one of flonicamid, cyantraniliprole, tolfenpyrad, sulfoxaflor, flubendiamide and chlorantraniliprole, and a weight ratio of the active component A to the active component B is 1:80-60:1. The composition provided by the invention has a synergy effect on a plurality of insects which is harm to agricultural production, reduces pesticide dose, reduces pesticide residual on crops, mitigates environment pollution, and has good compatibility on environment. It is difficult for the insects to generate resistance.

Description

A kind of efficient insecticide composition containing CGA 183893
Technical field
The invention belongs to technical field of pesticide, relate to the application of a kind of efficient insecticide composition containing CGA 183893 on crop pests.
Background technology
CGA 183893 (dicyclanil) chemical name: 4,6-diaminourea-2-cyclopropylamino pyrimidine-5-nitrile, molecular formula: C 8h 10n 6.The decortication of CGA 183893 interference insect, after being absorbed, stops larvae pupation or becomes worm by insect genital system.
Flonicamid (Flonicamid) chemical name: N-cyanogen methyl-4-(trifluoromethyl) vitamin PP, molecular formula: C 9h 6f 3n 3o.Flonicamid is tagged and stomach poison function except having, and also has good never poison and quick Antifeedant Effects.
The bromo-1-of bromine cyanogen insect amide (Cyantraniliprole) chemical name: 3-(3-chloro-2-pyridyl)-N-[4-cyano group-2-methyl-6-[(methylamino) hydroxyl] phenyl]-1H-pyrazoles-5-formamide, molecular formula: C 19h 14brClN 6o 2.Bromine cyanogen insect amide is pest control by the ryanodine receptor of activation target pest.The activation of ryanodine receptor can discharge the calcium ion of storing in striated muscle and smooth muscle cell, and result causes damaging muscular movement adjusting, paralysis, finally insect is dead.
The chloro-3-ethyl-1-of Tolfenpyrad (Tolfenpyrad) chemical name: 4-methyl-N-[4-(p-tolyl oxygen base) phenyl] pyrazoles-5-acid amides, molecular formula: C 21h 22clN 3o 2.The main mechanism of Tolfenpyrad is the oxidative phosphorylation that stops insect, also has ovicidal, presses down food, oviposition deterrence and bactericidal action.
Fluorine pyridine worm amine nitrile (sulfoxaflor) chemical name: [1-6-(trifluoromethyl) pyridin-3-yl] ethyl]-λ 4-sulfydryl cyanamide, molecular formula: C 10h 10f 3n 3oS.Fluorine pyridine worm amine nitrile is sulfimide insecticide, and sulfimide acts on the nervous system of insect, acts on binding site unique in choline receptor and brings into play insecticidal function.
The iodo-N ＇ of fipronil bisamide (Flubendiamide) chemical name: 3--(2-mesyl-1,1-dimethyl ethyl group-N-{4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl) ethyl]-0-tolyl } phthalamide, molecular formula: C 23h 22f 7iN 2o 4s.Fipronil bisamide belongs to Novel ortho benzenedicarboxamide insecticides, activates calcium release channel in blue Buddhist nun's alkali recipient cell, causes the property out of control of storing calcium ion to discharge.
The bromo-N-[4-chloro-2-methyl-6-[(of Rynaxypyr (Ahlorantraniliprole) chemical name: 3-methyl-carbamoyl) benzene]-1-(3-chloropyridine-2-yl)-1-hydrogen-pyridine-5-formamide, molecular formula: C 18h 14n 5o 2brCl 2.Rynaxypyr belongs to O-formammidotiazol-benzamide insecticide.Be mainly the blue Buddhist nun's alkali acceptor of activation, discharge the calcium ion of storing in smooth muscle and striated muscle cell, cause that muscle adjusting is weak, benumb until last insect is dead.
Yet in the real process of agricultural production, the problem that pest control the most easily produces is the generation of pest resistance to insecticide.Different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals is all additive effect, really has the seldom composite of synergistic effect, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Through inventor's research, after discovery is composite by CGA 183893 and flonicamid, bromine cyanogen insect amide, Tolfenpyrad, fluorine pyridine worm amine nitrile, fipronil bisamide, Rynaxypyr, can produce good synergistic effect, and not yet open about the composite relevant report of CGA 183893 and flonicamid, bromine cyanogen insect amide, Tolfenpyrad, fluorine pyridine worm amine nitrile, fipronil bisamide, Rynaxypyr.
Summary of the invention
The object of the invention is to propose a kind of have synergistic function, use cost is low, preventive effect the is good efficient insecticide composition containing CGA 183893.
The efficient insecticide composition containing CGA 183893 that the present invention proposes contains active components A and active component B, active components A and active component B weight ratio are 1 ︰ 80 ~ 60 ︰ 1, described active components A is selected from CGA 183893, active component B is selected from a kind of in flonicamid, bromine cyanogen insect amide, Tolfenpyrad, fluorine pyridine worm amine nitrile, fipronil bisamide, Rynaxypyr, and active components A and the preferred weight ratio of active component B are 1 ︰ 60 ~ 40 ︰ 1; More preferably the weight ratio of CGA 183893 and flonicamid is 1 ︰ 30 ~ 10 ︰ 1, the weight ratio of CGA 183893 and bromine cyanogen insect amide is 1 ︰ 20 ~ 20 ︰ 1, the weight ratio of CGA 183893 and Tolfenpyrad is 1 ︰ 25 ~ 5 ︰ 1, the weight ratio of CGA 183893 and fluorine pyridine worm amine nitrile is 1 ︰ 25 ~ 5 ︰ 1, the weight ratio of CGA 183893 and fipronil bisamide is 1 ︰ 20 ~ 10 ︰ 1, and the weight ratio of CGA 183893 and Rynaxypyr is 1 ︰ 20 ~ 20 ︰ 1; The weight ratio that most preferably is CGA 183893 and flonicamid is 1 ︰ 15 ~ 5 ︰ 1, the weight ratio of CGA 183893 and bromine cyanogen insect amide is 1 ︰ 10 ~ 10 ︰ 1, the weight ratio of CGA 183893 and Tolfenpyrad is 1 ︰ 15 ~ 1 ︰ 1, the weight ratio of CGA 183893 and fluorine pyridine worm amine nitrile is 1 ︰ 15 ~ 1 ︰ 1, the weight ratio of CGA 183893 and fipronil bisamide is 1 ︰ 10 ~ 5 ︰ 1, and the weight ratio of CGA 183893 and Rynaxypyr is 1 ︰ 10 ~ 10 ︰ 1.
The purposes of efficient insecticide composition containing CGA 183893 of the present invention for preventing and treating insect on crops, described crops comprise cereal crops, legume crop, fiber crop, sugar [yielding, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crop, flowers crop, medicinal crop, raw material crop, green manure pasture crop.
The purposes of efficient insecticide composition containing CGA 183893 of the present invention for preventing and treating insect on crops, described insect comprises beet armyworm, diamond-back moth, prodenia litura, apple leaf miner, striped rice borer, paddy stem borer, rice fulgorid, rice leaf roller, cotton bollworm, pink bollworm, fleahopper, heart-eating worm, aphid, flea beetle, thrips, aleyrodid, scale insect.
The weight ratio of active components A, active component B is 1 ︰ 80 ~ 60 ︰ 1.Conventionally in composition, the weight percentage of active component is gross weight 0.5%～90%, is preferably 5%～80%.According to different preparation types, active component content scope is different.Conventionally, liquid preparation contains 1%～70% active substance by weight, is preferably 5%～50%; Solid pharmaceutical preparation contains 5%～80% active substance by weight, is preferably 10%～80%.
In Pesticidal combination of the present invention, at least contain a kind of surfactant, the dispersion of active component in water while being beneficial to use.Surface-active contents is 5%～30% of total formulation weight amount, and surplus is solid or liquid diluent.
The selected surfactant of Pesticidal combination of the present invention is known in those skilled in the art: can be selected from one or more in dispersant, wetting agent, binding agent or defoamer.According to different dosage form, in preparation, can also contain disintegrant known in those skilled in the art, antifreeze etc.
Pesticidal combination of the present invention can be by user before use through dilution or directly use.Its preparation can be prepared by common processing method known in those skilled in the art, after being about to active substance and mixing with liquid flux or solid carrier, then add surfactant as one or more in dispersant, stabilizing agent, wetting agent, binding agent, defoamer etc.
Pesticidal combination of the present invention, can be processed on demand acceptable formulation on any agricultural chemicals, wherein more preferably formulation is wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
When making wetting powder, composition comprises following constituent content: active components A 0.5% ~ 60%, active component B0.5% ~ 80%, dispersant 2% ~ 10%, wetting agent 2% ~ 10%, filler surplus.
When making water dispersible granules, composition comprises following constituent content: active components A 0.5% ~ 60%, active component B0.5% ~ 80%, dispersant 3% ~ 12%, wetting agent 1% ~ 8%, disintegrant 1% ~ 10%, binding agent 0 ~ 8%, filler surplus.
When making suspending agent, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, dispersant 2% ~ 10%, wetting agent 2% ~ 10%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, antifreeze 0 ~ 8%, deionized water add to 100%.
When making suspension emulsion, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, dispersant 2% ~ 10%, defoamer 0.01% ~ 2%, solvent 1% ~ 15%, thickener 0 ~ 2%, emulsifier 2% ~ 12%, antifreeze 0 ~ 8%, deionized water add to 100%.
When making aqueous emulsion, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, solvent 1% ~ 30%, emulsifier 1% ~ 15%, antifreeze 0 ~ 8%, thickener 0 ~ 2%, defoamer 0.01% ~ 2%, deionized water are supplied surplus.
When making microemulsion, composition comprises following component and content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, emulsifier 3% ~ 25%, solvent 1% ~ 10%, antifreeze 0 ~ 8%, defoamer 0.01% ~ 2%, deionized water add to 100%.
When making microcapsule suspending agent, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, macromolecule cyst material 2% ~ 10%, dispersant 1% ~ 10%, organic solvent 1% ~ 10%, emulsifier 1% ~ 7%, defoamer 0.01% ~ 2%, pH adjusting agent 0.01% ~ 5%, deionized water add to 100%.
When making microcapsule suspension-suspending agent, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, macromolecule cyst material 2% ~ 10%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, organic solvent 1% ~ 15%, emulsifier 1% ~ 6%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, pH adjusting agent 0.01% ~ 5%, deionized water add to 100%.
Wetting powder the key technical indexes of the present invention:
Figure BDA0000177347461
Water dispersible granules the key technical indexes of the present invention:
Figure BDA0000177347462
Suspending agent the key technical indexes of the present invention:
Figure BDA0000177347463
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Figure BDA0000177347465
Microemulsion the key technical indexes of the present invention:
Figure BDA0000177347466
Microcapsule suspending agent the key technical indexes of the present invention:
Figure BDA0000177347467
Microcapsule suspension-suspending agent the key technical indexes of the present invention:
Figure BDA0000177347468
The invention has the advantages that:
(1) CGA 183893 and flonicamid, bromine cyanogen insect amide, Tolfenpyrad, fluorine pyridine worm amine nitrile, fipronil bisamide, Rynaxypyr composite after, there is obvious synergy and lasting effect; (2) cereal crops, legume crop, fiber crop, sugar [yielding, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crop, flowers crop, medicinal crop, raw material crop, green manure pasture crop insect are all had to greater activity; (3) reduce agricultural chemicals dosage, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution; (4), to person poultry safety, Environmental compatibility is good; And preparation adhesion strength strengthens, resistance of rainwater washing against.
Embodiment
Below in conjunction with embodiment, to further instruction of the present invention, the percentage in embodiment is all weight percentage, but the present invention is not limited thereto.
Application Example one
Example 1 ~ 16 wetting powder
CGA 183893, active component B, dispersant, wetting agent, filler are mixed in mixed cylinder, after airslide disintegrating mill is pulverized, mix again, can make wetting powder product of the present invention, specifically in Table 1.
Table 1 embodiment 1 ~ 16 each component and weight portion
Figure BDA0000177347469
Example 17 ~ 32 water dispersible granules
CGA 183893, active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained to the particle diameter needing through air-flow crushing together, then add other auxiliary agents such as binding agent (can add and can not add), obtain the materials of granulating.By item quantitatively send in fluidized bed granulation dryer through granulation and dry after, can make water dispersible granules product of the present invention, specifically in Table 2.
Table 2 embodiment 17 ~ 32 each component and weight portions
Figure BDA00001773474610
Example 33 ~ 48 suspending agents
By dispersant, wetting agent, defoamer, thickener (can add and can not add), antifreeze (can add and can not add), through high speed shear, mix, add CGA 183893, active component B, in ball mill, ball milling is 2 ~ 3 hours, make diameter of particle all below 5 μ m, surplus is supplied by deionized water, can make suspending agent product of the present invention, specifically in Table 3.
Table 3 embodiment 33 ~ 48 each component and weight portions
Figure BDA00001773474611
Example 49 ~ 58 suspension emulsions
Dispersant, defoamer, thickener (can add and can not add), antifreeze (can add and can not add) are mixed through high speed shear, add active component B, in ball mill, ball milling is 2 ~ 3 hours, make diameter of particle all below 5 μ m, make active component B suspending agent, then by CGA 183893, solvent, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, surplus is supplied by deionized water, make suspension emulsion product of the present invention, specifically in Table 4,5.
Table 4 embodiment 49 ~ 54 each group and weight portions
Figure BDA00001773474612
Table 5 embodiment 55 ~ 58 each group and weight portions
Figure BDA00001773474613
Example 59 ~ 68 aqueous emulsions
CGA 183893, active component B, solvent, emulsifier are added together, make to be dissolved into even oil phase; Deionized water, antifreeze (can add and can not add), thickener (can add and can not add), defoamer are mixed, become homogeneous water.Under high-speed stirred, water is added to oil phase, surplus is supplied by deionized water; Can make aqueous emulsion product of the present invention, specifically in Table 6.
Table 6 embodiment 59 ~ 68 each component and weight portions
Figure BDA00001773474614
Flonicamid, bromine cyanogen insect amide, Tolfenpyrad, fluorine pyridine worm amine nitrile, fipronil bisamide, Rynaxypyr in table 1 ~ 6 are exchanged, can make novel formulation.
Example 69 ~ 71 microemulsions
CGA 183893, active component B are dissolved in the homogenizer that solvent is housed, emulsifier, antifreeze (can add and can not add), defoamer are joined in the homogenizer that above-mentioned solution is housed, surplus gives strong mixing and homogenize after supplying by deionized water, finally obtain the as clear as crystal microemulsion product of the present invention of outward appearance.Specifically in Table 7.
Table 7 example 69 ~ 71 each component and content
Figure BDA00001773474615
Example 72,73 microcapsule suspending agents
By CGA 183893, active component B, macromolecule cyst material, solvent, make to be dissolved into even oil phase, under shearing condition, oil phase is joined in the aqueous phase solution that contains emulsifier, pH adjusting agent, dispersant, surplus is supplied by deionized water, bi-material reacts at oil-water interfaces, forms macromolecule cyst wall, makes the finely disseminated microcapsule suspending agent product of the present composition.Specifically in Table 8.
Table 8 embodiment 72,73 each component and weight portions
Figure BDA00001773474616
Example 74,75 microcapsule suspensions-suspending agent
By active component B, macromolecule cyst material, solvent, make to be dissolved into even oil phase, oil phase is joined in the aqueous phase solution that contains emulsifier, pH adjusting agent under shearing condition, make finely disseminated microcapsule suspending agent.Dispersant, wetting agent, defoamer, thickener (can add and can not add) are mixed through high speed shear, add CGA 183893, in ball mill, ball milling is 2 ~ 3 hours, make diameter of particle all below 5 μ m, make suspending agent, then suspending agent is joined in the aqueous phase solution of micro-capsule suspension, deionized water is supplied surplus, make the finely disseminated microcapsule suspension-suspending agent of present composition product, specifically in Table 9.
Table 9 embodiment 74,75 each component and weight portions
Figure BDA00001773474617
The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.First pass through Toxicity Determination, co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC < 80 is antagonism, 80≤CTC≤120 are summation action, CTC > 120 is synergistic effect, on this basis, then carry out field trial.
Test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, is placed in respectively beaker standby.Adopt and first to soak the method that connects worm after leaf, after the blade of the same size that does not contact any medicament is soaked to 5s in the liquid configuring, take out, naturally dry, put into insect box, then connect for examination larva, under 25 ℃ of conditions, raise, every processing repeats for 3 times, every to repeat examination borer population used be 50, establishes blank simultaneously, in 72h, checks dead borer population, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC 50value.If contrast lethality is greater than 10%, be considered as invalid test.Computing formula is as follows:
Insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value to (x), with method of least squares, draws virulence regression equation, and calculates thus the value of every kind of medicament, according to the abundant equation of Sun Yun, calculates co-toxicity coefficient CTC.Computing formula following (take CGA 183893 as standard medicament, its toxicity index is 100):
Figure BDA00001773474620
Figure BDA00001773474621
TI * the P of theoretical toxicity index (TTI)=CGA 183893 of M cGA 183893+tI * P of effective active composition B effective active composition B
Figure BDA00001773474622
In formula: the mixture that M is different proportionings
P effective active composition Bfor effective active composition B shared ratio in composition
P cGA 183893for CGA 183893 shared ratio in composition
B is selected from a kind of in flonicamid, bromine cyanogen insect amide, Tolfenpyrad, fluorine pyridine worm amine nitrile, fipronil bisamide, Rynaxypyr.
Application Example two:
For trying insect: cucumber aphid; Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd.; Experimental scheme: effective lethal concentration scope of determining the former medicine of CGA 183893 and flonicamid and the two different proportioning mixture through preliminary experiment.
Toxicity test result
The composite toxicity test analysis of results table to cucumber aphid of table 10 CGA 183893 and flonicamid
Figure BDA00001773474623
As shown in Table 10, CGA 183893 and flonicamid to cucumber aphid proportioning when 1 ︰ 80 ~ 60 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of CGA 183893 and flonicamid is during at 1 ︰ 30 ~ 10 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 215.Through applicant, test and find that the optimum ratio of CGA 183893 and flonicamid is 10:1,8:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:12,1:15,1:18,1:20,1:25,1:30, wherein when CGA 183893 and flonicamid weight ratio are 1:3, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.
Application Example three
For trying insect: cotton cotton bollworm; Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd.; Experimental scheme: effective lethal concentration scope of determining CGA 183893 and the former medicine of bromine cyanogen insect amide and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to cotton cotton bollworm of table 11 CGA 183893 and bromine cyanogen insect amide
Reagent agent Proportioning LC 50(ug/mL) Co-toxicity coefficient (CTC)
CGA 183893 － 1.75 －
Bromine cyanogen insect amide － 1.64 －
Huan Chong Jing ︰ bromine cyanogen insect amide 60:1 0.98 178.38?
Huan Chong Jing ︰ bromine cyanogen insect amide 40:1 0.91? 191.99?
Huan Chong Jing ︰ bromine cyanogen insect amide 30:1 0.86? 203.05?
Huan Chong Jing ︰ bromine cyanogen insect amide 20:1 0.79? 220.81?
Huan Chong Jing ︰ bromine cyanogen insect amide 10:1 0.75? 231.92?
Huan Chong Jing ︰ bromine cyanogen insect amide 5:1 0.72? 240.37?
Huan Chong Jing ︰ bromine cyanogen insect amide 1:1 0.66? 256.56?
Huan Chong Jing ︰ bromine cyanogen insect amide 1:5 0.68? 243.74?
Huan Chong Jing ︰ bromine cyanogen insect amide 1:10 0.70? 235.65?
Huan Chong Jing ︰ bromine cyanogen insect amide 1:20 0.74? 222.30?
Huan Chong Jing ︰ bromine cyanogen insect amide 1:40 0.79? 207.93?
Huan Chong Jing ︰ bromine cyanogen insect amide 1:60 0.85? 193.15?
Huan Chong Jing ︰ bromine cyanogen insect amide 1:80 0.91? 180.37?
As shown in Table 11, CGA 183893 and bromine cyanogen insect amide to cotton cotton bollworm proportioning when 1 ︰ 80 ~ 60 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of CGA 183893 and bromine cyanogen insect amide is during at 1 ︰ 20 ~ 20 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 220.Through applicant, test and find that the optimum ratio of CGA 183893 and bromine cyanogen insect amide is 20:1,15:1,10:1,9:1,8:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:10,1:15,1:20, wherein when CGA 183893 and bromine cyanogen insect amide weight ratio are 1:1, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.
Application Example four
For trying insect: brassicaceous vegetable diamond-back moth; Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..Experimental scheme: effective lethal concentration scope of determining the former medicine of CGA 183893 and Tolfenpyrad and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to brassicaceous vegetable diamond-back moth of table 12 CGA 183893 and Tolfenpyrad
Reagent agent Proportioning LC 50(ug/mL) Co-toxicity coefficient (CTC)
CGA 183893 － 1.79 －
Tolfenpyrad － 8.58 －
Huan Chong Jing ︰ Tolfenpyrad 60:1 1.09 166.38?
Huan Chong Jing ︰ Tolfenpyrad 40:1 1.02? 178.94?
Huan Chong Jing ︰ Tolfenpyrad 20:1 1.00? 186.01?
Huan Chong Jing ︰ Tolfenpyrad 10:1 0.99? 194.82?
Huan Chong Jing ︰ Tolfenpyrad 5:1 0.96? 214.79?
Huan Chong Jing ︰ Tolfenpyrad 1:1 1.31? 226.11?
Huan Chong Jing ︰ Tolfenpyrad 1:3 1.81? 243.31?
Huan Chong Jing ︰ Tolfenpyrad 1:5 1.98? 265.50?
Huan Chong Jing ︰ Tolfenpyrad 1:10 2.63? 242.60?
Huan Chong Jing ︰ Tolfenpyrad 1:15 2.97? 233.55?
Huan Chong Jing ︰ Tolfenpyrad 1:25 3.51? 213.34?
Huan Chong Jing ︰ Tolfenpyrad 1:40 4.02? 195.38?
Huan Chong Jing ︰ Tolfenpyrad 1:60 4.37? 184.86?
Huan Chong Jing ︰ Tolfenpyrad 1:80 4.59? 178.59?
As shown in Table 12, CGA 183893 and Tolfenpyrad to brassicaceous vegetable diamond-back moth proportioning when 1 ︰ 80 ~ 60 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of CGA 183893 and Tolfenpyrad is during at 1 ︰ 25 ~ 5 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 210.Through applicant, test and find that the optimum ratio of CGA 183893 and Tolfenpyrad is 5:1,3:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:11,1:12,1:13,1:14,1:15,1:18,1:20,1:25, wherein when CGA 183893 and Tolfenpyrad weight ratio are 1:5, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.
Application Example five
For trying insect: rice hoppers; Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..Experimental scheme: effective lethal concentration scope of determining CGA 183893 and the fluorine pyridine worm former medicine of amine nitrile and the two different proportioning mixture through preliminary experiment.
Table 13 CGA 183893 and the composite toxicity test analysis of results table to rice hoppers of fluorine pyridine worm amine nitrile
Reagent agent Proportioning LC 50(ug/mL) Co-toxicity coefficient (CTC)
CGA 183893 － 1.71 －
Fluorine pyridine worm amine nitrile － 8.42 －
Huan Chong Jing ︰ fluorine pyridine worm amine nitrile 60:1 1.05 165.01?
Huan Chong Jing ︰ fluorine pyridine worm amine nitrile 40:1 1.01? 172.66?
Huan Chong Jing ︰ fluorine pyridine worm amine nitrile 20:1 1.00? 177.74?
Huan Chong Jing ︰ fluorine pyridine worm amine nitrile 10:1 0.98? 188.12?
Huan Chong Jing ︰ fluorine pyridine worm amine nitrile 5:1 0.96? 205.41?
Huan Chong Jing ︰ fluorine pyridine worm amine nitrile 1:1 1.28? 222.08?
Huan Chong Jing ︰ fluorine pyridine worm amine nitrile 1:3 1.82? 233.53?
Huan Chong Jing ︰ fluorine pyridine worm amine nitrile 1:5 1.97? 258.40?
Huan Chong Jing ︰ fluorine pyridine worm amine nitrile 1:10 2.64? 235.07?
Huan Chong Jing ︰ fluorine pyridine worm amine nitrile 1:15 2.96? 228.43?
Huan Chong Jing ︰ fluorine pyridine worm amine nitrile 1:25 3.52? 207.83?
Huan Chong Jing ︰ fluorine pyridine worm amine nitrile 1:40 4.03? 190.67?
Huan Chong Jing ︰ fluorine pyridine worm amine nitrile 1:60 4.38? 180.61?
Huan Chong Jing ︰ fluorine pyridine worm amine nitrile 1:80 4.60? 174.58?
As shown in Table 13, CGA 183893 and fluorine pyridine worm amine nitrile to rice hoppers proportioning when 1 ︰ 80 ~ 60 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of CGA 183893 and fluorine pyridine worm amine nitrile is during at 1 ︰ 25 ~ 5 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 205.Through applicant, test and find that the optimum ratio of CGA 183893 and fluorine pyridine worm amine nitrile is 5:1,3:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:11,1:12,1:13,1:14,1:15,1:18,1:20,1:25, wherein when CGA 183893 and fluorine pyridine worm amine nitrile weight ratio are 1:5, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.
Application Example six
For trying insect: Laphygma exigua Hubner; Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..Experimental scheme: effective lethal concentration scope of determining the former medicine of CGA 183893 and fipronil bisamide and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to Laphygma exigua Hubner of table 14 CGA 183893 and fipronil bisamide
Reagent agent Proportioning LC 50(ug/mL) Co-toxicity coefficient (CTC)
CGA 183893 － 1.76 －
Fipronil bisamide － 3.12 －
Huan Chong Jing ︰ fipronil bisamide 60:1 0.95 186.60?
Huan Chong Jing ︰ fipronil bisamide 40:1 0.93? 191.28?
Huan Chong Jing ︰ fipronil bisamide 20:1 0.89? 201.94?
Huan Chong Jing ︰ fipronil bisamide 10:1 0.82? 223.49?
Huan Chong Jing ︰ fipronil bisamide 5:1 0.80? 237.24?
Huan Chong Jing ︰ fipronil bisamide 2:1 0.81? 254.22?
Huan Chong Jing ︰ fipronil bisamide 1:2 0.89? 278.76?
Huan Chong Jing ︰ fipronil bisamide 1:5 1.10? 251.28?
Huan Chong Jing ︰ fipronil bisamide 1:10 1.24? 235.10?
Huan Chong Jing ︰ fipronil bisamide 1:20 1.36? 221.27?
Huan Chong Jing ︰ fipronil bisamide 1:40 1.50? 204.15?
Huan Chong Jing ︰ fipronil bisamide 1:60 1.62? 190.18?
Huan Chong Jing ︰ fipronil bisamide 1:80 1.71? 180.73?
As shown in Table 14, CGA 183893 and fipronil bisamide to Laphygma exigua Hubner proportioning when 1 ︰ 80 ~ 60 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of CGA 183893 and fipronil bisamide is during at 1 ︰ 20 ~ 10 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 220.Through applicant, test and find that the optimum ratio of CGA 183893 and fipronil bisamide is 10:1,8:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:12,1:14,1:16,1:18,1:20, wherein when CGA 183893 and fipronil bisamide weight ratio are 1:2, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.
Application Example seven
For trying insect: paddy rice rice leaf roller; Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..Experimental scheme: effective lethal concentration scope of determining the former medicine of CGA 183893 and Rynaxypyr and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to paddy rice rice leaf roller of table 15 CGA 183893 and Rynaxypyr
Reagent agent Proportioning LC 50(ug/mL) Co-toxicity coefficient (CTC)
CGA 183893 － 1.69 －
Rynaxypyr － 1.77 －
Huan Chong Jing ︰ Rynaxypyr 60:1 0.96 176.17?
Huan Chong Jing ︰ Rynaxypyr 40:1 0.92? 183.90?
Huan Chong Jing ︰ Rynaxypyr 30:1 0.85? 199.11?
Huan Chong Jing ︰ Rynaxypyr 20:1 0.78? 217.13?
Huan Chong Jing ︰ Rynaxypyr 10:1 0.75? 226.26?
Huan Chong Jing ︰ Rynaxypyr 5:1 0.70? 243.26?
Huan Chong Jing ︰ Rynaxypyr 1:1 0.67? 258.07?
Huan Chong Jing ︰ Rynaxypyr 1:5 0.72? 243.91?
Huan Chong Jing ︰ Rynaxypyr 1:10 0.79? 223.09?
Huan Chong Jing ︰ Rynaxypyr 1:20 0.82? 215.37?
Huan Chong Jing ︰ Rynaxypyr 1:40 0.91? 194.28?
Huan Chong Jing ︰ Rynaxypyr 1:60 0.96? 184.23?
Huan Chong Jing ︰ Rynaxypyr 1:80 1.01? 175.15?
As shown in Table 15, CGA 183893 and Rynaxypyr to paddy rice rice leaf roller proportioning when 1 ︰ 80 ~ 60 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 80 ~ 60 ︰ 1 scopes, when the proportioning of CGA 183893 and Rynaxypyr is during at 1 ︰ 20 ~ 20 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 215.Through applicant, test and find that the optimum ratio of CGA 183893 and Rynaxypyr is 20:1,15:1,10:1,9:1,8:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:10,1:15,1:20, wherein when CGA 183893 and Rynaxypyr weight ratio are 1:1, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.
Through test, find: after CGA 183893 and active component B are composite, the control of the beet armyworm in various crop, diamond-back moth, prodenia litura, apple leaf miner, striped rice borer, paddy stem borer, rice fulgorid, rice leaf roller, cotton bollworm, pink bollworm, fleahopper, heart-eating worm, aphid, flea beetle, thrips, aleyrodid, scale insect is had to obvious synergistic effect, co-toxicity coefficient is all more than 120.
Experimental section: test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 20% CGA 183893 suspending agent (autogamy), 10% flonicamid water dispersible granules (autogamy), 10% bromine cyanogen insect amide suspending agent (autogamy), 15% Tolfenpyrad missible oil (autogamy), 22% fluorine pyridine worm amine nitrile suspending agent (autogamy), 20% fipronil bisamide water dispersible granules (autogamy), 5% Rynaxypyr suspending agent (commercial).
Application Example eight CGA 183893 and active component B and the composite control wild cabbage diamond-back moth test of pesticide effectiveness thereof, this test arrangement is at Xian District, Shanxi Province suburban area, investigation wild cabbage diamond-back moth insect pest index before medicine, in the dispenser of insect pest initial stage of origination, within after dispenser 3 days, 10 days, 20 days, investigate insect pest indexes and calculate preventive effect.Result of the test is as follows:
Table 16 CGA 183893 and active component B and the composite control wild cabbage diamond-back moth test of pesticide effectiveness thereof
As can be seen from Table 16, after CGA 183893 and active component B are composite, wild cabbage diamond-back moth can be effectively prevented and treated, through inventor's evidence CGA 183893 and active component B, also beet armyworm, prodenia litura, flea beetle can be effectively prevented and treated after composite.Control efficiency, all higher than 96%, is better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example nine CGA 183893 and active component B and the composite rice hoppers test of pesticide effectiveness of preventing and treating thereof, this test arrangement is in Hanzhong City suburb, Shaanxi Province, investigation rice hoppers insect pest index before medicine, in the dispenser of insect pest initial stage of origination, within after dispenser 3 days, 7 days, 15 days, investigate insect pest indexes and calculate preventive effect.Result of the test is as follows:
Table 17 CGA 183893 and active component B and the composite rice hoppers test of pesticide effectiveness of preventing and treating thereof
Figure BDA00001773474625
As can be seen from Table 17, after CGA 183893 and active component B are composite, rice hoppers can be effectively prevented and treated, through inventor's evidence CGA 183893 and active component B, also striped rice borer, paddy stem borer, rice leaf roller can be effectively prevented and treated after composite.Control efficiency, all higher than 96%, is better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten CGA 183893 and active component B and the composite control wheat aphid test of pesticide effectiveness thereof, this test arrangement is in Weinan City Pucheng County, Shaanxi Province, investigation wheat aphid insect pest index before medicine, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculates preventive effect for after dispenser 1 day, 3 days, 7 days.Result of the test is as follows:
Table 18 CGA 183893 and active component B and the composite control wheat aphid test of pesticide effectiveness thereof
Figure BDA00001773474626
As can be seen from Table 18, CGA 183893 and active component B and composite control wheat aphid thereof, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example 11 CGA 183893 and active component B and the composite control cucumber aleyrodid test of pesticide effectiveness thereof, this test arrangement is at Xian District, Shanxi Province suburban area, before medicine, investigation cucumber powder mite evil index, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculates preventive effect for after dispenser 3 days, 7 days, 15 days.Result of the test is as follows:
Table 19 CGA 183893 and active component B and the composite control cucumber aleyrodid test of pesticide effectiveness thereof
As can be seen from Table 19, after CGA 183893 and active component B are composite, can effectively prevent and treat cucumber aleyrodid, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example 12 CGA 183893 and active component B and the composite control cotton cotton bollworm test of pesticide effectiveness thereof, this test arrangement is in Weinan City Dali County, Shaanxi Province, investigation cotton cotton bollworm insect pest index before medicine, in the dispenser of insect pest initial stage of origination, within after dispenser 3 days, 10 days, 20 days, investigate insect pest indexes and calculate preventive effect.Result of the test is as follows:
Table 20 CGA 183893 and active component B and the composite control cotton cotton bollworm test of pesticide effectiveness thereof
As can be seen from Table 20, after CGA 183893 and active component B are composite, cotton cotton bollworm can be effectively prevented and treated, through inventor's evidence CGA 183893 and active component B, also pink bollworm, fleahopper can be effectively prevented and treated after composite.Control efficiency, all higher than 96%, is better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example 13 CGA 183893 and active component B and the composite control apple tree apple leaf miner test of pesticide effectiveness thereof, this test arrangement is at Shaanxi Province's Weinan City Baishui County, investigation apple tree apple leaf miner insect pest index before medicine, in the dispenser of insect pest initial stage of origination, within after dispenser 3 days, 10 days, 20 days, investigate insect pest indexes and calculate preventive effect.Result of the test is as follows:
Table 21 CGA 183893 and active component B and the composite control apple tree apple leaf miner test of pesticide effectiveness thereof
As can be seen from Table 21, can effectively preventing and treating apple-tree after CGA 183893 and active component B are composite apple leaf miner, through inventor's evidence CGA 183893 and active component B, also can effectively prevent and treat heart-eating worm after composite, control efficiency is all higher than 95%, the preventive effect that is better than single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example 14 CGA 183893 and active component B and the composite control rose thrips test of pesticide effectiveness thereof, this test arrangement is in nursery, Xi'an City, Shanxi Province, investigation rose thrips insect pest index before medicine, in the dispenser of insect pest initial stage of origination, within after dispenser 3 days, 7 days, 15 days, investigate insect pest indexes and calculate preventive effect.Result of the test is as follows:
Table 22 CGA 183893 and active component B and the composite control rose thrips test of pesticide effectiveness thereof
Figure BDA00001773474630
As can be seen from Table 22, after CGA 183893 and active component B are composite, can effectively prevent and treat rose thrips, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
After through different local throughout the country tests, draw, CGA 183893 and flonicamid, bromine cyanogen insect amide, Tolfenpyrad, fluorine pyridine worm amine nitrile, fipronil bisamide, Rynaxypyr composite rear to the preventive effect of the common insects such as the beet armyworm in various crop, diamond-back moth, prodenia litura, apple leaf miner, striped rice borer, paddy stem borer, rice fulgorid, rice leaf roller, cotton bollworm, pink bollworm, fleahopper, heart-eating worm, aphid, flea beetle, thrips, aleyrodid, scale insect all more than 95%, be better than single dose preventive effect, synergistic effect is obvious.

Claims (6)

1. the efficient insecticide composition containing CGA 183893, contain active components A and active component B, it is characterized in that: active components A and active component B weight ratio are 1 ︰ 80 ~ 60 ︰ 1, described active components A is selected from CGA 183893, and active component B is selected from a kind of in flonicamid, bromine cyanogen insect amide, Tolfenpyrad, fluorine pyridine worm amine nitrile, fipronil bisamide, Rynaxypyr.
2. the efficient insecticide composition containing CGA 183893 according to claim 1, is characterized in that: the weight ratio of active components A and active component B is 1 ︰ 60 ~ 40 ︰ 1.
3. the efficient insecticide composition containing CGA 183893 according to claim 2, is characterized in that:
The weight ratio of CGA 183893 and flonicamid is 1 ︰ 30 ~ 10 ︰ 1;
The weight ratio of CGA 183893 and bromine cyanogen insect amide is 1 ︰ 20 ~ 20 ︰ 1;
The weight ratio of CGA 183893 and Tolfenpyrad is 1 ︰ 25 ~ 5 ︰ 1;
The weight ratio of CGA 183893 and fluorine pyridine worm amine nitrile is 1 ︰ 25 ~ 5 ︰ 1;
The weight ratio of CGA 183893 and fipronil bisamide is 1 ︰ 20 ~ 10 ︰ 1;
The weight ratio of CGA 183893 and Rynaxypyr is 1 ︰ 20 ~ 20 ︰ 1.
4. according to the efficient insecticide composition containing CGA 183893 described in any one in claims 1 to 3, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
5. the efficient insecticide composition containing CGA 183893 according to claim 4 is used for the purposes of preventing and treating insect on crops.
6. purposes according to claim 5, is characterized in that: described insect comprises beet armyworm, diamond-back moth, prodenia litura, apple leaf miner, striped rice borer, paddy stem borer, rice fulgorid, rice leaf roller, cotton bollworm, pink bollworm, fleahopper, heart-eating worm, aphid, flea beetle, thrips, aleyrodid, scale insect.
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Application publication date: 20140115