CN103784329A - Powder skin cleanser - Google Patents
Powder skin cleanser Download PDFInfo
- Publication number
- CN103784329A CN103784329A CN201310487327.1A CN201310487327A CN103784329A CN 103784329 A CN103784329 A CN 103784329A CN 201310487327 A CN201310487327 A CN 201310487327A CN 103784329 A CN103784329 A CN 103784329A
- Authority
- CN
- China
- Prior art keywords
- powder
- fatty acid
- enumerate
- oil fatty
- skin cleanser
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/267—Heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
Abstract
The invention relates to a powder skin cleanser and specifically develops and provides a powder or granulated skin cleanser with excellent foam quality and foaming force. The powder or granulated skin cleanser is characterized by comprising N-acylglutamate and more one selected from a group composed of branch glucan with annular structure, hydroxypropyl starch phosphate, and polydextrose.
Description
Technical field
The present invention relates to a kind of Powdered or granular Irrigation product.
Background technology
All the time, powder Irrigation product are to prepare as the inorganic particle of abluent and builder or organic powder co-grinding, and, in the situation that making graininess Irrigation product, after co-grinding, carry out pelletize with optimum condition and prepare.Powdered or graininess Irrigation product without moisture, therefore can provide the higher goods of safety that do not mix antiseptic or antibacterial compared with liquid or gel.But Powdered or graininess Irrigation product, cannot uniform dissolution in the time being dissolved in the water with palm or sponge etc., has the shortcoming that can form the agglomerate that is called " powder ball " or " powder agglomates ".In addition, there is foaming characteristic also poor shortcoming compared with liquid or gel.Especially, because N-acyl glutamate is faintly acid, few to the stimulation of skin, therefore multiplexly make safe cleaning composition, be difficult to be dissolved in the water but exist, the poor shortcoming of foaming characteristic while making powder cleaning product.The applicant is by mixed-cation glucosan in formula, propose a kind of safe, improve the dissolubility while use, foaming characteristic is also excellent, and then does not produce while getting blisters foam with palm etc. coarse and improve the Irrigation product (patent documentation 2: TOHKEMY 2002-338994 communique) of usability.And then proposition is mixed with the cleaning product compositions (patent documentation 3: TOHKEMY 2009-196971 communique) of the foaming characteristic excellence of N-acyl glutamate or higher fatty acid salt and polyamino acid and neutral amino acid.But, need further to improve performance.
[prior art document]
[patent documentation]
[patent documentation 1] TOHKEMY 2002-338994 communique
[patent documentation 2] TOHKEMY 2009-196971 communique
Summary of the invention
[problem that invention will solve]
The object of the invention is to develop and a kind of cleaning product compositions is provided, they are alveolar substance and foaming characteristic excellence in the Powdered or granular Irrigation product that are mixed with N-acyl glutamate.
[method of dealing with problems]
The present invention is a kind of Powdered or granular Irrigation product; it is by by N-acyl glutamate and more than one combinations of selecting from maintain the group that side chain glucosan, hydroxypropyl starch phosphate ester, the polydextrose of circulus form, and realizes excellent alveolar substance and foaming characteristic.
Of the present invention being constructed as follows.
A kind of powder or granular Irrigation product, is characterized in that: its contain N-acyl glutamate and from maintain the group that side chain glucosan, hydroxypropyl starch phosphate ester, the polydextrose of circulus form, select more than one.
[invention effect]
According to composition of the present invention, develop and provide the Powdered or granular Irrigation product of a kind of alveolar substance and foaming characteristic excellence.
The specific embodiment
As the N-acyl glutamate using in the present invention, can enumerate: N-lauroyl glutamate salt, N-myristoyl glutamate, Glu, N-palmityl glutamate, Glu, N-stearyl glutamate, Glu, N-oleoyl glutamate, Glu etc.In addition; as its mixture, can enumerate: N-(coco-nut oil fatty acid/palm oil fatty acid/sunflower oil fatty acid) acyl glutamate, N-coco-nut oil fatty acid acyl glutamate, N-palm oil fatty acid acyl glutamate, N-hydrogenated tallow acyl glutamate etc.In addition, as salt, can enumerate: the alkali metal salts such as sodium, potassium, the alkanolamines such as triethanolamine, the alkaline amino acid salts such as lysine, arginine etc.
The part that the side chain glucosan that maintains circulus using in the present invention is side chain glucan structure forms the compound of ring, and the method for making that can record by Japanese Patent Laid-Open 2012-120471 communique is manufactured.Particularly, then make branching enzyme act on side chain glucosan makes 4-alpha-Glucanotransferase play a role, or then make 4-alpha-Glucanotransferase act on side chain glucosan makes branching enzyme play a role, or make branching enzyme and 4-alpha-Glucanotransferase act on side chain glucosan simultaneously, can manufacture thus the side chain glucosan that maintains circulus.
As the side chain glucosan that maintains circulus using in the present invention, can use commercially available product, for example can enumerate " the Network ラ ス タ ー デ キ ス ト リ Application " that japanese food chemical industry (strain) is manufactured.
The hydroxyalkyl starch phosphate ester using in the present invention forms through phosphoric acid is crosslinked for hydroxyalkyl starch.Hydroxyalkyl starch is to make starch and alkylene oxide, and for example oxirane, expoxy propane react and obtain.
Hydroxyalkyl starch phosphate ester can use commercially available product, for example, can enumerate the hydroxypropyl starch phosphate ester " STRUCTURE XL " that ア Network ゾ ノ ー ベ Le (strain) is manufactured.
The water solublity dietary fiber of the difficult digestibility of polydextrose using in the present invention is make glucose, sorbitol, citric acid reactions and obtain.
As polydextrose, can use commercially available product, for example can enumerate " ラ イ テ ス ウ Le ト ラ " that ダ ニ ス コ ジ ャ パ Application (strain) is manufactured.
Other blending constituent
In Irrigation product of the present invention, as surfactant, can mix N-acyl glutamate anion surfactant, amphoteric surfactant, cationic surfactant, non-ionic surface active agent in addition.
As anion surfactant, can enumerate: higher fatty acid salt, N-acyl group alanine salt, N-acyl methyl taurine salt, N-acyl isethinate, N-acylglycine salt, MAP, ether carboxylate, alkylsulfonate, sulfosuccinate etc.As amphoteric surfactant, can enumerate: carboxybetaine type surfactant, sulfobetaines type surfactant, amido betaine type surfactant, Imidazoline Surfactants etc.
Can make to contain in Irrigation product of the present invention polyalcohols, saccharide, sugar alcohols, organic powder, inorganic particle, high score subclass, antiseptic, chelating agen, UV absorbent, UV blockers, wetting agent, spice, pH adjusting agent, desiccant etc.Also can make it contain other active ingredient, physiologically active ingredient.
As polyalcohols, can enumerate: glycerol, 1,3 butylene glycol, dipropylene glycol, propylene glycol, isoamyl glycol, 1,2-pentanediol, 1,2-hexanediol, 1,2-ethohexadiol, diglycerol etc.
As saccharide, sugar alcohols, can enumerate: glucose, sorbitol, mannose, mannitol, galactose, galactitol, maltose, maltose alcohol, trehalose, red algae sugar, erythritol, xylose, xylitol, sucrose, lactose, lactose, two fructose acid anhydrides etc.
As organic powder, can enumerate: polyethylene powders, Polystyrene powder, polymethyl methacrylate powder, nylon powder, polyurethanes powder, agar powder, cork powder, starch etc.
As inorganic particle, can enumerate: Talcum, Kaolin, silicon dioxide, Muscovitum, zeolite, bentonite, titanium dioxide etc.
As high score subclass, can enumerate: arabic gum, Tragacanth, galactan, guar gum, carrageenin, pectin, xanthan gum, Fructus cydoniae oblongae seed glue, glucosan, cationization glucosan, amylopectin, carboxymethyl starch, collagen protein, casein, gelatin, methylcellulose, methylhydroxypropylcellulose, hydroxyethyl-cellulose, sodium carboxymethyl cellulose (CMC), hydroxypropyl emthylcellulose, sodium alginate, CVP Carbopol ETD2050 (CARBOPOL etc.) etc.
As antiseptic, for example, can enumerate: methyl parahydroxybenzoate, ethylparaben etc.
As chelating agen, for example, can enumerate: the edetates such as disodiumedetate, ethylenediaminetetraacetic acid, disodium edta.
As active ingredient, can enumerate: L-AA, L-AA phosphate ester, L-AA monopalmitate, L-AA dipalmitate, the vitamin c class of L-AA-2-glucosides etc. etc., glutathion, the whitening agent of Herba Saxifragae extract etc., Lac regis apis, the activating skin agent of beech wood extract etc., capsaicin, (4-hydroxy-3-methoxyphenyl)ethyl methyl ketone, Mylabris tincture, ichthyol, caffeine, the blood circulation accelerant of tannin gamma oryzanol etc., glycyrrhizin derivative, Enoxolone derivative, the antiinflammatory of azulene etc., the maltose sucrose condensation substance of normal bacteria controlling agent, lysozyme chloride etc.
Irrigation product compositions of the present invention is Powdered or graininess.
Irrigation product of the present invention can be used for washing one's face or the cleaning of health.
[embodiment]
Each composition shown in table 1 is mixed in N-(coco-nut oil fatty acid/palm oil fatty acid/sunflower oil fatty acid) acyl glutamic acid sodium with the concentration of 0.5,1,3,5 quality %, and each 4 kinds of Powdered Irrigation product of Preparation Example 1～3, comparative example 1～12.Alveolar substance and the foaming characteristic of the Powdered Irrigation product of preparing with following benchmark evaluation.
the evaluation of alveolar substance
Please 10 professionals in palm, get the sample 0.6g of preparation, add tap water approximately 2～3mL, the mode of rubbing both hands with the hands is got blisters to approximately 30 seconds of foam, then with the foam action that pounds of the air mode in bubble of being involved in.
To only have the alveolar substance of Powdered Irrigation product of (coco-nut oil fatty acid/palm oil fatty acid/sunflower oil fatty acid) acyl glutamic acid sodium as standard, evaluate by following benchmark.
4 points: obviously have elastic force, texture exquisiteness.
3 points: have elastic force, texture exquisiteness.
2 points: constant.
1 point: elastic force is little, texture is thick.
0 point: obviously elastic force is little, and texture is thick.
10 people's scoring meansigma methods is shown in to table 1.
the evaluation of foaming characteristic
Please 10 professionals in evaluating alveolar substance, foaming characteristic be evaluated.
To only have the foaming characteristic of Powdered Irrigation product of (coco-nut oil fatty acid/palm oil fatty acid/sunflower oil fatty acid) acyl glutamic acid sodium as standard, evaluate by following benchmark.
4 points: obviously bubble fast.
3 points: bubble fast.
2 points: constant.
1 point: bubble slow.
0 point: obviously bubble slower.
10 people's scoring meansigma methods is shown in to table 1.
overall merit
Add up to the evaluation meansigma methods of alveolar substance and the evaluation meansigma methods of foaming characteristic, evaluate by following benchmark.
◎: more than 6 points and below 8 points
6 points of zero: 5 point of above and less thaies
△: 5 points of 4 points of above and less thaies
╳: 4 points of less thaies
Overall merit is shown in to table 1.
[table 1]
The Powdered Irrigation product that are mixed with the embodiment 1～3 of side chain glucosan, the hydroxypropyl starch phosphate ester, the polydextrose that maintain circulus in (coco-nut oil fatty acid/palm oil fatty acid/sunflower oil fatty acid) acyl glutamic acid sodium are alveolar substance, foaming characteristic excellence.
The Powdered Irrigation product that are mixed with the comparative example 12 of octenyl succinated starches show excellent foaming characteristic in the combined amount of 0.5～1 quality %, but have the significantly reduced tendency of increase alveolar substance along with melting concn.
About the comparative example 4,5 that is mixed with PEG, while getting blisters foam when mixing with 1～5 quality %, obviously there is the agglomerate of insoluble matter, therefore do not judge.
Formulation Example 1 powder that washes one's face
Formulation Example 2 powder that washes one's face
Formulation Example 3 powder that washes one's face
Claims (1)
1. powder or graininess Irrigation product, is characterized in that: its contain N-acyl glutamate and from maintain the group that side chain glucosan, hydroxypropyl starch phosphate ester, the polydextrose of circulus form, select more than one.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012-239479 | 2012-10-30 | ||
| JP2012239479A JP5662986B2 (en) | 2012-10-30 | 2012-10-30 | Powder skin cleanser |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103784329A true CN103784329A (en) | 2014-05-14 |
Family
ID=50660675
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310487327.1A Pending CN103784329A (en) | 2012-10-30 | 2013-10-17 | Powder skin cleanser |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5662986B2 (en) |
| KR (1) | KR20140056061A (en) |
| CN (1) | CN103784329A (en) |
| TW (1) | TW201416088A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107184407A (en) * | 2017-05-24 | 2017-09-22 | 昆明贝泰妮生物科技有限公司 | A kind of soft and smooth moisturizing granulates clean face powder and preparation method thereof |
| CN112608800A (en) * | 2020-12-17 | 2021-04-06 | 江苏耐雀生物工程技术有限公司 | Handmade soap with anti-allergy function and preparation method thereof |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016093089A1 (en) * | 2014-12-12 | 2016-06-16 | ライオン株式会社 | Skin cleanser composition |
| JP7442991B2 (en) | 2019-07-25 | 2024-03-05 | ポーラ化成工業株式会社 | Oil-in-water emulsion type cosmetics |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5223171A (en) * | 1990-07-02 | 1993-06-29 | Rhone Poulenc Chimie | Detergent composition containing a biodegradable graft polysaccharide |
| JPH08134104A (en) * | 1994-09-13 | 1996-05-28 | Ezaki Glico Co Ltd | Glucan having ring structure |
| JP2003238337A (en) * | 2002-02-08 | 2003-08-27 | Kanebo Ltd | Powdery cosmetic |
| JP2005200413A (en) * | 2003-12-19 | 2005-07-28 | Ajinomoto Co Inc | Crystal of n-long chain acyl glutamic acid and/or its salt |
| JP2005232271A (en) * | 2004-02-18 | 2005-09-02 | Nippon Nsc Ltd | Foam stabilizer |
| CN101688151A (en) * | 2007-08-27 | 2010-03-31 | 株式会社芳珂 | Skin cleaner and the N-acyl glutamate that is used for this skin cleaner |
| JP2012239479A (en) * | 2011-05-13 | 2012-12-10 | Seven Dreamers Lab Inc | Nasal cavity insertion device coming-off prevention implement and nasal cavity insertion device set |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2095776C (en) * | 1992-05-12 | 2007-07-10 | Richard C. Fuisz | Rapidly dispersable compositions containing polydextrose |
| US6727209B2 (en) * | 2002-08-14 | 2004-04-27 | Unilever Home & Personal Care, Usa, Division Of Conopco, Inc. | Biphasic composition induced by polydextrose and sucrose |
| JP4738749B2 (en) * | 2004-02-18 | 2011-08-03 | アクゾノーベル株式会社 | Cosmetic composition |
| JP4696507B2 (en) * | 2004-09-13 | 2011-06-08 | 味の素株式会社 | Cleaning composition |
| JP2010196042A (en) * | 2009-01-28 | 2010-09-09 | Unitika Ltd | Highly flexible gel composition and use thereof |
-
2012
- 2012-10-30 JP JP2012239479A patent/JP5662986B2/en active Active
-
2013
- 2013-08-20 TW TW102129762A patent/TW201416088A/en unknown
- 2013-10-17 CN CN201310487327.1A patent/CN103784329A/en active Pending
- 2013-10-29 KR KR1020130129336A patent/KR20140056061A/en not_active Application Discontinuation
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5223171A (en) * | 1990-07-02 | 1993-06-29 | Rhone Poulenc Chimie | Detergent composition containing a biodegradable graft polysaccharide |
| JPH08134104A (en) * | 1994-09-13 | 1996-05-28 | Ezaki Glico Co Ltd | Glucan having ring structure |
| JP2003238337A (en) * | 2002-02-08 | 2003-08-27 | Kanebo Ltd | Powdery cosmetic |
| JP2005200413A (en) * | 2003-12-19 | 2005-07-28 | Ajinomoto Co Inc | Crystal of n-long chain acyl glutamic acid and/or its salt |
| JP2005232271A (en) * | 2004-02-18 | 2005-09-02 | Nippon Nsc Ltd | Foam stabilizer |
| CN101688151A (en) * | 2007-08-27 | 2010-03-31 | 株式会社芳珂 | Skin cleaner and the N-acyl glutamate that is used for this skin cleaner |
| JP2012239479A (en) * | 2011-05-13 | 2012-12-10 | Seven Dreamers Lab Inc | Nasal cavity insertion device coming-off prevention implement and nasal cavity insertion device set |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107184407A (en) * | 2017-05-24 | 2017-09-22 | 昆明贝泰妮生物科技有限公司 | A kind of soft and smooth moisturizing granulates clean face powder and preparation method thereof |
| CN112608800A (en) * | 2020-12-17 | 2021-04-06 | 江苏耐雀生物工程技术有限公司 | Handmade soap with anti-allergy function and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20140056061A (en) | 2014-05-09 |
| JP2014088347A (en) | 2014-05-15 |
| TW201416088A (en) | 2014-05-01 |
| JP5662986B2 (en) | 2015-02-04 |
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