CN103864465B - Cadmium-selenium red glaze - Google Patents
Cadmium-selenium red glaze Download PDFInfo
- Publication number
- CN103864465B CN103864465B CN201410101965.XA CN201410101965A CN103864465B CN 103864465 B CN103864465 B CN 103864465B CN 201410101965 A CN201410101965 A CN 201410101965A CN 103864465 B CN103864465 B CN 103864465B
- Authority
- CN
- China
- Prior art keywords
- frit
- additional
- red glaze
- cadmium
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Glass Compositions (AREA)
Abstract
The invention relates to high-temperature-resistant cadmium-selenium red glaze and a preparation method thereof. The cadmium-selenium red glaze is prepared from main ingredients, additional cellulose and additional pigment, wherein the main ingredients are as follows in percentage by mass: 86%-94% of frit, 3%-7% of quartz, and 3%-7% of Suzhou soil; the percentage of the additional cellulose and the percentage of the additional pigment taking up the main ingredients are respectively 0.08%-0.12% and 11%-13.5%. The preparation method comprises the steps: according to the preparation percentage, adding the main ingredients, the additional cellulose, the additional pigment and water into a ball mill and milling for 30-50 hours, to obtain the high-temperature-resistant cadmium-selenium red glaze, wherein the ratio of ballstone to ingredients to water is equal to 1.5:1:1, and the fineness is 0.02%-0.03% of million-mesh screen residue weight. The cadmium-selenium red glaze has the high-temperature-resistant characteristic, can be used under the condition of 1150DEG C-1200DEG C, and is stable in color and applicable to glaze decoration of bone china, magnesia porcelain and durable porcelain.
Description
Technical field
The present invention relates to the upper red glaze, particularly a kind of high temperature cadmium selenium red glaze used of pottery.
Background technology
The cadmium selenium red glaze that pottery uses, high thermal resistance is poor, can present redness more than 1000 DEG C, and after 1000 DEG C, colorant rolls into a ball due to vaporization at high temperature and oxidation that to become black even colourless, and therefore, the application for a long time in ceramic is very limited.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of resistant to elevated temperatures cadmium selenium red glaze.
For solving above technical problem, the technical solution used in the present invention is:
A kind of cadmium selenium red glaze, it by meeting the major ingredient of following mass percent, plus fiber element, additional pigment are formulated, wherein,
Major ingredient: frit 86%-94%, quartzy 3%-7% and Suzhou soil 3%-7%;
Plus fiber element and additional pigment account for the percentages of major ingredient with it, plus fiber element 0.08%-0.12%, additional pigment 11%-13.5%;
Frit is made up of the component meeting following mass percent: feldspar 45%-60%, quartzy 15%-19%, calcite 10%-14%, the little white spirit 6%-10% in Tangshan, talcum 2%-5%, kaolin 1%-3%, ZnO2%-6%;
Wherein, feldspar, quartz, calcite, the little white spirit in Tangshan, talcum and kaolinic moiety are as shown in the table:
| Title | SiO 2 | Al 2O 3 | Fe 2O 3 | TiO 2 | K 2O | Na 2O | CaO | MgO | IL |
| Feldspar | 67.24 | 17.05 | 0.13 | 0 | 12 | 2.67 | 0 | 0 | 0 |
| Quartz | 99.88 | 0.85 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
| The little white spirit in Tangshan | 25.48 | 2.45 | 0.46 | 0 | 0 | 0 | 19.41 | 19 | 30.63 |
| Calcite | 1.67 | 1.05 | 0 | 0 | 0 | 0 | 53.72 | 0.67 | 42.15 |
| Talcum | 61.06 | 0.2 | 0.65 | 0 | 0.06 | 0 | 0.08 | 33.18 | 5.02 |
| Kaolin | 51.45 | 34.52 | 0.16 | 0.01 | 2.5 | 0.07 | 0.99 | 0.14 | 10.99 |
Additional pigment is made up of the haematochrome of 93.5% and the yellow pigment of 6.5%.Additional pigment is the product of public sale on market, and pigment of the present invention belongs to look and wraps up in series, and the ratio of adjustment pigment can obtain, from dark red to a series of form and aspect such as orange, the present invention is to provide a kind of ratio of red glaze.
As the preferred scheme of one, in major ingredient, frit 90%, quartz 5%, Suzhou soil 5%.
As the preferred scheme of another kind, frit is made up of the component meeting following mass percent: feldspar 54%, quartz 17%, calcite 12%, the little white spirit 8% in Tangshan, talcum 3%, kaolin 2%, ZnO4%.
The present invention also provides a kind of method preparing above parent glaze simultaneously, that the major ingredient prepared in proportion, plus fiber element, additional pigment are added grinding in ball grinder 30-50 hour together with water, ballstone: material: water=1.5:1:1, fineness is the 0.02%-0.03% of 10000-hole sieve surplus, then obtains product.
Cadmium selenium red glaze provided by the invention has resistant to elevated temperatures characteristic, can use under the condition of 1150 DEG C-1200 DEG C, in colour-stable, is applicable to the glaze decorating of Bone China, magnesia porcelain, strengthening porcelain.The production method of cadmium selenium red glaze is simple, and abundant raw material source, can reduce production cost further.
Embodiment
Embodiment 1
Frit 900g, quartzy 50g, Suzhou soil 50g, plus fiber element 0.8g, additional pigment 110g;
Wherein, the composition of frit: feldspar 486g, quartzy 153g, calcite 108g, the little white spirit 72g in Tangshan, talcum 27g, kaolin 18g, ZnO36g; The composition of additional pigment: haematochrome 102.85g, yellow pigment 7.15g;
The major ingredient prepared in proportion, plus fiber element, additional pigment are added grinding in ball grinder 30 hours, ballstone together with water: material: water=1.5:1:1, fineness is the 0.02%-0.03% of 10000-hole sieve surplus, then obtains product.
Embodiment 2
Frit 860g, quartzy 70g, Suzhou soil 70g, plus fiber element 1.2g, additional pigment 135g;
Wherein, the composition of frit: feldspar 387g, quartzy 163.4g, calcite 120.4g, the little white spirit 86g in Tangshan, talcum 43g, kaolin 25.8g, ZnO34.4g; The composition of additional pigment: haematochrome 126.2g, yellow pigment 8.8g;
The major ingredient prepared in proportion, plus fiber element, additional pigment are added grinding in ball grinder 50 hours, ballstone together with water: material: water=1.5:1:1, fineness is the 0.02%-0.03% of 10000-hole sieve surplus, then obtains product.
Embodiment 3
Frit 940g, quartzy 30g, Suzhou soil 30g, plus fiber element 1.0g, additional pigment 120g;
Wherein, the composition of frit: feldspar 564g, quartzy 141g, calcite 94g, the little white spirit 56.4g in Tangshan, talcum 18.8g, kaolin 9.4g, ZnO56.4g; The composition of additional pigment: haematochrome 112.2g, yellow pigment 7.8g;
The major ingredient prepared in proportion, plus fiber element, additional pigment are added grinding in ball grinder 40 hours, ballstone together with water: material: water=1.5:1:1, fineness is the 0.02%-0.03% of 10000-hole sieve surplus, then obtains product.
Embodiment 4
Frit 900g, quartzy 30g, Suzhou soil 70g, plus fiber element 0.9g, additional pigment 130g;
Wherein, the composition of frit: feldspar 504g, quartzy 144g, calcite 117g, the little white spirit 63g in Tangshan, talcum 36g, kaolin 18g, ZnO18g; The composition of additional pigment: haematochrome 121.6g, yellow pigment 8.4g;
The major ingredient prepared in proportion, plus fiber element, additional pigment are added grinding in ball grinder 40 hours, ballstone together with water: material: water=1.5:1:1, fineness is the 0.02%-0.03% of 10000-hole sieve surplus, then obtains product.
Embodiment 5
Frit 900g, quartzy 40g, Suzhou soil 60g, plus fiber element 1.0g, additional pigment 120g;
Wherein, the composition of frit: feldspar 468g, quartzy 162g, calcite 99g, the little white spirit 81g in Tangshan, talcum 45g, kaolin 18g, ZnO27g; The composition of additional pigment: haematochrome 112.2g, yellow pigment 7.8g;
The major ingredient prepared in proportion, plus fiber element, additional pigment are added grinding in ball grinder 40 hours, ballstone together with water: material: water=1.5:1:1, fineness is the 0.02%-0.03% of 10000-hole sieve surplus, then obtains product.
Claims (3)
1. a cadmium selenium red glaze, is characterized in that: it by meet following mass percent major ingredient, plus fiber element, additional pigment is formulated, wherein,
Major ingredient: frit 86%-94%, quartzy 3%-7% and Suzhou soil 3%-7%;
Plus fiber element and additional pigment account for the percentages of major ingredient with it, plus fiber element 0.08%-0.12%, additional pigment 11%-13.5%;
Frit is made up of the component meeting following mass percent: feldspar 45%-60%, quartzy 15%-19%, calcite 10%-14%, the little white spirit 6%-10% in Tangshan, talcum 2%-5%, kaolin 1%-3%, ZnO2%-6%;
Additional pigment is made up of the haematochrome of 93.5% and the yellow pigment of 6.5%;
The major ingredient prepared in proportion, plus fiber element, additional pigment are added grinding in ball grinder 30-50 hour, ballstone together with water: material: water=1.5:1:1, fineness is the 0.02%-0.03% of 10000-hole sieve surplus, then obtains product.
2. cadmium selenium red glaze according to claim 1, is characterized in that: in major ingredient, frit 90%, quartz 5%, Suzhou soil 5%.
3. cadmium selenium red glaze according to claim 1, is characterized in that: frit is made up of the component meeting following mass percent: feldspar 54%, quartz 17%, calcite 12%, the little white spirit 8% in Tangshan, talcum 3%, kaolin 2%, ZnO4%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410101965.XA CN103864465B (en) | 2014-03-19 | 2014-03-19 | Cadmium-selenium red glaze |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410101965.XA CN103864465B (en) | 2014-03-19 | 2014-03-19 | Cadmium-selenium red glaze |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103864465A CN103864465A (en) | 2014-06-18 |
| CN103864465B true CN103864465B (en) | 2015-07-08 |
Family
ID=50903548
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410101965.XA Active CN103864465B (en) | 2014-03-19 | 2014-03-19 | Cadmium-selenium red glaze |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103864465B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104496553A (en) * | 2014-12-03 | 2015-04-08 | 谢泽武 | Vermeil glaze |
| CN112194475B (en) * | 2020-10-14 | 2022-09-27 | 平定莹玉陶瓷有限公司 | Antibacterial ivory porcelain |
| CN112194476B (en) * | 2020-10-14 | 2023-02-03 | 平定莹玉陶瓷有限公司 | Antibacterial dream porcelain |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1792996A (en) * | 2005-11-25 | 2006-06-28 | 长沙隆泰科技有限公司 | Microwave sintering process of packed cadmium selenium red glaze |
-
2014
- 2014-03-19 CN CN201410101965.XA patent/CN103864465B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1792996A (en) * | 2005-11-25 | 2006-06-28 | 长沙隆泰科技有限公司 | Microwave sintering process of packed cadmium selenium red glaze |
Non-Patent Citations (1)
| Title |
|---|
| 一次烧成Cd(S, Se)大红釉的研究;邵明梁等;《山东建材学院学报》;19990331;第13卷(第1期);第13-15页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103864465A (en) | 2014-06-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107188419B (en) | High-heat-resistance antibacterial glaze powder and preparation method thereof | |
| CN103896634B (en) | High-temperature domestic porcelain metallic bright glaze and product decorated by same | |
| CN101786904B (en) | Color-changing glaze for metallic luster ceramics and preparation method thereof | |
| UA93227C2 (en) | Ground boron-containing composition for the production of glaze, the process for its preparation and use, the process for glazing of ceramic product and the product therein | |
| CN102731168B (en) | Preparation method of white body ice crackle vitreous enamel and products produced from white body ice crackle vitreous enamel | |
| CN101050061B (en) | Pigment without lead for glass | |
| CN100447111C (en) | Crystalline glaze of iron, zinc and augite and its material compounding process | |
| CN101050060A (en) | Low temperature ceramic color without lead on glaze, and preparation method | |
| CN105330158A (en) | Glaze of brunet ceramic and preparation method of glaze | |
| CN103864465B (en) | Cadmium-selenium red glaze | |
| CN104150965A (en) | Copper red glaze formula and manufacturing process of copper red glaze porcelain | |
| CN102001864A (en) | Heat-resistant porcelain glaze | |
| CN102276149A (en) | Method for preparing fritted glaze for ancient glazed members | |
| CN105315015A (en) | Preparation method for architectural decoration flambe art ceramic tile | |
| CN100371291C (en) | Bone-green porcelain | |
| CN100594192C (en) | Ferric titanium dull kiln star spot variable composite color material and star spot glaze | |
| CN101255065A (en) | Low-temperature glaze leadless cadmium-free ceramic pigment flux | |
| CN100390089C (en) | Method for preparing flux for high-brightness pollution-less ceramic decorative material | |
| CN113800770A (en) | Intermediate-temperature double-layer transmutation fancy glaze and manufacturing method thereof | |
| CN102557753A (en) | Glaze for fine bone china | |
| CN102731075B (en) | Rustic tile prepared by utilization of Tenggeli yellow sand and preparation method thereof | |
| CN104909568A (en) | Ceramic with coffee crystal glaze layer on surface and preparation method therefor | |
| CN101565273B (en) | Vitreous enamel material, preparation method thereof and method for preparing vitreous enamel blue-white porcelain from vitreous enamel material | |
| CN113003938A (en) | Preparation method of antibacterial self-cleaning ceramic glaze | |
| CN107500740A (en) | A kind of environment-friendly black Ceramic Tiles and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |