CN204405884U - A kind of obstruct blue light hardening resin film - Google Patents

A kind of obstruct blue light hardening resin film Download PDF

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Publication number
CN204405884U
CN204405884U CN201420257435.XU CN201420257435U CN204405884U CN 204405884 U CN204405884 U CN 204405884U CN 201420257435 U CN201420257435 U CN 201420257435U CN 204405884 U CN204405884 U CN 204405884U
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China
Prior art keywords
blue light
resin
hardening resin
layer
obstruct
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Expired - Lifetime
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CN201420257435.XU
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Chinese (zh)
Inventor
施克炜
陈志安
陈晓东
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Taihu Lake Jin Zhang Science And Technology Co Ltd
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Taihu Lake Jin Zhang Science And Technology Co Ltd
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Abstract

The utility model relates to a kind of obstruct blue light hardening resin film; this obstruct blue light hardening resin film comprises protective seam, intercepts blue light hard resin-layer, PET film layer; protective seam posts on the upper strata intercepting blue light hard resin-layer, intercepts the upper strata that blue light hard resin-layer is uniformly coated on PET film layer.Intercept blue light hard resin-layer to be made up of hardening resin and filter blue light dyestuff, add filter blue light dyestuff in hardening resin to be formed intercepting blue light hard resin-layer.The utility model adopts and add filter blue light dyestuff in hardening resin; improve the optical property of hardening resin; hardening resin is made to possess the performance intercepting harmful blue light; can be applicable to the production of light polarizing film, brightness enhancement film, diffusion barrier, filter coating, and all kinds of diaphragm, blow-out disc, LED display and relate to the manufacturing field of the products such as LED light source.

Description

A kind of obstruct blue light hardening resin film
Technical field
The utility model relates to a kind of optical thin film, and particularly one intercepts blue light hardening resin film.
Background technology
In the light that display or light source send in use, high energy shortwave blue light is very large to the eye injury of people, such as popular at present LED screen, the short-and-medium wavelength blue light that the LED screen without special processing in use discharges can damage the retina of user.Shortwave blue light refers to the light of visible ray medium wavelength between 380 nanometers to 500 nanometers, and shortwave blue light has very high energies, can penetrate crystalline lens and to go directly retina.Blue light causes cellula visualis to accelerate death by improving cellula visualis to the susceptibility of light and photooxidation reaction intensity, under above-mentioned blue light illumination effect, retina can produce free radical, and these free radicals can cause retinal pigment epithelium to become feeble and die, epithelial decline can cause photaesthesia cell lack nutrient thus cause vision impairment, and these damages are irreversible, such as macula area is degenerated and cataract.If irradiation time was more than 10 seconds, the damage of infringement to eyes of the above-mentioned type just serves Main Function, and this damage is more than the several times of pyrolytic damage.Blue light causes the main cause producing digital visual fatigue (DEF) just.Luminous ray focuses on back focus difference within the eye, can form focal length difference between bifocal, and this is the main cause forming blurred vision.Long-time visual fatigue can cause other fatigue symptom.The injecting of blue light can aggravate focal length difference and dimness of vision degree, this is because blue light is after focusing, focus does not fall on the retina, but drops between retina and crystalline lens, thus it is poor to increase the focal length that light focuses within the eye.
Utility model content
In order to solve the problems of the technologies described above, the utility model discloses a kind of new technical scheme.
The utility model provides a kind of and intercepts blue light hardening resin film; described obstruct blue light hardening resin film comprises protective seam, intercepts blue light hard resin-layer, PET film layer; described protective seam posts the upper strata at described obstruct blue light hard resin-layer, and described obstruct blue light hard resin-layer is uniformly coated on the upper strata of described PET film layer.
Preferably, described obstruct blue light hard resin-layer is made up of hardening resin and filter blue light dyestuff, described filter blue light dyestuff is added in described hardening resin to forming described obstruct blue light hard resin-layer.
Preferably, the thickness of described PET film layer is 100-250 micron.
Preferably, described protective seam is PE diaphragm, PET protection film or PP diaphragm.
Preferably, the thickness of described obstruct blue light hard resin-layer is 5 microns-90 microns.
Preferably, described hardening resin is made up of any one in acrylic acid hardening resin, organosilicon-modified acrylic hardening resin, organic siliconresin, urethane resin and vibrin.
Preferably, described acrylic acid hardening resin be water-soluble acrylic resin, emulsifying pressure acrylic resin, solvent-type acrylic resinoid and non-solvent type acryl resinoid in any one, wherein polymerization methods comprises polymerized at normal temperature type acryl resin, heated polymerizable type acryl resin, ultraviolet light type polymeric acrylic acid resin, electron beam polymerization type acryl resin, with cross-linked polymeric type acryl resin.
Preferably, described acrylic acid hardening resin comprises containing any one or a few the potpourri in epoxy radicals, hydroxyl, itrile group, carboxylic acid group, ether, amino, amide group, phenyl ring, saturated rings, alkoxy, fluorine element and the acrylic acid of silicon atom and the monomeric compound of acrylate.
Preferably, described acrylic acid hardening resin also comprises containing epoxy radicals, hydroxyl, itrile group, carboxylic acid group, ether, amino, amide group, phenyl ring, saturated rings, alkoxy, fluorine element and the acrylic acid of silicon atom and the ethene derivatives of acrylate monomer compound.
Preferably, described filter blue light dyestuff is by azo, methine class, azo-methine class, ketimide class, ketimide-methine class, azo metal complexing class, naphthalimide, nitrodiphenylamine class, aminoketones, nitro class, Anthraquinones, quinolines, azines, cluck ton class, sulphur cluck ton class, benzothiazoles, benzanthrones, benzimidazole, acenaphthene class, spirooxazine-spiro-pyrans class, any one or a few potpourri composition in lactone type and Coumarins dyestuff, described azo is monoazo class and/or bisdiazo class, described filter blue light dyestuff accounts for and intercepts 0.0001% ~ 30% of blue light hard resin-layer gross mass.
Compared with prior art; obstruct blue light hardening resin film of the present utility model adopts and add filter blue light dyestuff in hardening resin; improve the optical property of hardening resin; define and intercept blue light hard resin-layer; hardening resin is made to possess the performance intercepting harmful blue light; can be applicable to the production of light polarizing film, brightness enhancement film, diffusion barrier, filter coating, and all kinds of diaphragm, blow-out disc, LED display and relate to the manufacturing field of the products such as LED light source.Be applied to the first filtering harmful blue light of internals of display, more reduce display dispatch from the factory after injury to user's eyesight.
Accompanying drawing explanation
Below in conjunction with the drawings and specific embodiments, the utility model is described in further detail.
Fig. 1 is the structural representation of obstruct blue light hardening resin film of the present utility model.
Embodiment
Below in conjunction with accompanying drawing, the utility model is described in further detail, and appended accompanying drawing, as illustrative purposes, is not used for limiting to the utility model.
As shown in Figure 1, for the structural representation of obstruct blue light hardening resin film of the present utility model, intercept blue light hardening resin film and comprise protective seam 1, intercept blue light hard resin-layer 2, PET film layer 3, protective seam 1 posts on the upper strata intercepting blue light hard resin-layer 2, intercept the upper strata that blue light hard resin-layer 2 is uniformly coated on PET film layer 3, intercept blue light hard resin-layer 2 to be made up of hardening resin and filter blue light dyestuff, filter blue light dyestuff is added in hardening resin and forms described obstruct blue light hard resin-layer 2, hardening resin is by acrylic acid hardening resin, organosilicon-modified acrylic hardening resin, organic siliconresin, any one composition in urethane resin and vibrin.Acrylic acid hardening resin be water-soluble acrylic resin, emulsifying pressure acrylic resin, solvent-type acrylic resinoid and non-solvent type acryl resinoid in any one, wherein polymerization methods comprises polymerized at normal temperature type acryl resin, heated polymerizable type acryl resin, ultraviolet light type polymeric acrylic acid resin, electron beam polymerization type acryl resin, with cross-linked polymeric type acryl resin.
Acrylic acid hardening resin comprises containing any one or a few the potpourri in epoxy radicals, hydroxyl, itrile group, carboxylic acid group, ether, amino, amide group, phenyl ring, saturated rings, alkoxy, fluorine element and the acrylic acid of silicon atom and the monomeric compound of acrylate, and acrylic acid hardening resin also comprises containing epoxy radicals, hydroxyl, itrile group, carboxylic acid group, ether, amino, amide group, phenyl ring, saturated rings, alkoxy, fluorine element and the acrylic acid of silicon atom and the ethene derivatives of acrylate monomer compound.
Filter blue light dyestuff also comprises fluorescent dye, filter blue light dyestuff is made up of any one or a few the potpourri in azo, methine class, azo-methine class, ketimide class, ketimide-methine class, azo metal complexing class, naphthalimide, nitrodiphenylamine class, aminoketones, nitro class, Anthraquinones, quinolines, azines, cluck ton class, sulphur cluck ton class, benzothiazoles, benzanthrones, benzimidazole, acenaphthene class, spirooxazine-spiro-pyrans class, lactone type and Coumarins dyestuff, and azo is monoazo class and/or bisdiazo class.Filter blue light dyestuff accounts for and intercepts 0.0001% ~ 30% of blue light hard resin-layer gross mass.
In order to further illustrate technical scheme of the present invention, following discloses instantiation.
Embodiment one
Acrylic resin HC-UVPCM-1 SAPIENCE 150g
Azo complex dyestuff 1 BASF 1g
Toluene technical grade 50g
Hardening resin is acrylic resin 150 grams, filter blue light dyestuff is azo complex dyestuff 1 gram, said mixture at room temperature stirs 30 minutes, said mixture is uniformly coated on 100 microns of transparent PET film surfaces, dry precipitation 2 minutes under 80 DEG C of environment, use high-pressure sodium lamp 800mJ/cm by above-mentioned curing of coatings, detect its 430 ~ 500nm blue light rejection rate.Toluene 50 grams can be added, technical grade in said mixture.
Embodiment two
Acrylic resin UV-HC ETERNAL 120g
Azo complex dyestuff 2 BASF 1g
Isopropyl alcohol technical grade 30g
Hardening resin is acrylic resin 120 grams, filter blue light dyestuff is azo complex dyestuff 1 gram, said mixture at room temperature stirs 30 minutes, said mixture is uniformly coated on 100 microns of transparent PET film surfaces, dry precipitation 2 minutes under 80 DEG C of environment, use high-pressure sodium lamp 800mJ/cm by above-mentioned curing of coatings, detect its 430 ~ 500nm blue light rejection rate.Isopropyl alcohol 30 grams can be added, technical grade in said mixture.
Embodiment three
Butyl acrylate chemical pure 160g
Hydroxy-ethyl acrylate chemical pure 32g
Methyl methacrylate chemical pure 20g
Azo complex dyestuff 3 BASF 0.5g
Darocure4265 ciba 6g
Butyl acrylate 160 grams, hydroxy-ethyl acrylate 32 grams, methyl methacrylate 20 grams, azo complex dyestuff 0.5 gram and polymerization initiator are at room temperature stirred 30 minutes, said mixture is uniformly coated under 35 DEG C of environment 188 microns of transparent PET film surfaces, use high-pressure sodium lamp 1000mJ/cm by above-mentioned curing of coatings, mould embossing.Above-mentioned polymerization initiator can be that 6 grams of Darocure4265, CIBA produce.
Embodiment four
Acrylic resin HC-UVPCM-1 SAPIENCE 150g
The pure 20g of isobornyl methacrylate monomer chemistries
Hydroxyethyl methylacrylate chemical pure 20g
Hydroxy propyl methacrylate chemical pure 10g
Azo complex dyestuff 4 BASF 5g
Darocure4265 ciba 3g
Acrylic resin 150 grams, isobornyl methacrylate monomer 20 grams, hydroxyethyl methylacrylate 20 grams, hydroxy propyl methacrylate 10 grams, azo complex dyestuff 5 grams and polymerization initiator are at room temperature stirred 30 minutes, said mixture is uniformly coated under 45 DEG C of environment 250 microns of transparent PET film surfaces, use high-pressure sodium lamp 1200mJ/cm by above-mentioned curing of coatings, mould embossing.Above-mentioned polymerization initiator can be that 3 grams of Darocure4265, CIBA produce.
Embodiment five
UV hardening resin UV-R5090 ANVICTOR 150g
Acrylic resin HC-UVPCM-1 SAPIENCE 50g
Hydroxy-ethyl acrylate chemical pure 20g
Butyl acrylate chemical pure 10g
Azo complex dyestuff 4 BASF 5g
Darocure4265 ciba 3g
UV hardening resin 150 grams, acrylic resin 50 grams, hydroxy-ethyl acrylate 20 grams, butyl acrylate 10 grams, azo complex dyestuff 5 grams and polymerization initiator are at room temperature stirred 30 minutes, said mixture is uniformly coated under 45 DEG C of environment 250 microns of transparent PET film surfaces, use high-pressure sodium lamp 1200mJ/cm by above-mentioned curing of coatings, mould embossing.Above-mentioned polymerization initiator can be that 3 grams of Darocure4265, CIBA produce.
In above embodiment, the performance index of product see the following form:
The obstruct blue light hardening resin film of this programme is not limited to content disclosed in embodiment, and those skilled in the art also belong to the scope of this programme in conjunction with the simple alternative that common practise is made according to this programme.

Claims (7)

1. one kind intercepts blue light hardening resin film; it is characterized in that; described obstruct blue light hardening resin film comprises protective seam, intercepts blue light hard resin-layer, PET film layer; described protective seam posts the upper strata at described obstruct blue light hard resin-layer, and described obstruct blue light hard resin-layer is uniformly coated on the upper strata of described PET film layer.
2. obstruct blue light hardening resin film according to claim 1, it is characterized in that, described obstruct blue light hard resin-layer is made up of hardening resin and filter blue light dyestuff, described filter blue light dyestuff is added in described hardening resin to forming described obstruct blue light hard resin-layer.
3. obstruct blue light hardening resin film according to claim 1, is characterized in that, the thickness of described PET film layer is 100-250 micron.
4. obstruct blue light hardening resin film according to claim 1, is characterized in that, described protective seam is PE diaphragm, PET protection film or PP diaphragm.
5. obstruct blue light hardening resin film according to claim 1, is characterized in that, the thickness of described obstruct blue light hard resin-layer is 5 microns-90 microns.
6. obstruct blue light hardening resin film according to claim 2, it is characterized in that, described hardening resin is made up of any one in acrylic acid hardening resin, organosilicon-modified acrylic hardening resin, organic siliconresin, urethane resin and vibrin.
7. obstruct blue light hardening resin film according to claim 6, it is characterized in that, described acrylic acid hardening resin be water-soluble acrylic resin, emulsifying pressure acrylic resin, solvent-type acrylic resinoid and non-solvent type acryl resinoid in any one, wherein polymerization methods comprises polymerized at normal temperature type acryl resin, heated polymerizable type acryl resin, ultraviolet light type polymeric acrylic acid resin, electron beam polymerization type acryl resin, with cross-linked polymeric type acryl resin.
CN201420257435.XU 2014-05-20 2014-05-20 A kind of obstruct blue light hardening resin film Expired - Lifetime CN204405884U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104977640A (en) * 2015-08-07 2015-10-14 京东方科技集团股份有限公司 Brightness enhancement film, backlight module and display device
CN106291790A (en) * 2015-05-22 2017-01-04 郑秀真 The blooming of blue light and uv damage can be reduced
CN106863968A (en) * 2017-01-24 2017-06-20 杭州科翼科技有限公司 A kind of UV resistance blue light diaphragm
CN109284656A (en) * 2017-07-21 2019-01-29 致伸科技股份有限公司 Surface treatment method
CN111823744A (en) * 2020-08-21 2020-10-27 河南卓立膜材料股份有限公司 Heat transfer film for photochromic vehicle and preparation method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106291790A (en) * 2015-05-22 2017-01-04 郑秀真 The blooming of blue light and uv damage can be reduced
CN104977640A (en) * 2015-08-07 2015-10-14 京东方科技集团股份有限公司 Brightness enhancement film, backlight module and display device
CN106863968A (en) * 2017-01-24 2017-06-20 杭州科翼科技有限公司 A kind of UV resistance blue light diaphragm
CN106863968B (en) * 2017-01-24 2019-11-08 杭州科翼科技有限公司 A kind of UV resistance blue light protective film
CN109284656A (en) * 2017-07-21 2019-01-29 致伸科技股份有限公司 Surface treatment method
CN111823744A (en) * 2020-08-21 2020-10-27 河南卓立膜材料股份有限公司 Heat transfer film for photochromic vehicle and preparation method thereof
CN111823744B (en) * 2020-08-21 2022-05-06 焦作卓立膜材料有限责任公司 Heat transfer film for photochromic vehicle and preparation method thereof

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Granted publication date: 20150617