CN103804083B - The special zinc fertilizer of wheat and preparation thereof and the method for the production of rich zinc wheat - Google Patents

The special zinc fertilizer of wheat and preparation thereof and the method for the production of rich zinc wheat Download PDF

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CN103804083B
CN103804083B CN201410037814.2A CN201410037814A CN103804083B CN 103804083 B CN103804083 B CN 103804083B CN 201410037814 A CN201410037814 A CN 201410037814A CN 103804083 B CN103804083 B CN 103804083B
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zinc
wheat
fertilizer
special
weight
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CN103804083A (en
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王张民
潘斐
刘琦
毛彦军
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WEIGANG BIOTECHNOLOGY JIANGSU Co Ltd
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WEIGANG BIOTECHNOLOGY JIANGSU Co Ltd
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Abstract

The invention discloses the special zinc fertilizer of a grow wheat and preparation thereof and the method for the production of rich zinc wheat.The special zinc fertilizer of this wheat, the component containing, for example lower parts by weight: zinc source, with the weighing scale 0.5 ~ 25 of zinc, sorbent material 2 ~ 4, acidity regulator 0.5 ~ 2, fertilizer 10 ~ 25; Also containing fertilizer binding agent in the special zinc fertilizer of described wheat, wherein, the weight of fertilizer binding agent is 0.3% ~ 0.5% of the special zinc fertilizer weight of described wheat.The special zinc fertilizer of wheat is applied in wheat planting process.Utilize the wheat that zinc fertilizer of the present invention and method cultivate, its Zn content reaches as high as 160mg/kg, is more than 4 times of common wheat Zn content, and the wheat cultivated in this way is a kind of natural zinc-rich wheat, and the absorption of human body utilization ratio of this biological zinc is high.

Description

The special zinc fertilizer of wheat and preparation thereof and the method for the production of rich zinc wheat
Technical field
The invention belongs to proportion of crop planting field, be specifically related to the special zinc fertilizer of a grow wheat and preparation thereof and the method for the production of rich zinc wheat.
Background technology
Zinc is one of trace element of needed by human, plays an important role in growth in humans's growth course, is often described as " flowers of life " and " source of intelligence " by people.Scientist's research shows, zinc take part in the metabolic process of more than 80 kind of enzyme in human body, especially DNA and RNA polymerase, it participates in the synthesis of nucleic acid protein directly, the Differentiation and proliferation of cell and many metabolism, also has the activation of some enzyme require zinc in human body, and play its active function, therefore, zinc is requisite material in the important physiological processs such as growth in humans grows, reproduction heredity, immune and endocrine system, nerve, body fluid, and scarce zinc can have a negative impact to each system of human body.
The recommended intake of everyone zinc every day of being grown up is 10 ~ 15mg, and pregnancy period and lactating women increase 5mg, children everyone every day of 5 ~ 10mg.In global range, due to the zn deficiencie phenomenon ubiquity that causes of zinc intake deficiency, at present, the whole world about has 40% population to face trace element deficiency, especially the women of developing country poverty-stricken area and children.
The 3 kinds of main policies in the past solving zinc nutrition bad problem were: medicament supplements (Zinc Gluuconate Oral Solution etc. as market is sold), nutrient fortified food is (as the production method of the rich zinc flour of the patent report of CN102106358A, its technique for spraying zinc supplementation agent etc. and in addition mechanical stirring forms in flour) and vary the diet (reduce vegetable food, increase the food such as meat product, sea-food).The nutritional status that medicament supplements improving rapidly nutritive deficiency individuality is very useful, but cost is comparatively large, and people are acceptable poor to it, and on the other hand, its side effect also has to cause the attention of people; Nutrient fortified food also will be increased input usually, and the perception of food and local flavor can be made to change, and be also not easily accepted, equally, the security of nourishing reinforced food also can not be ignored; Varying the diet is overcome underfed most desirable route, but in developing country because the reason such as economic or social is also difficult to realize, even if in developed country, due to reasons such as individual human diet's hobbies, varying the diet neither be all feasible to everyone.Therefore, until in today world wide the mankind take the photograph the malnutritive situation of people and be controlled effectively not yet.
In recent years, a kind of strategy has newly caused the common concern of scientist, and the abundance namely by improving staple food Meso-and micro-nutrients zinc meets the demand of people to micronutrient.By Breeding and cultivation approach, improving the Zn content of crop edible portion, when not changing traditional food, the micronutrient needed for people can be provided by staple food steadily in the long term.Economical, effective, essence can solve the malnutritive problem of developing country's population of dependence staple food existence like this.
Wheat is one of staple food crop of the mankind, and Guo Minghui have studied the Zn content of 17 parts of Shanxi wheat, and its variation range is 21-43mg/kg, and average Zn content is that Guo 29.3mg/kg(is intelligent, 2011); Also point out in the review article of Cao Xinyou that the average content of current wheat zinc is about 30mg/kg, wheat grain Zn content has much room for improvement (Cao Xinyou, 2012); As can be seen here, the Zn content in wheat is totally on the low side, can not meet human body aequum every day, the increase slightly of its Zn content, is that the not enough problem of resident's zinc nutrition of staple food has broad spectrum for solving with wheat.
For the Zn content being improved wheat edible portion by breeding methods, international HarvestPlus plan and its sisters project HarvestPlus-China are using the major objective one of of the content improving trace element zinc as crop breeding, to eliminate " recessive hunger ", be now bred as high zinc content (44mg/kg) new variety of wheat " middle wheat 175 "; The patent of CN100493342C also reports a kind of breeding method of wheat with high iron-zinc content, cultivates the wheat " Qinhei No.1 " of a kind of Zn content 135mg/kg, is 4.1 times of common wheat, occupies in the world first of existing cereal crop.By genetic breeding improvement, cultivate rich zinc wheat breed, being a cause of putting things right once and for all to improving wheat zinc nutrition value, being also the work of a permanence, having vast potential for future development; But it is a long-term systems engineering, and wheat breed has certain regional adaptability, just current progress, apart from also applying early, can not solve zinc nutrition lacking problem to maximum range; But after some time, along with going deep into of research, the discovery of specific gene, utilizing traditional breeding method to cultivate zinc-rich nutrient function wheat will come true.Cultivate rich zinc wheat by transgenic technology and achieve major progress at present, but the biosafety debate of genetically modified food seems forever without final conclusion, applying of transgenic wheat also has many obstacles.
And for improving wheat Zinc Nutrition Status by the rich zinc cultivation technique of wheat, utilize the Common Wheat Varieties of existing popularization, in its growth with growth course, improve nutrient environment, improve wheat zinc nutrition utilization ratio, increase wheat Zn content, the research of this problem is seen in report seldom at present, current main research mostly is executes zinc on the impact of wheat yield or prevent wheat to lack the research of zinc, also there is part to improve the research of crop Zn content by foliage-spray zinc fertilizer simultaneously, the Investigation on intensification of wheat zinc seldom can find, but find from rare several research, this rich zinc approach of wheat or feasible, but wheat Zn content increase rate is also on the low side, generally can not more than 50mg/kg.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides the special zinc fertilizer of wheat and preparation thereof and the method for the production of rich zinc wheat.The method is in the process of growth of wheat, execute mode with soil apply the special zinc fertilizer of wheat, and results wheat when wheat is ripe, obtain rich zinc wheat, its Zn content reaches as high as 160mg/kg.
The special zinc fertilizer of wheat provided by the invention, the component containing, for example lower parts by weight:
Also containing fertilizer binding agent in the special zinc fertilizer of described wheat, wherein, the weight of fertilizer binding agent is 0.3% ~ 0.5% of the special zinc fertilizer weight of described wheat.
Preferably, described zinc source is containing the one in the mineral material of zinc element, zinc salt or zinc oxide or its two or more any mixture; Described sorbent material is attapulgite, wilkinite, diatomite or humic acid; Described acidity regulator is sulphur.
Preferably, described zinc salt is one in zinc sulfate, zinc chloride, zinc nitrate, zinc carbonate, Zinc Gluconate, zinc glycinate, zinc lactate, zinc citrate or zinc acetate or its two or more any mixture; The described mineral material containing zinc element is zink sulphide powder.
Further preferably, described zinc source is one in zink sulphide powder, zinc sulfate, zinc oxide, zinc citrate or zinc acetate or its two or more any mixture.
The invention provides the preparation method of the special zinc fertilizer of above-mentioned wheat, comprise the steps:
1) zinc source and fertilizer are pulverized as powder; Sorbent material becomes particle diameter to be less than the powder of 48 μm with acidity regulator micronizing and the part by weight wherein shared by Nano grade is 3 ~ 25%;
2) the zinc source power, absorbent powder, acidity regulator powder and the fertilizer powder that step 1) are obtained according to described amount mix;
3) by step 2) described in mixture granulation on disk, add fertilizer binding agent during granulation, gained fertiliser granulates is the agent of wheat zinc-rich nutrient.
Preferably, above-mentioned method, comprises the steps:
1) described sorbent material is attapulgite, and described acidity regulator is sulphur; By modified through 100 ~ 200 DEG C of heat treated of adsorbent attapulgite soil, mix with acidity regulator sulphur, then micronizing is be less than the powder of 48 μm, and the part by weight wherein shared by Nano grade is 3 ~ 25%; Zinc source and fertilizer are pulverized as powder;
2) zinc source power, absorbent powder, acidity regulator powder and fertilizer powder are mixed;
3) by step 2) mixture granulation on granulating disc of obtaining, spray fertilizer binding agent during disc granulation.
The invention provides the method for the special zinc fertilizer of above-mentioned wheat for the production of rich zinc wheat: the special zinc fertilizer of described wheat as base manure, tillering regularity is fertile, the jointing initial stage fertile, jointing mid-term is fertile, the booting initial stage is fertile or one of them or two or more arbitrary combination of flowering initial stage fertilizer are used, wherein, the consumption of the special zinc fertilizer of described wheat counts 0.5 ~ 25kg/ mu with the weight of zinc.
Preferably, the consumption of the special zinc fertilizer of described wheat counts 2.5 ~ 24kg/ mu with the weight of zinc.
Preferably, the consumption of the special zinc fertilizer of described wheat counts 4 ~ 12kg/ mu with the weight of zinc.
More preferably, the consumption of the special zinc fertilizer of described wheat counts 8kg/ mu with the weight of zinc.
The special zinc fertilizer of wheat provided by the invention and preparation thereof and the method for the production of rich zinc wheat.Utilize the wheat that zinc fertilizer of the present invention and method cultivate, its Zn content reaches as high as 160mg/kg, it is more than 4 times of common wheat Zn content, the wheat cultivated in this way is a kind of natural zinc-rich wheat, the absorption of human body utilization ratio of this biological zinc is high, which overcome the deficiency of the zinc fraction security in zinc nutrition fortified flour, and the residue problem of the zinc fertilizer of foliage-spray in seed, and avoid the biosafety issues arguement of transgenic wheat, thus develop this new function wheat of rich zinc wheat by this approach and will have boundless application prospect.The rich zinc wheat that present method cultivates makes people carry out trace element supplement zinc by diet mode becomes possibility, and the scarce zinc problem for the crowd of solution is significant, the zinc nutrition deficiency improving the people is had to the meaning of reality.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, can better understand the present invention and can be implemented, but illustrated embodiment is not as a limitation of the invention to make those skilled in the art.
Embodiment 1
Select Ding Yan town, Rugao City of Jiangsu Province wheat paddock as effect of fertilizer experimental plot, Wheat cultivar is the Yang Mai-16 that territory, Yangtze Delta Plain is widely planted, each small test group be set to 3 wheat plantings capable × community of 2.2 meters × 10 meters=66 square metres, each cell periphery retains the isolation distance of 1 meter.Select one of them community as the control group of conventional wheat cultivation (not adding the special zinc fertilizer of wheat of the present invention), all the other groups adding the special zinc fertilizer of wheat of the present invention adopt the cultivation technique identical with control group, when gathering in the crops, gather wheat grain, measure Zn content wherein, the Zn content recording control group wheat grain is 41.5mg/kg.
Embodiment 2-13
First, by the modification of natural nano-material attapulgite powder through 100 ~ 200 DEG C of heat treated, take respectively appropriate attapulgite modified (0.2 ~ 0.4kg), add appropriate sulphur (0.05 ~ 0.2kg) respectively, mix (concrete array mode takes according in following table, during mixing below and consumption mode see the following form together) afterwards, micronizing is the powder that particle diameter is less than 48 μm, the ratio wherein shared by Nano grade is made to be 3 ~ 25%, for subsequent use; Then take the zinc salts (in zinc 0.25kg) such as moderate amount of sulfuric acid zinc, zinc oxide, zinc citrate, zinc acetate respectively, be crushed to Powdered, then add the attapulgite of corresponding amount and the mixture of sulphur, mixed; Finally add the fertilizer (purchased from Fei Ye company limited green for a long time of Jiangyin City) (1 ~ 2.5kg) after appropriate pulverizing; granulation on granulating disc after fully mixing; (fertilizer fertilizer binding agent commercially available arbitrarily, can be carboxymethyl cellulose to spray appropriate fertilizer binding agent during disc granulation.), the consumption of fertilizer binding agent is 0.3 ~ 0.5% of the obtained special zinc fertilizer gross weight of wheat, and pack, seals and stick composition label, for subsequent use.Be sprinkled in wheatland mid-term by every bag of special zinc fertilizer of wheat at wheat jointing, every community is spread fertilizer over the fields one bag (every bag containing zinc 0.25kg), when harvesting wheat, gathers wheat grain, measures Zn content wherein, gather in following table:
Embodiment 14-23
First, by the modification of natural nano-material attapulgite powder through 100 ~ 200 DEG C of heat treated, take the attapulgite modified of 0.3kg respectively, add the sulphur of 0.1kg, after mixing, micronizing is the powder that particle diameter is less than 48 μm, makes the ratio wherein shared by Nano grade be 3 ~ 25%, for subsequent use; Then take moderate amount of sulfuric acid zinc (in zinc 0.05 ~ 2.5kg) respectively, be crushed to Powdered, then add the attapulgite of corresponding amount and the mixture of sulphur, mixed; Finally add fertilizer (purchased from Fei Ye company limited green for a long time of the Jiangyin City) powder after 1.5kg pulverizing; granulation on granulating disc after fully mixing; appropriate fertilizer binding agent (consumption of fertilizer binding agent is 0.5% of the obtained special zinc fertilizer gross weight of wheat) is sprayed during disc granulation; pack (every bag containing zinc 0.05 ~ 2.5kg); seal and stick composition label, for subsequent use.
Every bag of special zinc fertilizer of wheat is sprinkled into (concrete Dressing date was used according to the period in following table) in wheatland in the specific period of wheat growth, and every community spreads fertilizer over the fields one bag, when harvesting wheat, gathers wheat grain, measures Zn content wherein, gather in following table:
Embodiment 24
First, through the modification of 100 ~ 200 DEG C of heat treated after diatomite is pulverized, take appropriate modification infusorial earth (0.3kg), add appropriate sulphur (0.1kg), after mixing, micronizing is the powder that particle diameter is less than 48 μm, makes the ratio wherein shared by Nano grade be 3 ~ 25%, for subsequent use; Then take moderate amount of sulfuric acid zinc (in zinc 2kg), be crushed to Powdered, then add the modification infusorial earth of above-mentioned corresponding amount and the mixture of sulphur, mixed; Finally add appropriate fertilizer (1.25kg); granulation on granulating disc after fully mixing, sprays appropriate fertilizer binding agent (consumption of fertilizer binding agent is 0.3% of the obtained special zinc fertilizer gross weight of wheat), pack during disc granulation; seal and stick composition label, for subsequent use.Special for the wheat manufactured zinc fertilizer is divided into two parts, is sprinkled into a copy of it in wheatland mid-term at wheat jointing, portion is sprinkled into wheat paddock at the wheat flowering initial stage in addition, and when harvesting wheat, gather wheat grain, measuring Zn content wherein, is 135.1mg/kg.
As can be seen from the above embodiments: utilize the wheat that method provided by the invention cultivates, its Zn content can reach about 160mg/kg, it is more than 4 times of common wheat Zn content, it is exactly a kind of natural zinc-rich wheat can to say the wheat cultivated in this way, the absorption of human body utilization ratio of this biological zinc is high, which overcome the deficiency of enriched nutritive flour, and avoid the biosafety issues arguement of transgenic wheat, thus develop this new function wheat of rich zinc wheat by this approach and will have boundless application prospect, and the zinc nutrition deficiency improving the people is had to the meaning of reality.
The above embodiment is only that protection scope of the present invention is not limited thereto in order to absolutely prove the preferred embodiment that the present invention lifts.The equivalent alternative or conversion that those skilled in the art do on basis of the present invention, all within protection scope of the present invention.Protection scope of the present invention is as the criterion with claims.

Claims (8)

1. the special zinc fertilizer of a grow wheat, is characterized in that, be made up of following component: zinc source, sorbent material, acidity regulator, fertilizer and fertilizer binding agent,
Wherein, the weight part in zinc source, counts 0.5 ~ 25 with the weight of zinc,
The weight part of sorbent material is 2 ~ 4,
The weight part of acidity regulator is 0.5 ~ 2,
The weight part of fertilizer is 10 ~ 25;
The weight of fertilizer binding agent is 0.3% ~ 0.5% of the special zinc fertilizer weight of described wheat;
Described zinc source is zinc salt; Described sorbent material is attapulgite, wilkinite, diatomite or humic acid; Described acidity regulator is sulphur;
It is prepared in the following way:
1) zinc source and fertilizer are pulverized as powder; Sorbent material becomes particle diameter to be less than the powder of 48 μm with acidity regulator micronizing and the part by weight wherein shared by Nano grade is 3 ~ 25%;
2) the zinc source power, absorbent powder, acidity regulator powder and the fertilizer powder that step 1) are obtained according to described amount mix;
3) by step 2) described in mixture granulation on disk, add fertilizer binding agent during granulation, gained fertiliser granulates is the special zinc fertilizer of wheat.
2. the special zinc fertilizer of wheat according to claim 1, it is characterized in that, described zinc salt is one in zinc sulfate, zinc chloride, zinc nitrate, zinc carbonate, Zinc Gluconate, zinc glycinate, zinc lactate, zinc citrate or zinc acetate or its two or more any mixture.
3. the special zinc fertilizer of wheat according to claim 1, is characterized in that, described zinc source is one in zinc sulfate, zinc citrate or zinc acetate or its two or more any mixture.
4. the special zinc fertilizer of wheat according to claim 1, it is characterized in that, it is prepared in the following way:
1) described sorbent material is attapulgite, and described acidity regulator is sulphur; By modified through 100 ~ 200 DEG C of heat treated of adsorbent attapulgite soil, mix with acidity regulator sulphur, then micronizing is be less than the powder of 48 μm, and the part by weight wherein shared by Nano grade is 3 ~ 25%; Zinc source and fertilizer are pulverized as powder;
2) zinc source power, absorbent powder, acidity regulator powder and fertilizer powder are mixed;
3) by step 2) mixture granulation on granulating disc of obtaining, spray fertilizer binding agent during disc granulation.
5. the special zinc fertilizer of the wheat described in any one of claim 1 ~ 4 is for the production of the method for rich zinc wheat, it is characterized in that, the special zinc fertilizer of described wheat as base manure, tillering regularity is fertile, the jointing initial stage fertile, jointing mid-term is fertile, the booting initial stage is fertile or one of them or two or more arbitrary combination of flowering initial stage fertilizer are used, wherein, the consumption of the special zinc fertilizer of described wheat counts 0.5 ~ 25kg/ mu with the weight of zinc.
6. method according to claim 5, is characterized in that, the consumption of the special zinc fertilizer of described wheat counts 2.5 ~ 24kg/ mu with the weight of zinc.
7. method according to claim 5, is characterized in that, the consumption of the special zinc fertilizer of described wheat counts 4 ~ 12kg/ mu with the weight of zinc.
8. method according to claim 5, is characterized in that, the consumption of the special zinc fertilizer of described wheat counts 8kg/ mu with the weight of zinc.
CN201410037814.2A 2014-01-26 2014-01-26 The special zinc fertilizer of wheat and preparation thereof and the method for the production of rich zinc wheat Expired - Fee Related CN103804083B (en)

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104823645A (en) * 2015-04-20 2015-08-12 唐兴龙 Method for cultivating zinc-rich wheat
CN105061079B (en) * 2015-08-18 2018-06-15 浙江大学 Nanometer zinc fertilizer is promoting crop to the application in the accumulation of zinc
CN105993343A (en) * 2016-06-14 2016-10-12 山东省农业科学院作物研究所 Wheat zinc fertilizer application method based on soil fertility
CN107439635A (en) * 2017-09-20 2017-12-08 苏州硒泰克生物科技有限公司 Zinc-rich coarse grain biscuit and preparation method thereof
CN109717023A (en) * 2018-12-29 2019-05-07 西北农林科技大学 A kind of method of green manure-wheat crop rotation production zinc-rich wheat
CN116041109A (en) * 2023-02-09 2023-05-02 苏州硒谷科技有限公司 Zinc-rich grain special water-soluble fertilizer and preparation method and application thereof

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CN101492319A (en) * 2009-02-27 2009-07-29 北京市农林科学院 Special-purpose fertilizer for wheat and uses thereof
CN102633559A (en) * 2012-04-06 2012-08-15 苏州安德鲁尹生物技术咨询有限公司 Activated carbon slow-release zinc fertilizer and preparation method thereof
CN103333004A (en) * 2013-06-27 2013-10-02 深圳市芭田生态工程股份有限公司 Agricultural granular zinc sulfate fertilizer and preparation method thereof

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Publication number Priority date Publication date Assignee Title
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CN102633559A (en) * 2012-04-06 2012-08-15 苏州安德鲁尹生物技术咨询有限公司 Activated carbon slow-release zinc fertilizer and preparation method thereof
CN103333004A (en) * 2013-06-27 2013-10-02 深圳市芭田生态工程股份有限公司 Agricultural granular zinc sulfate fertilizer and preparation method thereof

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