CN103875688A - Pesticide composition containing pymetrozine and abamectin - Google Patents
Pesticide composition containing pymetrozine and abamectin Download PDFInfo
- Publication number
- CN103875688A CN103875688A CN201410102352.8A CN201410102352A CN103875688A CN 103875688 A CN103875688 A CN 103875688A CN 201410102352 A CN201410102352 A CN 201410102352A CN 103875688 A CN103875688 A CN 103875688A
- Authority
- CN
- China
- Prior art keywords
- pymetrozine
- avermectin
- abamectin
- pesticide composition
- composition containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005925 Pymetrozine Substances 0.000 title claims abstract description 25
- QHMTXANCGGJZRX-WUXMJOGZSA-N pymetrozine Chemical compound C1C(C)=NNC(=O)N1\N=C\C1=CC=CN=C1 QHMTXANCGGJZRX-WUXMJOGZSA-N 0.000 title claims abstract description 25
- 239000005660 Abamectin Substances 0.000 title claims abstract description 21
- 239000000203 mixture Substances 0.000 title claims abstract description 19
- 239000000575 pesticide Substances 0.000 title claims abstract description 14
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 title abstract 3
- 229950008167 abamectin Drugs 0.000 title abstract 3
- 239000008187 granular material Substances 0.000 claims abstract description 5
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims description 18
- 229920002101 Chitin Polymers 0.000 claims description 9
- 239000004480 active ingredient Substances 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 229920001661 Chitosan Polymers 0.000 abstract 1
- 206010059866 Drug resistance Diseases 0.000 abstract 1
- 241000238631 Hexapoda Species 0.000 description 7
- 241000176086 Sogatella furcifera Species 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 4
- 241000209094 Oryza Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 229960003692 gamma aminobutyric acid Drugs 0.000 description 3
- 238000011835 investigation Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- 241000426497 Chilo suppressalis Species 0.000 description 2
- 108010062745 Chloride Channels Proteins 0.000 description 2
- 102000011045 Chloride Channels Human genes 0.000 description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 210000005036 nerve Anatomy 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- OGNSCSPNOLGXSM-UHFFFAOYSA-N (+/-)-DABA Natural products NCCC(N)C(O)=O OGNSCSPNOLGXSM-UHFFFAOYSA-N 0.000 description 1
- HUTNOYOBQPAKIA-UHFFFAOYSA-N 1h-pyrazin-2-one Chemical class OC1=CN=CC=N1 HUTNOYOBQPAKIA-UHFFFAOYSA-N 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241001124076 Aphididae Species 0.000 description 1
- 241000238421 Arthropoda Species 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- 241001414720 Cicadellidae Species 0.000 description 1
- 241000008892 Cnaphalocrocis patnalis Species 0.000 description 1
- 241001466042 Fulgoromorpha Species 0.000 description 1
- 241001556089 Nilaparvata lugens Species 0.000 description 1
- 241000819999 Nymphes Species 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000002457 bidirectional effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 230000002102 hyperpolarization Effects 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 231100000518 lethal Toxicity 0.000 description 1
- 230000001665 lethal effect Effects 0.000 description 1
- 231100000225 lethality Toxicity 0.000 description 1
- 231100001225 mammalian toxicity Toxicity 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 210000001640 nerve ending Anatomy 0.000 description 1
- 230000002232 neuromuscular Effects 0.000 description 1
- 210000002569 neuron Anatomy 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 210000004894 snout Anatomy 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 210000000225 synapse Anatomy 0.000 description 1
- 230000005062 synaptic transmission Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
The invention relates to a pesticide composition containing pymetrozine and abamectin. The effective component is compounded from pymetrozine abamectin and chitosan in a weight ratio of (1-3):(1-3):1:3. The pesticide composition is prepared into granules for use. The composition has obvious compound synergistic effect, can postpone the drug resistance of the single agent, lowers the pesticide consumption and saves the input cost.
Description
Technical field
The present invention relates to a kind of composition pesticide containing pymetrozine and Avermectin.
Background technology
Pymetrozine, has another name called pyrazinones, and English name pymetrozine is a kind of pyridine heterocycle insecticides of brand new, is mainly used in the control of aphid, aleyrodid, leafhopper and various plant hoppers on all kinds of crops.Pymetrozine has interior suction conductivity in plant corpus, enters in plant corpus through the parenchyma of plant, carries out to top with to the Bidirectional Conduction of root in plant phloem and xylem.Pymetrozine or a kind of environmentally friendly insecticide, toxicology data shows, pymetrozine is very low to mammalian toxicity, arthropods to most of non-targets, birds, fish, Predatory Mites class natural enemies security, and its metabolite leaching, minimum to groundwater contamination, therefore in integrated control (IPM), there is outstanding performance.The insecticidal mechanism uniqueness of pymetrozine, once insect contacts this medicament, stops taking food immediately, produce " lancet puncture is blocked " effect, and this process is irreversible physical action.Also just because of its unique insecticidal mechanism, insect stops taking food generally wants the 3-5 talent can be hungry to death afterwards, causes knocking down property of insect slow, and peasant household is difficult to acceptance psychologically.
Avermectin is a kind of never poison, its mechanism is the GABA acceptor that acts on insect neuron cynapse or neuromuscular synapse, the information transmission of nerve endings in interference insect body, excite nerve not the tip emit neurotransmission inhibitor γ-aminobutyric acid (GA-BA), impel the chloride channel of GABA gate to extend open, chloride channel is had to activation, a large amount of chlorions pour in and cause the hyperpolarization of neu current potential, cause neu in holddown, thereby block nerves is contacting of the tip and muscle not, makes insect paralysis, food refusal, death.Because of its mechanism of action uniqueness, thus with conventional medicament without cross resistance.At present, Avermectin is mainly used in preventing and treating soil insect, mite class and rice leaf roll snout moth's larva.
The inventor is in once accidental chance, in a field that simultaneously breaks out rice leaf roller and rice fulgorid, use after Avermectin and pymetrozine simultaneously, after medicine 1 day, rice fulgorid is shown to significantly knocking down property, and after medicine, investigation in 2-3 days does not bring back to life, and then the mixture effect of Avermectin and pymetrozine is made further research, also studied subsequently and to have added the synergistic effect of spreading fertilizer over the fields use after chitin, the present invention obtains based on this just.
Summary of the invention
Technical problem to be solved by this invention is to provide the composition pesticide that a kind of compound synergic significantly contains pymetrozine and Avermectin.
The present invention solves the problems of the technologies described above taked technical scheme: a kind of composition pesticide containing pymetrozine and Avermectin, to be that 1-3:1-3:1:3 is composite by pymetrozine, Avermectin and chitin according to weight ratio form active ingredient.
Further, described composition pesticide is prepared into granule use.
Compared with prior art, compound synergic of the present invention is obvious, can delay the pesticide resistance that single dose is used, and reduces pesticide dosage, saves input cost.
Embodiment
By the following examples technical scheme of the present invention and beneficial effect are described further.
One, indoor joint toxicity measuring test
Pymetrozine, Avermectin and chitin are mixed and are made into binary built agent as No. 9, No. 1-mixture of mixture by active ingredient part by weight 1:1:1,1:3:1,1:3:3,3:1:1,3:1:3,1:1:2,1:2:2,2:2:3,3:1:2 respectively, by No. 9, pymetrozine and 2 kinds of single doses of Avermectin and No. 1-mixture of mixture from 20ppm according to 6 concentration of the each dilution of geometric ratio gradient, chitin single dose according to 6 concentration of the each dilution of geometric ratio gradient, is processed as blank using clear water from 200ppm.Take Brown Planthopper nymph in 3 age as examination worm, adopt rice stem infusion process to measure, after 72 hours, investigate respectively dead borer population, calculate lethality, lethal in dense and co-toxicity coefficient.Final statistics is as shown in the table:
The measurement result of indoor joint toxicity measuring test shows above, and No. 1-mixture of mixture is all greater than 120 to the co-toxicity coefficient of rice fulgorid No. 9, shows obvious synergistic effect.
Two, product Preparation Example
Embodiment 1
18% pymetrozine Avermectin chitin wetting powder
Formula: pymetrozine 6kg, Avermectin 6kg, chitin 6kg, lauryl sodium sulfate 2kg, calcium lignosulfonate 2kg, Negel 2kg, pulls open powder 1kg, and bentonite complements to 100kg.
Said components is mixed and make wetting powder in mixing after air-flow crushing in proportion.
Embodiment 2
0.7% pymetrozine Avermectin chitin granule
Formula: pymetrozine 0.3kg, Avermectin 0.1kg, chitin 0.3kg, naphthalenesulfonate formaldehyde condensation compound 2kg, lauryl sodium sulfate 2kg, starch 2kg, kaolin complements to 100kg.
Said components is mixed, pulverize, stir after adding water-wet, then use screw extruder pelletizer granulation, sieving after dry makes granule.
Three, product Application Example
Field experiment 1: embodiment 1 products obtained therefrom is watered to spraying in rice fulgorid outburst peak period and uses.Result is as shown in the table:
Field experiment 2: embodiment 2 products obtained therefroms are used after 15 days after rice transplanting, and rice fulgorid when outburst first round is carried out the rice fulgorid investigation of causing harm, the first round is carried out the striped rice borer investigation of causing harm when striped rice borer is broken out.
The final statistics of above-mentioned field experiment is as shown in the table:
Claims (2)
1. containing a composition pesticide for pymetrozine and Avermectin, it is characterized in that, to be that 1-3:1-3:1:3 is composite by pymetrozine, Avermectin and chitin according to weight ratio form active ingredient.
2. the composition pesticide containing pymetrozine and Avermectin according to claim 1, is characterized in that, described composition pesticide is prepared into granule and uses.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410102352.8A CN103875688B (en) | 2014-03-19 | 2014-03-19 | A kind of composition pesticide containing pymetrozine and Avermectin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410102352.8A CN103875688B (en) | 2014-03-19 | 2014-03-19 | A kind of composition pesticide containing pymetrozine and Avermectin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103875688A true CN103875688A (en) | 2014-06-25 |
| CN103875688B CN103875688B (en) | 2015-10-14 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410102352.8A Expired - Fee Related CN103875688B (en) | 2014-03-19 | 2014-03-19 | A kind of composition pesticide containing pymetrozine and Avermectin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103875688B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999025188A2 (en) * | 1997-11-14 | 1999-05-27 | Novartis Ag | Pesticidal compositions comprising abamectin |
| CN1961670A (en) * | 2005-11-11 | 2007-05-16 | 周弘 | Coated coccid killing medicinal liquid used for plant shooting and leaf surface and mixing preparation method thereof |
| CN101223881A (en) * | 2007-01-18 | 2008-07-23 | 青岛科技大学 | Desinsection acaricides compounds mixed with abamectin or banleptm |
| CN101416634A (en) * | 2008-11-06 | 2009-04-29 | 张少武 | Insecticidal composition containing pymetrozine |
-
2014
- 2014-03-19 CN CN201410102352.8A patent/CN103875688B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999025188A2 (en) * | 1997-11-14 | 1999-05-27 | Novartis Ag | Pesticidal compositions comprising abamectin |
| CN1961670A (en) * | 2005-11-11 | 2007-05-16 | 周弘 | Coated coccid killing medicinal liquid used for plant shooting and leaf surface and mixing preparation method thereof |
| CN101223881A (en) * | 2007-01-18 | 2008-07-23 | 青岛科技大学 | Desinsection acaricides compounds mixed with abamectin or banleptm |
| CN101416634A (en) * | 2008-11-06 | 2009-04-29 | 张少武 | Insecticidal composition containing pymetrozine |
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| Publication number | Publication date |
|---|---|
| CN103875688B (en) | 2015-10-14 |
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Owner name: GU XIANGMAO Free format text: FORMER OWNER: HUANG YEXIN Effective date: 20150826 Free format text: FORMER OWNER: YANG XINLAN Effective date: 20150826 |
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Effective date of registration: 20150826 Address after: 266000 Licang, Qingdao, No. nine East water road, No. 320, No. Applicant after: Gu Xiangmao Address before: Binyang city Nanning County Yang Cun 530423 the Guangxi Zhuang Autonomous Region Wangling old Mongolia Applicant before: Huang Yexin Applicant before: Yang Xinlan |
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Address after: 225327 Taizhou City, Jiangsu province high port town of Yongan East Road, No. 80 Patentee after: Gu Xiangmao Address before: 266000 Licang, Qingdao, No. nine East water road, No. 320, No. Patentee before: Gu Xiangmao |
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Effective date of registration: 20170615 Address after: 415000, Changde Hanshou Economic Development Zone Hunan star neighborhood committee Golden Road (Changde Jin Jiang cement factory next to) Patentee after: HUNAN DONGYONG CHEMICAL CO.,LTD. Address before: 510000 unit 2414-2416, building, No. five, No. 371, Tianhe District, Guangdong, China Patentee before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Effective date of registration: 20170615 Address after: 510000 unit 2414-2416, building, No. five, No. 371, Tianhe District, Guangdong, China Patentee after: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Address before: 225327 Taizhou City, Jiangsu province high port town of Yongan East Road, No. 80 Patentee before: Gu Xiangmao |
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Effective date of registration: 20210426 Address after: 415000 South West intersection of Longxing Avenue and Jinma Road, daoliuping community, Hanshou hi tech Industrial Park, Changde City, Hunan Province Patentee after: Hanshou Jincan Agricultural Technology Co.,Ltd. Address before: 415000 Hunan Changde Hanshou Economic Development Zone Tianxing neighborhood committee Golden Road (beside Changde Jin Jiang cement factory) Patentee before: HUNAN DONGYONG CHEMICAL Co.,Ltd. |
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