CN103535346A - Mixed pesticide spray assistant prepared from waste animal-plant oil mixture and its preparation method and use method - Google Patents
Mixed pesticide spray assistant prepared from waste animal-plant oil mixture and its preparation method and use method Download PDFInfo
- Publication number
- CN103535346A CN103535346A CN201310474466.0A CN201310474466A CN103535346A CN 103535346 A CN103535346 A CN 103535346A CN 201310474466 A CN201310474466 A CN 201310474466A CN 103535346 A CN103535346 A CN 103535346A
- Authority
- CN
- China
- Prior art keywords
- miscella
- discarded animals
- plants
- plants miscella
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007921 spray Substances 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title claims abstract description 36
- 239000000203 mixture Substances 0.000 title claims abstract description 19
- 239000000575 pesticide Substances 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims abstract description 11
- 239000002699 waste material Substances 0.000 title abstract description 16
- 239000010773 plant oil Substances 0.000 title abstract description 8
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 21
- 238000005886 esterification reaction Methods 0.000 claims abstract description 17
- 230000032050 esterification Effects 0.000 claims abstract description 16
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims abstract description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 9
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims abstract description 9
- 229920000053 polysorbate 80 Polymers 0.000 claims abstract description 9
- 235000019483 Peanut oil Nutrition 0.000 claims abstract description 7
- 235000019484 Rapeseed oil Nutrition 0.000 claims abstract description 7
- 239000000312 peanut oil Substances 0.000 claims abstract description 7
- 241000196324 Embryophyta Species 0.000 claims description 52
- 241001465754 Metazoa Species 0.000 claims description 52
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 51
- 239000002671 adjuvant Substances 0.000 claims description 43
- 239000012752 auxiliary agent Substances 0.000 claims description 22
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 239000002131 composite material Substances 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 17
- 230000000361 pesticidal effect Effects 0.000 claims description 9
- 239000006228 supernatant Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- 238000013517 stratification Methods 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 6
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 claims description 5
- 239000005875 Acetamiprid Substances 0.000 claims description 5
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000000047 product Substances 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 208000030208 low-grade fever Diseases 0.000 claims description 3
- 239000000376 reactant Substances 0.000 claims description 3
- GRONZTPUWOOUFQ-UHFFFAOYSA-M sodium;methanol;hydroxide Chemical compound [OH-].[Na+].OC GRONZTPUWOOUFQ-UHFFFAOYSA-M 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 3
- 238000011084 recovery Methods 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 17
- 235000019198 oils Nutrition 0.000 description 17
- 239000003905 agrochemical Substances 0.000 description 8
- 230000002195 synergetic effect Effects 0.000 description 7
- 239000004009 herbicide Substances 0.000 description 6
- 238000011160 research Methods 0.000 description 6
- 239000002917 insecticide Substances 0.000 description 5
- 239000003814 drug Substances 0.000 description 3
- 230000002363 herbicidal effect Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 235000021190 leftovers Nutrition 0.000 description 2
- 150000004702 methyl esters Chemical class 0.000 description 2
- 230000002633 protecting effect Effects 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 241000008892 Cnaphalocrocis patnalis Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- -1 after stratification Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000021393 food security Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 1
- 235000015277 pork Nutrition 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000012747 synergistic agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a mixed pesticide spray assistant prepared from a waste animal-plant oil mixture and its preparation method and use method. The mixed pesticide spray assistant is prepared from the waste animal-plant oil mixture subjected to methyl esterification and a compound emulsifier. The waste animal-plant oil mixture mainly comprises rapeseed oil, peanut oil and lard. The compound emulsifier comprises Span-80 and Tween-80. The preparation method comprises the following steps that the waste animal-plant oil mixture undergoes a methyl esterification reaction; and the mixed pesticide spray assistant is prepared from the methyl esterification product and the compound emulsifier. The use method comprises that the mixed pesticide spray assistant is added into a pesticide preparation. The mixed pesticide spray assistant realizes reasonable recovery on the waste animal-plant oil mixture, has a low cost and has obvious synergism effects on the pesticide preparation.
Description
Technical field
The present invention relates to a kind of blended spray adjuvants that utilizes discarded animals and plants miscella and preparation method thereof and using method, this insecticides adjuvant is particularly useful for the agricultural chemicals of insecticide, bactericide, weed killer herbicide, plant growth regulator class, belongs to pesticide spray auxiliary agent technical field.
Background technology
The general designations that waste oil is people to all kinds of poor oils in life, long-term edible may be diseases induced, very harmful to human body.Waste oil can be divided three classes: the one, and the waste oil of narrow sense, is about to greasy floating thing in sewer or by the leftovers of hotel, restaurant, the oil of leftovers (common name swill) through simply processing, extracting; The 2nd, pork inferior, haslet, pigskin processing and the oil that refines rear output; The 3rd, for the oily access times of fried food, surpass after certain number of times, then be reused or toward wherein adding the oil of reusing after some fresh oils.
Waste oil has become a harm greatly of China's food security at present, avoid waste oil to pass back into dining table, and one of best solution is exactly the special high added value treatment technologies for waste oil of research and development, can recycle waste oil, turns waste into wealth.The General Office of the State Council, also in July, 2010 file publishing, determines to organize trench wet goods city kitchen castoff recycling and harmless treatment pilot work.
According to the applicant understood, the application of external oil-type adjuvant in agricultural chemicals is very general, and the existing 30 various new oil emu of the U.S. are applied in weed killer herbicide, bactericide and insecticide at present.Meanwhile, China also has more research report about oil-type adjuvant with the mixed and synergistic effect of weed killer herbicide, insecticide.
Because oil-type adjuvant has solubility problem, the amount conventionally directly adding is less, and generally by bucket mix into.The effect of oil-type adjuvant is better than the effect of general surfactant, particularly, under certain environment condition, agricultural chemicals is had to obvious synergistic effect.Conventionally, oil-type adjuvant can be accelerated the absorption efficiency of crop to foliar spray agricultural chemicals, and oil-type adjuvant can form the emulsion of stable homogeneous with agricultural chemicals, water etc., contribute to the absorption of target crop to agricultural chemicals during foliar spray.
In recent years, China is also obtaining some effects aspect the research of esterified vegetable oil emulsion.Although it is own through there being very long history that methylated vegetable oil is used as insecticide, methylated vegetable oil is used as pesticide synergistic agent research and starts from late nineteen eighties, and research history is shorter.China does not also develop at present can commercial plant oil auxiliary agent of weedicide, and on market, common plant oil auxiliary agent has Hessen that fast 7, the Australia of U.S.'s development produces and letter moral treasured etc. at home.
In addition, according to the knowledge of the applicant, spray adjuvants enters the Chinese market history of existing more than ten years, but spray adjuvants is very slow in Chinese development, its reason have following some: (1) though the application of spray adjuvants can reduce agricultural chemicals dosage, reduces drug cost, and the price of pesticidal preparations own is lower at home, even if application spray adjuvants can reduce costs, be also difficult to allow peasant spend a extra money to remove to buy spray adjuvants.(2) because per hectare is ploughed, too high spouting liquid has also weakened the economic benefit of being brought by spray adjuvants at home.Application quantity and the spouting liquid of some spray adjuvantses are directly proportional, and are generally the 0.125%-1% that spray adjuvants accounts for spouting liquid, owing to there being such ratio to exist, so higher spouting liquid has improved the application cost of per hectare spray adjuvants naturally.And sometimes high spouting liquid can reduce the synergistic effect of spray adjuvants on the contrary.(3) domestic less to spray adjuvants research, spray adjuvants kind is single.The nonionic surfactants auxiliary agent of weedicide that late nineteen eighties, the early 1990s ， China promote is made solvent mainly with ethanol, as YZ-901, AA-921 etc.In certain humidity range, agricultural chemicals is had to synergistic effect, but synergy is not obvious under drought condition.
Summary of the invention
The goal of the invention that the present invention will realize is: overcome the problem that prior art exists, a kind of blended spray adjuvants that utilizes discarded animals and plants miscella and preparation method thereof and using method are provided, can rationally recycle discarded animals and plants miscella.This auxiliary agent is with low cost, and pesticidal preparations is had to obvious synergistic effect.
For achieving the above object, technical scheme of the present invention is as follows:
A blended spray adjuvants for discarded animals and plants miscella, is characterized in that, formulated by discarded animals and plants miscella and the composite emulsifier of esterification; Described discarded animals and plants miscella is mainly comprised of rapeseed oil, peanut oil and lard; Described composite emulsifier is comprised of Span-80 and Tween-80.
Preferably, the discarded animals and plants miscella of described esterification and the volume ratio of composite emulsifier are 80-85:15-20.
Preferably, in described composite emulsifier, the volume ratio of Span-80 and Tween-80 is 0.8-1:1-1.2.
The present invention also provides:
A blended spray adjuvants preparation method for discarded animals and plants miscella, is characterized in that, comprises the following steps:
The discarded animals and plants miscella of the first step, preparation esterification:
S1. get discarded animals and plants miscella, in water-bath, be preheated to 45 ℃-55 ℃; Described discarded animals and plants miscella is mainly comprised of rapeseed oil, peanut oil and lard;
S2. get absolute methanol, in absolute methanol, add sodium hydroxide, then in water-bath, be preheated to 45 ℃-55 ℃; The mass ratio of described absolute methanol and discarded animals and plants miscella is 1-1.5:5, the mass ratio 1:95-105 of described sodium hydroxide and discarded animals and plants miscella;
S3. S2 gained absolute methanol-sodium hydroxide mixture is added in the discarded animals and plants miscella of S1 gained to stirring reaction 0.8-1h at 45 ℃-55 ℃;
S4. naturally cooling S3 gained reactant, collects supernatant liquid after stratification;
S5. after S4 gained liquid being washed by deionized water, collect supernatant liquid after stratification, heating is removed after Trace Methanol wherein, is dried 0.8-1h at 105 ℃-110 ℃, obtains the discarded animals and plants miscella of esterification;
Second step, prepare composite emulsifier: by Span-80 and Tween-80 by volume 0.8-1:1-1.2 prepare and obtain composite emulsifier;
The 3rd step, prepare blended spray adjuvants: by the discarded animals and plants miscella of first step gained esterification and second step gained composite emulsifier by volume 80-85:15-20 prepare and obtain auxiliary agent finished product.
Preferably, in first step S4, after stratification, supernatant liquid is yellow, and lower floor is reddish brown.
Preferably, in first step S5, when Trace Methanol is removed in heating, with low-grade fever, remove methyl alcohol.
Preferably, in first step S5, while washing by deionized water, divide 3-5 time with a small amount of deionized water washing.
The present invention also provides:
A blended spray adjuvants using method for discarded animals and plants miscella, is characterized in that, comprises the following steps:
The first step, adopt aforementioned preparation method to prepare blended spray adjuvants;
Second step, first step gained auxiliary agent is added in pesticidal preparations, and mix; The mass percent of described auxiliary agent in mixture is 0.05-0.06%.
Preferably, described pesticidal preparations is the compound pesticide preparation that contains 50mg/kg Rynaxypyr and 50mg/kg Acetamiprid.
Applicant thinks, different types of waste oil contained oil component is different, the technological means that the waste oil research and development that should form for special component are specially recycled, can improve like this treatment effeciency, realizes reliable and stable treatment effect, obtain the stable product of component.Based on this understanding, applicant selects the discarded animals and plants miscella being mainly comprised of rapeseed oil, peanut oil and lard as processing object after a large amount of in depth practical studies, again with above-mentioned preparation method, directly will discard animals and plants miscella and make methyl esters carburetion, before esterification, need not to discarded animals and plants miscella, carry out other extra process (as filtered, regulating acid number etc.) again; Meanwhile, applicant draws through repeatedly practising research the composite emulsifier being used in conjunction with aforementioned methyl esters carburetion, pesticidal preparations is had to obvious synergistic effect after both are mixed with to auxiliary agent.So just formed the simple and easy technological means of the discarded animals and plants miscella of special recycling, products obtained therefrom is with low cost, added value is high, and the oil ingredient ratio of discarded animals and plants miscella is had no requirement, and is conducive to promote to reclaim the discarded animals and plants miscella of various ratios.
Embodiment
Below by embodiment, the present invention will be further described, but the present invention is not limited only to these examples.The pesticidal preparations that embodiment 1 preparation contains auxiliary agent
Concrete steps are as follows:
The discarded animals and plants miscella of the first step, preparation esterification:
S1. get discarded animals and plants miscella 100g, in water-bath, be preheated to 45 ℃-55 ℃ (for example 48 ℃); Discarded animals and plants miscella is mainly comprised of rapeseed oil, peanut oil and lard;
S2. the mass ratio of getting absolute methanol 24g(absolute methanol and discarded animals and plants miscella is 1.2:5); In absolute methanol, add 1.0g sodium hydroxide (mass ratio of sodium hydroxide and discarded animals and plants miscella is 1.0:100), then in water-bath, be preheated to 45 ℃-55 ℃ (for example 48 ℃);
S3. S2 gained absolute methanol-sodium hydroxide mixture is added in the discarded animals and plants miscella of S1 gained, for example, under 45 ℃-55 ℃ (48 ℃), stirring reaction 0.8-1h(is as 0.9h);
S4. naturally cooling S3 gained reactant, after stratification, supernatant liquid is yellow, and lower floor is reddish brown, collects supernatant liquid;
S5. by deionized water washing rear (dividing 3-5 time with a small amount of deionized water washing) for S4 gained liquid, after stratification, collect supernatant liquid, heating is removed after Trace Methanol wherein and (with low-grade fever, is removed methyl alcohol), in 105 ℃-110 ℃ (as 108 ℃) lower dry 0.8-1h(as 0.9h), obtain the discarded animals and plants miscella of esterification.
Second step, prepare composite emulsifier:
By Span-80 and Tween-80 by volume 0.8-1:1-1.2(as 0.9:1.1) prepare and obtain composite emulsifier.
Span-80 and Tween-80 buyable, manufacturer is as Tianjin Kermel Chemical Reagent Co., Ltd..
The 3rd step, prepare blended spray adjuvants:
By the discarded animals and plants miscella of first step gained esterification and second step gained composite emulsifier by volume 80-85:15-20(as 82:18) prepare and obtain auxiliary agent finished product.
The 4th step, the 3rd step gained auxiliary agent is added in the compound pesticide preparation that contains 50mg/kg Rynaxypyr and 50mg/kg Acetamiprid, and mix; The mass percent of auxiliary agent in mixture is 0.05-0.06%.
Wherein the process for preparation of compound pesticide preparation is as follows: get respectively Rynaxypyr 20% suspending agent and Acetamiprid 40% water dispersible granules, mix respectively after dilution, make Rynaxypyr and Acetamiprid concentration all reach 50mg/kg.
Embodiment 2 auxiliary agent effect confirmatory tests
Detect respectively the mixture of embodiment 1 the 4th step gained mixture, embodiment 1 the 4th step compound pesticide preparation used and ordinary adjuvants AOE-9 and embodiment 1 the 4th step compound pesticide preparation used itself for the drug effect of preventing and treating of rice leaf roller.Result is as shown in the table.
AEO-9 buyable, manufacturer is as Shanghai Wenhua chemical color Co., Ltd.
After medicine 8 days time, protecting effect of leaves aspect, adopts embodiment 1 auxiliary agent to improve 8.5% than adding assistant not, than adding ordinary adjuvants, improves 12.5%; Insecticidal effect aspect, adopts embodiment 1 auxiliary agent than not adding assistant raising 15.1%, than adding ordinary adjuvants, improves 7.9%.
After medicine 14 days time, protecting effect of leaves aspect, adopts embodiment 1 auxiliary agent to improve 25.2% than adding assistant not, than adding ordinary adjuvants, improves 6.3%; Insecticidal effect aspect, adopts embodiment 1 auxiliary agent than not adding assistant raising 44.0%, than adding ordinary adjuvants, improves 6.2%.
From above result, auxiliary agent of the present invention has obvious synergistic effect to pesticidal preparations.
Claims (9)
1. utilize a blended spray adjuvants for discarded animals and plants miscella, it is characterized in that, formulated by discarded animals and plants miscella and the composite emulsifier of esterification; Described discarded animals and plants miscella is mainly comprised of rapeseed oil, peanut oil and lard; Described composite emulsifier is comprised of Span-80 and Tween-80.
2. utilize according to claim 1 the blended spray adjuvants of discarded animals and plants miscella, it is characterized in that, the discarded animals and plants miscella of described esterification and the volume ratio of composite emulsifier are 80-85:15-20.
3. utilize according to claim 2 the blended spray adjuvants of discarded animals and plants miscella, it is characterized in that, in described composite emulsifier, the volume ratio of Span-80 and Tween-80 is 0.8-1:1-1.2.
4. utilize a blended spray adjuvants preparation method for discarded animals and plants miscella, it is characterized in that, comprise the following steps:
The discarded animals and plants miscella of the first step, preparation esterification:
S1. get discarded animals and plants miscella, in water-bath, be preheated to 45 ℃-55 ℃; Described discarded animals and plants miscella is mainly comprised of rapeseed oil, peanut oil and lard;
S2. get absolute methanol, in absolute methanol, add sodium hydroxide, then in water-bath, be preheated to 45 ℃-55 ℃; The mass ratio of described absolute methanol and discarded animals and plants miscella is 1-1.5:5, the mass ratio 1:95-105 of described sodium hydroxide and discarded animals and plants miscella;
S3. S2 gained absolute methanol-sodium hydroxide mixture is added in the discarded animals and plants miscella of S1 gained to stirring reaction 0.8-1h at 45 ℃-55 ℃;
S4. naturally cooling S3 gained reactant, collects supernatant liquid after stratification;
S5. after S4 gained liquid being washed by deionized water, collect supernatant liquid after stratification, heating is removed after Trace Methanol wherein, is dried 0.8-1h at 105 ℃-110 ℃, obtains the discarded animals and plants miscella of esterification;
Second step, prepare composite emulsifier: by Span-80 and Tween-80 by volume 0.8-1:1-1.2 prepare and obtain composite emulsifier;
The 3rd step, prepare blended spray adjuvants: by the discarded animals and plants miscella of first step gained esterification and second step gained composite emulsifier by volume 80-85:15-20 prepare and obtain auxiliary agent finished product.
5. utilize according to claim 4 the blended spray adjuvants preparation method of discarded animals and plants miscella, it is characterized in that, in first step S4, after stratification, supernatant liquid is yellow, and lower floor is reddish brown.
6. utilize according to claim 4 the blended spray adjuvants preparation method of discarded animals and plants miscella, it is characterized in that, in first step S5, when Trace Methanol is removed in heating, with low-grade fever, remove methyl alcohol.
7. utilize according to claim 4 the blended spray adjuvants preparation method of discarded animals and plants miscella, it is characterized in that, in first step S5, while washing by deionized water, divide 3-5 time with a small amount of deionized water washing.
8. utilize a blended spray adjuvants using method for discarded animals and plants miscella, it is characterized in that, comprise the following steps:
The first step, adopt aforementioned preparation method to prepare blended spray adjuvants;
Second step, first step gained auxiliary agent is added in pesticidal preparations, and mix; The mass percent of described auxiliary agent in mixture is 0.05-0.06%.
9. utilize according to claim 8 the blended spray adjuvants using method of discarded animals and plants miscella, it is characterized in that, described pesticidal preparations is the compound pesticide preparation that contains 50mg/kg Rynaxypyr and 50mg/kg Acetamiprid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310474466.0A CN103535346B (en) | 2013-10-11 | 2013-10-11 | Utilize blended spray adjuvants of discarded animals and plants miscella and preparation method thereof and using method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310474466.0A CN103535346B (en) | 2013-10-11 | 2013-10-11 | Utilize blended spray adjuvants of discarded animals and plants miscella and preparation method thereof and using method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103535346A true CN103535346A (en) | 2014-01-29 |
| CN103535346B CN103535346B (en) | 2015-10-07 |
Family
ID=49959515
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310474466.0A Expired - Fee Related CN103535346B (en) | 2013-10-11 | 2013-10-11 | Utilize blended spray adjuvants of discarded animals and plants miscella and preparation method thereof and using method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103535346B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107624775A (en) * | 2017-09-29 | 2018-01-26 | 当涂县瑞龙果树种植专业合作社 | A kind of chlorimuronethyl herbicide of esterification soybean oil synergy and preparation method thereof |
| CN107624804A (en) * | 2017-09-29 | 2018-01-26 | 当涂县瑞龙果树种植专业合作社 | A kind of weed removal mulch film of esterification soybean oil synergy and preparation method thereof |
| CN107624823A (en) * | 2017-09-29 | 2018-01-26 | 当涂县瑞龙果树种植专业合作社 | A kind of esterification soybean oil Synergistic herbicidal agents containing garlic oil and preparation method thereof |
| CN107646880A (en) * | 2017-09-29 | 2018-02-02 | 当涂县瑞龙果树种植专业合作社 | A kind of weed removal mulch film of oleander extract synergy and preparation method thereof |
| CN107751228A (en) * | 2017-09-29 | 2018-03-06 | 当涂县瑞龙果树种植专业合作社 | A kind of chlorimuronethyl herbicide of silica absorption and preparation method thereof |
| CN112385655A (en) * | 2019-08-15 | 2021-02-23 | 烟台七微肥料有限公司 | Application of fatty acid methyl ester in plant pesticide and plant pesticide |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0933025A1 (en) * | 1998-01-20 | 1999-08-04 | American Cyanamid Company | Emulsifiable concentrate containing one or more pesticides |
| CN1701663A (en) * | 2005-06-24 | 2005-11-30 | 福建省泉州德盛农药有限公司 | Pesticide auxiliary agent |
| CN101057590A (en) * | 2006-04-23 | 2007-10-24 | 孟祥宁 | Pesticide additive |
-
2013
- 2013-10-11 CN CN201310474466.0A patent/CN103535346B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0933025A1 (en) * | 1998-01-20 | 1999-08-04 | American Cyanamid Company | Emulsifiable concentrate containing one or more pesticides |
| CN1701663A (en) * | 2005-06-24 | 2005-11-30 | 福建省泉州德盛农药有限公司 | Pesticide auxiliary agent |
| CN101057590A (en) * | 2006-04-23 | 2007-10-24 | 孟祥宁 | Pesticide additive |
Non-Patent Citations (2)
| Title |
|---|
| 安国栋 等: "植物油助剂在农药中的研究与应用进展", 《中国植物保护会2011年学术会论文集》, 6 November 2011 (2011-11-06), pages 853 * |
| 鲁梅 等: "甲酯化植物油助剂对除草剂的药效增强作用", 《植物保护学报》, vol. 32, no. 3, 30 September 2005 (2005-09-30), pages 295 - 299 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107624775A (en) * | 2017-09-29 | 2018-01-26 | 当涂县瑞龙果树种植专业合作社 | A kind of chlorimuronethyl herbicide of esterification soybean oil synergy and preparation method thereof |
| CN107624804A (en) * | 2017-09-29 | 2018-01-26 | 当涂县瑞龙果树种植专业合作社 | A kind of weed removal mulch film of esterification soybean oil synergy and preparation method thereof |
| CN107624823A (en) * | 2017-09-29 | 2018-01-26 | 当涂县瑞龙果树种植专业合作社 | A kind of esterification soybean oil Synergistic herbicidal agents containing garlic oil and preparation method thereof |
| CN107646880A (en) * | 2017-09-29 | 2018-02-02 | 当涂县瑞龙果树种植专业合作社 | A kind of weed removal mulch film of oleander extract synergy and preparation method thereof |
| CN107751228A (en) * | 2017-09-29 | 2018-03-06 | 当涂县瑞龙果树种植专业合作社 | A kind of chlorimuronethyl herbicide of silica absorption and preparation method thereof |
| CN112385655A (en) * | 2019-08-15 | 2021-02-23 | 烟台七微肥料有限公司 | Application of fatty acid methyl ester in plant pesticide and plant pesticide |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103535346B (en) | 2015-10-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103535345B (en) | Mixed pesticide spray auxiliary prepared from waste soybean oil-sunflower oil mixture, and preparation method and application method thereof | |
| CN103535346B (en) | Utilize blended spray adjuvants of discarded animals and plants miscella and preparation method thereof and using method | |
| CN103734148A (en) | Weeding composition containing pyroxasulfone | |
| CN103262847A (en) | Biogenic pesticide containing xanthoxylin and abamectin and preparation method thereof | |
| CN104054716B (en) | Weeding composition containing tembotrione | |
| CN102177887A (en) | Diafenthiuron emulsion in water and preparation method thereof | |
| CN105010337A (en) | Method of preparing mosquito repellant by utilizing cassia oil extraction waste liquid | |
| CN103688961A (en) | A pesticide composition containing fluoropyridine furanone | |
| CN101743982A (en) | Mixed insecticide of tea saponin and nereistoxin insecticide | |
| CN104082300A (en) | Insecticide acaricide composition containing pyriproxyfen and spirodiclofen | |
| CN104106593A (en) | Insecticide acaricidal composition containing xiaochongthion and etoxazole | |
| CN103907648B (en) | A kind of Synthesis and applications preventing and treating the compound plant bactericide of plant downy mildew | |
| CN102017969B (en) | Pesticide composition containing Bifenazate and Diafenthiuron | |
| CN104381294A (en) | Insect and mite killing composition containing xiaochongliulin and spirodiclofen | |
| CN104286010B (en) | Composition pesticide containing sulfur-phosphor and Bifenazate | |
| CN103828805B (en) | A kind of snout moth's larva of rice repellant and preparation method thereof | |
| CN104115850A (en) | Insect and mite killing composition containing etoxazole and spirotetramat | |
| CN102165958A (en) | Pesticide composite containing bifenazate and triazophos | |
| CN104585178A (en) | Synergetic acaricidal composition containing cyenopyrafen and spirodiclofen | |
| CN104222125A (en) | Pesticide composition containing lufenuron and fluazinam | |
| CN103461354A (en) | Celastrus angulatus plant source insecticidal emulsifiable concentrate | |
| CN104082322B (en) | A kind of containing Nylar with the insecticide acaricide composition of Bifenazate | |
| CN102715166A (en) | Pesticide composition containing chlorfenapyr benzamide | |
| CN103503876A (en) | Insecticidal composition containing bromantraniliprole and nereistoxin | |
| CN101213968B (en) | Tubatoxin and miticide blending pesticide preparations |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151007 |