CN103823258A - Blue light-blocking diffusion film - Google Patents

Blue light-blocking diffusion film Download PDF

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Publication number
CN103823258A
CN103823258A CN201410032921.6A CN201410032921A CN103823258A CN 103823258 A CN103823258 A CN 103823258A CN 201410032921 A CN201410032921 A CN 201410032921A CN 103823258 A CN103823258 A CN 103823258A
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Prior art keywords
blue light
resin
light diffusion
metal complex
diffusion barrier
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CN201410032921.6A
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CN103823258B (en
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施克炜
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Taihu Lake Jin Zhang Science And Technology Co Ltd
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Taihu Lake Jin Zhang Science And Technology Co Ltd
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Abstract

The invention discloses a blue light-blocking diffusion film. The blue light-blocking diffusion film comprises a substrate and a blue light-proof diffusion layer fixed on a single surface or two surfaces of the substrate; and the blue light-proof diffusion layer is formed by coating and fixing a coating liquid with metal complex dye-containing resin beads and resin on the surface of the substrate. Through controlling the particle size of the metal complex dye-containing resin bead added in the diffusion film, the density and the thickness of the coating layer, a certain blue light inhibition effect by the blue light-blocking diffusion film is provided, the blue light-blocking diffusion film can play an inhibition role on light with wavelength of 380 to 500nm, and harm to eyes of a person by the blue light can be greatly reduced.

Description

A kind of blue light diffusion barrier that intercepts
Technical field
The present invention relates to a kind of for flat-panel monitor screen or illuminating obstruct blue light diffusion barrier.
Background technology
The effect of optical diffusion is the area source that the light of pointolite or line source is evenly diffused into homogeneous, high brightness.This optical diffusion is widely used in the backlight module and novel illumination light source of flat-panel monitor, as TV, computer monitor, notebook computer, mobile phone, digital camera, MP4 player, GPS navigation instrument and various daily and industrial lighting source etc.
And high energy shortwave blue light is very large to people's eye injury in the light that these displays or light source send in use.Shortwave blue light refer to visible ray medium wavelength in 380 nanometers to the light between 500 nanometers.
Shortwave blue light has very high energies, can penetrate the through retina of crystalline lens.Blue light illumination retina can produce free radical, and these free radicals can cause retinal pigment epithelium decline, thereby epithelial decline can cause photaesthesia cell to lack nutrient causes vision impairment, and these damages are irreversible.If irradiation time exceedes 10 seconds, this its Main Function of infringement mechanism, and be more than the several times of pyrolytic damage.
Blue light causes producing the main cause of digital visual fatigue (DEF) just.Luminous ray focuses on back focus difference within the eye, can form focal length poor between bifocal.This is the main cause that forms blurred vision.Long-time visual fatigue can cause other fatigue symptoms.Injecting of blue light can the poor and dimness of vision degree of aggravation focal length.Be that focus does not drop on retina, but dropped between retina and crystalline lens because blue light is after focusing on, increased the focal length that light focuses within the eye poor.
Conventionally; ordinary optical diffusion barrier is only to complete the diffusion to light, and for the blue light producing in electronic curtain or light source luminescent process, without any safeguard measure; human eye is exposed in high-octane shortwave blue light, people's eye health is formed to very big hidden danger.
So need a kind of product, there is the effect that intercepts blue light, do not affect again the basic function of diffusion barrier.
Summary of the invention
The present invention, for overcoming the defect of existing product, has the effect that suppresses blue light, good optics diffusion.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
Intercept blue light diffusion barrier, it comprises base material and is bonded to the anti-blue light diffusion layer of base material one or two sides, contains anti-blue light optics diffusant, resin in anti-blue light diffusion layer.
Described base material is the one in mylar, polycarbonate film, nylon film, polyethylene film, polyvinyl chloride film, and base material thickness is 18-200 micron.
Described anti-blue light diffusion layer is to be that the coating fluid of 1:0.2-6 anti-blue light optics diffusant, resin or light-cured resin anchors on the surface of described base material and forms by containing mass ratio, and the thickness of anti-blue light diffusion layer is 10-50 micron.
Described anti-blue light optics diffusant is the resin microballon that contains metal complex class dyestuff, can be the one in polyacrylate, the polymethylmethacrylate that contains metal complex class dyestuff that contains metal complex class dyestuff, the polystyrene that contains metal complex class dyestuff or the polysiloxane that contains metal complex class dyestuff, mean grain size be 1-40 micron.
Described resin is selected from acryl resin, vibrin, urethane resin, epoxy acrylate, light-cured resin is the acrylic resin of ultraviolet light polymerization, also comprising can be by the urethane acrylate of ultraviolet light polymerization, polyester acrylate, polyether acrylate, pure acrylate or organic siliconresin.
Described anti-blue light optics diffusant is inhibited to the light of wavelength 380-500 nanometer; Make to intercept blue light diffusion barrier blue light is had to iris action, guarantee that the optics diffusion of diffusion barrier reaches request for utilization simultaneously.
The present invention can, by regulating the thickness of anti-blue light diffusion layer and institute to add the concentration of anti-blue light optics diffusant, change the rejection rate of obstruct blue light diffusion barrier to blue light, and variation range is 10~70%.
Advantage of the present invention:
The present invention adds the thickness of particle diameter, density and the coating of anti-blue light optics diffusant in anti-blue light diffusion layer by being controlled at, make this obstruct blue light diffusion barrier have the inhibiting effect to blue light; The present invention is inhibited to the light of wavelength 380~500 nanometers, has greatly reduced the injury of the eyes of blue light to people.
Accompanying drawing explanation
Fig. 1 obstruct blue light of the present invention diffusion barrier structural representation.
1, anti-blue light optics diffusant, 2, resin or light-cured resin, 3, base material.
Embodiment
Below by embodiment, the present invention is described further:
Embodiment 1
The preparation of diffusion layer coating fluid:
Butanone 20 mass parts
Toluene 100 mass parts
Propylene glycol monomethyl ether 15 mass parts
Acryl resin microballon (20 microns of mean grain sizes) 100 mass parts that contain metal complex class dyestuff
Acryl resin 100 mass parts
Isocyanate crosslinking 20 mass parts
Above-mentioned material stirring is mixed, make optical diffusion layer coating fluid.
Using thickness as polyethylene terephthalate (PET) film of 100 microns is as base material, coat diffusion layer coating fluid in its one side, heated-air drying makes its build be about 10 microns.Make and intercept blue light diffusion barrier, test its performance.
Embodiment 2
The preparation of diffusion layer coating fluid:
Butanone 20 mass parts
Toluene 100 mass parts
Propylene glycol monomethyl ether 15 mass parts
Acryl resin microballon (20 microns of mean grain sizes) 150 mass parts that contain metal complex class dyestuff
Acryl resin 100 mass parts
Isocyanate crosslinking 20 mass parts
Above-mentioned material stirring is mixed, make optical diffusion layer coating fluid.
Using thickness as polyethylene terephthalate (PET) film of 100 microns is as base material, coat diffusion layer coating fluid in its one side, heated-air drying makes its build be about 10 microns.Make and intercept blue light diffusion barrier, test its performance.
Embodiment 3
The preparation of diffusion layer coating fluid:
Butanone 20 mass parts
Toluene 100 mass parts
Propylene glycol monomethyl ether 15 mass parts
Acryl resin microballon (20 microns of mean grain sizes) 100 mass parts that contain metal complex class dyestuff
Light-cured acrylic resin 100 mass parts
Above-mentioned material stirring is mixed, make optical diffusion layer coating fluid.
Using thickness as polyethylene terephthalate (PET) film of 100 microns is as base material, coat diffusion layer coating fluid in its one side, heated-air drying makes its build be about 10 microns, and through 450mj/cm 2ultraviolet ray irradiate, make and intercept blue light diffusion barrier, test its performance.
Embodiment 4
The preparation of diffusion layer coating fluid:
Butanone 20 mass parts
Toluene 100 mass parts
Propylene glycol monomethyl ether 15 mass parts
Acryl resin microballon (20 microns of mean grain sizes) 150 mass parts that contain metal complex class dyestuff
Light-cured acrylic resin 100 mass parts
Above-mentioned material stirring is mixed, make optical diffusion layer coating fluid.
Using thickness as polyethylene terephthalate (PET) film of 100 microns is as base material, coat diffusion layer coating fluid in its one side, heated-air drying makes its build be about 10 microns, and through 450mj/cm 2ultraviolet ray irradiate, make and intercept blue light diffusion barrier, test its performance.
The method of testing of product resistance blue light performance is as follows:
Use spectrophotometer test 380~500 nano waveband light source transmitance, i.e. blue light rejection rates;
Use photoelectricity mist degree instrument test transmitance and mist degree.
Table 1: product properties table
Figure BDA0000460851290000041
As can be seen from Table 1, use after the resin microballon that contains metal complex class dyestuff, intercept blue light diffusion barrier blue light is had to obvious iris action, and can not affect the blue effect of screen color, guarantee product optics diffusion effect simultaneously.

Claims (6)

1. intercept a blue light diffusion barrier, it is characterized in that: it comprises base material and be bonded to the anti-blue light diffusion layer of base material one or two sides, contains anti-blue light optics diffusant, resin in anti-blue light diffusion layer.
2. obstruct blue light diffusion barrier according to claim 1, is characterized in that, described base material is the one in mylar, polycarbonate film, nylon film, polyethylene film, polyvinyl chloride film, and base material thickness is 18-200 micron.
3. obstruct blue light diffusion barrier according to claim 1, it is characterized in that, described anti-blue light diffusion layer is to be that the coating fluid of 1:0.2-6 anti-blue light optics diffusant, resin or light-cured resin anchors on the surface of described base material and forms by containing mass ratio, and the thickness of anti-blue light diffusion layer is 10-50 micron.
4. obstruct blue light diffusion barrier according to claim 3, it is characterized in that, described anti-blue light optics diffusant is the resin microballon that contains metal complex class dyestuff, can be the one in polyacrylate, the polymethylmethacrylate that contains metal complex class dyestuff that contains metal complex class dyestuff, the polystyrene that contains metal complex class dyestuff or the polysiloxane that contains metal complex class dyestuff, mean grain size be 1-40 micron.
5. obstruct blue light diffusion barrier according to claim 1, it is characterized in that, described resin is selected from acryl resin, vibrin, urethane resin, epoxy acrylate, light-cured resin is the acrylic resin of ultraviolet light polymerization, and also comprising can be by the urethane acrylate of ultraviolet light polymerization, polyester acrylate, polyether acrylate, pure acrylate or organic siliconresin.
6. obstruct blue light diffusion barrier according to claim 1, is characterized in that, described anti-blue light optics diffusant is inhibited to the light of wavelength 380-500 nanometer.
CN201410032921.6A 2014-01-23 2014-01-23 Blue light-blocking diffusion film Active CN103823258B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104534338A (en) * 2015-01-30 2015-04-22 太湖金张科技股份有限公司 Blue-light-shielding anti-glare LED lamp
CN106291794A (en) * 2015-06-05 2017-01-04 象山激智新材料有限公司 A kind of anti-blue light preventing ultraviolet light-transmissive film or plate and application thereof
CN106291777A (en) * 2015-05-19 2017-01-04 象山激智新材料有限公司 The light-transmissive film of a kind of anti-blue light or plate and application thereof
CN107561608A (en) * 2017-09-30 2018-01-09 凯鑫森(上海)功能性薄膜产业有限公司 A kind of LED light device low blue light optical film and preparation method thereof
CN108680980A (en) * 2018-07-10 2018-10-19 宁波激智科技股份有限公司 A kind of novel anti-blue light optical thin film and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1396465A (en) * 2001-06-25 2003-02-12 旭硝子株式会社 Optical film
AU2012101848A4 (en) * 2012-12-18 2013-01-24 Yi-Chen Li Protective screen lens structure for a computer and a television
WO2013056009A1 (en) * 2011-10-13 2013-04-18 Intematix Corporation Photoluminescence wavelength conversion components for solid-state light emitting devices and lamps
CN103955016A (en) * 2014-04-22 2014-07-30 上海大学 Photodiffusion film with blue light shielding function
CN104516033A (en) * 2013-10-03 2015-04-15 惠和株式会社 Light diffusion sheet, and backlight unit for liquid crystal display device

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1396465A (en) * 2001-06-25 2003-02-12 旭硝子株式会社 Optical film
WO2013056009A1 (en) * 2011-10-13 2013-04-18 Intematix Corporation Photoluminescence wavelength conversion components for solid-state light emitting devices and lamps
AU2012101848A4 (en) * 2012-12-18 2013-01-24 Yi-Chen Li Protective screen lens structure for a computer and a television
CN104516033A (en) * 2013-10-03 2015-04-15 惠和株式会社 Light diffusion sheet, and backlight unit for liquid crystal display device
CN103955016A (en) * 2014-04-22 2014-07-30 上海大学 Photodiffusion film with blue light shielding function

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104534338A (en) * 2015-01-30 2015-04-22 太湖金张科技股份有限公司 Blue-light-shielding anti-glare LED lamp
CN106291777A (en) * 2015-05-19 2017-01-04 象山激智新材料有限公司 The light-transmissive film of a kind of anti-blue light or plate and application thereof
CN106291777B (en) * 2015-05-19 2018-06-19 象山激智新材料有限公司 The light-transmissive film or plate of a kind of anti-blue light and its application
CN106291794A (en) * 2015-06-05 2017-01-04 象山激智新材料有限公司 A kind of anti-blue light preventing ultraviolet light-transmissive film or plate and application thereof
CN107561608A (en) * 2017-09-30 2018-01-09 凯鑫森(上海)功能性薄膜产业有限公司 A kind of LED light device low blue light optical film and preparation method thereof
CN107561608B (en) * 2017-09-30 2023-07-21 凯鑫森(上海)功能性薄膜产业股份有限公司 Low-blue light optical film for LED lighting device and preparation method thereof
CN108680980A (en) * 2018-07-10 2018-10-19 宁波激智科技股份有限公司 A kind of novel anti-blue light optical thin film and preparation method thereof
CN108680980B (en) * 2018-07-10 2024-03-15 宁波激智科技股份有限公司 Blue light prevention optical film and preparation method thereof

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