CN103882707A - Environment-friendly type textile sizing agent - Google Patents
Environment-friendly type textile sizing agent Download PDFInfo
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- CN103882707A CN103882707A CN201410147128.0A CN201410147128A CN103882707A CN 103882707 A CN103882707 A CN 103882707A CN 201410147128 A CN201410147128 A CN 201410147128A CN 103882707 A CN103882707 A CN 103882707A
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Abstract
The invention relates to environment-friendly type textile sizing agent. The environment-friendly type textile sizing agent comprises following components in parts by mass: 72 parts of nano silicon dioxide modified starch, 15 parts of a protein sizing agent, 11 parts of polyacrylate emulsion, 2 parts of an organic silicon de-foaming agent, 3 parts of protein amino acid, 4 parts of kaolin, 3 parts of sodium sulfamate and 1 part of polyacrylate. The sizing agent with the formula has good film-forming property and permeability; the formula does not contain polyvinyl alcohol, thus the environment-friendly type textile sizing agent is very environment-friendly.
Description
Technical field
The present invention relates to a kind of environment-friendly type spinning sizing agent.
Background technology
Warp sizing is the key link of weaving engineering, and the object of sizing is mainly to improve the ABRASION RESISTANCE of yarn, reduces filoplume, suitably increases the brute force of yarn, reduces degree of stretching, the mechanicals efforts being subject in weaving process to bear warp thread, the weavability of raising yarn.
The slurry of warp sizing mainly contains starch, polyvinyl alcohol (PVA) and the large slurry of polyacrylic three at present.Starch is natural polysaecharides high polymer, and Size-Film Forming Properties is good, strong with natural fabric affinity, is easy to destarch; But starch size slashing strength is inadequate, not wear-resisting, and also inadequate with polyster fibre affinity.Polyvinyl alcohol pulp serous coat is powerful large, and pliability is good, and slurry fluidity is good, but polyvinyl alcohol is difficult to destarch, and big for environment pollution.Polyacrylic acid size is the general name of homopolymers, copolymer and the blend of acrylic monomer, its viscosity is lower, good fluidity, synthetic fiber are had to good adhesiveness, can be mixed well with starch, PVA slurry, be applicable to the warp sizing of each fibrid, but polyacrylic acid size price is high, raise the production cost of printing and dyeing enterprise.
Summary of the invention
The object of the invention is to: overcome the defect of above-mentioned prior art, propose a kind of environment-friendly type spinning sizing agent.
In order to achieve the above object, the present invention propose a kind of environment-friendly type spinning sizing agent, its component by mass ratio as follows:
Nano SiO 2 modified starch: 72 parts, albumen slurry: 15 parts, polyacrylate dispersion: 11 parts, silicone defoaming agent: 2 parts;
Described nano SiO 2 modified starch adds in deionized water after being mixed with silica flour by hydroxypropyl converted starch, and add NaOH and methyl alcohol, after being hydrolyzed, dry purification obtains, wherein, hydroxypropyl converted starch: silica flour: NaOH: the quality proportioning of methyl alcohol is: 100:5:0.1:0.2;
It is in 0.2% sodium hydroxide solution that described albumen slurry adds concentration by soybean protein, at the uniform velocity stirs after 15 minutes at 45 ℃ and obtains after elimination sediment;
Described silicone defoaming agent is polysiloxane-modified polyethers.
Environment-friendly type spinning sizing agent of the present invention also has following improvement:
1, environment-friendly type spinning sizing agent of the present invention, also comprises the Argine Monohydrochloride of 3 parts by mass.
2, environment-friendly type spinning sizing agent of the present invention, also comprises the kaolin of 4 parts by mass.
3, environment-friendly type spinning sizing agent of the present invention, also comprises the sulfamic acid sodium of 3 parts by mass.
4, environment-friendly type spinning sizing agent of the present invention, also comprises the polyacrylate of 1 parts by mass.
The present invention's formula contains nano SiO 2 modified starch, albumen slurry, polyacrylate dispersion, silicone defoaming agent, and these four kinds of batchings are carried out to proportioning restriction, this kind of slurry has good film forming and permeability, and owing to not containing polyvinyl alcohol, therefore environmental protection more in formula.
In slurry of the present invention, hydroxypropyl converted starch and nano silicon combine, on the one hand, hydroxypropyl has hydrophily, can weaken the internal hydrogen bond strength of starch granules structure, make it be easy to expand, gelatinization is easy, paste liquid is transparent, good fluidity, a little less than retrogradation, stability is high, make the film forming of slurry better, improved the sizing performance of slurry; Nano silicon contributes to the dispersion of starch in slurry on the other hand, has also improved to a certain extent the sizing performance of slurry.The albumen slurry and the modified starch that add promote mutually, and the polyacrylate dispersion being used in conjunction with, and can further improve the sizing performance of slurry.Plant material for first three, the present invention selects silicone defoaming agent as defoamer, can effectively eliminate the foam producing in starching process, make slurry more fully with clothing in contact, improve starching efficiency, save slurry.
The specific embodiment
Below in conjunction with specific embodiment, the present invention will be further described.
The present embodiment environment-friendly type spinning sizing agent, its component by mass ratio as follows:
Nano SiO 2 modified starch: 72 parts, albumen slurry: 15 parts, polyacrylate dispersion: 11 parts, silicone defoaming agent: 2 parts, Argine Monohydrochloride: 3 parts; Kaolin: 4 parts; Sulfamic acid sodium: 3 parts; Polyacrylate: 1 part;
Nano SiO 2 modified starch adds in deionized water after being mixed with silica flour by hydroxypropyl converted starch, and add NaOH and methyl alcohol, after being hydrolyzed, dry purification obtains, wherein, and hydroxypropyl converted starch: silica flour: NaOH: the quality proportioning of methyl alcohol is: 100:5:0.1:0.2;
It is in 0.2% sodium hydroxide solution that albumen slurry adds concentration by soybean protein, at the uniform velocity stirs after 15 minutes at 45 ℃ and obtains after elimination sediment;
Silicone defoaming agent is polysiloxane-modified polyethers.
In addition to the implementation, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of requirement of the present invention.
Claims (5)
1. an environment-friendly type spinning sizing agent, its component by mass ratio as follows:
Nano SiO 2 modified starch: 72 parts, albumen slurry: 15 parts, polyacrylate dispersion: 11 parts, silicone defoaming agent: 2 parts;
Described nano SiO 2 modified starch adds in deionized water after being mixed with silica flour by hydroxypropyl converted starch, and add NaOH and methyl alcohol, after being hydrolyzed, dry purification obtains, wherein, hydroxypropyl converted starch: silica flour: NaOH: the quality proportioning of methyl alcohol is: 100:5:0.1:0.2;
It is in 0.2% sodium hydroxide solution that described albumen slurry adds concentration by soybean protein, at the uniform velocity stirs after 15 minutes at 45 ℃ and obtains after elimination sediment;
Described silicone defoaming agent is polysiloxane-modified polyethers.
2. environment-friendly type spinning sizing agent according to claim 1, is characterized in that: the Argine Monohydrochloride that also comprises 3 parts by mass.
3. environment-friendly type spinning sizing agent according to claim 2, is characterized in that: the kaolin that also comprises 4 parts by mass.
4. environment-friendly type spinning sizing agent according to claim 3, is characterized in that: the sulfamic acid sodium that also comprises 3 parts by mass.
5. environment-friendly type spinning sizing agent according to claim 4, is characterized in that: the polyacrylate that also comprises 1 parts by mass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410147128.0A CN103882707A (en) | 2014-04-14 | 2014-04-14 | Environment-friendly type textile sizing agent |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410147128.0A CN103882707A (en) | 2014-04-14 | 2014-04-14 | Environment-friendly type textile sizing agent |
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| CN103882707A true CN103882707A (en) | 2014-06-25 |
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| CN201410147128.0A Pending CN103882707A (en) | 2014-04-14 | 2014-04-14 | Environment-friendly type textile sizing agent |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104233805A (en) * | 2014-08-29 | 2014-12-24 | 湖州天鑫皮革涂饰剂厂 | Yarn sizing agent |
| CN106381704A (en) * | 2016-11-17 | 2017-02-08 | 无锡明盛纺织机械有限公司 | Starch textile pulp replacing PVA (Polyvinyl Alcohol) |
| CN106637966A (en) * | 2016-11-17 | 2017-05-10 | 无锡明盛纺织机械有限公司 | Starch textile sizing agent for replacing PVA (polyvinyl alcohol) |
| CN107893331A (en) * | 2017-11-29 | 2018-04-10 | 苏州润弘贸易有限公司 | A kind of spinning sizing agent |
| CN109267343A (en) * | 2018-07-26 | 2019-01-25 | 常州依丝特纺织服饰有限公司 | A kind of underlinen fabric environmentally friendly hydrophily slurry and preparation method thereof |
| CN110424159A (en) * | 2019-07-10 | 2019-11-08 | 南通缘喜纺织品有限公司 | A kind of spinning sizing agent and preparation method thereof |
| CN110453497A (en) * | 2019-07-10 | 2019-11-15 | 南通缘喜纺织品有限公司 | A kind of preparation method of energy saving and environment friendly spinning sizing agent |
| CN110540677A (en) * | 2018-05-28 | 2019-12-06 | 句容市华冠服帽厂 | Preparation method of carrier for attaching dye |
| CN111321597A (en) * | 2020-04-19 | 2020-06-23 | 湖南万家工贸实业有限公司 | Modified polyester slurry and preparation method thereof |
| CN117089210A (en) * | 2023-10-18 | 2023-11-21 | 广州市瑞合新材料科技有限公司 | Silicon rubber for medical protection and preparation method thereof |
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| CN103087332A (en) * | 2013-01-21 | 2013-05-08 | 东华大学 | Preparation method of proteins and protein-based sizes for warp sizing |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104233805A (en) * | 2014-08-29 | 2014-12-24 | 湖州天鑫皮革涂饰剂厂 | Yarn sizing agent |
| CN106381704A (en) * | 2016-11-17 | 2017-02-08 | 无锡明盛纺织机械有限公司 | Starch textile pulp replacing PVA (Polyvinyl Alcohol) |
| CN106637966A (en) * | 2016-11-17 | 2017-05-10 | 无锡明盛纺织机械有限公司 | Starch textile sizing agent for replacing PVA (polyvinyl alcohol) |
| CN107893331A (en) * | 2017-11-29 | 2018-04-10 | 苏州润弘贸易有限公司 | A kind of spinning sizing agent |
| CN110540677A (en) * | 2018-05-28 | 2019-12-06 | 句容市华冠服帽厂 | Preparation method of carrier for attaching dye |
| CN110540677B (en) * | 2018-05-28 | 2021-11-26 | 普宁市联发服装洗染有限公司 | Preparation method of carrier for attaching dye |
| CN109267343A (en) * | 2018-07-26 | 2019-01-25 | 常州依丝特纺织服饰有限公司 | A kind of underlinen fabric environmentally friendly hydrophily slurry and preparation method thereof |
| CN110453497A (en) * | 2019-07-10 | 2019-11-15 | 南通缘喜纺织品有限公司 | A kind of preparation method of energy saving and environment friendly spinning sizing agent |
| CN110424159A (en) * | 2019-07-10 | 2019-11-08 | 南通缘喜纺织品有限公司 | A kind of spinning sizing agent and preparation method thereof |
| CN111321597A (en) * | 2020-04-19 | 2020-06-23 | 湖南万家工贸实业有限公司 | Modified polyester slurry and preparation method thereof |
| CN111321597B (en) * | 2020-04-19 | 2020-11-03 | 湖南万家工贸实业有限公司 | Modified polyester slurry and preparation method thereof |
| CN117089210A (en) * | 2023-10-18 | 2023-11-21 | 广州市瑞合新材料科技有限公司 | Silicon rubber for medical protection and preparation method thereof |
| CN117089210B (en) * | 2023-10-18 | 2024-02-09 | 广州市瑞合新材料科技有限公司 | Silicon rubber for medical protection and preparation method thereof |
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Application publication date: 20140625 |