CN103828821A - Sterilization composition containing ametoctradin and methoxyacrylates - Google Patents
Sterilization composition containing ametoctradin and methoxyacrylates Download PDFInfo
- Publication number
- CN103828821A CN103828821A CN201210493406.9A CN201210493406A CN103828821A CN 103828821 A CN103828821 A CN 103828821A CN 201210493406 A CN201210493406 A CN 201210493406A CN 103828821 A CN103828821 A CN 103828821A
- Authority
- CN
- China
- Prior art keywords
- azoles mepanipyrim
- azoles
- active component
- mepanipyrim
- weight ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 49
- 239000005726 Ametoctradin Substances 0.000 title abstract description 4
- GGKQIOFASHYUJZ-UHFFFAOYSA-N ametoctradin Chemical compound NC1=C(CCCCCCCC)C(CC)=NC2=NC=NN21 GGKQIOFASHYUJZ-UHFFFAOYSA-N 0.000 title abstract description 4
- 230000001954 sterilising effect Effects 0.000 title abstract description 4
- 238000004659 sterilization and disinfection Methods 0.000 title abstract description 4
- LQAQMOIBXDELJX-UHFFFAOYSA-N 2-methoxyprop-2-enoic acid Chemical class COC(=C)C(O)=O LQAQMOIBXDELJX-UHFFFAOYSA-N 0.000 title abstract 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 46
- 201000010099 disease Diseases 0.000 claims abstract description 44
- 239000005762 Dimoxystrobin Substances 0.000 claims abstract description 20
- 239000005800 Kresoxim-methyl Substances 0.000 claims abstract description 20
- WXUZAHCNPWONDH-DYTRJAOYSA-N dimoxystrobin Chemical compound CNC(=O)C(=N\OC)\C1=CC=CC=C1COC1=CC(C)=CC=C1C WXUZAHCNPWONDH-DYTRJAOYSA-N 0.000 claims abstract description 20
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 claims abstract description 20
- JHIPUJPTQJYEQK-ZLHHXESBSA-N orysastrobin Chemical compound CNC(=O)C(=N\OC)\C1=CC=CC=C1CO\N=C(/C)\C(=N\OC)\C(\C)=N\OC JHIPUJPTQJYEQK-ZLHHXESBSA-N 0.000 claims abstract description 20
- 150000003851 azoles Chemical class 0.000 claims description 119
- 239000005805 Mepanipyrim Substances 0.000 claims description 96
- CIFWZNRJIBNXRE-UHFFFAOYSA-N mepanipyrim Chemical compound CC#CC1=CC(C)=NC(NC=2C=CC=CC=2)=N1 CIFWZNRJIBNXRE-UHFFFAOYSA-N 0.000 claims description 96
- 239000000375 suspending agent Substances 0.000 claims description 26
- 241000233679 Peronosporaceae Species 0.000 claims description 22
- 241000894006 Bacteria Species 0.000 claims description 19
- 150000002148 esters Chemical class 0.000 claims description 19
- 239000005784 Fluoxastrobin Substances 0.000 claims description 18
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 claims description 18
- 235000007164 Oryza sativa Nutrition 0.000 claims description 15
- 230000000844 anti-bacterial effect Effects 0.000 claims description 15
- 235000009566 rice Nutrition 0.000 claims description 15
- 239000003094 microcapsule Substances 0.000 claims description 14
- 239000000839 emulsion Substances 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 10
- 238000009736 wetting Methods 0.000 claims description 10
- 206010039509 Scab Diseases 0.000 claims description 9
- 239000000725 suspension Substances 0.000 claims description 7
- 239000004530 micro-emulsion Substances 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- 241000221785 Erysiphales Species 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- 241001530056 Athelia rolfsii Species 0.000 claims description 4
- 241000582441 Peronospora tabacina Species 0.000 claims description 4
- 230000035613 defoliation Effects 0.000 claims description 4
- 240000007594 Oryza sativa Species 0.000 claims 1
- 230000002195 synergetic effect Effects 0.000 abstract description 27
- 239000000575 pesticide Substances 0.000 abstract description 15
- 239000005730 Azoxystrobin Substances 0.000 abstract description 2
- 238000012271 agricultural production Methods 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 239000004480 active ingredient Substances 0.000 abstract 6
- WFDXOXNFNRHQEC-GHRIWEEISA-N azoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1OC1=CC(OC=2C(=CC=CC=2)C#N)=NC=N1 WFDXOXNFNRHQEC-GHRIWEEISA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 244000144972 livestock Species 0.000 abstract 1
- HIIRDDUVRXCDBN-OBGWFSINSA-N metominostrobin Chemical compound CNC(=O)C(=N\OC)\C1=CC=CC=C1OC1=CC=CC=C1 HIIRDDUVRXCDBN-OBGWFSINSA-N 0.000 abstract 1
- 239000000447 pesticide residue Substances 0.000 abstract 1
- URXNNPCNKVAQRA-XMHGGMMESA-N pyraoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1COC1=CC(C=2C=CC(Cl)=CC=2)=NN1C URXNNPCNKVAQRA-XMHGGMMESA-N 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 52
- 239000002131 composite material Substances 0.000 description 41
- 239000003814 drug Substances 0.000 description 32
- 230000003449 preventive effect Effects 0.000 description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 241000209094 Oryza Species 0.000 description 14
- 239000008367 deionised water Substances 0.000 description 14
- 229910021641 deionized water Inorganic materials 0.000 description 14
- 239000012071 phase Substances 0.000 description 14
- 239000002270 dispersing agent Substances 0.000 description 13
- 239000013530 defoamer Substances 0.000 description 12
- 239000003995 emulsifying agent Substances 0.000 description 10
- 240000008067 Cucumis sativus Species 0.000 description 9
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 9
- 230000002528 anti-freeze Effects 0.000 description 9
- 239000000470 constituent Substances 0.000 description 9
- 239000000080 wetting agent Substances 0.000 description 9
- 239000002904 solvent Substances 0.000 description 8
- 239000002562 thickening agent Substances 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 7
- 230000005764 inhibitory process Effects 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 231100000820 toxicity test Toxicity 0.000 description 7
- 206010067482 No adverse event Diseases 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 229940079593 drug Drugs 0.000 description 6
- 238000011835 investigation Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 241000207199 Citrus Species 0.000 description 5
- 206010011732 Cyst Diseases 0.000 description 5
- 241000227653 Lycopersicon Species 0.000 description 5
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 5
- 230000010165 autogamy Effects 0.000 description 5
- 235000020971 citrus fruits Nutrition 0.000 description 5
- 208000031513 cyst Diseases 0.000 description 5
- 235000013399 edible fruits Nutrition 0.000 description 5
- 229920002521 macromolecule Polymers 0.000 description 5
- 241000223600 Alternaria Species 0.000 description 4
- 241000510928 Erysiphe necator Species 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000003002 pH adjusting agent Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000013543 active substance Substances 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 239000003899 bactericide agent Substances 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000007884 disintegrant Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 241000219112 Cucumis Species 0.000 description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 210000003608 fece Anatomy 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- 235000021374 legumes Nutrition 0.000 description 2
- 239000010871 livestock manure Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- 208000031968 Cadaver Diseases 0.000 description 1
- 241000222290 Cladosporium Species 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- 241000219095 Vitis Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- -1 azoxystrobin compound Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- YWBFPKPWMSWWEA-UHFFFAOYSA-O triazolopyrimidine Chemical class BrC1=CC=CC(C=2N=C3N=CN[N+]3=C(NCC=3C=CN=CC=3)C=2)=C1 YWBFPKPWMSWWEA-UHFFFAOYSA-O 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a sterilization composition containing ametoctradin and methoxyacrylates. The composition comprises an active ingredient A and an active ingredient B, wherein the active ingredient A is selected from ametoctradin; the active ingredient B is selected from any one of compounds as follows: azoxystrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, metominostrobin and pyraoxystrobin; the weight ratio of the active ingredient A to the active ingredient B is (1: 80) to (80: 1). According to the composition, a synergistic effect on various diseases harmful to agricultural production is achieved, the pesticide dose is reduced, the pesticide residues on crops are reduced, the environmental pollution is alleviated, the harm cannot be caused to human and livestock, the environmental compatibility is good, and the pesticide resistance cannot be easily generated for the diseases.
Description
Technical field
The invention belongs to technical field of pesticide, relate to the application of a kind of bactericidal composition containing azoles mepanipyrim and methoxy acrylic on corps diseases.
Background technology
Azoles mepanipyrim (ametoctradin) is obtained interim registration in China, and azoles mepanipyrim is brand-new triazolo pyrimidine series bactericidal agent, for the downy mildew of prevention and control cucumber and grape crop.
Fluoxastrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, SSF 126 or azoles bacterium ester all belong to methoxy acrylic bactericide, are widely used in the disease of crops.
But in the real process of agricultural production, preventing and treating the problem that disease the most easily produces is the generation of disease drug resistance.Different cultivars composition carries out composite, is to prevent and treat the very common method of resistance disease.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of sterilization is all additive effect, really have a synergistic effect composite seldom, especially synergistic effect very obviously, synergy ratio very high composite just still less.Through inventor's research, find azoles mepanipyrim and Fluoxastrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, SSF 126 or azoles bacterium ester can produce good synergistic effect after composite, and not yet open about azoles mepanipyrim and the composite relevant report of Fluoxastrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, SSF 126 or azoles bacterium ester.
Summary of the invention
The object of the invention is to propose a kind of have synergistic function, use cost is low, preventive effect the is good bactericidal composition containing azoles mepanipyrim and methoxy acrylic.
The bactericidal composition containing azoles mepanipyrim and methoxy acrylic that the present invention proposes contains active components A and active component B, active components A and active component B weight ratio are 1 ︰ 80 ~ 80 ︰ 1, described active components A is selected from azoles mepanipyrim, active component B is selected from the one in Fluoxastrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, SSF 126 or azoles bacterium ester, and active components A and the preferred weight ratio of active component B are 1 ︰ 50 ~ 50 ︰ 1; More preferably the weight ratio of azoles mepanipyrim and Fluoxastrobin is 1 ︰ 30 ~ 30 ︰ 1, the weight ratio of azoles mepanipyrim and kresoxim-methyl or dimoxystrobin or orysastrobin is 1 ︰ 20 ~ 25 ︰ 1, the weight ratio of azoles mepanipyrim and SSF 126 is 1 ︰ 25 ~ 20 ︰ 1, and the weight ratio of azoles mepanipyrim and azoles bacterium ester is 1 ︰ 25 ~ 30 ︰ 1; The weight ratio that most preferably is azoles mepanipyrim and Fluoxastrobin is 1 ︰ 5 ~ 5 ︰ 1, the weight ratio of azoles mepanipyrim and kresoxim-methyl or dimoxystrobin or orysastrobin is 1 ︰ 4 ~ 9 ︰ 1, the weight ratio of azoles mepanipyrim and SSF 126 is 1 ︰ 9 ~ 4 ︰ 1, and the weight ratio of azoles mepanipyrim and azoles bacterium ester is 1 ︰ 5 ~ 11 ︰ 1.
The bactericidal composition containing azoles mepanipyrim and methoxy acrylic that the present invention proposes is for preventing and treating the purposes of disease on crops, and described crops comprise cereal crops, legume crop, fiber crop, sugar [yielding, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crop, flowers crop, medicinal crop, raw material crop, green manure pasture crop; Described disease comprises downy mildew, powdery mildew, epidemic disease, leaf mold, shot hole, scab, peronospora tabacina, anthracnose, spot defoliation, rust, rice blast, banded sclerotial blight, brown spot.
The weight ratio of active components A, active component B is 1 ︰ 80 ~ 80 ︰ 1.Conventionally in composition, the weight percentage of active component is gross weight 0.5%~90%, is preferably 5%~80%.According to different preparation types, active component content scope is different.Conventionally, liquid preparation contains 1%~70% active substance by weight, is preferably 5%~50%; Solid pharmaceutical preparation contains 5%~80% active substance by weight, is preferably 10%~80%.
In bactericidal composition of the present invention, at least contain a kind of surfactant, the dispersion of active component in water while being beneficial to use.Surface-active contents is 5%~30% of total formulation weight amount, and surplus is solid or liquid diluent.
Bactericidal composition of the present invention can be by user before use through dilution or directly use.Its preparation can be prepared by common processing method known in those skilled in the art, after mixing with liquid flux or solid carrier by active substance, then add surfactant as one or more in dispersant, stabilizing agent, wetting agent, binding agent, defoamer, disintegrant, antifreeze etc.
Bactericidal composition of the present invention, can be processed on demand acceptable formulation in any sterilization, wherein more preferably formulation is wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
When making wetting powder, composition comprises following constituent content: active components A 1% ~ 80%, active component B1% ~ 80%, dispersant 2% ~ 10%, wetting agent 2% ~ 10%, filler surplus.
When making water dispersible granules, composition comprises following constituent content: active components A 1% ~ 80%, active component B1% ~ 80%, dispersant 3% ~ 12%, wetting agent 1% ~ 8%, disintegrant 1% ~ 10%, binding agent 0 ~ 8%, filler surplus.
When making suspending agent, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, dispersant 2% ~ 10%, wetting agent 2% ~ 10%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, antifreeze 0 ~ 8%, deionized water add to 100%.
When making suspension emulsion, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, dispersant 2% ~ 10%, defoamer 0.01% ~ 2%, solvent 1% ~ 15%, thickener 0 ~ 2%, emulsifier 2% ~ 12%, antifreeze 0 ~ 8%, deionized water add to 100%.
When making aqueous emulsion, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, solvent 1% ~ 30%, emulsifier 1% ~ 15%, antifreeze 0 ~ 8%, thickener 0 ~ 2%, defoamer 0.01% ~ 2%, deionized water are supplied surplus.
When making microemulsion, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, solvent 1% ~ 30%, emulsifier 3% ~ 25%, antifreeze 0 ~ 8%, defoamer 0.01% ~ 2%, deionized water are supplied surplus.
When making microcapsule suspending agent, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, macromolecule cyst material 2% ~ 10%, dispersant 1% ~ 10%, organic solvent 1% ~ 10%, emulsifier 1% ~ 7%, defoamer 0.01% ~ 2%, pH adjusting agent 0.01% ~ 5%, deionized water add to 100%.
When making microcapsule suspension-suspending agent, composition comprises following constituent content: active components A 0.5% ~ 50%, active component B0.5% ~ 50%, macromolecule cyst material 2% ~ 10%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, organic solvent 1% ~ 15%, emulsifier 1% ~ 6%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, pH adjusting agent 0.01% ~ 5%, deionized water add to 100%;
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension-suspending agent the key technical indexes of the present invention:
The invention has the advantages that:
(1) azoles mepanipyrim and Fluoxastrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, SSF 126 or azoles bacterium ester composite after, there is obvious synergy and lasting effect; (2) disease on cereal crops, legume crop, fiber crop, sugar [yielding, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crop, flowers crop, medicinal crop, raw material crop, green manure pasture crop is all had to greater activity; (3) reduce agricultural chemicals dosage, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution; (4), to person poultry safety, Environmental compatibility is good; And preparation adhesion strength strengthens, resistance of rainwater washing against.
Embodiment
Below in conjunction with embodiment, to further instruction of the present invention, the percentage in embodiment is all weight percentage, but the present invention is not limited thereto.
Application Example one
Embodiment 1~16 wetting powder
Azoles mepanipyrim, active component B, dispersant, wetting agent, filler are mixed in mixed cylinder, after airslide disintegrating mill is pulverized, mix again, can make wetting powder product of the present invention, specifically in table 1.
The each component of table 1 embodiment 1~16 and weight portion
Embodiment 17~32 water dispersible granules
Azoles mepanipyrim, active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained to the particle diameter needing through air-flow crushing together, then add other auxiliary agents such as binding agent (can add and can not add), obtain the materials of granulating.By item quantitatively send in fluidized bed granulation dryer through granulation and dry after, can make water dispersible granules product of the present invention, specifically in table 2.
The each component of table 2 embodiment 17~32 and weight portion
Embodiment 33~48 suspending agents
By dispersant, wetting agent, defoamer, thickener (can add and can not add), antifreeze (can add and can not add), mix through high speed shear, add azoles mepanipyrim, active component B, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μ m, surplus is supplied by deionized water, can make suspending agent product of the present invention, specifically in table 3.
The each component of table 3 embodiment 33~48 and weight portion
Embodiment 49~56 suspension emulsions
Dispersant, defoamer, thickener (can add and can not add), antifreeze (can add and can not add) are mixed through high speed shear, add azoles mepanipyrim, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μ m, make azoles mepanipyrim suspending agent, then by active component B, solvent, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, surplus is supplied by deionized water, make suspension emulsion product of the present invention, specifically in table 4,5.
The each component of table 4 embodiment 49~52 and weight portion
The each component of table 5 embodiment 53~56 and weight portion
Embodiment 57~66 aqueous emulsions
Azoles mepanipyrim, active component B, solvent, emulsifier are added together, make to be dissolved into even oil phase; Deionized water, antifreeze (can add and can not add), thickener (can add and can not add), defoamer are mixed, become homogeneous water.Under high-speed stirred, water is added to oil phase, surplus is supplied by deionized water; Can make aqueous emulsion product of the present invention, specifically in table 6.
The each component of table 6 embodiment 57~66 and weight portion
By Fluoxastrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, SSF 126 or azoles bacterium ester interchange in table 1 ~ 6, can make novel formulation.
Embodiment 67~69 microemulsions
Azoles mepanipyrim, active component B, solvent, emulsifier, antifreeze (can add and can not add), defoamer are fully mixed into the oil phase of homogeneous transparent, under agitation slowly add deionized water, form WO emulsion, again through agitating heating, make it rapid phase inversion and become oil-in-water type, be chilled to room temperature and make it to reach balance, after filtration, surplus is supplied by deionized water; Can make microemulsion product of the present invention, specifically in table 7.
The each component of table 7 embodiment 67~69 and weight portion
Embodiment 70,71 microcapsule suspending agents
By azoles mepanipyrim, active component B, macromolecule cyst material, solvent, make to be dissolved into even oil phase, under shearing condition, oil phase is joined in the aqueous phase solution that contains emulsifier, pH adjusting agent, dispersant, surplus is supplied by deionized water, bi-material reacts at oil-water interfaces, forms macromolecule cyst wall, makes the finely disseminated microcapsule suspending agent product of the present composition.Specifically in table 8.
Table 8 embodiment 70,71 each component and weight portions
Embodiment 72,73 microcapsule suspensions-suspending agent
By active component B, macromolecule cyst material, solvent, make to be dissolved into even oil phase, oil phase is joined in the aqueous phase solution that contains emulsifier, pH adjusting agent under shearing condition, make finely disseminated microcapsule suspending agent.Dispersant, wetting agent, defoamer, thickener (can add and can not add) are mixed through high speed shear, add azoles mepanipyrim, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μ m, make suspending agent, then suspending agent is joined in the aqueous phase solution of micro-capsule suspension, deionized water is supplied surplus, make the finely disseminated microcapsule suspension-suspending agent of present composition product, specifically in table 9.
Table 9 embodiment 72,73 each component and weight portions
The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.First by Toxicity Determination, the synergy ratio (SR) after clear and definite two kinds of medicaments are composite by a certain percentage, SR < 0.5 is antagonism, 0.5≤SR≤1.5 are summation action, SR > 1.5 is synergistic effect, on this basis, then carries out field trial.
Test method: after the effective inhibition concentration scope of each medicament is determined in prerun, medicament is established respectively 5 dosage processing by active constituent content, establishes clear water contrast.Carry out with reference to " farm-chemical indoor determination test rule bactericide ", adopt mycelial growth rate method to measure the virulence of medicament to crop germ.After 72h, measure colony diameter by right-angled intersection method, calculate each processing net growth, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value to (x), tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates thus the EC of every kind of medicament
50value.Calculate the different proportioning synergy ratios of two medicaments (SR) according to Wadley method, SR < 0.5 is antagonism simultaneously, and 0.5≤SR≤1.5 are summation action, and SR > 1.5 is synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively active components A and active component B shared ratio in combination;
A is azoles mepanipyrim;
B is selected from the one in Fluoxastrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, SSF 126 or azoles bacterium ester.
Application Example two:
For trying disease: cucumber downy mildew
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective inhibition concentration scope of determining the former medicine of azoles mepanipyrim and Fluoxastrobin and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 10 azoles mepanipyrim and the azoxystrobin compound toxicity test analysis of results table to cucumber downy mildew
As shown in Table 10, azoles mepanipyrim and the Fluoxastrobin proportioning synergy ratio SR to cucumber downy mildew in the time of 1 ︰ 80 ~ 80 ︰ 1 is all greater than 1.5, illustrate that both all show synergistic effect at mixture in 1 ︰ 80 ~ 80 ︰ 1 scopes, when the proportioning of azoles mepanipyrim and Fluoxastrobin is during at 1 ︰ 30 ~ 30 ︰ 1, synergistic effect is more outstanding, and synergy ratio is all more than 2.25.Test and find that the optimum ratio of azoles mepanipyrim and Fluoxastrobin is 30:1,20:1,15:1,10:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:10,1:13,1:15,1:20,1:25,1:30 through applicant, especially synergy ratio maximum in the time that azoles mepanipyrim and Fluoxastrobin weight ratio are 1:1, synergistic effect is the most obvious.
Application Example three
For trying disease: grape powdery mildew
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective inhibition concentration scope of determining the former medicine of azoles mepanipyrim and kresoxim-methyl and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to grape powdery mildew of table 11 azoles mepanipyrim and kresoxim-methyl
As shown in Table 11, azoles mepanipyrim and the kresoxim-methyl proportioning synergy ratio SR to grape powdery mildew in the time of 1 ︰ 80 ~ 80 ︰ 1 is all greater than 1.5, illustrate that both all show synergistic effect at mixture in 1 ︰ 80 ~ 80 ︰ 1 scopes, when the proportioning of azoles mepanipyrim and kresoxim-methyl is during at 1 ︰ 20 ~ 25 ︰ 1, synergistic effect is more outstanding, and synergy ratio is all more than 2.15.Test and find that the optimum ratio of azoles mepanipyrim and kresoxim-methyl is 25:1,20:1,15:1,10:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:8,1:10,1:12,1:15,1:20 through applicant, especially synergy ratio maximum in the time that azoles mepanipyrim and kresoxim-methyl weight ratio are 2:1, synergistic effect is the most obvious.Application Example four
For trying disease: downy mildew of garpe
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective inhibition concentration scope of determining the former medicine of azoles mepanipyrim and dimoxystrobin and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to downy mildew of garpe of table 12 azoles mepanipyrim and dimoxystrobin
As shown in Table 12, azoles mepanipyrim and the dimoxystrobin proportioning synergy ratio SR to downy mildew of garpe in the time of 1 ︰ 80 ~ 80 ︰ 1 is all greater than 1.5, illustrate that both all show synergistic effect at mixture in 1 ︰ 80 ~ 80 ︰ 1 scopes, when the proportioning of azoles mepanipyrim and dimoxystrobin is during at 1 ︰ 20 ~ 25 ︰ 1, synergistic effect is more outstanding, and synergy ratio is all more than 2.20.Test and find that the optimum ratio of azoles mepanipyrim and dimoxystrobin is 25:1,20:1,15:1,10:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:8,1:10,1:12,1:15,1:20 through applicant, especially synergy ratio maximum in the time that azoles mepanipyrim and dimoxystrobin weight ratio are 2:1, synergistic effect is the most obvious.
Application Example five
For trying disease: rice sheath blight disease
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective inhibition concentration scope of determining the former medicine of azoles mepanipyrim and orysastrobin and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to rice sheath blight disease of table 13 azoles mepanipyrim and orysastrobin
As shown in Table 13, azoles mepanipyrim and the orysastrobin proportioning synergy ratio SR to rice sheath blight disease in the time of 1 ︰ 80 ~ 80 ︰ 1 is all greater than 1.5, illustrate that both all show synergistic effect at mixture in 1 ︰ 80 ~ 80 ︰ 1 scopes, when the proportioning of azoles mepanipyrim and orysastrobin is during at 1 ︰ 20 ~ 25 ︰ 1, synergistic effect is more outstanding, and synergy ratio is all more than 2.15.Test and find that the optimum ratio of azoles mepanipyrim and orysastrobin is 25:1,20:1,15:1,10:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:8,1:10,1:12,1:15,1:20 through applicant, especially synergy ratio maximum in the time that azoles mepanipyrim and orysastrobin weight ratio are 2:1, synergistic effect is the most obvious.
Application Example six
For trying disease: rice blast
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective inhibition concentration scope of determining the former medicine of azoles mepanipyrim and SSF 126 and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to rice blast of table 14 azoles mepanipyrim and SSF 126
As shown in Table 14, azoles mepanipyrim and the SSF 126 proportioning synergy ratio SR to rice blast in the time of 1 ︰ 80 ~ 80 ︰ 1 is all greater than 1.5, illustrate that both all show synergistic effect at mixture in 1 ︰ 80 ~ 80 ︰ 1 scopes, when the proportioning of azoles mepanipyrim and SSF 126 is during at 1 ︰ 25 ~ 20 ︰ 1, synergistic effect is more outstanding, and synergy ratio is all more than 2.20.Test and find that the optimum ratio of azoles mepanipyrim and SSF 126 is 20:1,15:1,10:1,8:1,6:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:10,1:15,1:20,1:25 through applicant, especially synergy ratio maximum in the time that azoles mepanipyrim and SSF 126 weight ratio are 1:2, synergistic effect is the most obvious.
Application Example seven
For trying disease: downy mildew of garpe
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective inhibition concentration scope of determining azoles mepanipyrim and the former medicine of azoles bacterium ester and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to downy mildew of garpe of table 15 azoles mepanipyrim and azoles bacterium ester
As shown in Table 15, azoles mepanipyrim and the azoles bacterium ester proportioning synergy ratio SR to downy mildew of garpe in the time of 1 ︰ 80 ~ 80 ︰ 1 is all greater than 1.5, illustrate that both all show synergistic effect at mixture in 1 ︰ 80 ~ 80 ︰ 1 scopes, when the proportioning of azoles mepanipyrim and azoles bacterium ester is during at 1 ︰ 25 ~ 30 ︰ 1, synergistic effect is more outstanding, and synergy ratio is all more than 2.20.Test and find that the optimum ratio of azoles mepanipyrim and azoles bacterium ester is 30:1,20:1,10:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:8,1:10,1:15,1:20,1:25 through applicant, especially synergy ratio maximum in the time that azoles mepanipyrim and azoles bacterium ester weight ratio are 3:1, synergistic effect is the most obvious.
Find through test: after azoles mepanipyrim and active component B are composite, the control of the downy mildew in various crop, powdery mildew, epidemic disease, leaf mold, shot hole, scab, peronospora tabacina, anthracnose, spot defoliation, rust, rice blast, banded sclerotial blight, brown spot is had to obvious synergistic effect, synergy ratio SR is all greater than 1.5.
Effect experiment part: test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 20% azoles mepanipyrim suspending agent (autogamy), 250 grams per liter Fluoxastrobin suspending agents (commercial), 30% kresoxim-methyl wetting powder (commercial), 20% dimoxystrobin wetting powder (autogamy), 20% orysastrobin wetting powder (autogamy), 20% SSF 126 wetting powder (autogamy), 20% azoles bacterium ester suspending agent (autogamy).
Application Example eight azoles mepanipyrims and active component B and the composite control cucumber downy mildew test of pesticide effectiveness thereof
This test arrangement is at Xian District, Shanxi Province suburban area, and investigation cucumber downy mildew disease index before medicine, in the dispenser of disease initial stage of origination, investigates disease indexes and calculate preventive effect for after dispenser 5 days, 15 days, 30 days.Result of the test is as follows:
Table 16 azoles mepanipyrim and active component B and the composite control cucumber downy mildew test of pesticide effectiveness thereof
As can be seen from Table 16, after azoles mepanipyrim and active component B are composite, can effectively prevent and treat cucumber downy mildew, test and find that azoles mepanipyrim and active component B also can effectively prevent and treat powdery mildew of cucumber, epidemic disease after composite through applicant, control efficiency is all higher than 96%, be better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example nine azoles mepanipyrims and active component B and the composite control tomato blight test of pesticide effectiveness thereof
This test arrangement is at Xian District, Shanxi Province suburban area, and investigation tomato blight disease index before medicine, in the dispenser of disease initial stage of origination, investigates disease indexes and calculate preventive effect for after dispenser 3 days, 10 days, 20 days.Result of the test is as follows:
Table 17 azoles mepanipyrim and active component B and the composite control tomato blight test of pesticide effectiveness thereof
As can be seen from Table 17, after azoles mepanipyrim and active component B are composite, can effectively prevent and treat tomato blight, test and find that azoles mepanipyrim and active component B also can effectively prevent and treat cladosporium leaf and fruit mould of tomato after composite through applicant, control efficiency is all higher than 96%, be better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten azoles mepanipyrims and active component B and the composite control rice blast test of pesticide effectiveness thereof
This test arrangement is in Hanzhong City suburb, Shaanxi Province, and investigation rice blast disease index before medicine, in the dispenser of disease initial stage of origination, investigates disease indexes and calculate preventive effect for after dispenser 5 days, 15 days, 30 days.Result of the test is as follows:
Table 18 azoles mepanipyrim and active component B and the composite control rice blast test of pesticide effectiveness thereof
As can be seen from Table 18, azoles mepanipyrim and active component B and composite control rice blast thereof, test and find that azoles mepanipyrim and active component B also can effectively prevent and treat rice sheath blight disease after composite through applicant, and control efficiency is all higher than 95%, be better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example 11 azoles mepanipyrims and active component B and the composite control alternaria leaf spot of apple test of pesticide effectiveness thereof
This test arrangement is at Shaanxi Province's Weinan City Baishui County, and investigation alternaria leaf spot of apple disease index before medicine, in the dispenser of disease initial stage of origination, investigates disease indexes and calculate preventive effect for after dispenser 3 days, 10 days, 20 days.Result of the test is as follows:
Table 19 azoles mepanipyrim and active component B and the composite control alternaria leaf spot of apple test of pesticide effectiveness thereof
As can be seen from Table 19, after azoles mepanipyrim and active component B are composite, can effectively prevent and treat alternaria leaf spot of apple, test and find that azoles mepanipyrim and active component B also can effectively prevent and treat apple scab, rust, brown spot after composite through applicant, control efficiency is all higher than 95%, be better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten diazole mepanipyrims and active component B and the composite citrus scab test of pesticide effectiveness of preventing and treating thereof
This test arrangement is in Hanzhong City suburb, Shaanxi Province, and investigation citrus scab disease index before medicine, in the dispenser of disease initial stage of origination, investigates disease indexes and calculate preventive effect for after dispenser 10 days, 20 days, 30 days.Result of the test is as follows:
Table 20 azoles mepanipyrim and active component B and the composite citrus scab test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 20, after azoles mepanipyrim and active component B are composite, can effectively prevent and treat citrus scab, test and find that azoles mepanipyrim and active component B also can effectively prevent and treat citrus anthracnose after composite through applicant, control efficiency is all higher than 95%, be better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten triazole mepanipyrims and active component B and the composite downy mildew of garpe test of pesticide effectiveness of preventing and treating thereof
This test arrangement is in Weinan City Dali County, Shaanxi Province, and investigation downy mildew of garpe disease index before medicine, in the dispenser of disease initial stage of origination, investigates disease indexes and calculate preventive effect for after dispenser 7 days, 14 days, 25 days.Result of the test is as follows:
Table 21 azoles mepanipyrim and active component B and the composite downy mildew of garpe test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 21, after azoles mepanipyrim and active component B are composite, can effectively prevent and treat downy mildew of garpe, test and find that azoles mepanipyrim and active component B also can effectively prevent and treat grape powdery mildew after composite through applicant, control efficiency is all higher than 96%, be better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
After draw through different local throughout the country tests, azoles mepanipyrim and Fluoxastrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, SSF 126 or azoles bacterium ester composite rear to the preventive effect of the Common Diseases such as the downy mildew in various crop, powdery mildew, epidemic disease, leaf mold, shot hole, scab, peronospora tabacina, anthracnose, spot defoliation, rust, rice blast, banded sclerotial blight, brown spot all more than 95%, be better than single dose preventive effect, synergistic effect is obvious.
Claims (6)
1. the bactericidal composition containing azoles mepanipyrim and methoxy acrylic, effective active composition is active components A and active component B, it is characterized in that: active components A and active component B weight ratio are 1 ︰ 80 ~ 80 ︰ 1, described active components A is selected from azoles mepanipyrim, and active component B is selected from the one in Fluoxastrobin, kresoxim-methyl, dimoxystrobin, orysastrobin, SSF 126 or azoles bacterium ester.
2. the bactericidal composition containing azoles mepanipyrim and methoxy acrylic according to claim 1, is characterized in that: the weight ratio of active components A and active component B is 1 ︰ 50 ~ 50 ︰ 1.
3. the bactericidal composition containing azoles mepanipyrim and methoxy acrylic according to claim 2, is characterized in that:
The weight ratio of azoles mepanipyrim and Fluoxastrobin is 1 ︰ 30 ~ 30 ︰ 1;
The weight ratio of azoles mepanipyrim and kresoxim-methyl or dimoxystrobin or orysastrobin is 1 ︰ 20 ~ 25 ︰ 1;
The weight ratio of azoles mepanipyrim and SSF 126 is 1 ︰ 25 ~ 20 ︰ 1;
The weight ratio of azoles mepanipyrim and azoles bacterium ester is 1 ︰ 25 ~ 30 ︰ 1.
4. according to the bactericidal composition containing azoles mepanipyrim and methoxy acrylic described in any one in claims 1 to 3, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent or microcapsule suspension-suspending agent.
5. the bactericidal composition containing azoles mepanipyrim and methoxy acrylic according to claim 4 is for preventing and treating the purposes of disease on crops.
6. purposes according to claim 5, is characterized in that, described disease comprises: downy mildew, powdery mildew, epidemic disease, leaf mold, shot hole, scab, peronospora tabacina, anthracnose, spot defoliation, rust, rice blast, banded sclerotial blight or brown spot.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210493406.9A CN103828821B (en) | 2012-11-27 | 2012-11-27 | A kind of bactericidal composition containing azoles mepanipyrim and methoxy acrylic |
CN201510771333.9A CN105265455A (en) | 2012-11-27 | 2012-11-27 | Sterilization composition containing ametoctradin and methoxyl acrylics |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210493406.9A CN103828821B (en) | 2012-11-27 | 2012-11-27 | A kind of bactericidal composition containing azoles mepanipyrim and methoxy acrylic |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510771333.9A Division CN105265455A (en) | 2012-11-27 | 2012-11-27 | Sterilization composition containing ametoctradin and methoxyl acrylics |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103828821A true CN103828821A (en) | 2014-06-04 |
CN103828821B CN103828821B (en) | 2016-01-13 |
Family
ID=50792973
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210493406.9A Expired - Fee Related CN103828821B (en) | 2012-11-27 | 2012-11-27 | A kind of bactericidal composition containing azoles mepanipyrim and methoxy acrylic |
CN201510771333.9A Pending CN105265455A (en) | 2012-11-27 | 2012-11-27 | Sterilization composition containing ametoctradin and methoxyl acrylics |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510771333.9A Pending CN105265455A (en) | 2012-11-27 | 2012-11-27 | Sterilization composition containing ametoctradin and methoxyl acrylics |
Country Status (1)
Country | Link |
---|---|
CN (2) | CN103828821B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103190417A (en) * | 2013-04-10 | 2013-07-10 | 浙江威尔达化工有限公司 | Sterilization composite containing initium and azoxystrobin and application of sterilization composite |
WO2018068772A1 (en) * | 2016-10-10 | 2018-04-19 | 江苏辉丰生物农业股份有限公司 | Bactericidal composition containing benzisothiazolinone and ametoctradin |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101232814A (en) * | 2005-07-27 | 2008-07-30 | 巴斯福股份公司 | Fungicidal mixtures based on azolopyrimidinylamines |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101306446B1 (en) * | 2004-03-10 | 2013-09-09 | 바스프 에스이 | 5,6-dialkyl-7-amino-triazolopyrimidines, method for their production, their use for controlling pathogenic fungi and agents containing said compounds |
KR20090105974A (en) * | 2007-01-30 | 2009-10-07 | 바스프 에스이 | Pesticidal mixtures based on azolopyrimidinylamines derivatives and insecticides |
US8461077B2 (en) * | 2007-03-23 | 2013-06-11 | Basf Se | Combinations of active substances |
-
2012
- 2012-11-27 CN CN201210493406.9A patent/CN103828821B/en not_active Expired - Fee Related
- 2012-11-27 CN CN201510771333.9A patent/CN105265455A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101232814A (en) * | 2005-07-27 | 2008-07-30 | 巴斯福股份公司 | Fungicidal mixtures based on azolopyrimidinylamines |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103190417A (en) * | 2013-04-10 | 2013-07-10 | 浙江威尔达化工有限公司 | Sterilization composite containing initium and azoxystrobin and application of sterilization composite |
WO2018068772A1 (en) * | 2016-10-10 | 2018-04-19 | 江苏辉丰生物农业股份有限公司 | Bactericidal composition containing benzisothiazolinone and ametoctradin |
Also Published As
Publication number | Publication date |
---|---|
CN103828821B (en) | 2016-01-13 |
CN105265455A (en) | 2016-01-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104642360A (en) | Sterilization composition containing fluorothiazole pyriethanone and methoxyl acrylate | |
CN104336033A (en) | A compound sterilization composition containing oxathiapiprolin and thiocarbamate | |
CN103651451A (en) | Pesticide composition containing penthiopyrad | |
CN103583521A (en) | Efficient sterilization composition | |
CN103651460B (en) | Pesticide composition containing fluorine azole activated ester and methoxy acrylic esters | |
CN103828821B (en) | A kind of bactericidal composition containing azoles mepanipyrim and methoxy acrylic | |
CN103918719A (en) | High-efficiency sterilization composition containing brevibacillus laterosporus | |
CN104137836A (en) | Sterilization composition containing penflufen and methoxy acrylate | |
CN103651414B (en) | Fungicidal composition containing fluoro-azole acibenzolar and methoxyl acrylate | |
CN105211118A (en) | A kind of bactericidal composition containing Gentrin Knotweed P.E and ZJ0712 or azoles bacterium ester | |
CN103651417A (en) | Bactericidal composition containing zoxamide and methoxyacrylate | |
CN103583536A (en) | Pesticide composition | |
CN103621562A (en) | Bactericidal composition | |
CN103891739A (en) | Sterilization composition containing initium and amides | |
CN103858884A (en) | Sterilization composition containing metrafenone and methoxy acrylate | |
CN104412994A (en) | Bactericidal composition containing famoxadone and methoxyacrylates | |
CN104642336A (en) | High-efficiency bactericidal composition containing fluorothiazole pyrithylone | |
CN103688962B (en) | Bactericidal composition containing 1,2,3-benzothiadiazole-7-carboxylic acid, 2,2,2-trifluoroethyl ester | |
CN103583534B (en) | Efficient pesticide composition containing cyclohexyl flusulfamide | |
CN103563935B (en) | A kind of bactericidal composition containing bromuconazole and aminodithioformic acid lipid | |
CN104026142A (en) | Pesticide composition containing fenpyrazamine and strobilurin | |
CN104012556A (en) | Microbicide composition containing diflumetorim and thiocarbamate | |
CN104106582A (en) | Bactericidal composition containing triclopyricarb and thiocarbamate | |
CN104413023A (en) | Efficient pesticide composition containing nitrobenzene carboxamide and methoxy acrylate | |
CN104106581A (en) | Sterilization composition containing tricyclopyricarb and triazole |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160113 |