CN103898759B - A kind of spinning sizing agent being applicable to sodolin - Google Patents
A kind of spinning sizing agent being applicable to sodolin Download PDFInfo
- Publication number
- CN103898759B CN103898759B CN201410149755.8A CN201410149755A CN103898759B CN 103898759 B CN103898759 B CN 103898759B CN 201410149755 A CN201410149755 A CN 201410149755A CN 103898759 B CN103898759 B CN 103898759B
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- parts
- sodolin
- applicable
- sizing agent
- modified starch
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- 238000004513 sizing Methods 0.000 title claims abstract description 22
- 238000009987 spinning Methods 0.000 title claims abstract description 15
- 239000002002 slurry Substances 0.000 claims abstract description 23
- 229920000881 Modified starch Polymers 0.000 claims abstract description 18
- 239000004368 Modified starch Substances 0.000 claims abstract description 18
- 235000019426 modified starch Nutrition 0.000 claims abstract description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000003921 oil Substances 0.000 claims abstract description 13
- 239000013530 defoamer Substances 0.000 claims abstract description 11
- 229910004298 SiO 2 Inorganic materials 0.000 claims abstract description 9
- 235000011187 glycerol Nutrition 0.000 claims abstract description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 4
- ZCJHFOLNXNSZJG-UHFFFAOYSA-N [Na].NS(O)(=O)=O Chemical compound [Na].NS(O)(=O)=O ZCJHFOLNXNSZJG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 229910019142 PO4 Inorganic materials 0.000 claims description 8
- 239000010452 phosphate Substances 0.000 claims description 8
- -1 phosphate ester Chemical class 0.000 claims description 8
- 150000003376 silicon Chemical class 0.000 claims description 8
- 235000013312 flour Nutrition 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 108010073771 Soybean Proteins Proteins 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 230000008030 elimination Effects 0.000 claims description 3
- 238000003379 elimination reaction Methods 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 238000000746 purification Methods 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000013049 sediment Substances 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 235000019710 soybean protein Nutrition 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract description 7
- 238000009955 starching Methods 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000002474 experimental method Methods 0.000 abstract description 2
- 230000035699 permeability Effects 0.000 abstract description 2
- 229920002472 Starch Polymers 0.000 description 5
- 239000008107 starch Substances 0.000 description 5
- 235000019698 starch Nutrition 0.000 description 5
- 239000000835 fiber Substances 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000005543 nano-size silicon particle Substances 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of spinning sizing agent being applicable to sodolin, its component by mass ratio as follows: 75 parts, albumen slurry, nano SiO 2 modified starch 15 parts, glycerine 8 parts, modified silicon oil defoamer: 2 parts, Argine Monohydrochloride 6 parts; 3 parts, sulfamic acid sodium; Polyacrylate 1 part.The present invention's formula is based on albumen slurry, be auxiliary with nano SiO 2 modified starch, glycerine, modified silicon oil is as defoamer, and proportioning restriction has been carried out to these four kinds of batchings, this kind of slurry has good film forming and permeability, experiment shows the starching being particularly suitable for sodolin, and owing to not containing polyvinyl alcohol, therefore environmental protection more in formula.
Description
Technical field
The present invention relates to a kind of spinning sizing agent being applicable to sodolin.
Background technology
Warp sizing is the key link of weaving engineering, and the object of sizing mainly improves the ABRASION RESISTANCE of yarn, reduces filoplume, suitably increases the brute force of yarn, reduces degree of stretching, and to bear the mechanicals efforts that warp thread is subject in weaving process, improves the weavability of yarn.
The slurry of current warp sizing mainly contains the large slurry of starch, polyvinyl alcohol (PVA) and polyacrylic three.Starch is natural polysaecharides high polymer, and Size-Film Forming Properties is good, strong with natural fabric affinity, is easy to destarch; But starch size slashing strength is inadequate, not wear-resisting, and inadequate with polyster fibre affinity.Polyvinyl alcohol pulp serous coat is powerful large, and pliability is good, and slurry fluidity is good, but polyvinyl alcohol is difficult to destarch, and big for environment pollution.Polyacrylic acid size is the general name of the homopolymers of acrylic monomer, copolymer and blend, its viscosity is lower, good fluidity, good adhesiveness is had to synthetic fiber, can be mixed well with starch, PVA slurry, be applicable to the warp sizing of each fibrid, but polyacrylic acid size price is high, raise the production cost of printing and dyeing enterprise.
Summary of the invention
The object of the invention is to: the defect overcoming above-mentioned prior art, propose a kind of spinning sizing agent being applicable to sodolin.
In order to achieve the above object, the present invention propose a kind of spinning sizing agent being applicable to sodolin, its component by mass ratio as follows:
Albumen slurry: 75 parts, nano SiO 2 modified starch: 15 parts, glycerine: 8 parts, modified silicon oil defoamer: 2 parts;
Described nano SiO 2 modified starch adds in deionized water after being mixed with silica flour by phosphate ester modified starch, and add NaOH and methyl alcohol, after being hydrolyzed, dry purification obtains, wherein, phosphate ester modified starch: silica flour: NaOH: the quality proportioning of methyl alcohol is: 100:6:0.1:0.2;
It is in the ethanolic solution of 70% that described albumen slurry adds concentration by soybean protein, after at the uniform velocity stirring 15 minutes at 46 DEG C, adopt concentration be the salt acid for adjusting pH value of 30% to 7-8, obtain after elimination sediment;
Described modified silicon oil defoamer by quality proportioning be the polyethers of 1:15 and silicon oil of low hydrogen content modification temperature 1000 DEG C, obtained under modification time 1.5h.
The spinning sizing agent that the present invention is applicable to sodolin also has following improvement:
1, the present invention is applicable to the spinning sizing agent of sodolin, also comprises the Argine Monohydrochloride of 4 parts by mass.
2, the present invention is applicable to the spinning sizing agent of sodolin, also comprises the sulfamic acid sodium of 2 parts by mass.
3, the present invention is applicable to the spinning sizing agent of sodolin, also comprises the polyacrylate of 2 parts by mass.
The present invention's formula is based on albumen slurry, be auxiliary with nano SiO 2 modified starch, glycerine, modified silicon oil is as defoamer, and proportioning restriction has been carried out to these four kinds of batchings, this kind of slurry has good film forming and permeability, experiment shows the starching being particularly suitable for sodolin, and owing to not containing polyvinyl alcohol, therefore environmental protection more in formula.
Flax is pure natural fiber, and the albumen slurry in slurry of the present invention and linen fibre have good affinity, and effect of impregnation is better; And phosphate ester modified starch and nano silicon are combined in formula, on the one hand, phosphate ester modified starch is suitable for sodolin starching; Nano silicon contributes to starch dispersion in the slurry on the other hand, also improves the sizing performance of slurry to a certain extent.The modified starch added and albumen slurry promote mutually, with the use of glycerine, can improve the sizing performance of slurry further.Plant material for first three, the present invention selects modified silicon oil defoamer as defoamer, can effectively eliminate the foam produced in sizing process, make slurry more fully with clothing in contact, improve starching efficiency, save slurry.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be further described.
The present embodiment is applicable to the spinning sizing agent of sodolin, its component by mass ratio as follows:
Albumen slurry: 75 parts, nano SiO 2 modified starch: 15 parts, glycerine: 8 parts, modified silicon oil defoamer: 2 parts, Argine Monohydrochloride: 4 parts; Sulfamic acid sodium: 2 parts; Polyacrylate: 2 parts;
Nano SiO 2 modified starch adds in deionized water after being mixed with silica flour by phosphate ester modified starch, and add NaOH and methyl alcohol, after being hydrolyzed, dry purification obtains, wherein, and phosphate ester modified starch: silica flour: NaOH: the quality proportioning of methyl alcohol is: 100:6:0.1:0.2;
It is in the ethanolic solution of 70% that albumen slurry adds concentration by soybean protein, after at the uniform velocity stirring 15 minutes at 46 DEG C, adopt concentration be the salt acid for adjusting pH value of 30% to 7-8, obtain after elimination sediment;
Modified silicon oil defoamer by quality proportioning be the polyethers of 1:15 and silicon oil of low hydrogen content modification temperature 1000 DEG C, obtained under modification time 1.5h.
In addition to the implementation, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of application claims.
Claims (4)
1. be applicable to a spinning sizing agent for sodolin, its component by mass ratio as follows:
Albumen slurry: 75 parts, nano SiO 2 modified starch: 15 parts, glycerine: 8 parts, modified silicon oil defoamer: 2 parts;
Described nano SiO 2 modified starch adds in deionized water after being mixed with silica flour by phosphate ester modified starch, and add NaOH and methyl alcohol, after being hydrolyzed, dry purification obtains, wherein, phosphate ester modified starch: silica flour: NaOH: the quality proportioning of methyl alcohol is: 100:6:0.1:0.2;
It is in the ethanolic solution of 70% that described albumen slurry adds concentration by soybean protein, after at the uniform velocity stirring 15 minutes at 46 DEG C, adopt concentration be the salt acid for adjusting pH value of 30% to 7-8, obtain after elimination sediment;
Described modified silicon oil defoamer by quality proportioning be the polyethers of 1:15 and silicon oil of low hydrogen content modification temperature 100 DEG C, obtained under modification time 1.5h.
2. the spinning sizing agent being applicable to sodolin according to claim 1, is characterized in that: the Argine Monohydrochloride also comprising 4 parts by mass.
3. the spinning sizing agent being applicable to sodolin according to claim 2, is characterized in that: the sulfamic acid sodium also comprising 2 parts by mass.
4. the spinning sizing agent being applicable to sodolin according to claim 3, is characterized in that: the polyacrylate also comprising 2 parts by mass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410149755.8A CN103898759B (en) | 2014-04-15 | 2014-04-15 | A kind of spinning sizing agent being applicable to sodolin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410149755.8A CN103898759B (en) | 2014-04-15 | 2014-04-15 | A kind of spinning sizing agent being applicable to sodolin |
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| Publication Number | Publication Date |
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| CN103898759A CN103898759A (en) | 2014-07-02 |
| CN103898759B true CN103898759B (en) | 2016-03-09 |
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| CN201410149755.8A Expired - Fee Related CN103898759B (en) | 2014-04-15 | 2014-04-15 | A kind of spinning sizing agent being applicable to sodolin |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106521953B (en) * | 2016-11-17 | 2019-10-18 | 过冬 | A kind of environment-friendly type spinning sizing agent and preparation method thereof |
| CN106480728B (en) * | 2016-11-17 | 2019-05-17 | 过冬 | A kind of spinning sizing agent and preparation method thereof |
| CN107237132A (en) * | 2017-06-04 | 2017-10-10 | 于世金 | The preparation method and applications of soybean protein isolate environment-friendly size |
| CN107761387A (en) * | 2017-11-29 | 2018-03-06 | 苏州润弘贸易有限公司 | Fabric size |
| CN107893331A (en) * | 2017-11-29 | 2018-04-10 | 苏州润弘贸易有限公司 | A kind of spinning sizing agent |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1382864A (en) * | 2002-06-12 | 2002-12-04 | 弘生集团有限公司 | Size composition for textile |
| CN101935951A (en) * | 2010-09-16 | 2011-01-05 | 湖北达雅化工技术发展有限公司 | Textile size combination |
| CN103087332A (en) * | 2013-01-21 | 2013-05-08 | 东华大学 | Preparation method of proteins and protein-based sizes for warp sizing |
| CN103643515A (en) * | 2013-12-30 | 2014-03-19 | 张海峰 | Textile size and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0247371A (en) * | 1988-08-08 | 1990-02-16 | Kiyoueishiya Yushi Kagaku Kogyo Kk | Silicone-based softening agent composition for textile |
| JP3618484B2 (en) * | 1996-08-28 | 2005-02-09 | 日澱化學株式会社 | Polyvinyl acetate emulsion and non-accumulating fiber glue |
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2014
- 2014-04-15 CN CN201410149755.8A patent/CN103898759B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1382864A (en) * | 2002-06-12 | 2002-12-04 | 弘生集团有限公司 | Size composition for textile |
| CN101935951A (en) * | 2010-09-16 | 2011-01-05 | 湖北达雅化工技术发展有限公司 | Textile size combination |
| CN103087332A (en) * | 2013-01-21 | 2013-05-08 | 东华大学 | Preparation method of proteins and protein-based sizes for warp sizing |
| CN103643515A (en) * | 2013-12-30 | 2014-03-19 | 张海峰 | Textile size and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| Soy proteins as environmentally friendly sizing agents to replace polyvinyl alcohol);Lihong Chen et.al;《Environmental Science and Pollution Research》;20130328;第20卷(第9期);第6085-6095页 * |
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| CN103898759A (en) | 2014-07-02 |
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