CN101057590A - Pesticide additive - Google Patents
Pesticide additive Download PDFInfo
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- CN101057590A CN101057590A CNA2006100773861A CN200610077386A CN101057590A CN 101057590 A CN101057590 A CN 101057590A CN A2006100773861 A CNA2006100773861 A CN A2006100773861A CN 200610077386 A CN200610077386 A CN 200610077386A CN 101057590 A CN101057590 A CN 101057590A
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- oil
- grease
- agent
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- fat
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Abstract
The invention relates to a pesticide adjuvant, comprising fat and oil. The fat and oil can be animal fat, vegetable oil or the mixture of them. The invention enhances the penetrability, stick-ability and blocking prosperity for pesticide of preventing disease and insects for branch and root during its producing process, which increases the preventing effect for disease and insect on branch and root. Mixed with pesticide or used individually to spray onto branch and root, the adjuvant can not only prevent disease and insect, but also can insulate cold, reduce water loss and promote tissue assimilation.
Description
Technical field
The invention relates to a kind of insecticides adjuvant.
Background technology
Agricultural chemicals make or use in need to add insecticides adjuvant, increase effects such as emulsification, the Seepage of agricultural chemicals is saturating, adhesion, sealing with this, reach that agricultural chemicals is best to be renderd a service.Aspect plant pest management; anti-cure that plant branch is done and the rhizome damage by disease and insect is very important plant protection link; because the damage by disease and insect at plant limb and rhizome position is caused harm at cork layer, phloem or xylem mostly; general agricultural chemicals sprays to above-mentioned position Jiao Nan Seepage and arrives thoroughly in these tissues; therefore, control efficiency is relatively poor.At present, aspect the plant limb and the rhizome extermination of disease and insect pest, owing to lack tool for a long time the insecticides adjuvant that the saturating property of Seepage is strong, adhesivity is strong, closure is strong is arranged, a lot of plant limbs and rhizome damage by disease and insect can not get good control.The ring spot that takes place as: apple limb and root, rot, root timber rot, southern blight, stick up subcutaneous two spotted spider mite etc. always, these damage by disease and insect can not get good control for a long time on producing, thereby output and the quality of apple tree have been had a strong impact on, shortened the economic life, produced for the fruit industry and caused the tremendous economic loss.Therefore, there is the saturating property of Seepage insecticides adjuvant strong, that adhesivity is strong, closure is strong to be used for pesticide producing manufacturing, agricultural chemicals to use or the plant protection integrated control pressing for a kind of tool aspect the plant limb and the rhizome extermination of disease and insect pest, improves control efficiency plant limb and rhizome damage by disease and insect with this.
Because at present insecticides adjuvant is that substituted benzene toluene, dimethylbenzene, benzene mixed etc. are used in a large number as the insecticides adjuvant component in the agricultural chemicals manufacturing mostly, therefore, can brings people, animal are caused and inhale people's harm and the pollution of environment.Substituted benzene (toluene, dimethylbenzene, benzene mixed) is the strong carcinogen that the World Health Organization announces, be the harmful chemical that causes leukemia and child's birth defects, more American-European developed countries have begun to limit and have forbidden utilizing the insecticides adjuvant of these material productions to use in pesticide producing or in using.Therefore, developing the insecticides adjuvant with environment-friendly type has important practical significance.
Publication number is that the application for a patent for invention of CN 1701663A discloses a kind of insecticides adjuvant, relate to a kind of agricultural chemicals, especially relating to a vegetable oil, auxiliary agent, surfactant is the environmental protection type agricultural chemical auxiliary agent of raw material, providing a kind of is the environmental protection type agricultural chemical auxiliary agent of raw material with vegetable oil, cosolvent, surfactant, its raw material and be: vegetable oil 100 by the content of mass ratio, cosolvent 0～50, surfactant 5～55.Can be used for preparing formulation is missible oil, oily suspension, thermal fog, bucket mixture, ultra low volume spraying agent and insecticide, miticide, bactericide, disinfectant, hygienic insecticide, plant growth regulator.Replace substituted benzene with vegetable oil, can reduce the demand to petroleum resources, the cost of reduction pesticidal preparations, its physical and chemical stability and Nian the saturating property of Seepage, anti-drift, safety and integrated control effect and all are better than the preparation of processing with substituted benzene.
Summary of the invention
The present invention organizes the saturating property of agricultural medicine Seepage after the dispenser, adhesivity, this technical problem of closure difference in order to solve plant limb and rhizome damage by disease and insect disease portion, improve the saturating property of agricultural chemicals De Seepage, adhesivity, closure, reach the good purpose of preventing and treating, the present inventor is through repeatedly research, finally invented and utilized the new purposes of grease, especially the new purposes and the using method thereof of the insecticides adjuvant of conduct control plant limb and rhizome damage by disease and insect as insecticides adjuvant.As everyone knows, grease for vegetable fiber and wooden be to have the very saturating property of Qiang De Seepage, adhesivity and closure, therefore, agricultural chemicals mixed being sprayed on the sick worm of plant limb or the rhizome position of causing harm with grease, medicament can arrive plant tissue inside kill pathogens or insect thoroughly than holding easy Seepage; Because fat and oil don't dissolve in water, can not fallen by rain drop erosion, so good adhesivity and closure are arranged, the spore of the damage by disease and insect that is closed, mycelia, ovum, larva, adult etc. are difficult for propagating to the external world, can reduce the damage by disease and insect spread scope effectively; You Zhi Seepage can worsen disease worm living environment thoroughly in sick worm is caused harm tissue in addition, make the disease worm lose suitable life condition and death, soaked into by grease as fiber, the germ mycelium can't be grown, grease is with the ventilating slit sealing of cork layer, phloem, xylem, and sick worm can not get sufficient oxygen and is choked to death; The present invention not only can play the insecticides adjuvant effect, also the present invention can be used separately spray to plant limb or rhizome position and play and prevent that damage by disease and insect from infecting and spread, playing winter protection, reducing and set the body dehydration and promote effect such as disease portion organization healing.
Constituent of the present invention is made up of grease, grease comprises animal fat (be commonly called as animal oil, hereinafter no longer add this explanation) and vegetable fat (be commonly called as vegetable oil, hereinafter no longer add this explanation), therefore, this constituent can be the constituent more than a kind or 2 kinds of animal fat; It can be the constituent more than a kind or 2 kinds of vegetable fat; It can be the constituent of animal fat and vegetable fat; The constituent that also comprises the animal fat, vegetable fat and the animals and plants compound lard that utilize physical method and chemical method to make; In addition, the grease that contains impurity (as: waste oil that is commonly called as, saliva oil, waste oil etc.) that also comprises the grease that becomes sour, sex change grease, catering trade and industrial discharge or product.
Animal fat in the described grease comprises lard, sheep oil, butter, donkey oil, house oil, chicken fat, goose oil, duck oil, fish oil, vegetable fat comprises palm oil, tung oil, peanut oil, rapeseed oil, soya-bean oil, sesame oil, sunflower oil, cottonseed oil, but be not limited only to listed animal fat and vegetable fat, constituent of the present invention is an at least a above grease of above-mentioned animal fat and vegetable fat.
The invention provides a kind of insecticides adjuvant, it is characterized in that forming the glyceryl ester of the main component fatty acid of grease.
The invention provides a kind of insecticides adjuvant, it is characterized in that the fatty acid that the glyceryl ester hydrolysis of described fatty acid forms.
The invention provides a kind of insecticides adjuvant, it is characterized in that glyceryl ester and fatty acid, form by the above-mentioned wherein material more than 2 kinds by grease, fatty acid.
The present invention also provides a kind of insecticides adjuvant, it is characterized in that described animal fat, animal fat and vegetable fat mixture, utilize the animal fat that physical method or chemical method make and the constituent of animals and plants compound lard, grease becomes sour, the sex change grease, the grease that the contains impurity (as: waste oil that is commonly called as of catering trade and industrial discharge or product, saliva oil, waste oil etc.) and surfactant, cosolvent, thinner, anticoagulant, antifreezing agent, filler, carrier, stabilizing agent, sustained release agent, synergist, anti-drift agent, dust-proofing agent, the poisoning palliative, dyestuff, pigment, water, 1 kind or the constituent of multiple material that mineral oil and organic matter are above-mentioned.
The invention provides a kind of insecticides adjuvant, it is characterized in that the glyceryl ester and a kind above-mentioned or the constituent of multiple material of surfactant, cosolvent, thinner, anticoagulant, antifreezing agent, filler, carrier, stabilizing agent, sustained release agent, synergist, anti-drift agent, dust-proofing agent, poisoning palliative, dyestuff, pigment, water, mineral oil and organic matter of fatty acid.
The invention provides a kind of insecticides adjuvant, it is characterized in that by fatty acid and a kind above-mentioned or the constituent of multiple material of surfactant, cosolvent, thinner, anticoagulant, antifreezing agent, filler, carrier, stabilizing agent, sustained release agent, synergist, anti-drift agent, dust-proofing agent, poisoning palliative, dyestuff, pigment, water, mineral oil and organic matter.
The invention provides a kind of insecticides adjuvant, it is characterized in that by the glyceryl ester of grease, fatty acid and fatty acid a kind above-mentioned or the constituent of multiple material of the constituent of material and surfactant, cosolvent, thinner, anticoagulant, antifreezing agent, filler, carrier, stabilizing agent, sustained release agent, synergist, anti-drift agent, dust-proofing agent, poisoning palliative, dyestuff, pigment, water, mineral oil and organic matter more than 2 kinds wherein.
The present invention is used to prepare the pesticidal preparations that formulation is missible oil, oil suspending agent, bucket mixture, ultra low volume spraying agent.
The present invention is used to prepare insecticide, bactericide, miticide, plant growth regulator.
The present invention mixes or is used to separately prevent and treat plant pest with agricultural chemicals, especially utilize spray cloth or be coated with and rinse control plant limb or rhizome damage by disease and insect, can mix spray cloth in back with agricultural chemicals or be brushed to plant limb or the sick worm of the rhizome position of causing harm, after also can be earlier executing agricultural chemicals at plant limb or rhizome damage by disease and insect position, again insecticides adjuvant of the present invention is sprayed cloth or is brushed to the dispenser position, also can spray pre-preventing disease and pest is played in cloth or brushing at the position that the anosis worm of plant limb and rhizome is caused harm effect.
The present invention mixes separately or with agricultural chemicals sprays cloth or is painted on plant limb or rhizome can play winter protection, reduces dehydration and promote the organization healing effect of disease portion.
Compared with the prior art, substantive distinguishing features of the present invention and advance are:
The present invention uses as insecticides adjuvant, can effectively improve the saturating property of agricultural chemicals De Seepage, adhesivity, closure;
Raw material of the present invention is to derive from vegeto-animal grease, belongs to the insecticides adjuvant of environment-friendly type, can reduce after applying to people and animals' harm with to the pollution of environment;
Raw oil material price of the present invention is more cheap than other raw materials such as substituted benzene (toluene, dimethylbenzene, benzene mixed), uses the production cost that can also reduce pesticidal preparations as insecticides adjuvant with it.
Raw material of the present invention can use become sour, the sex change grease, also can adopt the waste oil that contains impurity of catering trade or industrial waste, can eliminate the environmental pollution of these expense product, accomplish twice laid.
Embodiment
Following examples will the invention will be further described.
The embodiments of the present invention key is: grease and the agricultural chemicals that at first will select to be fit to certain plant limb or the rhizome extermination of disease and insect pest, the active ingredient of guaranteeing this agricultural chemicals can mix in constituent of the present invention or mix by auxiliary agent, and mixed medicament is had than the saturating property of Qiang De Seepage, adhesivity and closure.If selected grease and pesticide active ingredient mix easily, just do not need to add auxiliary agent, otherwise, if selected grease and pesticide active ingredient are not easy to mix, just need to add auxiliary agent, itself and pesticide active ingredient are mixed.After choosing constituent of the present invention and agricultural chemicals, earlier constituent of the present invention is added in reactor or the container, if constituent of the present invention is two or more grease, can add in the ratio of determining in advance, then grease be heated, temperature adjusting is at 60 ℃～80 ℃, selected agricultural chemicals is added in the grease of fusing, add other auxiliary agents again with in other auxiliary agents interpolations as needs, then, by stirring or homogeneous pesticide active ingredient is mixed and get final product.When the soup for preparing can not use immediately, soup is parked a period of time if solidify, need before using to use again with after its fusing of heating, if when the weather temperature is low, solidify for the medicament that prevents to mix, the convenient use, also can when grease and agricultural chemicals mixing, add anticoagulant,, increase departmental cost though made things convenient for use like this.
Embodiment 1: lard mixes with 40% green newborn copper missible oil to use prevents and treats eyespot in apple limb
99 parts of lards, 1 part of 40% green newborn copper missible oil, with lard be put into heat in the container fusing after, temperature is controlled at 60 ℃～80 ℃, again 40% green newborn copper is added in the lard of fusing, manually mix and get final product, the medicament for preparing is brushed on the eyespot in apple limb scab uniformly, use again after the fusing of need heating after the soup condensation for preparing.
The active ingredient of green newborn copper missible oil can be evenly distributed in the lard, soup is brushed to disease portion tissue, because lard has the very saturating property of Qiang De Seepage, adhesivity and closure to the plant cork layer, therefore, active ingredient to green newborn copper sterilization can play good De Zhu Seepage effect, makes Yao Ji Seepage organize kill pathogens to sick portion thoroughly, and by its adhesivity and closure the sick worm tissue of causing harm is closed, make germ distribute conidium and propagate, reach the purpose of control germ to the outside.
Embodiment 2: lard, two kinds of animal fats of butter mix with 40% green newborn copper missible oil to use prevents and treats the apple scurf
50 parts of lards, 49 parts in butter, 1 part of 40% green newborn copper missible oil, lard and butter are put into the fusing of heating in the container according to the above ratio after, temperature is controlled at 60 ℃～80 ℃, 40% green newborn copper missible oil is added in the grease of fusing again, manually mixes to get final product.Again the medicament for preparing is brushed on the eyespot in apple limb scab uniformly.Its effect is with embodiment 1.
Embodiment 3: palm oil mixes with 40% green newborn copper missible oil to use prevents and treats the apple southern blight.
98 parts of palm oils, 2 parts of 40% green newborn copper missible oil, with palm oil be put into according to the above ratio heat in the container fusing after, temperature is controlled at 60 ℃～80 ℃, again 40% green newborn copper missible oil is added in the palm oil of fusing, manually mix and get final product, the medicament for preparing is brushed on the apple rhizome southern blight scab uniformly gets final product, can play kill pathogens and prevent the wooden rotten effect of disease portion, the portion's of having wholesome effects healing.
Embodiment 4: palm oil, soya-bean oil mix with 40% green newborn copper missible oil to use prevents and treats the apple southern blight
50 parts of palm oils, 48 parts in soya-bean oil, 2 parts of 40% green newborn copper missible oil, after palm oil and soya-bean oil was put into the fusing of heating in the container according to the above ratio, temperature was controlled at 60 ℃～80 ℃, 40% green newborn copper missible oil is added again, manually mix and get final product, the medicament for preparing is brushed on the apple rhizome southern blight scab uniformly, can plays kill pathogens and prevent the wooden rotten effect of disease portion, the portion's of having wholesome effects healing.
Embodiment 5: lard, palm oil mix with 40% green newborn copper missible oil to use prevents and treats eyespot in apple limb
50 parts of lards, 49 parts of palm oils, 1 part of 40% green newborn copper missible oil, after lard and palm oil be put into the fusing of heating in the container according to the above ratio, temperature is controlled at 60 ℃～80 ℃, 40% green newborn copper missible oil is added again, and manually mixes to get final product, the medicament for preparing is brushed on the eyespot in apple limb scab uniformly, and its effect is with embodiment 1.
Embodiment 6: lard, sheep oil, palm oil mix with 40% green newborn copper missible oil to use prevents and treats eyespot in apple limb
30 parts of lards, 20 parts of sheep oil, 49 parts of palm oils, 1 part of 40% green newborn copper missible oil, with lard, sheep oil and palm oil be put into according to the above ratio heat in the container fusing after, temperature is controlled at 60 ℃～80 ℃, again 40% green newborn copper missible oil is added, manually mix and get final product, the medicament for preparing is brushed on the eyespot in apple limb scab uniformly, its effect is with embodiment 1.
Embodiment 7: the mixing animal fat that industrial processes is produced mixes with 40% green newborn copper missible oil to use prevents and treats eyespot in apple limb
Industrial processes is mixed animal fat, as use lard, sheep oil, fish oil, etc. the animal fat be processed into through physical method of two or more animal fats also can be used as the insecticides adjuvant use.99 parts of the mixing animal fats of industrial processes, 1 part of 40% green newborn copper missible oil, after the mixing animal fat of industrial processes is put into the fusing of heating in the container according to the above ratio, temperature is controlled at 60 ℃～80 ℃, again 40% green missible oil copper is added, manually mix and get final product, the medicament for preparing is brushed on the eyespot in apple limb scab uniformly, its effect is with embodiment 1.
Embodiment 8: the mixed plant grease that industrial processes is produced mixes with 40% green newborn copper missible oil to use prevents and treats eyespot in apple limb
Use peanut oil, soya-bean oil, palm oil, etc. the vegetable fat be processed into through physical method of two or more vegetable fat also can be used as insecticides adjuvant and use, 99 parts of the mixed plant greases of industrial processes, 1 part of 40% green newborn copper missible oil, after the mixed plant grease of industrial processes is put into the fusing of heating in the container according to the above ratio, temperature is controlled at 60 ℃～80 ℃, again 40% green newborn copper missible oil is added, manually mix and get final product, the medicament for preparing is brushed on the eyespot in apple limb scab uniformly, and its effect is with embodiment 1.
Embodiment 9: the mixing animal and plant fat that industrial processes is produced mixes with 40% green newborn copper missible oil to use prevents and treats eyespot in apple limb
Use lard, the animal and plant fat that sheep oil, fish oil, palm oil, peanut oil, cottonseed wet goods animal and plant fat are processed into through chemical method also can be used as insecticides adjuvant and uses, 99 parts of the mixing animal and plant fats of industrial processes, 1 part of 40% green newborn copper missible oil, after the mixing animal and plant fat of industrial processes is put into the fusing of heating in the container according to the above ratio, temperature is controlled at 60 ℃～80 ℃, again 40% green newborn copper missible oil is added, manually mix and get final product, the medicament for preparing is brushed on the eyespot in apple limb scab uniformly, and its effect is with embodiment 1.
Embodiment 10: the grease that becomes sour mixes with 40% green newborn copper missible oil to use prevents and treats eyespot in apple limb
Become sour 99 parts of greases, after 1 part of 40% green newborn copper missible oil, the grease that will become sour were put into the fusing of heating in the container according to the above ratio, temperature was controlled at 60 ℃～80 ℃, 40% green newborn copper missible oil was added again, and manually mixed to get final product.Be brushed to uniformly on the eyespot in apple limb scab at the medicament that will prepare, its effect is with embodiment 1.
Embodiment 11: denatured peanut oil mixes with 40% green newborn copper missible oil to use prevents and treats eyespot in apple limb
99 parts of denatured peanut oil, 1 part of 40% green newborn copper missible oil, with the sex change grease be put into according to the above ratio heat in the container fusing after, temperature is controlled at 60 ℃～80 ℃, again 40% green newborn copper missible oil is added, manually mix and get final product, the medicament for preparing is brushed on the eyespot in apple limb scab uniformly, its effect is with embodiment 1.
Embodiment 12: waste oil (the catering trade discharging contains the compound lard of impurity) mixes with 40% green newborn copper missible oil to use prevents and treats eyespot in apple limb
99 parts of waste oils, 1 part of 40% green newborn copper missible oil, with waste oil be put into according to the above ratio heat in the container fusing after, temperature is controlled at 60 ℃～80 ℃, again 40% green newborn copper missible oil is added, manually mix and get final product, the medicament for preparing is brushed on the eyespot in apple limb scab uniformly, its effect is with embodiment 1.
Embodiment 13: the glyceryl ester of forming the fatty acid of grease mixes with 40% green newborn copper missible oil to use prevents and treats 99 parts of eyespot in apple limb glyceryl esters, 1 part of 40% green newborn copper missible oil, with glyceryl ester be put into heat in the container fusing after, temperature is controlled at 60 ℃～80 ℃, again 40% green newborn copper missible oil is added, manually mix and get final product, the medicament for preparing is brushed on the eyespot in apple limb scab uniformly.Its effect is with embodiment 1.
Embodiment 14: the fatty acid of forming glyceryl ester mixes with 40% green newborn copper missible oil to use prevents and treats eyespot in apple limb
99 parts in fatty acid, 1 part of 40% green newborn copper missible oil, with fatty acid be put into heat in the container fusing after, temperature is controlled at 60 ℃～80 ℃, again 40% green newborn copper missible oil is added, manually mix and get final product, the medicament for preparing is brushed on the eyespot in apple limb scab uniformly.Its effect is with embodiment 1.
Embodiment 15: grease, glyceryl ester and fatty acid mix with 40% green newborn copper to use prevents and treats eyespot in apple limb
40 parts of greases (vegetable and animals oils such as lard, sheep oil, soya-bean oil all can), 30 parts of glyceryl esters, 29 parts in fatty acid, 1 part of 40% green newborn copper missible oil, after grease, glyceryl ester and fatty acid was put into the fusing of heating in the container, temperature was controlled at 60 ℃～80 ℃, 40% green newborn copper missible oil is added again, manually mix and get final product, the medicament for preparing is brushed on the eyespot in apple limb scab uniformly.
Embodiment 16: lard, cosolvent, anticoagulant and copper 8-hydroxyquinolinate are produced the organic copper bactericide
64 parts of lards, 6 parts in acetone (cosolvent), 25 parts of 8 copper quinolinates, after lard and acetone (cosolvent) is put into the fusing of heating in the reactor, temperature is controlled at 60 ℃～80 ℃, mixing is stirred under 150～230 rev/mins of rotating speeds, again 8 copper quinolinates is added to mix to get final product, and this medicament can be used for the control of apple limb rot.
Embodiment 17: lard, palm oil, cosolvent mix with copper 8-hydroxyquinolinate produces the organic copper bactericide
40 parts of lards, palm oil 29,6 parts in acetone (cosolvent), 25 parts of 8 copper quinolinates, with lard, palm oil and acetone (cosolvent) be put into heat in the reactor fusing after, temperature is controlled at 60 ℃～80 ℃, under 150～230 rev/mins of rotating speeds, mix and stir, again 8 copper quinolinates are added to mix and get final product, this medicament can be used for the control of apple limb rot.
Embodiment 18: lard, emulsifier and water mix the control eyespot in apple limb with 40% green newborn copper
29 parts of lards, 5 parts of alkyl poly glucoside emulsifier, 1 part of 40% green newborn copper missible oil, 65 parts in water, lard, alkyl poly glucoside emulsifier, 40% green newborn copper missible oil and water are put in the homogenizer tank diameter, temperature is controlled at 60 ℃～80 ℃, gets final product through homogenizer emulsification, and the medicament that emulsification is good sprays cloth uniformly or is brushed on the eyespot in apple limb scab.
Embodiment 19: the emulsion spraying apple limb of lard, emulsifier and water is used to prevent and treat eyespot in apple limb, the winter protection of tree body, reduces the limb dehydration and promote the organization healing of disease portion.
30 parts of lards, 5 parts of alkyl poly glucoside emulsifier, 65 parts in water, lard, alkyl poly glucoside emulsifier and water are put in the homogenizer tank diameter, temperature is controlled at 60 ℃～80 ℃, get final product through homogenizer emulsification, again that emulsification is good emulsion (perhaps thin up after) is as required sprayed cloth uniformly or is brushed on the apple limb.
Embodiment 20: palm oil, heavy oil mix with 40% green newborn copper missible oil to use prevents and treats the apple southern blight
50 parts of palm oils, 49 parts in heavy oil, 1 part of 40% green newborn copper missible oil, after palm oil and heavy oil was put into the fusing of heating in the container according to the above ratio, temperature was controlled at 60 ℃～80 ℃, 40% green newborn copper missible oil is added again, manually mix and get final product, the medicament for preparing is brushed on the apple rhizome southern blight scab uniformly, can plays kill pathogens and play disease portion xylem antisepsis, the portion of having wholesome effects heals as early as possible.
Embodiment 21: butter, heavy oil mix with 40% green newborn copper missible oil to use prevents and treats the apple southern blight
50 parts in butter, 49 parts in heavy oil, 1 part of 40% green newborn copper missible oil, after butter and heavy oil was put into the fusing of heating in the container according to the above ratio, temperature was controlled at 60 ℃～80 ℃, 40% green newborn copper missible oil is added again, manually mix and get final product, the medicament for preparing is brushed on the apple rhizome southern blight scab uniformly, can plays kill pathogens and prevent the wooden rotten effect of disease portion, the portion's of having wholesome effects healing.
Embodiment 22: lard, palm oil, heavy oil mix with 40% green newborn copper missible oil to use prevents and treats the apple southern blight
30 parts of lards, 30 parts of palm oils, 39 parts in heavy oil, 1 part of 40% green newborn copper missible oil, after lard, palm oil and heavy oil was put into the fusing of heating in the container according to the above ratio, temperature was controlled at 60 ℃～80 ℃, 40% green newborn copper missible oil is added again, manually mix and get final product, be brushed to uniformly on the apple rhizome southern blight scab at the medicament that will prepare, can play kill pathogens and prevent the wooden rotten effect of disease portion, the portion's of having wholesome effects healing.
Embodiment 23: the glyceryl ester of fatty acid, emulsifier and water mix the control eyespot in apple limb with 40% green newborn copper missible oil
30 parts of the glyceryl esters of fatty acid, 5 parts of alkyl poly glucoside emulsifier, 1 part of 40% green newborn copper missible oil, 64 parts in water, glyceryl ester, alkyl poly glucoside emulsifier, 40% green newborn copper missible oil and water are put in the homogenizer tank diameter, temperature is controlled at 60 ℃～80 ℃, gets final product through homogenizer emulsification, again the medicament for preparing is sprayed cloth uniformly or is brushed on the eyespot in apple limb scab.
Embodiment 24: the emulsion spraying apple limb of the glyceryl ester of fatty acid, emulsifier and water is used to prevent and treat eyespot in apple limb, the winter protection of tree body, reduces the limb dehydration and promote the organization healing of disease portion.
30 parts of the glyceryl esters of fatty acid, 5 parts of alkyl poly glucoside emulsifier, 65 parts in water, glyceryl ester, alkyl poly glucoside emulsifier and water are put in the homogenizer tank diameter, temperature is controlled at 60 ℃～80 ℃, get final product through homogenizer emulsification, again that emulsification is good emulsion (perhaps behind the thin up) is sprayed cloth uniformly or is brushed on the apple limb.
Embodiment 25: fatty acid, emulsifier and water mix the control eyespot in apple limb with 40% green newborn copper missible oil
30 parts in fatty acid, 5 parts of alkyl poly glucoside emulsifier, 1 part of 40% green newborn copper missible oil, 64 parts in water, fatty acid, alkyl poly glucoside emulsifier, 40% green newborn copper missible oil and water are put in the homogenizer tank diameter, temperature is controlled at 60 ℃～80 ℃, gets final product through homogenizer emulsification, again the medicament for preparing is sprayed cloth uniformly or is brushed on the eyespot in apple limb scab.
Embodiment 26: fatty acid, alkyl polysaccharide glycoside emulsifier and water-in-oil emulsion spraying apple limb are used to prevent and treat eyespot in apple limb, the winter protection of tree body, reduce the limb dehydration and promote the organization healing of disease portion.
30 parts in fatty acid, 5 parts of alkyl poly glucoside emulsifier, 65 parts in water, fatty acid, alkyl poly glucoside emulsifier and water are put in the homogenizer tank diameter, temperature is controlled at 60 ℃～80 ℃, get final product through homogenizer emulsification, again that emulsification is good emulsion (perhaps behind the thin up) is sprayed cloth uniformly or is brushed on the apple limb.
Embodiment 27: the glyceryl ester of fatty acid, fatty acid, emulsifier and water mix the control eyespot in apple limb with 40% green newborn copper missible oil
15 parts of the glyceryl esters of fatty acid, 15 parts in fatty acid, 5 parts of alkyl poly glucoside emulsifier, 1 part of 40% green newborn copper missible oil, 64 parts in water is put into glyceryl ester, fatty acid, alkyl poly glucoside emulsifier, 40% green newborn copper missible oil and the water of fatty acid in the homogenizer tank diameter, and temperature is controlled at 60 ℃～80 ℃, get final product through homogenizer emulsification, again the medicament for preparing is sprayed cloth uniformly or be brushed to eyespot in apple limb in the class sick.
Embodiment 28: the emulsion spraying apple limb of the glyceryl ester of fatty acid, fatty acid, emulsifier and water is used to prevent and treat eyespot in apple limb, the winter protection of tree body, reduces the limb dehydration and promote the organization healing of disease portion.
15 parts in the glyceryl ester 15 of fatty acid, fatty acid, 5 parts of alkyl poly glucoside emulsifier, 65 parts in water, glyceryl ester, fatty acid, alkyl poly glucoside emulsifier and the water of fatty acid are put in the homogenizer tank diameter, temperature is controlled at 60 ℃～80 ℃, get final product through homogenizer emulsification, again that emulsification is good emulsion (perhaps behind the thin up) is sprayed cloth uniformly or is brushed on the apple limb.
Embodiment 29: lard preparation copper naphthenate missible oil
To mix in 77 parts of lards, 2 parts of calcium dodecyl benzene sulfonates and 1 part of adding reactor of alkyl phenol formaldehyde resin polyoxyethylene ether, again with in 20 parts of adding reactors of copper naphthenate, after mixing stirring under 160～200 rev/mins of rotating speeds, both can obtain 20% copper naphthenate cream preparation, this bactericide can be used for preventing and treating pear scab, fruit white rot of grape etc.
Embodiment 30: lard and copper naphthenate preparation bucket mixture
99 parts of lards, 1 part of 8% copper naphthenate after the lard heat fused, gets final product mixing and stirring in the lard of 8% copper naphthenate adding fusing again, and the soup for preparing is coated onto on the eyespot in apple limb scab, can be prevented and treated effectively.
Embodiment 31: lard, palm oil and copper naphthenate preparation ring spot bucket mixture
50 parts of lards, 49 parts of palm oils, 1 part of 8% copper naphthenate, after lard, palm oil heat fused, again mixing and stirring in the grease of 8% copper naphthenate adding fusing is got final product, the soup for preparing is coated onto on the eyespot in apple limb scab, can be prevented and treated effectively.
Embodiment 32: lard, 2.5% Biphenthrin missible oil preparation ultra low volume spraying agent
25 parts of 2.5% Biphenthrin missible oil active ingredients, 50 parts of lards, 20 parts of rapeseed oils, 5 parts of surface-active matter get final product being uniformly dispersed in 2.5% Biphenthrin missible oil, lard, rapeseed oil and the surface-active matter input homogenizer, and this medicament can be used for preventing and treating peach fruit borer, oriental fruit moth.
Embodiment 33: sheep oil preparation 1% gibberellin plant growth regulator
1 part of gibberellin (active ingredient), 85 parts of sheep oil, ethanol 8%, surfactant 6% gets final product being uniformly dispersed in gibberellin, sheep oil, ethanol and the surfactant input homogenizer.
Embodiment 34: lard and 40% green newborn copper missible oil are used alternatingly control limb ring rot of apple
Earlier 40% green newborn copper missible oil dilution is sprayed cloth to the eyespot in apple limb scab, then, again lard is brushed on the scab of the green newborn copper of spray cloth, also can play Zhu Seepage, sealing process.
Embodiment 35: lard and 40% green newborn copper missible oil can play limb and rhizome winter protection, reduce the effect of setting the body dehydration and promoting the organization healing of disease portion when being blended in control plant limb and rhizome damage by disease and insect
1 part of 40% green newborn copper missible oil with after 99 parts of lards mix, is brushed to the disease portion tissue and healthy limb the going up of not catching an illness and can plays control or prevent apple limb rot, ring spot, dry rot, two spotted spider mite before apple germinates; Because the main component of soup is a lard, with its spray cloth or be brushed to good closure, adhesivity, thermal insulation and anti-corrosive properties are arranged on the limb, therefore, can plays winter protection, reduce tree body dehydration and promote the effect of disease portion organization healing.
Embodiment 36: use separately lard spraying apple limb to play to prevent that damage by disease and insect from infecting, winter protection, minimizing tree body dehydration and promote the organization healing effect of disease portion
Lard is sprayed on the apple limb, and to go up its closure, adhesivity, thermal insulation and anti-corrosive properties better because lard sprays to limb, therefore, can play and prevent that damage by disease and insect from infecting, winter protection, minimizing tree body dehydration and promote the effect of disease portion organization healing.
Claims (13)
1, a kind of insecticides adjuvant is characterized in that being made up of grease, and grease comprises animal fat (being commonly called as animal oil) and vegetable fat (being commonly called as vegetable oil), and therefore, this constituent can be the constituent more than a kind or 2 kinds of animal fat; It can be the constituent more than a kind or 2 kinds of vegetable fat; It can be the constituent of animal fat (being commonly called as animal oil) and vegetable fat (being commonly called as vegetable oil); The constituent that also comprises the animal fat (being commonly called as animal oil), vegetable fat (being commonly called as vegetable oil) and the animals and plants compound lard that utilize physical method and chemical method to make; In addition, the grease that contains impurity (as: waste oil that is commonly called as, saliva oil, waste oil etc.) that also comprises the grease that becomes sour, sex change grease, catering trade and industrial discharge or product.
2, a kind of insecticides adjuvant according to claim 1, it is characterized in that described grease comprises animal fat (being commonly called as animal oil) and vegetable fat (being commonly called as vegetable oil), animal fat (being commonly called as animal oil) comprising: lard, sheep oil, butter, donkey oil, house oil, chicken fat, goose oil, duck oil, fish oil; Vegetable fat (being commonly called as vegetable oil) comprises palm oil, tung oil, peanut oil, rapeseed oil, soya-bean oil, sesame oil, sunflower oil, cottonseed oil, but be not limited only to listed animal fat (being commonly called as animal oil) and vegetable fat (being commonly called as vegetable oil), at least a above grease of above-mentioned animal fat (being commonly called as animal oil) and vegetable fat (being commonly called as vegetable oil).
3, a kind of insecticides adjuvant according to claim 1 is characterized in that the glyceryl ester of the main component fatty acid of described grease.
4, a kind of insecticides adjuvant according to claim 3 is characterized in that the fatty acid that the glyceryl ester hydrolysis of described fatty acid forms.
5,, it is characterized in that the glyceryl ester and the fatty acid of described grease, fatty acid, by the above-mentioned wherein constituent of material more than 2 kinds according to claim 1 or 2 or 3 described a kind of insecticides adjuvants.
6, the described a kind of insecticides adjuvant of claim 1 is characterized in that described animal fat (being commonly called as animal oil), animal fat (being commonly called as animal oil) and vegetable fat (being commonly called as vegetable oil) mixture, the grease that becomes sour, sex change grease, contains impurity grease and a kind above-mentioned or the constituent of multiple material of surfactant, cosolvent, thinner, anticoagulant, antifreezing agent, filler, carrier, stabilizing agent, sustained release agent, synergist, anti-drift agent, dust-proofing agent, poisoning palliative, dyestuff, pigment, water, mineral oil and organic matter.
7, claim 3 insecticides adjuvant is characterized in that the glyceryl ester and a kind above-mentioned or the constituent of multiple material of surfactant, cosolvent, thinner, anticoagulant, antifreezing agent, filler, carrier, stabilizing agent, sustained release agent, synergist, anti-drift agent, dust-proofing agent, poisoning palliative, dyestuff, pigment, water, mineral oil and organic matter of fatty acid.
8, claim 4 insecticides adjuvant is characterized in that by fatty acid and a kind above-mentioned or the constituent of multiple material of surfactant, cosolvent, thinner, anticoagulant, antifreezing agent, filler, carrier, stabilizing agent, sustained release agent, synergist, anti-drift agent, dust-proofing agent, poisoning palliative, dyestuff, pigment, water, mineral oil and organic matter.
9, a kind of insecticides adjuvant according to claim 5 is characterized in that by the glyceryl ester of grease, fatty acid and fatty acid a kind above-mentioned or the constituent of multiple material of the constituent of material and surfactant, cosolvent, thinner, anticoagulant, antifreezing agent, filler, carrier, stabilizing agent, sustained release agent, synergist, anti-drift agent, dust-proofing agent, poisoning palliative, dyestuff, pigment, water, mineral oil and organic matter more than 2 kinds wherein.
10, right 1 or 2 or 3 or 4 or 5 or 6 or 7 or the 8 or 9 described a kind of insecticides adjuvants that require are used to prepare the pesticidal preparations that formulation is missible oil, oil suspending agent, bucket mixture, ultra low volume spraying agent.
11, right 1 or 2 or 3 or 4 or 5 or 6 or 7 or the 8 or 9 described a kind of insecticides adjuvants that require are used to prepare insecticide, bactericide, miticide, disinfectant, plant growth regulator.
12, described a kind of insecticides adjuvant 1 or 2 or 3 or 4 or 5 or 6 or 7 or 8 or 9 of claim mixes or is used to separately prevent and treat plant pest with agricultural chemicals, especially utilize spray cloth or be coated with and rinse control plant limb or rhizome damage by disease and insect, can mix spray cloth in back with agricultural chemicals or be brushed to plant limb or the sick worm of the rhizome position of causing harm, after also can be earlier executing agricultural chemicals at plant limb or rhizome damage by disease and insect position, again insecticides adjuvant constituent of the present invention is sprayed cloth or is brushed to the dispenser position, also can spray pre-preventing disease and pest is played in cloth or brushing at the position that the anosis worm of plant limb and rhizome is caused harm effect.
13, described a kind of insecticides adjuvants of requiring of right 1 or 2 or 3 or 4 or 5 or 6 or 7 or 8 or 9 mix separately or with agricultural chemicals and are painted on plant limb and rhizome can play winter protection, reduces dehydration and promote the organization healing effect of disease portion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006100773861A CN101057590A (en) | 2006-04-23 | 2006-04-23 | Pesticide additive |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006100773861A CN101057590A (en) | 2006-04-23 | 2006-04-23 | Pesticide additive |
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| CN101057590A true CN101057590A (en) | 2007-10-24 |
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| CNA2006100773861A Pending CN101057590A (en) | 2006-04-23 | 2006-04-23 | Pesticide additive |
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Open date: 20071024 |