CN103823258B - Blue light-blocking diffusion film - Google Patents

Blue light-blocking diffusion film Download PDF

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Publication number
CN103823258B
CN103823258B CN201410032921.6A CN201410032921A CN103823258B CN 103823258 B CN103823258 B CN 103823258B CN 201410032921 A CN201410032921 A CN 201410032921A CN 103823258 B CN103823258 B CN 103823258B
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China
Prior art keywords
blue light
resin
metal complex
base material
diffusion layer
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CN201410032921.6A
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Chinese (zh)
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CN103823258A (en
Inventor
施克炜
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Taihu Lake Jin Zhang Science And Technology Co Ltd
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Taihu Lake Jin Zhang Science And Technology Co Ltd
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Priority to CN201410032921.6A priority Critical patent/CN103823258B/en
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Abstract

The invention discloses a blue light-blocking diffusion film. The blue light-blocking diffusion film comprises a substrate and a blue light-proof diffusion layer fixed on a single surface or two surfaces of the substrate; and the blue light-proof diffusion layer is formed by coating and fixing a coating liquid with metal complex dye-containing resin beads and resin on the surface of the substrate. Through controlling the particle size of the metal complex dye-containing resin bead added in the diffusion film, the density and the thickness of the coating layer, a certain blue light inhibition effect by the blue light-blocking diffusion film is provided, the blue light-blocking diffusion film can play an inhibition role on light with wavelength of 380 to 500nm, and harm to eyes of a person by the blue light can be greatly reduced.

Description

One kind intercepts blue light diffusion barrier
Technical field
The present invention relates to a kind of be used for flat panel display screen or illuminating obstruct blue light diffusion barrier.
Background technology
The effect of optical diffusion is that the light of point source or line source is uniformly diffused into into homogeneous, high brightness area source. This optical diffusion is widely used in the backlight module of flat faced display and novel illumination light source, and such as TV, computer show Show device, notebook computer, mobile phone, digital camera, MP4 players, GPS navigator and various daily and industrial lighting source Deng.
And high energy shortwave blue light is very big to the eye injury of people in the light that these display or light source send when in use. Shortwave blue light refers to light of the visible ray medium wavelength between 380 nanometers to 500 nanometers.
Shortwave blue light has very high energies, can penetrate the through retina of crystalline lenses.Blue light illumination retina can be produced from By base, and these free radicals can cause retinal pigment epithelium to become feeble and die, and the decline of epithelial cell can cause photaesthesia cell Lack nutrient so as to cause vision impairment, and these damages are irreversible.If irradiation time was more than 10 seconds, this infringement As many as mechanism its Main Function, and be the several times of pyrolytic damage.
Blue light exactly causes to produce digital visual fatigue(DEF)Main cause.Luminous ray focus within the eye after focus Difference, can form focal length poor between bifocal.This is the main cause to form blurred vision.Long-time visual fatigue can draw Send out other fatigue symptoms.Injecting for blue light can aggravate focal length difference and dimness of vision degree.Blue light is because after focusing, it is burnt Point is not fallen within retina, but fall between retina and crystalline lenses, increase focus that light focuses within the eye away from Deviation.
Generally, ordinary optical diffusion barrier is can only to complete the diffusion to light, and for electronic curtain or light The blue light produced in the luminescence process of source, without any protective measure, human eye is exposed in the shortwave blue light of high-energy, to people's Eye health constitutes very big hidden danger.
So a kind of product is needed, the effect with obstruct blue light, and do not affect the basic function of diffusion barrier.
The content of the invention
The present invention is used to overcome the defect of existing product, with the effect for suppressing blue light, excellent optics diffusion.
To solve above-mentioned technical problem, the technical solution used in the present invention is:
Blue light diffusion barrier is intercepted, it includes base material and is bonded to the anti-blue light diffusion layer of base material one or two sides, anti- Contain anti-blue light optical diffusant, resin in blue light diffusion layer.
The base material is in mylar, polycarbonate film, nylon film, polyethylene film, polyvinyl chloride film One kind, base material thickness is 18-200 microns.
The anti-blue light diffusion layer be by containing mass ratio be 1:0.2-6 anti-blue light optical diffusants, resin or photocuring The coating fluid of resin anchors at what is formed on the surface of the base material, and the thickness of anti-blue light diffusion layer is 10-50 microns.
The anti-blue light optical diffusant is the resin microbeads containing metal complex class dyestuff, can be containing metal complex The polyacrylate of class dyestuff, the polymethyl methacrylate containing metal complex class dyestuff, containing metal complex class dyestuff One kind in polystyrene or the polysiloxanes containing metal complex class dyestuff, mean diameter is 1-40 microns.
The resin is selected from acrylic resin, polyester resin, polyurethane resin, epoxy acrylate, and light-cured resin is The acrylic resin of ultraviolet light polymerization, also including can be by the urethane acrylate of ultraviolet light polymerization, polyester acrylic Ester, polyether acrylate, pure acrylate or organic siliconresin.
Described anti-blue light optical diffusant is inhibited to the light of wavelength 380-500 nanometers;So that intercepting blue Optical diffusion film has iris action to blue light, while the optics diffusion for ensureing diffusion barrier reaches use requirement.
The present invention can pass through to adjust the thickness of anti-blue light diffusion layer and the concentration of added anti-blue light optical diffusant, Change the rejection rate for intercepting blue light diffusion barrier to blue light, excursion is 10~70%.
Advantages of the present invention:
The present invention adds particle diameter, density and the coating of anti-blue light optical diffusant by control in anti-blue light diffusion layer Thickness so that this obstruct blue light diffusion barrier has inhibitory action to blue light;The present invention is to 380~500 nanometers of wavelength Light is inhibited, greatly reduces injury of the blue light to the eyes of people.
Description of the drawings
The obstruct blue light diffusion barrier structural representation of Fig. 1 present invention.
1st, anti-blue light optical diffusant, 2, resin or light-cured resin, 3, base material.
Specific embodiment
The present invention is described further below by embodiment:
Embodiment 1
The preparation of diffusion layer coating fluid:
The mass parts of butanone 20
The mass parts of toluene 100
The mass parts of propylene glycol monomethyl ether 15
Acrylic resin microballon containing metal complex class dyestuff(20 microns of mean diameter)100 mass parts
The mass parts of acrylic resin 100
The mass parts of isocyanate crosslinking 20
By above-mentioned material stirring mix homogeneously, optical diffusion layer coating fluid is obtained.
With the polyethylene terephthalate that thickness is 100 microns(PET)Thin film simultaneously coats expansion as base material at it Scattered layer coating fluid, hot air drying makes its build be about 10 microns.Obstruct blue light diffusion barrier is made, its performance is tested.
Embodiment 2
The preparation of diffusion layer coating fluid:
The mass parts of butanone 20
The mass parts of toluene 100
The mass parts of propylene glycol monomethyl ether 15
Acrylic resin microballon containing metal complex class dyestuff(20 microns of mean diameter)150 mass parts
The mass parts of acrylic resin 100
The mass parts of isocyanate crosslinking 20
By above-mentioned material stirring mix homogeneously, optical diffusion layer coating fluid is obtained.
With the polyethylene terephthalate that thickness is 100 microns(PET)Thin film simultaneously coats expansion as base material at it Scattered layer coating fluid, hot air drying makes its build be about 10 microns.Obstruct blue light diffusion barrier is made, its performance is tested.
Embodiment 3
The preparation of diffusion layer coating fluid:
The mass parts of butanone 20
The mass parts of toluene 100
The mass parts of propylene glycol monomethyl ether 15
Acrylic resin microballon containing metal complex class dyestuff(20 microns of mean diameter)100 mass parts
The mass parts of light-cured acrylic resin 100
By above-mentioned material stirring mix homogeneously, optical diffusion layer coating fluid is obtained.
With the polyethylene terephthalate that thickness is 100 microns(PET)Thin film simultaneously coats expansion as base material at it Scattered layer coating fluid, hot air drying makes its build be about 10 microns, and through 450mj/cm2Ultraviolet irradiation, make resistance Every blue light diffusion barrier, its performance is tested.
Embodiment 4
The preparation of diffusion layer coating fluid:
The mass parts of butanone 20
The mass parts of toluene 100
The mass parts of propylene glycol monomethyl ether 15
Acrylic resin microballon containing metal complex class dyestuff(20 microns of mean diameter)150 mass parts
The mass parts of light-cured acrylic resin 100
By above-mentioned material stirring mix homogeneously, optical diffusion layer coating fluid is obtained.
With the polyethylene terephthalate that thickness is 100 microns(PET)Thin film simultaneously coats expansion as base material at it Scattered layer coating fluid, hot air drying makes its build be about 10 microns, and through 450mj/cm2Ultraviolet irradiation, make resistance Every blue light diffusion barrier, its performance is tested.
The method of testing of product resistance blue light performance is as follows:
380~500 nano waveband light source transmitances, i.e. blue light rejection rate are tested using spectrophotometer;
Transmitance and mist degree are tested using photoelectricity mist degree instrument.
Table 1:Product properties table
From table 1 it follows that after using the resin microbeads containing metal complex class dyestuff, intercepting blue light diffusion barrier to indigo plant Light has obvious iris action, and does not interfere with the blue color effect of screen color, while ensureing product optics diffusion effect.

Claims (1)

  1. It is 1. a kind of to intercept blue light diffusion barrier, it is characterised in that:It includes base material and is bonded to the anti-indigo plant of base material one or two sides Light diffusion layer, contains anti-blue light optical diffusant, resin in anti-blue light diffusion layer;The base material is mylar, poly- carbonic acid One kind in ester film, nylon film, polyethylene film, polyvinyl chloride film, base material thickness is 18-200 microns;It is described anti- Blue light diffusion layer be by containing mass ratio be 1:0.2-6 anti-blue light optical diffusants, the coating fluid of light-cured resin anchor at institute State what is formed on the surface of base material, the thickness of anti-blue light diffusion layer is 10-50 microns;The anti-blue light optical diffusant is Resin microbeads containing metal complex class dyestuff are the polyacrylate containing metal complex class dyestuff, containing metal complex class The polymethyl methacrylate of dyestuff, the polystyrene containing metal complex class dyestuff or the poly- silicon containing metal complex class dyestuff One kind in oxygen alkane, mean diameter is 1-40 microns;
    The resin is selected from acrylic resin, polyester resin, polyurethane resin, epoxy acrylate, and light-cured resin is ultraviolet The acrylic resin of photocuring, also including can by the urethane acrylate of ultraviolet light polymerization, polyester acrylate, gather Ether acrylate, pure acrylate or organic siliconresin;
    Described anti-blue light optical diffusant is inhibited to the light of wavelength 380-500 nanometers.
CN201410032921.6A 2014-01-23 2014-01-23 Blue light-blocking diffusion film Active CN103823258B (en)

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Application Number Priority Date Filing Date Title
CN201410032921.6A CN103823258B (en) 2014-01-23 2014-01-23 Blue light-blocking diffusion film

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Application Number Priority Date Filing Date Title
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CN103823258A CN103823258A (en) 2014-05-28
CN103823258B true CN103823258B (en) 2017-04-19

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104534338A (en) * 2015-01-30 2015-04-22 太湖金张科技股份有限公司 Blue-light-shielding anti-glare LED lamp
CN106291777B (en) * 2015-05-19 2018-06-19 象山激智新材料有限公司 The light-transmissive film or plate of a kind of anti-blue light and its application
CN106291794A (en) * 2015-06-05 2017-01-04 象山激智新材料有限公司 A kind of anti-blue light preventing ultraviolet light-transmissive film or plate and application thereof
CN107561608B (en) * 2017-09-30 2023-07-21 凯鑫森(上海)功能性薄膜产业股份有限公司 Low-blue light optical film for LED lighting device and preparation method thereof
CN108680980B (en) * 2018-07-10 2024-03-15 宁波激智科技股份有限公司 Blue light prevention optical film and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030001321A (en) * 2001-06-25 2003-01-06 아사히 가라스 가부시키가이샤 Optical film
TWI614452B (en) * 2011-10-13 2018-02-11 英特曼帝克司公司 Photoluminescence wavelength conversion components for solid-state light emitting devices and lamps
AU2012101848A4 (en) * 2012-12-18 2013-01-24 Yi-Chen Li Protective screen lens structure for a computer and a television
JP5965881B2 (en) * 2013-10-03 2016-08-10 恵和株式会社 Backlight unit for light diffusion sheet and liquid crystal display device
CN103955016A (en) * 2014-04-22 2014-07-30 上海大学 Photodiffusion film with blue light shielding function

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