CN103882708A - Low-pollution textile sizing agent - Google Patents
Low-pollution textile sizing agent Download PDFInfo
- Publication number
- CN103882708A CN103882708A CN201410147255.0A CN201410147255A CN103882708A CN 103882708 A CN103882708 A CN 103882708A CN 201410147255 A CN201410147255 A CN 201410147255A CN 103882708 A CN103882708 A CN 103882708A
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- parts
- sizing agent
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- low pollution
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- 238000004513 sizing Methods 0.000 title claims abstract description 27
- 239000004753 textile Substances 0.000 title abstract 3
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 12
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 12
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 10
- 229920000881 Modified starch Polymers 0.000 claims abstract description 9
- 239000004368 Modified starch Substances 0.000 claims abstract description 9
- 235000019426 modified starch Nutrition 0.000 claims abstract description 9
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- 239000002002 slurry Substances 0.000 claims description 21
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 18
- 238000009987 spinning Methods 0.000 claims description 15
- 229920002472 Starch Polymers 0.000 claims description 13
- 239000008107 starch Substances 0.000 claims description 13
- 235000019698 starch Nutrition 0.000 claims description 13
- 239000003921 oil Substances 0.000 claims description 10
- -1 hydroxypropyl Chemical group 0.000 claims description 8
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 7
- 239000013530 defoamer Substances 0.000 claims description 7
- 150000003376 silicon Chemical class 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 6
- 235000013312 flour Nutrition 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 108010073771 Soybean Proteins Proteins 0.000 claims description 3
- ZCJHFOLNXNSZJG-UHFFFAOYSA-N [Na].NS(O)(=O)=O Chemical compound [Na].NS(O)(=O)=O ZCJHFOLNXNSZJG-UHFFFAOYSA-N 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 230000008030 elimination Effects 0.000 claims description 3
- 238000003379 elimination reaction Methods 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 238000000746 purification Methods 0.000 claims description 3
- 239000013049 sediment Substances 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 235000019710 soybean protein Nutrition 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000005543 nano-size silicon particle Substances 0.000 abstract description 3
- 230000035699 permeability Effects 0.000 abstract description 2
- 102000004169 proteins and genes Human genes 0.000 abstract 2
- 108090000623 proteins and genes Proteins 0.000 abstract 2
- CZFMLDUNXATLOW-XKZIYDEJSA-N (5z)-5-[[3-(2-hydroxyethoxymethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical group C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1COCCO CZFMLDUNXATLOW-XKZIYDEJSA-N 0.000 abstract 1
- 150000001413 amino acids Chemical class 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000004088 foaming agent Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229920002545 silicone oil Polymers 0.000 abstract 1
- QDWYPRSFEZRKDK-UHFFFAOYSA-M sodium;sulfamate Chemical compound [Na+].NS([O-])(=O)=O QDWYPRSFEZRKDK-UHFFFAOYSA-M 0.000 abstract 1
- 229920002125 Sokalan® Polymers 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000009955 starching Methods 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention relates to a low-pollution textile sizing agent. The low-pollution textile sizing agent comprises following components in parts by mass: 64 parts of nano silicon dioxide modified starch, 18 parts of a protein sizing agent, 5 parts of polyvinyl alcohol, 11 parts of polyacrylate emulsion, 2 parts of a modified silicone oil de-foaming agent, 3 parts of protein amino acid, 4 parts of kaolin, 3 parts of sodium sulfamate and 1 part of polyacrylate. The sizing agent with the formula has good film-forming property and permeability; the formula contains less polyvinyl alcohol so that the pollution to the environment is low.
Description
Technical field
The present invention relates to a kind of low pollution spinning sizing agent.
Background technology
Warp sizing is the key link of weaving engineering, and the object of sizing is mainly to improve the ABRASION RESISTANCE of yarn, reduces filoplume, suitably increases the brute force of yarn, reduces degree of stretching, the mechanicals efforts being subject in weaving process to bear warp thread, the weavability of raising yarn.
The slurry of warp sizing mainly contains starch, polyvinyl alcohol (PVA) and the large slurry of polyacrylic three at present.Starch is natural polysaecharides high polymer, and Size-Film Forming Properties is good, strong with natural fabric affinity, is easy to destarch; But starch size slashing strength is inadequate, not wear-resisting, and also inadequate with polyster fibre affinity.Polyvinyl alcohol pulp serous coat is powerful large, and pliability is good, and slurry fluidity is good, but polyvinyl alcohol is difficult to destarch, and big for environment pollution.Polyacrylic acid size is the general name of homopolymers, copolymer and the blend of acrylic monomer, its viscosity is lower, good fluidity, synthetic fiber are had to good adhesiveness, can be mixed well with starch, PVA slurry, be applicable to the warp sizing of each fibrid, but polyacrylic acid size price is high, raise the production cost of printing and dyeing enterprise.
Summary of the invention
The object of the invention is to: overcome the defect of above-mentioned prior art, propose a kind of low pollution spinning sizing agent.
In order to achieve the above object, the present invention propose the low pollution spinning sizing agent of one, its component by mass ratio as follows:
Nano SiO 2 modified starch: 64 parts, albumen slurry: 18 parts, polyvinyl alcohol: 5 parts; Polyacrylate dispersion: 11 parts, modified silicon oil defoamer: 2 parts;
Described nano SiO 2 modified starch adds in deionized water after being mixed with silica flour by hydroxypropyl converted starch, and add NaOH and methyl alcohol, after being hydrolyzed, dry purification obtains, wherein, hydroxypropyl converted starch: silica flour: NaOH: the quality proportioning of methyl alcohol is: 100:5:0.1:0.2;
It is in 0.2% sodium hydroxide solution that described albumen slurry adds concentration by soybean protein, at the uniform velocity stirs after 15 minutes at 45 ℃ and obtains after elimination sediment;
The polyethers that described modified silicon oil defoamer is 1:15 by quality proportioning and silicon oil of low hydrogen content, 1000 ℃ of modification temperatures, make under modification time 1.5h.
The present invention is low, and pollution spinning sizing agent also has following improvement:
1, the low pollution spinning sizing agent of the present invention, also comprises the Argine Monohydrochloride of 3 parts by mass.
2, the low pollution spinning sizing agent of the present invention, also comprises the kaolin of 4 parts by mass.
3, the low pollution spinning sizing agent of the present invention, also comprises the sulfamic acid sodium of 3 parts by mass.
4, the low pollution spinning sizing agent of the present invention, also comprises the polyacrylate of 1 parts by mass.
The present invention's formula contains nano SiO 2 modified starch, albumen slurry, polyacrylate dispersion, silicone defoaming agent and a small amount of polyvinyl alcohol, and these five kinds of batchings are carried out to proportioning restriction, this kind of slurry has good film forming and permeability, and because polyvinyl alcohol content in formula is lower, therefore environmental pollution is less.
In slurry of the present invention, hydroxypropyl converted starch and nano silicon combine, on the one hand, hydroxypropyl has hydrophily, can weaken the internal hydrogen bond strength of starch granules structure, make it be easy to expand, gelatinization is easy, paste liquid is transparent, good fluidity, a little less than retrogradation, stability is high, make the film forming of slurry better, improved the sizing performance of slurry; Nano silicon contributes to the dispersion of starch in slurry on the other hand, has also improved to a certain extent the sizing performance of slurry.The albumen slurry and the modified starch that add promote mutually, and the polyacrylate dispersion being used in conjunction with, and can further improve the sizing performance of slurry.For front four kinds of materials, the present invention selects modified silicon oil defoamer can effectively eliminate the foam producing in starching process, make slurry more fully with clothing in contact, improve starching efficiency, save slurry.
The specific embodiment
Below in conjunction with specific embodiment, the present invention will be further described.
The low pollution spinning sizing agent of the present embodiment, its component by mass ratio as follows:
Nano SiO 2 modified starch: 64 parts, albumen slurry: 18 parts, polyvinyl alcohol: 5 parts; Polyacrylate dispersion: 11 parts, modified silicon oil defoamer: 2 parts; Argine Monohydrochloride: 3 parts; Kaolin: 4 parts; Sulfamic acid sodium: 3 parts; Polyacrylate: 1 part;
Nano SiO 2 modified starch adds in deionized water after being mixed with silica flour by hydroxypropyl converted starch, and add NaOH and methyl alcohol, after being hydrolyzed, dry purification obtains, wherein, and hydroxypropyl converted starch: silica flour: NaOH: the quality proportioning of methyl alcohol is: 100:5:0.1:0.2;
It is in 0.2% sodium hydroxide solution that albumen slurry adds concentration by soybean protein, at the uniform velocity stirs after 15 minutes at 45 ℃ and obtains after elimination sediment;
The polyethers that modified silicon oil defoamer is 1:15 by quality proportioning and silicon oil of low hydrogen content, 1000 ℃ of modification temperatures, make under modification time 1.5h.
In addition to the implementation, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of requirement of the present invention.
Claims (5)
1. a low pollution spinning sizing agent, its component by mass ratio as follows:
Nano SiO 2 modified starch: 64 parts, albumen slurry: 18 parts, polyvinyl alcohol: 5 parts; Polyacrylate dispersion: 11 parts, modified silicon oil defoamer: 2 parts;
Described nano SiO 2 modified starch adds in deionized water after being mixed with silica flour by hydroxypropyl converted starch, and add NaOH and methyl alcohol, after being hydrolyzed, dry purification obtains, wherein, hydroxypropyl converted starch: silica flour: NaOH: the quality proportioning of methyl alcohol is: 100:5:0.1:0.2;
It is in 0.2% sodium hydroxide solution that described albumen slurry adds concentration by soybean protein, at the uniform velocity stirs after 15 minutes at 45 ℃ and obtains after elimination sediment;
The polyethers that described modified silicon oil defoamer is 1:15 by quality proportioning and silicon oil of low hydrogen content, 1000 ℃ of modification temperatures, make under modification time 1.5h.
2. low pollution spinning sizing agent according to claim 1, is characterized in that: the Argine Monohydrochloride that also comprises 3 parts by mass.
3. low pollution spinning sizing agent according to claim 2, is characterized in that: the kaolin that also comprises 4 parts by mass.
4. low pollution spinning sizing agent according to claim 3, is characterized in that: the sulfamic acid sodium that also comprises 3 parts by mass.
5. low pollution spinning sizing agent according to claim 4, is characterized in that: the polyacrylate that also comprises 1 parts by mass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410147255.0A CN103882708B (en) | 2014-04-14 | 2014-04-14 | A kind of low stain spinning sizing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410147255.0A CN103882708B (en) | 2014-04-14 | 2014-04-14 | A kind of low stain spinning sizing agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103882708A true CN103882708A (en) | 2014-06-25 |
| CN103882708B CN103882708B (en) | 2016-04-06 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410147255.0A Expired - Fee Related CN103882708B (en) | 2014-04-14 | 2014-04-14 | A kind of low stain spinning sizing agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103882708B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106637966A (en) * | 2016-11-17 | 2017-05-10 | 无锡明盛纺织机械有限公司 | Starch textile sizing agent for replacing PVA (polyvinyl alcohol) |
| CN106676887A (en) * | 2016-12-19 | 2017-05-17 | 长兴荣煜纺织科技有限公司 | Low-pollution textile sizing agent and preparation method thereof |
| CN107881782A (en) * | 2017-11-29 | 2018-04-06 | 苏州润弘贸易有限公司 | Spinning sizing agent |
| CN107893331A (en) * | 2017-11-29 | 2018-04-10 | 苏州润弘贸易有限公司 | A kind of spinning sizing agent |
| CN108103767A (en) * | 2017-12-15 | 2018-06-01 | 江苏新瑞贝科技股份有限公司 | A kind of Efficient textile slurry and preparation method thereof |
| CN109267343A (en) * | 2018-07-26 | 2019-01-25 | 常州依丝特纺织服饰有限公司 | A kind of underlinen fabric environmentally friendly hydrophily slurry and preparation method thereof |
| CN109594339A (en) * | 2018-10-12 | 2019-04-09 | 徐州华奥纺织有限公司 | A kind of environmental protection spinning sizing agent and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1382864A (en) * | 2002-06-12 | 2002-12-04 | 弘生集团有限公司 | Size composition for textile |
| CN101545204A (en) * | 2009-04-24 | 2009-09-30 | 杨川辉 | Size for spinning warp sizing |
| CN101597861A (en) * | 2009-06-23 | 2009-12-09 | 华中师范大学 | The preparation method of composite textile pulp by nanometer polymer emulsion |
| CN101676485A (en) * | 2008-09-19 | 2010-03-24 | 海安县银桥纺织品有限公司 | Environment-friendly size used for 60 count all cotton yarn |
| CN103087332A (en) * | 2013-01-21 | 2013-05-08 | 东华大学 | Preparation method of proteins and protein-based sizes for warp sizing |
-
2014
- 2014-04-14 CN CN201410147255.0A patent/CN103882708B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1382864A (en) * | 2002-06-12 | 2002-12-04 | 弘生集团有限公司 | Size composition for textile |
| CN101676485A (en) * | 2008-09-19 | 2010-03-24 | 海安县银桥纺织品有限公司 | Environment-friendly size used for 60 count all cotton yarn |
| CN101545204A (en) * | 2009-04-24 | 2009-09-30 | 杨川辉 | Size for spinning warp sizing |
| CN101597861A (en) * | 2009-06-23 | 2009-12-09 | 华中师范大学 | The preparation method of composite textile pulp by nanometer polymer emulsion |
| CN103087332A (en) * | 2013-01-21 | 2013-05-08 | 东华大学 | Preparation method of proteins and protein-based sizes for warp sizing |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106637966A (en) * | 2016-11-17 | 2017-05-10 | 无锡明盛纺织机械有限公司 | Starch textile sizing agent for replacing PVA (polyvinyl alcohol) |
| CN106676887A (en) * | 2016-12-19 | 2017-05-17 | 长兴荣煜纺织科技有限公司 | Low-pollution textile sizing agent and preparation method thereof |
| CN107881782A (en) * | 2017-11-29 | 2018-04-06 | 苏州润弘贸易有限公司 | Spinning sizing agent |
| CN107893331A (en) * | 2017-11-29 | 2018-04-10 | 苏州润弘贸易有限公司 | A kind of spinning sizing agent |
| CN108103767A (en) * | 2017-12-15 | 2018-06-01 | 江苏新瑞贝科技股份有限公司 | A kind of Efficient textile slurry and preparation method thereof |
| CN109267343A (en) * | 2018-07-26 | 2019-01-25 | 常州依丝特纺织服饰有限公司 | A kind of underlinen fabric environmentally friendly hydrophily slurry and preparation method thereof |
| CN109594339A (en) * | 2018-10-12 | 2019-04-09 | 徐州华奥纺织有限公司 | A kind of environmental protection spinning sizing agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103882708B (en) | 2016-04-06 |
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