CN103828814A - Fruit tree sterilization coating agent prepared from swill-cooked dirty oil and preparation method thereof - Google Patents
Fruit tree sterilization coating agent prepared from swill-cooked dirty oil and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a fruit tree sterilization coating agent prepared from swill-cooked dirty oil and a preparation method of the coating agent. The coating agent specifically comprises the following components: 1-5% of active matters, 0.1-1% of salicylic acid, 0.05-0.1% of a growth regulating agent, 1-10% of a surfactant, 1-5% of an organic solvent, 0.1-1% of a stabilizing agent, 0.1-10% of biochemical fulvic acid, 0.1-1% of warning colouration and the balance of swill-cooked dirty oil. A composition, that is, the coating agent disclosed by the invention, is stable in property, is a coating agent for fruit tree rot, can prevent and treat bacterial or fungoid diseases such as fruit tree rot and canker and can eliminate fruit tree rot scab within a short period, new bark can grow, and the lasting period can be six months. A specific application method comprises the steps of directly coating the composition disclosed by the invention onto scab on trucks of fruit trees, or the composition can be diluted by swill-cooked dirty oil or other plant oil and is subsequently directly coated on the scab of fruit trees without scraping the scab with cutters, and meanwhile resource utilization of the swill-cooked dirty oil is achieved.
Description
Technical field
The present invention relates to pesticide technology preparation field, be specifically related to a kind of fruit tree sterilization plastics of manufacturing with waste oil and preparation method thereof.
Background technology
Apple valsa canker is commonly called as smelly skin disease, skin rot, string skin disease, is one of more serious disease of China's apple producing region harm, and scab has ulcer and withered two types of branch.Ulcer type: sick portion is bronzing, water stain shape, slightly protuberance, diseased tissues is soft rots, and permanent current goes out yellowish-brown juice, has vinasse taste.Later stage drying shrinkage, sink, and there is obvious pore (being pycnidium) in sick portion, when moist. the crocus tendril thing of gushing out from pore.The withered type of branch: mostly occur at positions such as sprig, Guo Tai, dry stakes, sick portion is not water stain shape, and dehydration is withered rapidly causes full branch withered, upper raw black small grain point.Fruit is injured, scab chocolate, and circular or irregular shape, has wheel line, is soft rotten shape, slightly vinasse taste, often there is obvious pore at scab middle part.Cause of disease is apple black skin shell Valsa mali Miyabe et Yamada. for there being condition, is Ascomycotina; Be shell capsule spore Cytospora sp. without condition.Germ mainly survives the winter on field diseased plant and invalid body with mycelium, pycnidium and perithecium, becomes the main source of just infecting of morbidity in the coming year.Valsa mali parasitism is more weak, generally can only invade dead cortical tissue from wound, but also can invade from leaf scar, carpopodium trace and hole skin.Valsa mali has the characteristic of hiding, after germ is invaded, and first in the p of E existence of hiding, if tree growing way stalwartness, when premunition is strong, pathogen just can not further expand pathogenic, and hides for a long time.When setting, body or local organization are weak, and when premunition reduces, the mycelia that hides is just further expanded, reveal any symptoms.This disease mainly occurs in on bearing-age tree in age, and grave illness orchard is usually that disease scar is innumerable, and limb is incomplete, is apple production is threatened to very large destructive disease.This disease, except harm apple tree, also infects Chinese pear-leaved crabapple, Chinese pear-leaved crabapple, Malus spectabilis, Malus baccata etc.
The conventional method of preventing and treating is at present: 10～20 times of liquid of Fubiqing wetting powder; The paste of 2 times of liquid of the rotten Lingshui Spring agent of 1% apple, 30～50 times of liquid of 5% octicin solution, enemy's 20～30 times of liquid, 2～3 times of liquid of Fubiqing emulsion, 843 rehabilitation agent stostes and the bactericide that rot, but it is short that these schemes all show as the lasting period, prevent and treat not thorough, large usage quantity, in paste due to active ingredient with pressed powder form exist, particle is larger, general 10～50 microns of active ingredient particle diameter, the absorption of smearing position and the availability of fruit tree are extremely low, the medicament of smearing easily come off lost efficacy problem, the problem that the lasting period is short; Need to strike off the scab ability daubing medicament on trunks of fruit trees with stage property, working strength and the difficulty of large area operation are larger simultaneously.
Plastics is by formulated by science to functional component and macromolecule filming material; active matter particle diameter is molecule rank; product can form the stable diaphragm of one deck plant or wounds in animals surface after using; realize wound mouth and extraneous isolation; thereby protected disease position avoid the repeated injury of other germ and built the good environment of repairing disease position, and functional component in film can effectively promote the speed that plant epidermis is repaired.Plastics technique functions comes from daily use chemicals, medical research field, have preparation technology simple, easy to use, do not need wrapping and the advantage such as adhesion strength is strong, oneself is widely used in the medicines such as human epidermal wound, disease of skin.In addition, plastics technology also has certain application in agricultural products fresh-keeping field.But this technology is applied to the still rare report of exploitation of control of plant disease medicament.
described Tebuconazole, common name: Tebuconazole (Tebuconazole)
Chemical name: (RS)-1-(4-chlorphenyl)-4,4-dimethyl-3-(1H-1,2,4 triazol-1-yl methyl) penta-3-alcohol
Molecular weight: 307.8, molecular formula: C16H22ClN3O, No. CAS: 107534-96-3
Structural formula:
Physicochemical property: these product are clear crystal, fusing point is 102.4 ℃, vapour pressure 0.0133mPa(20 ℃): solvability (20 ℃): water 32mg/L, toluene 50-100g/L.
Toxicity: low toxicity, rat acute per os LD.。Be about 4 000mg/kg, female, male chmice acute per os LD.。Be respectively 3 933mg/kg and 2 000mg/kg, rat acute is through skin LDso >5 000mg/kg.
Purposes: these product belong to triazole type sterilization pesticide, it is sterol demethylation inhibitor, for the seed treatment of Important Economic crop or the efficient germicide of foliage spray, can effectively prevent and treat multiple rust, powdery mildew, net blotch, root rot, the head blight of cereal crop, smut and kind pass zonate spot and Rice shealth blighy etc.
Toxicity: by Chinese pesticide toxicity grading criteria, this medicine belongs to low toxicity bactericide.Rat acute LD50 of passing through mouth 4000mg/kg, the about 2000mg/kg of male chmice acute LD50 of passing through mouth, female chmice acute LD50 of passing through mouth 3933mg/kg, rat acute is through skin LD50>5000mg/kg.Rat acute sucks LC50(4h) >0.8mg/l air (aerosol), >5.1mg/l(pulvis).This medicine is to fish moderate toxicity, goldfish LC50(96 hour) 8.7 mg/litre.Environmental influence: use on request honeybee safety.Fish LD50(96h, mg/L): golden graining 8.7, rainbow trout 6.4; Acute oral LD50 (mg/kg): chicken 4438, Japanese quail 4438(hero), 2912(is female), North America quail 1988.Laboratory test is decomposed very slow in soil, very fast at degradation.
Tebuconazole is a kind of efficient, wide spectrum, interior absorption triazole type sterilization pesticide, has protection, treats, roots out three large functions, and fungicidal spectrum is wide, the lasting period is long.The same with all triazole bactericidal agents, the biosynthesis of the ergosterol that Tebuconazole can Antifungi.
described propiconazole, Universal Chinese character title: propiconazole, english common name: propiconazole,
Chemical name: 1-[2-(2,4-dichlorophenyl)-4-propyl group-DOX-2-methyl]-1 hydrogen-1,2,4-triazoles, molecular formula: C
15h
17c
l2n
3o
2, molecular weight: 342.2, No. CAS: 60207-90-1
Physicochemical property: former medicine outward appearance is faint yellow sticky silk fabric liquid, 180 ℃ of boiling points (13.3Pa), vapour pressure (20 ℃) 0.133mPa, index of refraction 1.5468, proportion (20 ℃) 1.27g/cm3.In water, solvability is 110mg/L, is soluble in organic solvent.320 ℃ following stable, more stable to light, is hydrolyzed not obvious.More stable in acidity, alkaline medium, not corroding metal.
Toxicity: low toxicity, former medicine is to rat acute LD50 of passing through mouth >1517mg/kg, acute through skin LD50>4000mg/kg.Rabbit eyes and skin are had to slight spread effect
Propiconazole (Propiconazol) is a kind of interior absorption triazole type New-type wide-spectrum bactericide with treatment and protection double action; can be absorbed by root, stem, leaf portion; and can be soon in plant strain body on conduction; the disease that control sac fungi, basidiomycetes and imperfect fungus cause; particularly the diseases such as take-all, powdery mildew, rust, root rot, bakanae disease of rice, banded sclerotial blight, sigatoka are had to special efficacy; can effectively prevent and treat the disease that most of higher fungies cause, but invalid to oomycetes disease.The propiconazole longevity of residure is about 1 month.
Propiconazole has the features such as fungicidal spectrum is extensive, activity is high, sterilization speed is fast, the lasting period is long, interior suction conductivity is strong, has become the emerging broad-spectrum germicide Representative Cultivars of large-tonnage triazole type in the world.
Described salicylic acid Chinese: salicylic acid, English name: salicylic acid; SA, other titles: septichen, salicylic acid is white crystalline powder, odorless, taste first turns pungent after micro-hardship.Fusing point 157-159 ℃, capital variable color gradually under illumination.Relative density 1.44, approximately 211 ℃/2.67kPa of boiling point, 76 ℃ of distillations, under normal pressure, sharply heating is decomposed into phenol and carbonic acid gas, and its concrete existence form is sodium salicylate or salicylic acid, the secondary metabolite of plant, there is sterilization and physiological regulatory action, as induced flowering and disease resistance etc.
Summary of the invention
In order to overcome the shortcoming of prior art, in order to overcome above-mentioned the deficiencies in the prior art, the object of the present invention is to provide kind of a kind of fruit tree sterilization plastics of manufacturing with waste oil and preparation method thereof, solve the technological deficiency that above-mentioned existing product and scheme exist.In composition of the present invention, active matter is the existence of molecular state form, and outward appearance presents faint yellow clear state or translucent white state, directly acts on the site of pathological change of fruit tree, and different component collocation has realized quick-acting and combination holding effect.Quick-acting composition salicylic acids can be removed rapidly the germ spore of the surface of a wound, and sick inducing plant body produces resistance, the Tebuconazole of low toxicity, propiconazole, absorption and scab position that epoxiconazole isoreactivity composition energy is permanent, thoroughly kill pathogen, and growth regulator and nutriment biochemical fulvic acid can promote the growth of the position cambium of scab, generate new skin, make fruit tree to recover life in the shorter time, because the waste oil of pure ecology or vegetable oil and plant tissue have stronger affinity, non-volatile, cover surface, scab position and form oil film, there is obvious ability to resist splash erosion, the composition lasting period of the present invention reaches more than 6 months, owing to really plucking stopping the fruit phase after fruit during dispenser, avoid fruit growth period, fruit residue of pesticide are stopped completely, and make waste oil have the legal approach that utilizes, the risk and the probability that flow to dining table are reduced.
The technical solution that this practicality invention adopts is:
A kind of fruit tree sterilization plastics of manufacturing with waste oil, it is characterized in that: described manufactures fruit tree sterilization plastics with waste oil, by mass percentage, comprises following component: 1%～5% active matter, 0.1～1% salicylic acid, 0.05 ~ 0.1% growth regulator, 0～10% surfactant, 1～5% organic solvent, 0.1～1% stabilizing agent, biochemical fulvic acid 0.1～10%, 0.1 ~ 1% warning colouration, surplus is waste oil.
Described a kind of fruit tree sterilization plastics of manufacturing with waste oil, is characterized in that, described active matter is one or several compositions in Tebuconazole, propiconazole, the mould ketone of thiophene, Flusilazole, epoxiconazole, Difenoconazole, pungent bacterium amine, kasugarnycin.
Described a kind of fruit tree sterilization plastics of manufacturing with waste oil, is characterized in that, described growth regulator is: compound sodium nitrophenolate, the fresh fat of amine, indolebutyric acid, gibberellin, one or several compositions in 6-benzylaminopurine.
Described a kind of fruit tree sterilization plastics of manufacturing with waste oil, it is characterized in that, described surfactant is: polyoxyethylene nonylphenol ether, OPEO, fatty alcohol-polyoxyethylene ether, anhydrous sorbitol APEO, sorbitan carboxylic esters, styrylphenol polyoxyethylene ether, benzyl dimethyl phenol polyethenoxy ether, styryl phenol formaldehyde resin PULLRONIC F68 block type polyethers, one or several compositions in styryl phenol formaldehyde resin APEO.
Described a kind of fruit tree sterilization plastics of manufacturing with waste oil, is characterized in that, described organic solvent is: N-N dimethyl formamide, cyclohexanone, dimethyl sulfoxide (DMSO), one or several compositions in certain herbaceous plants with big flowers acid amides.
Described a kind of fruit tree sterilization plastics of manufacturing with waste oil, is characterized in that, described stabilizing agent is: epoxidized soybean oil, epoxychloropropane, one or several compositions in BHT.
Described a kind of fruit tree sterilization plastics of manufacturing with waste oil, is characterized in that, described warning colouration is: famille rose, oil red, one or several compositions in transparent red.
Described a kind of fruit tree sterilization plastics of manufacturing with waste oil, it is characterized in that, described waste oil is: through tentatively filtering, refine the dining table waste grease of recovery, or the infiltration oil of process preliminary purification, or the composition of other vegetable oil and animal fat etc.
A kind of preparation method of the fruit tree sterilization plastics of manufacturing with waste oil, it is characterized in that: described method is: by 1%～5% active matter, 0.1～1% salicylic acid, 0.05 ~ 0.1% growth regulator, 0.1～1% stabilizing agent, 0.1～10% biochemical fulvic acid, adds 1～5% organic solvent, is stirred to transparent; Then add 0～10% surfactant, surplus is that waste oil continues to be stirred to system homogeneous, finally adds 0.1 ~ 1% warning colouration again, makes the described fruit tree sterilization plastics of manufacturing with waste oil.
The invention has the beneficial effects as follows: the invention provides a kind of fruit tree sterilization plastics of manufacturing with waste oil and preparation method thereof, the solution existing product lasting period is short, and medicament is seriously polluted, the problem of preventive effect deficiency, can directly smear, also can strike off daubing medicament after lesions position.In composition of the present invention, active matter is the existence of molecular state form, directly acts on the site of pathological change of fruit tree, and different component collocation has realized quick-acting and combination holding effect.Quick-acting composition salicylic acids can be removed rapidly the germ spore of the surface of a wound, and sick inducing plant body produces resistance; What other active components energy of Tebuconazole, the propiconazole etc. of low toxicity were permanent is adsorbed in scab position, thoroughly kill pathogen, and growth regulator and nutriment biochemical fulvic acid can promote the growth of the position cambium of scab, generate new skin, make fruit tree to recover life in the shorter time, because pure biogenic waste oil or vegetable oil and plant tissue have stronger affinity, cover surface, scab position and form oil film, not volatile have an obvious ability to resist splash erosion, and the composition lasting period of the present invention reaches more than 6 months.Said composition self also has the function that increases Genes For Plant Tolerance environment-stress, and inducing plant produces defense mechanism, strengthens the resistivity to damage by disease and insect.Make the waste oil effectively to have realized recycling simultaneously, opened up waste oil new utilize approach, reduced the channel that flows to dining table.
Embodiment
below in conjunction with specific embodiment, the present invention is described in further detail.
A kind of fruit tree sterilization plastics of manufacturing with waste oil and preparation method thereof, specifically comprises following component (by mass percentage)
embodiment 1:
By 1% Tebuconazole, 1% salicylic acid, 0.05% diethyl aminoethyl hexanoate, 0.1% BHT, 10% biochemical fulvic acid, adds 3% N-N dimethyl formamide, is stirred to transparent; Then add 1% polyoxyethylene nonylphenol ether, surplus is that waste oil continues to be stirred to system homogeneous, finally adds 0.2% oil red again, makes the described fruit tree sterilization plastics of manufacturing with waste oil;
embodiment 2:
By 0.8% Tebuconazole, the epoxiconazole of 0.2 %, 0.2% salicylic acid, 0.05% reinstate phenol sodium, 1% epoxidized soybean oil, 5% biochemical fulvic acid, adds 5% dimethyl sulfoxide (DMSO), is stirred to transparent; Then add 5% sorbitan carboxylic esters, surplus is that waste oil continues to be stirred to system homogeneous, finally adds 0.1% oil red again, makes the described fruit tree sterilization plastics of manufacturing with waste oil;
embodiment 3:
By 0.5% Tebuconazole, 0.5% Flusilazole, 1% salicylic acid, 0.1% gibberellin, 0.1% BHT, 0.1% biochemical fulvic acid, adds 1% N-N dimethyl formamide, is stirred to transparent; Then add 1% OPEO, surplus is that waste oil continues to be stirred to system homogeneous, finally adds 0.2% oil red again, makes the described fruit tree sterilization plastics of manufacturing with waste oil;
embodiment 4:
By 0.1% pungent bacterium amine, 1% salicylic acid, the mould ketone of 2% thiophene, 0.5% epoxychloropropane, 2% biochemical fulvic acid, adds 2% certain herbaceous plants with big flowers acid amides, is stirred to transparent; Then add 5% fatty alcohol-polyoxyethylene ether, surplus is that waste oil continues to be stirred to system homogeneous, finally adds 0.2% oil red again, makes the described fruit tree sterilization plastics of manufacturing with waste oil;
embodiment 5:
By 1% Tebuconazole, 0.1% kasugarnycin, 0.1% salicylic acid, 0.05% reinstate phenol sodium, 0.1% BHT, 0.1% biochemical fulvic acid, adds 5% cyclohexanone, is stirred to transparent; Then add 1% anhydrous sorbitol APEO, surplus is that waste oil continues to be stirred to system homogeneous, finally adds 0.2% oil red again, makes the described fruit tree sterilization plastics of manufacturing with waste oil;
embodiment 6:
By 5% Tebuconazole, 0.1% salicylic acid, 0.05% diethyl aminoethyl hexanoate, 0.1% BHT, 0.1% biochemical fulvic acid, adds 5% N-N dimethyl formamide, is stirred to transparent; Then add 1% styrylphenol polyoxyethylene ether, surplus is that waste oil continues to be stirred to system homogeneous, finally adds 0.2% oil red again, makes the described fruit tree sterilization plastics of manufacturing with waste oil;
embodiment 7:
By 1% Tebuconazole, 0.1% propiconazole, 0.1% salicylic acid, 0.05% indolebutyric acid, 1% BHT, 0.1% biochemical fulvic acid, adds 5% cyclohexanone, is stirred to transparent; Then add 1% benzyl dimethyl phenol polyethenoxy ether, surplus is that waste oil continues to be stirred to system homogeneous, finally adds 0.5% oil red again, makes the described fruit tree sterilization plastics of manufacturing with waste oil;
embodiment 8:
By 1% Tebuconazole, 0.1% propiconazole, 0.1% salicylic acid, 0.05% 6-benzylaminopurine, 0.1% BHT, 0.1% biochemical fulvic acid, adds 5% cyclohexanone, is stirred to transparent; Then add 1% styryl phenol formaldehyde resin PULLRONIC F68 block type polyethers, surplus is that waste oil continues to be stirred to system homogeneous, finally adds 0.2% oil red again, makes the described fruit tree sterilization plastics of manufacturing with waste oil;
embodiment 9:
By 1% Tebuconazole, 0.1% propiconazole, 0.1% salicylic acid, 0.08% indolebutyric acid, 0.1% BHT, 0.1% biochemical fulvic acid, adds 5% cyclohexanone, is stirred to transparent; Then add 10% styryl phenol formaldehyde resin APEO, surplus is that waste oil continues to be stirred to system homogeneous, finally adds 0.5% oil red again, makes the described fruit tree sterilization plastics of manufacturing with waste oil;
embodiment 10:
By 1% Tebuconazole, 0.1% Difenoconazole, 0.1% salicylic acid, 0.05% gibberellin, 1% BHT, 0.1% biochemical fulvic acid, adds 5% cyclohexanone, is stirred to transparent; Then add 1% fatty alcohol-polyoxyethylene ether, surplus is that waste oil continues to be stirred to system homogeneous, finally adds 0.2% transparent red again, makes the described fruit tree sterilization plastics of manufacturing with waste oil;
embodiment 11:
By 1% Tebuconazole, 0.1% propiconazole, 0.1% salicylic acid, 0.05% reinstate phenol sodium, 0.1% BHT, 0.1% biochemical fulvic acid, adds 5% cyclohexanone, is stirred to transparent; Then add 10% sorbitan carboxylic esters, surplus is that waste oil continues to be stirred to system homogeneous, finally adds 0.2% transparent red again, makes the described fruit tree sterilization plastics of manufacturing with waste oil;
embodiment 12:
By 1% Tebuconazole, 0.1% Flusilazole, 0.1% salicylic acid, 0.05% reinstate phenol sodium, 0.1% BHT, 0.1% biochemical fulvic acid, adds 5% cyclohexanone, is stirred to transparent; Then add 1% anhydrous sorbitol APEO, surplus is that waste oil continues to be stirred to system homogeneous, finally adds 1% oil red again, makes the described fruit tree sterilization plastics of manufacturing with waste oil;
the test of pesticide effectiveness of the present invention:
Prevent and treat the test of pesticide effectiveness contrast of rot with carry out fruit tree containing the present composition and commercially available similar medicament.
1) experimental subjects apple valsa canker
2) experiment place: king of medicine shop town, Liquan County, Shaanxi Province
3) the experiment date: on November 3rd, 2012
3) pilot survey method
With a kind of commercial like product of manufacturing fruit tree sterilization plastics composition and three each and every one similar functions with waste oil of the present invention, a blank, be applied in respectively rot lesions position, strike off and smear after focus bark and pruning wound site, 5 apple trees are in spite of illness selected in each community, repeat each community 2, calculating mean value.
One of the present invention is manufactured fruit tree sterilization plastics composition with waste oil, burst rotten clever, 4% thiophanate-methyl paste, 430g/L Tebuconazole SC (diluting 400 times), at the fruit tree hibernation initial stage or before early spring, fruit tree sprouted, medicament spreads upon on trunk wound or lesions position according to explanation equably, is advisable to fill scar.Scab spread scenarios and the wound healing situation of after medicine, after 3 months, 6 months, observing respectively coating position, be divided into 9 grades according to the recovery extent of focus area; Completely healing bear new skin for or wound healing be 1 grade without infection process; Lesions position dries up, bears most of new skin, wound is 2 grades without infecting; No longer extended surface is dried, bears a half new skin to focus, wound is 3 grades without infecting; Focus no longer dry, the new skin of extended surface generate be less than focus area 50%, wound is 3 grades without infecting; The contrast of not dispenser of focus clear water, focus area continue expansion, wound infection is 5 grades, between the two 0.5 grade, with this evaluation experimental drug effect.
4) test result analysis
Can according to drug effect data analysis; a kind of fruit tree sterilization plastics of manufacturing with waste oil of the present invention and preparation method thereof; adopt direct semar technique and rossing semar technique all can reach one-level preventive effect; compared with other like product successfuls; can meet the demand of actual agricultural production; the waste oil in ecological source forms grease diaphragm at lesions position, has controlled further infecting of germ.
Claims (9)
1. a fruit tree sterilization plastics of manufacturing with waste oil, it is characterized in that: described manufactures fruit tree sterilization plastics with waste oil, by mass percentage, comprises following component: 1%～5% active matter, 0.1～1% salicylic acid, 0.05 ~ 0.1% growth regulator, 0～10% surfactant, 1～5% organic solvent, 0.1～1% stabilizing agent, biochemical fulvic acid 0.1～10%, 0.1 ~ 1% warning colouration, surplus is waste oil.
2. a kind of fruit tree sterilization plastics of manufacturing with waste oil according to claim 1, it is characterized in that, described active matter is one or several compositions in Tebuconazole, propiconazole, the mould ketone of thiophene, Flusilazole, epoxiconazole, Difenoconazole, pungent bacterium amine, kasugarnycin.
3. a kind of fruit tree sterilization plastics of manufacturing with waste oil according to claim 1, is characterized in that, described growth regulator is: compound sodium nitrophenolate, the fresh fat of amine, indolebutyric acid, gibberellin, one or several compositions in 6-benzylaminopurine.
4. a kind of fruit tree sterilization plastics of manufacturing with waste oil according to claim 1, it is characterized in that, described surfactant is: polyoxyethylene nonylphenol ether, OPEO, fatty alcohol-polyoxyethylene ether, anhydrous sorbitol APEO, sorbitan carboxylic esters, styrylphenol polyoxyethylene ether, benzyl dimethyl phenol polyethenoxy ether, styryl phenol formaldehyde resin PULLRONIC F68 block type polyethers, one or several compositions in styryl phenol formaldehyde resin APEO.
5. a kind of fruit tree sterilization plastics of manufacturing with waste oil according to claim 1, is characterized in that, described organic solvent is: N-N dimethyl formamide, cyclohexanone, dimethyl sulfoxide (DMSO), one or several compositions in certain herbaceous plants with big flowers acid amides.
6. a kind of fruit tree sterilization plastics of manufacturing with waste oil according to claim 1, is characterized in that, described stabilizing agent is: epoxidized soybean oil, epoxychloropropane, one or several compositions in BHT.
7. a kind of fruit tree sterilization plastics of manufacturing with waste oil according to claim 1, is characterized in that, described warning colouration is: famille rose, oil red, one or several compositions in transparent red.
8. a kind of fruit tree sterilization plastics of manufacturing with waste oil according to claim 1, it is characterized in that, described waste oil is: through tentatively filtering, refine the dining table waste grease of recovery, or through the infiltration oil of preliminary purification, or the composition of other vegetable oil and animal fat etc.
9. the preparation method of a fruit tree sterilization plastics of manufacturing with waste oil, it is characterized in that: described method is: by 1%～5% active matter, 0.1～1% salicylic acid, 0.05 ~ 0.1% growth regulator, 0.1～1% stabilizing agent, 0.1～10% biochemical fulvic acid, adds 1～5% organic solvent, is stirred to transparent; Then add 0～10% surfactant, surplus is that waste oil continues to be stirred to system homogeneous, finally adds 0.1 ~ 1% warning colouration again, makes the described fruit tree sterilization plastics of manufacturing with waste oil.
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| CN106135264A (en) * | 2015-03-25 | 2016-11-23 | 青岛星牌作物科学有限公司 | A kind of paste preparation method and application of composite containing flusilazole |
| CN107353131A (en) * | 2017-08-25 | 2017-11-17 | 新疆农业科学院土壤肥料与农业节水研究所(新疆维吾尔自治区新型肥料研究中心) | It is a kind of to prevent and treat the shrivelled Pesticidal foliage fertilizer of walnut leaf margin and its preparation and administration |
| WO2022185037A1 (en) * | 2021-03-01 | 2022-09-09 | UPL Corporation Limited | Agricultural composition comprising kasugamycin |
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