CN101223881A - Desinsection acaricides compounds mixed with abamectin or banleptm - Google Patents
Desinsection acaricides compounds mixed with abamectin or banleptm Download PDFInfo
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- CN101223881A CN101223881A CNA2007100132570A CN200710013257A CN101223881A CN 101223881 A CN101223881 A CN 101223881A CN A2007100132570 A CNA2007100132570 A CN A2007100132570A CN 200710013257 A CN200710013257 A CN 200710013257A CN 101223881 A CN101223881 A CN 101223881A
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- CN
- China
- Prior art keywords
- chitin
- water
- avermectin
- desinsection
- microemulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000005660 Abamectin Substances 0.000 title claims abstract description 33
- 239000000642 acaricide Substances 0.000 title claims abstract description 11
- 150000001875 compounds Chemical class 0.000 title abstract description 4
- 230000000895 acaricidal effect Effects 0.000 title abstract description 3
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 title description 3
- 229950008167 abamectin Drugs 0.000 title description 3
- 229920002101 Chitin Polymers 0.000 claims abstract description 44
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 238000002360 preparation method Methods 0.000 claims abstract description 11
- 241000244206 Nematoda Species 0.000 claims abstract description 9
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 8
- 239000006184 cosolvent Substances 0.000 claims abstract description 8
- 150000003839 salts Chemical class 0.000 claims description 25
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexyloxide Natural products O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 17
- 229920001661 Chitosan Polymers 0.000 claims description 12
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 10
- 238000009313 farming Methods 0.000 claims description 7
- 239000004480 active ingredient Substances 0.000 claims description 5
- 238000009472 formulation Methods 0.000 claims description 5
- 241000238631 Hexapoda Species 0.000 claims description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
- 239000003905 agrochemical Substances 0.000 claims description 3
- 239000002671 adjuvant Substances 0.000 claims description 2
- 210000000481 breast Anatomy 0.000 claims 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 1
- 125000002243 cyclohexanonyl group Chemical group *C1(*)C(=O)C(*)(*)C(*)(*)C(*)(*)C1(*)* 0.000 claims 1
- 239000008367 deionised water Substances 0.000 claims 1
- 229910021641 deionized water Inorganic materials 0.000 claims 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 claims 1
- 239000002736 nonionic surfactant Substances 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- 241000607479 Yersinia pestis Species 0.000 abstract description 3
- 201000010099 disease Diseases 0.000 abstract description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 3
- 239000002917 insecticide Substances 0.000 abstract description 3
- 238000012271 agricultural production Methods 0.000 abstract description 2
- 239000002552 dosage form Substances 0.000 abstract description 2
- 239000000575 pesticide Substances 0.000 abstract description 2
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 abstract 2
- 230000002265 prevention Effects 0.000 abstract 2
- 241000238876 Acari Species 0.000 abstract 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000003995 emulsifying agent Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 230000003115 biocidal effect Effects 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000036039 immunity Effects 0.000 description 2
- 230000001939 inductive effect Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical compound CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 description 1
- 241001124076 Aphididae Species 0.000 description 1
- 241001182720 Cacopsylla pyrisuga Species 0.000 description 1
- 102000012286 Chitinases Human genes 0.000 description 1
- 108010022172 Chitinases Proteins 0.000 description 1
- 241001498622 Cixius wagneri Species 0.000 description 1
- 241000594033 Liriomyza bryoniae Species 0.000 description 1
- 241000243785 Meloidogyne javanica Species 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 241000256247 Spodoptera exigua Species 0.000 description 1
- 235000001231 Streptopus amplexifolius Nutrition 0.000 description 1
- 244000305550 Streptopus amplexifolius Species 0.000 description 1
- 241000018137 Trialeurodes vaporariorum Species 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000001679 anti-nematodal effect Effects 0.000 description 1
- 230000037358 bacterial metabolism Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 210000001136 chorion Anatomy 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- GCKZANITAMOIAR-XWVCPFKXSA-N dsstox_cid_14566 Chemical compound [O-]C(=O)C1=CC=CC=C1.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H]([NH2+]C)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 GCKZANITAMOIAR-XWVCPFKXSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000003120 macrolide antibiotic agent Substances 0.000 description 1
- 229940041033 macrolides Drugs 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000000593 microemulsion method Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000002073 mitogenetic effect Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- -1 polyoxyethylene Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Abstract
The invention relates to a composition of chitin and avermectin or emamectin benzoate for insecticide and acaricide, and is characterized in that the dosage form of the compound preparation is microemulsion and the weight percentage of effective components in the compound preparation contains 0.5 to 10 percent of the chitin, 0.2 to 2 percent of the avermectin or 0.2 to 1.5 percent of the emamectin benzoate, with the rest of an auxiliary agent, a cosolvent and water. The pesticide preparation of the invention has no public pollution and can be applied to prevention of pests and mites in agricultural production, in particular to the prevention of plant nematode diseases.
Description
Technical field
The present invention relates to a kind of agricultural insecticidal, kill the mite novel formulation, specifically contain chitin and Avermectin or first and tie up the desinsection of salt composition, kill the mite microemulsion.
Background technology
Chitin (Chitin) has another name called chitin, chitin etc., and outward appearance is white translucent chip solid, water insoluble, diluted acid and diluted alkaline.Become chitosan behind the de-acetyl chitin, have another name called shitosan (Chitosan), water insoluble and dilute alkaline soln, but dissolve in most diluted acids, claim soluble chitin again; Chitin or shitosan can get chitin soluble in water through some reaction, also claim water-soluble chitosan.
At present agricultural goes up the chitin that uses and mainly contains soluble chitin and water-soluble chitosan, the latter at plant immune adjusting, inducing anti-disease, induce the root of the crop cell mitogenetic and do to have better physiologically active aspect deposits yields chitinase dissolving nematode body wall and the chorion control nematode by inducing.Water-soluble chitosan must not add the chitin water soluble liquid that organic or inorganic acid can be prepared high level, and with chemistry or Biocidal, miticide good compatibility stability is arranged.Though water-soluble chitosan tentatively is used for agricultural production as nuisanceless anti-nematode agent,, must use in advance and preventive effect factor such as have much room for improvement is failed penetration and promotion because its use cost is higher.
Avermectin (Abamectin) is the macrolides Biocidal miticide that produces by the biofermentation bacterial metabolism.Pure product are white crystal, are dissolved in alcohol, ketone, ester isopolarity organic solvent, and are water insoluble.Avermectin has desirable control efficiency to common insect, evil mite such as aphid, mite, diamond-back moth, plant hopper, trialeurodes vaporariorum, liriomyza bryoniae, pear sucker, root-knot nematode etc. on the agricultural.Important super-high-efficient Biocidal, miticide kind have been become.The emamectin-benzoate (first dimension salt) that is formed through structure of modification by Avermectin has been inherited the biologically active characteristics of Avermectin, and some refractories reason insects such as beet armyworm, nematode etc. are had higher biologically active and quick-acting.But Avermectin or first dimension salt all exist pest to its risk that develops immunity to drugs, and the control cost remains to be reduced.
Summary of the invention
The object of the invention is the deficiency that exists separately at chitin and Avermectin or first dimension salt, and a kind of efficient, wide spectrum, moderate, the nuisanceless desinsection that is difficult for developing immunity to drugs of cost, mite-killing preparation are provided.Said preparation can be used for the control of control, the especially nematode of agriculture common insect, evil mite.
Desinsection of the present invention, kill and to contain chitin and Avermectin or two kinds of active ingredients of first dimension salt in the mite microemulsion.Because there are many disadvantages in insoluble chitin and soluble chitin on solubility property and physiologically active, so the preferred water-soluble chitosan of the present invention.Water-soluble chitosan is promoting crop precocity, volume increase, is improving quality, obtaining very ten-strike aspect disease-resistant, the degeneration-resistant and Synergistic fertilizer, especially prevent and treat Plant nematode aspect and Avermectin or first dimension salt etc. and have diverse mechanism of action, between do not have cross resistance, and complementary synergistic effect is arranged.Water-soluble chitosan and Avermectin or first dimension salt is composite, can be from different perspectives, different aspect kills nematode, and control efficiency is subjected to the influence of spraying time less, produces delaying Avermectin or first dimension salt pesticide resistance, and it is very effective to improve integrated control effect.Microemulsion is to be the environment friendly agricultural formulation of medium with water, and active ingredient is biological insecticides in the preparation, therefore as the preferred microemulsion of the formulation of public nuisance-free agricultural chemicals preparation.
Desinsection of the present invention, the weight percentage that kills the mite microemulsion are as follows:
Chitin 0.5～10%
Avermectin 0.2～2%
Or first dimension salt 0.2～1.5%
Auxiliary agent, cosolvent, water add to 100%
The suitableeest weight percentage that provides product for the economic usability that improves product is as follows:
Chitin 3～6%
Avermectin 0.8～1.5%
Or first dimension salt 0.5～1.0%
Auxiliary agent, cosolvent, water add to 100%
Wherein the chitin as active ingredient can be former powder of water-soluble chitosan or mother liquor; Avermectin can be former powder or ointment, and first dimension salt can be the crude product of content 60～70% or the elaboration behind the recrystallization.Adjuvant used is to produce agricultural chemicals with known non-ionic monomer such as the newborn 600# of farming, Nongru-700, agricultural newborn 100# etc., it also can be the compound of nonionic and anion (as the newborn 500# of farming), also can add the wetting and penetrating agent that improves wetting, permeance property such as alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, penetrant t, azone etc., used cosolvent can be toluene, methyl alcohol, ethanol, isopropyl alcohol, n-butanol, cyclohexanone, N, one or more compositions in the dinethylformamide etc.Desinsection of the present invention, the preparation of killing the mite microemulsion or production method are microemulsion production methods commonly used, being about to Avermectin or first dimension salt dissolves with cosolvent, adding auxiliary agent stirs evenly, till mixing to clear with chitin water soluble liquid, promptly get chitin and Avermectin or first dimension salt microemulsion.
Advantage of the present invention:
1, reduced environmental pollution, production, storing safety have been improved, Avermectin and first dimension salt regular dosage form are missible oil, because the preparation effective content is generally 0.2～1.8%, in the preparation poisonous, inflammable benzene, alcohols solvent, and primary solvent is a water in the microemulsion, only contains a small amount of organic solvent, therefore more environmental protection, safer.
2, improved control efficiency and The comprehensive performance: active ingredient Avermectin or first dimension salt particle degree reaches nanoscale in the microemulsion, soup pest and plant leaf surface are had higher opening up, wetting, osmosis, effective rate of utilization increases substantially; Simultaneously the short length of chitin, lure anti-and synergistic effect to significantly improve the comprehensive function of product.Through field plot trial, 1000 times of liquid of 6% chitin aqua, in 2000 times of liquid irrigating root controls of 1.8% abamectin emulsifiable concentrate cucumber root nematode, 20 preventive effects are respectively 47.0% and 53.8% behind the medicine, and the preventive effect of 5.9% chitin, 2000 times of liquid of avermectin micro-emulsion (embodiment 1) dilution reaches 64.2%, promptly still has the highest preventive effect under the situation that Avermectin reduces by half.
Specific embodiment given below is to further specify rather than limitation of the present invention of the present invention:
Embodiment 1:
Chitin 5.0%
Avermectin 0.9%
Cyclohexanone 5.0%
The newborn 601# 6.0% of farming
QK-2 emulsifier 5.0%
Water surplus
Avermectin is dissolved with cyclohexanone, add agricultural newborn 601# and QK-2 emulsifier and stir evenly, mix to stir to clear promptly getting 5.9% chitin A Wei microemulsion with chitin water soluble liquid.
Embodiment 2:
Chitin 4.5%
First dimension salt 0.5%
Dimethyl formamide 1.0%
Cyclohexanone 4.0%
The newborn 601# 6.0% of farming
OP-7 2.0％
QK-2 emulsifier 7.0%
Water surplus
By above-mentioned prescription, first is tieed up salt with dimethyl formamide and cyclohexanone dissolving, add OP-7 and QK-2 emulsifier, mix to clear with chitin water soluble liquid after stirring evenly and promptly get 5% chitin first dimension salt microemulsion.
Embodiment 3:
Chitin 3.0%
Avermectin 1.5%
JFC 2.0％
Nongru-700 # 3.0%
Dimethyl formamide 5.0%
Toluene 5.0%
QK-2 emulsifier 7.0%
Water surplus
With the Avermectin dissolution with solvents, the adding auxiliary agent stirs evenly the back and mixes to clear with chitin water soluble liquid, promptly gets 4.5% chitin A Wei microemulsion.
Embodiment 4:
Chitin 3.5%
First dimension salt 1.0%
Methyl alcohol 4.0%
Cyclohexanone 6.0%
The newborn 1601# 5.0% of farming
OP-8 1.0％
QK-1 emulsifier 6.0%
Water surplus
By above-mentioned prescription, first is tieed up salt with methyl alcohol and cyclohexanone dissolving, add auxiliary agent and stir evenly, promptly get 4.5% chitin first to clear and tie up the salt microemulsion with stirring after chitin water soluble liquid mixes.
Claims (5)
1. one kind contains desinsection, the miticide composition that chitin, Avermectin or first are tieed up salt, and the formulation that it is characterized in that the said composition preparation is a microemulsion, and the weight percentage of chitin, Avermectin or two kinds of active ingredients of first dimension salt is as follows:
Chitin 0.5～10%
Avermectin 0.2～2%
Or first dimension salt 0.2～1.5%
All the other are auxiliary agent, cosolvent and water.
2. desinsection as claimed in claim 1, miticide composition is characterized in that chitin is soluble chitin or water-soluble chitosan, more preferably water-soluble chitosan.
3. desinsection as claimed in claim 1, miticide composition, it is characterized in that adjuvant used is to produce the known auxiliary agent of agricultural chemicals, as farming breast 600
#, Nongru-700
#, farming breast 1600
#, OP series non-ionic surfactants etc.
4. desinsection as claimed in claim 1, miticide composition is characterized in that used cosolvent is cyclohexanone, n-butanol, DMF, acetate etc.More preferably cyclohexanone is a cosolvent, and its feature is that also institute's water is running water or deionized water.
5. desinsection as claimed in claim 1, miticide composition is characterized in that this microemulsion formulation can execute mode by foliar spray or root and prevent and treat plant and insect, mite are arranged, the especially control of Plant nematode.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007100132570A CN101223881A (en) | 2007-01-18 | 2007-01-18 | Desinsection acaricides compounds mixed with abamectin or banleptm |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007100132570A CN101223881A (en) | 2007-01-18 | 2007-01-18 | Desinsection acaricides compounds mixed with abamectin or banleptm |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101223881A true CN101223881A (en) | 2008-07-23 |
Family
ID=39856263
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007100132570A Pending CN101223881A (en) | 2007-01-18 | 2007-01-18 | Desinsection acaricides compounds mixed with abamectin or banleptm |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101223881A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102342278A (en) * | 2011-11-09 | 2012-02-08 | 江西海科瑞特作物科学有限公司 | Sterilization composition containing cyproconazole and chitin |
| CN102428966A (en) * | 2011-09-29 | 2012-05-02 | 山东靠山生物科技有限公司 | Composite bio-formulation for preventing crop diseases and application thereof |
| CN102613214A (en) * | 2008-12-31 | 2012-08-01 | 浙江世佳科技有限公司 | Microemulsion of propylene glycol alginate and emamectin benzoate |
| CN102696636A (en) * | 2011-03-27 | 2012-10-03 | 山东海利尔化工有限公司 | Insecticidal composition containing biological pesticide |
| CN102771503A (en) * | 2012-08-03 | 2012-11-14 | 广西汇丰生物科技有限公司 | Granule containing chitin |
| CN103875688A (en) * | 2014-03-19 | 2014-06-25 | 黄业新 | Pesticide composition containing pymetrozine and abamectin |
| CN104719345A (en) * | 2015-03-31 | 2015-06-24 | 青州伟格生物科技有限公司 | Preparation method of biological preparation for preventing and controlling vegetable nematode disease |
| WO2015114590A1 (en) * | 2014-02-03 | 2015-08-06 | Pacific Agrosciencies S.A.I.C. | Liquid non-aqueous pesticide composition, method for preparing the liquid non-aqueous pesticide composition and method for eliminating insects, acarids and nematodes in cultures |
| CN107087639A (en) * | 2017-05-11 | 2017-08-25 | 河南农业大学 | A kind of virus insect disinfestation suspension agent containing chitin and preparation method thereof |
| CN109355236A (en) * | 2018-12-07 | 2019-02-19 | 山东土木启生物科技有限公司 | A kind of complex micro organism fungicide and preparation method with prevention and treatment nematode |
| CN111700065A (en) * | 2020-07-16 | 2020-09-25 | 河南农业大学 | Avermectin nano slow-release body and preparation method and application thereof |
-
2007
- 2007-01-18 CN CNA2007100132570A patent/CN101223881A/en active Pending
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102613214A (en) * | 2008-12-31 | 2012-08-01 | 浙江世佳科技有限公司 | Microemulsion of propylene glycol alginate and emamectin benzoate |
| CN102696636A (en) * | 2011-03-27 | 2012-10-03 | 山东海利尔化工有限公司 | Insecticidal composition containing biological pesticide |
| CN102428966B (en) * | 2011-09-29 | 2014-10-22 | 耿小青 | Composite bio-formulation for preventing crop diseases and application thereof |
| CN102428966A (en) * | 2011-09-29 | 2012-05-02 | 山东靠山生物科技有限公司 | Composite bio-formulation for preventing crop diseases and application thereof |
| CN102342278A (en) * | 2011-11-09 | 2012-02-08 | 江西海科瑞特作物科学有限公司 | Sterilization composition containing cyproconazole and chitin |
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| CN107087639B (en) * | 2017-05-11 | 2020-04-10 | 河南农业大学 | Chitin-containing virus insecticidal suspending agent and preparation method thereof |
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