CN103783045A - Acaricide composite - Google Patents
Acaricide composite Download PDFInfo
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- CN103783045A CN103783045A CN201210431848.0A CN201210431848A CN103783045A CN 103783045 A CN103783045 A CN 103783045A CN 201210431848 A CN201210431848 A CN 201210431848A CN 103783045 A CN103783045 A CN 103783045A
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- fatty acid
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- phonetic mite
- acaricide
- mite amine
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Abstract
The invention relates to an acaricide composite. The acaricide composite comprises 5-70% by weight of acaricide adopted as the active component, 0.1-30% by weight of a synergist, 1-30% by weight of a surfactant and 1-60% by weight of a carrier. Research finds that the synergist suitable for the acaricide composite is one or more selected from an aliphatic ester compound, an aliphatic ester polymer and a 1-dodecylazacycloheptan-2-one compound. The acaricide composite is advantageous in that: 1) the active compound in the composite is stable; and 2) the synergist in the composite has synergistic effects and improves the acaricidal activity of the acaricide.
Description
Technical field
The invention belongs to field of agrochemicals, relate to a kind of phonetic mite amine agricultural acaricides containing building component of exploitation, be specifically related to a kind of acaricide composition.
Background technology
Chinese invention patent CN101906075A discloses the purposes of a kind of E-type phenyl acrylates compounds containing substituted anilino pyrimidine group and Control pests thereof, evil mite, wherein compound 9(Universal Chinese character name: phonetic mite amine, English common name: pyriminostrobin) can be used for preventing and treating various pests, do harm to mite, especially mite class is had to outstanding control efficiency, the chemical structural formula of phonetic mite amine is as follows:
Inventor finds in to the further further investigation process of phonetic mite amine, although this compound biologically active excellence, but in the time of process preparation, run into beyond thought problem: when prepare the formulations such as phonetic mite amine suspending agent or oil-suspending agent with conventional method, acaricidal activity declines to a great extent; Even if adjustment pharmaceutical formulation, can not fundamentally address this problem.
Summary of the invention
The object of the present invention is to provide all good phonetic mite amine acaricide compositions of a kind of insecticidal effect and stability, the problem declining to solve preparation drug effect is developed the phonetic mite amine miticide preparation that several biologically actives are good, meet practical application needs simultaneously.
For achieving the above object, inventor for the characteristic of phonetic mite amine former medicine itself and with it compatibility auxiliary agent carried out large quantity research and screening, find to add one or more fatty acid ester compounds, fatty acid ester base polymer or Azone as synergist in phonetic mite amine acaricide composition, can significantly improve the acaricidal activity of phonetic mite amine.This synergist both can be used alone, and also can combine use, and was applicable to prepare the phonetic mite amine miticide of multiple formulation.Inventor develops a kind of acaricide composition containing building component thus, and said composition contains four class materials: 1. active component; 2. synergist; 3. surfactant; 4. carrier.Here, described active component is phonetic mite amine or the upper acceptable salt of its agricultural.Research is found: by selecting suitable and appropriate synergist, surfactant and carrier, can obviously improve the acaricidal activity of phonetic mite amine composition; Meanwhile, the synergist that the present invention selects also goes for improving the acaricidal biologically active of other methoxy acrylics.
Technical scheme of the present invention is as follows:
A kind of acaricide composition, active component is phonetic mite amine, also contains synergist, surfactant and carrier in composition, in composition, the weight percentage of each component is as follows: phonetic mite amine 5-70%, synergist 0.1-30%, surfactant 1-30%, carrier 1-60%.
In the present invention, so-called phonetic mite amine active component is phonetic mite amine or its salt.
The present invention more preferably technical scheme is that in composition, the weight percentage of each component is as follows: phonetic mite amine 10-50%, synergist 1-30%, surfactant 1-30%, carrier 10-60%.
The further preferred technical scheme of the present invention is that in composition, the weight percentage of each component is as follows: phonetic mite amine 10-30%, synergist 5-30%, surfactant 1-30%, carrier 20-60%.
The above-mentioned acaricide composition containing synergist can be processed into multiple formulation on demand.The formulation being mainly concerned with has aqueous emulsion, aqueous suspension agent, suspended emulsion, oil-suspending agent, wetting powder, water dispersion granule etc., and in above-mentioned formulation, active component is to exist with small particles form, thereby has affected drug effect and normally bring into play.
Research discovery, the synergist that is applicable to acaricide composition of the present invention is selected from one or more fatty acid ester compounds, fatty acid ester base polymer, Azone compound.Described synergist is selected from, but be not limited to for example glycerin mono-fatty acid ester, glyceryl monolaurate, methyl oleate, stearic acid methyl esters, 12, tetradecyl alchohol oleate, propylene glycol mono-oleate, vegetable oil methylates, polyoxyethylene sorbitan fatty acid ester, APEO sorbitan fatty acid ester, cithrol, polyoxyethylene groups fatty acid ester, fatty acid polyglycerol ester or polyoxypropylene fatty acid ester, Azone, ethoxylated castor wet goods.In composition, these synergist can use separately, also can select wherein two or more to be used in combination; In the situation that synergist is used in combination, their additional proportion can be selected arbitrarily.Described synergist is one or more oleate compounds and polymer thereof preferably.In the above-mentioned various formulations of mentioning, add the raising biologically active that one or more oleate classes and polymer thereof all can be in various degree.
Described surfactant is selected from anion surfactant and/or non-ionic surface active agent.Described anion surfactant is selected from for example fatty acid salt, polycarboxylate, alkylsulfonate, alkylaryl sulfonates, arylsulphonate or lignosulfonates; Wherein preferably alkylsulfonate, polycarboxylate and arylsulphonate etc.Described non-ionic surface active agent is selected from the compounds such as such as fatty alcohol polyethenoxy ether class, alkylphenol polyoxyethylene class, aliphatic amine polyoxyethylene ether class, vegetable and animals oils polyethenoxy ether class, alkyl glycoside class or cellulose ethers.Above-mentioned surfactant can be used alone or as a mixture.
In above-mentioned synergist, a part is because having oleophylic and hydrophilic radical in chemical constitution, play the effect of surfactant, due to the particularity of its structure, in pharmaceutical formulation, using such synergist to play increases the double effects of the consumption of active ingredient biologically active and reduction surfactant simultaneously; In like manner, in above-mentioned surfactant, have too the molecular structure of part material to have the bioactive effect of the active ingredient of increasing, the two can be mutually promoted.
Described carrier comprises solid carrier or liquid-carrier.Described solid carrier can be diatomite, precipitated calcium carbonate, kaolin, bentonite, White Carbon black, ammonium sulfate, ammonium hydrogen sulfate, cellulose family, xanthans, anhydrous sodium sulfate etc. or its two or more mixture.Described liquid-carrier is mainly selected from solvent naphtha-150(S-150), cyclohexanone, triethyl phosphate, octylpyrrolidone, nitrogen methyl pyrrolidone etc. or its two or more mixture.According to prepared formulation difference, in composition, add above-mentioned solid carrier and/or liquid-carrier.If desired, add other auxiliary agents such as appropriate defoamer, this point is appreciated by those skilled in the art.
Mixed and obtained phonetic mite amine composition of the present invention by said components, can be prepared into as required multiple formulation, can be for example can wet-milling, aqueous emulsion, suspending agent, suspended emulsion, oil-suspending agent, water-dispersible granules etc.Composition of the present invention can by by each component of ormal weight with random order or simultaneously mix, obtain required formulation with processing method well-known to those skilled in the art.A large amount of development test results show, the building component of selecting by adding the present invention, the acaricidal activity of the phonetic mite amine preparation of above-mentioned each formulation is significantly better than the reference examples sample that does not add synergist, this shows one or more fatty acid esters, fatty acid ester base polymer or Azone and they combine to use and can be used as the effective synergist of the present invention, wherein preferred oil acid esters compound, multiple oleate base polymer or Azone and they combine use, can obviously improve the acaricidal activity of phonetic mite amine or the upper acceptable salt of its agricultural.Therefore another technical scheme of the present invention be above-mentioned composition is made can wet-milling, the dosage form such as aqueous emulsion, suspending agent, suspended emulsion, oil-suspending agent or water-dispersible granules is as the purposes of agricultural acaricides.
Phonetic mite amine composition of the present invention has the following advantages: 1. the former drug stabilisation in composition; 2. the synergist in composition has synergistic effect, has improved phonetic mite amine acaricidal activity, can meet the requirement as agricultural acaricides.
Embodiment
Following examples are used for describing in further detail the present invention, but are not construed as limiting the invention, and composition of the present invention only limits to absolutely not these embodiment.The self-control of phonetic mite An Yuanyaowei Shenyang Chemical Engineering Inst. Co., Ltd, content 98%, folding hundred post doses add; Other raw materials have commercially available.Each material is all measured and is added by weight.
Formulation Example
The phonetic mite amine aqueous suspension agent of embodiment 1 15%
The phonetic mite amine aqueous suspension agent of reference examples 1 15%
Processing method: by formula requirement, by various auxiliary agents, filler, adds in blender after former medicine metering, starts high shear machine, after shearing evenly, drops in sand mill, pulverizes by wet grinding.The good material of sand milling, after mixing, obtains 15% phonetic mite amine aqueous suspension agent product.
The phonetic mite amine aqueous suspension agent of embodiment 2 10%
The phonetic mite amine aqueous suspension agent of reference examples 2 10%
Processing method: by formula requirement, by various auxiliary agents, filler, adds in blender after former medicine metering, starts high shear machine, after shearing evenly, drops in sand mill, pulverizes by wet grinding.The good material of sand milling, after mixing, obtains 10% phonetic mite amine aqueous suspension agent product.
The phonetic mite amine aqueous suspension agent of embodiment 3 20%
The phonetic mite amine aqueous suspension agent of reference examples 3 20%
Processing method: by formula requirement, by various auxiliary agents, filler, adds in blender after former medicine metering, starts high shear machine, after shearing evenly, drops in sand mill, pulverizes by wet grinding.The good material of sand milling, after mixing, obtains 20% phonetic mite amine aqueous suspension agent product.
The phonetic mite amine aqueous suspension agent of embodiment 4 30%
The phonetic mite amine aqueous suspension agent of reference examples 4 30%
Processing method: by formula requirement, by various auxiliary agents, filler, adds in blender after former medicine metering, starts high shear machine, after shearing evenly, drops in sand mill, pulverizes by wet grinding.The good material of sand milling, after mixing, obtains 30% phonetic mite amine aqueous suspension agent product.
The phonetic mite amine oil-suspending agent of embodiment 5 10%
The phonetic mite amine oil-suspending agent of reference examples 5 10%
Processing method: by formula requirement, by various auxiliary agents, filler, adds in blender after former medicine metering, starts high shear machine, after shearing evenly, drops in sand mill, pulverizes by wet grinding.The good material of sand milling, after mixing, obtains 10% phonetic mite amine oil-suspending agent product.
The phonetic mite amine oil-suspending agent of embodiment 6 15%
The phonetic mite amine oil-suspending agent of reference examples 6 15%
Processing method: by formula requirement, by various auxiliary agents, filler, adds in blender after former medicine metering, starts high shear machine, after shearing evenly, drops in sand mill, pulverizes by wet grinding.The good material of sand milling, after mixing, obtains 15% phonetic mite amine oil-suspending agent product.
The phonetic mite amine oil-suspending agent of embodiment 7 20%
The phonetic mite amine oil-suspending agent of reference examples 7 20%
Processing method: by formula requirement, by various auxiliary agents, filler, adds in blender after former medicine metering, starts high shear machine, after shearing evenly, drops in sand mill, pulverizes by wet grinding.The good material of sand milling, after mixing, obtains 20% phonetic mite amine oil-suspending agent product.
The phonetic mite amine water-dispersible granules of embodiment 8 25%
The phonetic mite amine water-dispersible granules of reference examples 8 25%
Processing method: by formula requirement, by various auxiliary agents, filler, adds in mixer after former medicine metering, starts stirring, after mixing, puts into intermediate bunker, pulverizes by ultrafine crusher.Add adhesive to mix the material crushing, to be mixed evenly after, by granulator granulation, obtain 25% phonetic mite amine water-dispersible granules product.
The phonetic mite amine wetting powder of embodiment 9 30%
The phonetic mite amine wetting powder of reference examples 9 30%
Processing method: by formula requirement, by various auxiliary agents, filler, adds in mixer after former medicine metering, starts stirring, after mixing, puts into intermediate bunker, pulverizes by ultrafine crusher.Obtain 30% phonetic mite amine wetting powder product.
The phonetic mite amine aqueous emulsion of embodiment 10 10%
The phonetic mite amine aqueous emulsion of reference examples 10 10%
Processing method: by formula requirement, by various auxiliary agents, add in raw material blending tank after former medicine, solvent metering, start stirring, meter adds the water of surplus to continue to be stirred to evenly after mixing, and obtains 10% phonetic mite amine aqueous emulsion product.
The phonetic mite amine suspended emulsion of embodiment 11 10%
The phonetic mite amine suspended emulsion of reference examples 11 10%
Processing method: by formula requirement, by various auxiliary agents, filler, adds in blender after former medicine metering, starts high shear machine, after shearing evenly, drops in sand mill, pulverizes by wet grinding.The good material of sand milling, after mixing, obtains 15% phonetic mite amine suspended emulsion product.
Preparation stability test
The stability of test the various embodiments described above preparation is carried out the test of control sample (being laboratory self-control) simultaneously.Test condition is: in 54 ± 2 ℃ of constant temperature ovens, store 14 days.Content after storing by liquid-phase chromatographic analysis, utilizes following formula to calculate the resolution ratio of active constituent:
Computing formula: active constituent resolution ratio X is calculated as follows:
In formula: M
0---the percentage composition before the storage of sample heat, %;
M
1---the percentage composition after the storage of sample heat, %.
Heat storage stability result of the test is listed in table 1.
Table 1
| Product | Resolution ratio |
| Embodiment 1 | 3.1% |
| Reference examples 1 | 3.3% |
| Embodiment 2 | 3.3% |
| Reference examples 2 | 2.9% |
| Embodiment 3 | 3.1% |
| Reference examples 3 | 2.7% |
| Embodiment 4 | 2.6% |
| Reference examples 4 | 2.8% |
| Embodiment 5 | 2.2% |
| Reference examples 5 | 2.1% |
| Embodiment 6 | 3.1% |
| Reference examples 6 | 3.2% |
| Embodiment 7 | 3.5% |
| Reference examples 7 | 3.2% |
| Embodiment 8 | 4.1% |
| Reference examples 8 | 3.8% |
| Embodiment 9 | 3.3% |
| Reference examples 9 | 3.5% |
| Embodiment 10 | 4.1% |
| Reference examples 10 | 4.2% |
| Embodiment 11 | 3.7% |
| Reference examples 11 | 3.9% |
Make as can be seen from the table the formulation resolution ratios such as aqueous suspension agent, suspended emulsion, oil-suspending agent, aqueous emulsion, water dispersible granules, wetting powder and be all less than 5%, meet the national standard requirement of each formulation, in various preparations, phonetic mite amination has good stability.
Biological activity test embodiment
Under greenhouse experiment, utilize potted plant test method to study for the sensitive varieties Tetranychus cinnabarinus of indoor feeding.The present invention has studied the active control situation of embodiment 1-11 and reference examples 1-11.
Test method: adopt potted plant seedling spray-on process to measure the activity size that Tetranychus cinnabarinus is become to mite.First Tetranychus cinnabarinus of the same size is become mite to receive on the Tolerance of Kidney Bean Seedlings blade in first pair of open and flat phase of true leaf, after becoming mite stable, count radix; Then press the order even spraying of experimental scheme from low dosage to high dose, every strain 1.5mL, every processing repeats for 3 times, separately establishes blank.Examination material after treatment is placed in observation ward, and the temperature of observation ward, humidity, illumination are adjustable as required.72 hours " Invest, Then Investigate " mite numbers dead, alive.By abbott formula calculation correction lethality, carry out statistical analysis with DPS data processing software.
Liquid preparation: according to different tests needs, accurately take respectively test sample with electronic analytical balance, the serial liquid that leaves standstill water and become according to experimental scheme dose dilution tool finite concentration gradient for preparation.
The acaricidal activity test result of embodiment and reference examples is in table 2, and wherein using dosage is effective dose.
Table 2
From table, data can be found out, the acaricidal activity of each embodiment is significantly better than the reference examples sample that does not add synergist.This shows, in acaricide composition of the present invention, one or more fatty acid esters, fatty acid ester base polymer or Azone and they are combined and are used as synergist, wherein preferably oleic acid acid esters compound, multiple oleate base polymer or Azone and they combine use, can obviously improve its acaricidal activity to phonetic mite amine or the upper acceptable salt of its agricultural.
Claims (10)
1. an acaricide composition, active component is phonetic mite amine, also contains synergist, surfactant and carrier in composition, in composition, the weight percentage of each component is as follows: phonetic mite amine 5-70%, synergist 0.1-30%, surfactant 1-30%, carrier 1-60%.
2. acaricide composition according to claim 1, is characterized in that: in composition, the weight percentage of each component is as follows: phonetic mite amine 10-50%, synergist 1-30%, surfactant 1-30%, carrier 10-60%.
3. acaricide composition according to claim 2, is characterized in that: in composition, the weight percentage of each component is as follows: phonetic mite amine 10-30%, synergist 5-30%, surfactant 1-30%, carrier 20-60%.
4. according to the acaricide composition described in claim 1,2 or 3 any one, it is characterized in that: described phonetic mite amine active component is phonetic mite amine or its salt.
5. according to the acaricide composition described in claim 1,2 or 3 any one, it is characterized in that: described synergist is selected from one or more fatty acid ester compounds, fatty acid ester base polymer or Azone compound.
6. acaricide composition according to claim 5, is characterized in that: described synergist is selected from one or more glycerin mono-fatty acid esters, glyceryl monolaurate, methyl oleate, stearic acid methyl esters, 12, tetradecyl alchohol oleate, propylene glycol mono-oleate, the vegetable oil that methylates, polyoxyethylene sorbitan fatty acid ester, APEO sorbitan fatty acid ester, cithrol, polyoxyethylene groups fatty acid ester, fatty acid polyglycerol ester or polyoxypropylene fatty acid ester, Azone or ethoxy castor oil.
7. according to the acaricide composition described in claim 1,2 or 3 any one, it is characterized in that: described surfactant is selected from one or more anion surfactants and/or non-ionic surface active agent.
8. acaricide composition according to claim 7, is characterized in that: described anion surfactant is selected from for example fatty acid salt, polycarboxylate, alkylsulfonate, alkylaryl sulfonates, arylsulphonate or lignosulfonates; Described non-ionic surface active agent is selected from the compounds such as such as fatty alcohol polyethenoxy ether class, alkylphenol polyoxyethylene class, aliphatic amine polyoxyethylene ether class, vegetable and animals oils polyethenoxy ether class, alkyl glycoside class or cellulose ethers.
9. according to the acaricide composition described in claim 1,2 or 3 any one, it is characterized in that: the formulation of composition is aqueous emulsion, aqueous suspension agent, suspended emulsion, oil-suspending agent, wetting powder or water dispersion granule.
10. an acaricide composition according to claim 9 is as the purposes of disinfectant use in agriculture.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104823972A (en) * | 2015-05-28 | 2015-08-12 | 苏州丰倍生物科技有限公司 | Pesticide synergist and preparation method |
| CN108902162A (en) * | 2018-08-02 | 2018-11-30 | 郑州信联生化科技有限公司 | A kind of plant growth regualting composition, preparation and its application |
| WO2021214215A1 (en) * | 2020-04-23 | 2021-10-28 | Arch Uk Biocides Ltd | Synergistic biocide composition with a polyglycerol ester |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1179883A (en) * | 1996-09-04 | 1998-04-29 | 山东省栖霞市化工厂 | High permeable emulsible solution for killing acarid |
| CN101156591A (en) * | 2007-09-19 | 2008-04-09 | 湖南万家丰科技有限公司 | Mite-killing composition containing fenbutatin |
| CN101530078A (en) * | 2008-03-14 | 2009-09-16 | 北京绿色农华植保科技有限责任公司 | Preparation method of propargite microemulsion |
| CN101530074A (en) * | 2008-03-14 | 2009-09-16 | 北京绿色农华植保科技有限责任公司 | Preparation method of pyridaben micro-emulsion |
| CN102395569A (en) * | 2009-06-05 | 2012-03-28 | 中国中化股份有限公司 | E-type phenyl acrylic ester compounds containing substituted anilino pyrimidine group and uses thereof |
-
2012
- 2012-11-01 CN CN201210431848.0A patent/CN103783045A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1179883A (en) * | 1996-09-04 | 1998-04-29 | 山东省栖霞市化工厂 | High permeable emulsible solution for killing acarid |
| CN101156591A (en) * | 2007-09-19 | 2008-04-09 | 湖南万家丰科技有限公司 | Mite-killing composition containing fenbutatin |
| CN101530078A (en) * | 2008-03-14 | 2009-09-16 | 北京绿色农华植保科技有限责任公司 | Preparation method of propargite microemulsion |
| CN101530074A (en) * | 2008-03-14 | 2009-09-16 | 北京绿色农华植保科技有限责任公司 | Preparation method of pyridaben micro-emulsion |
| CN102395569A (en) * | 2009-06-05 | 2012-03-28 | 中国中化股份有限公司 | E-type phenyl acrylic ester compounds containing substituted anilino pyrimidine group and uses thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104823972A (en) * | 2015-05-28 | 2015-08-12 | 苏州丰倍生物科技有限公司 | Pesticide synergist and preparation method |
| CN108902162A (en) * | 2018-08-02 | 2018-11-30 | 郑州信联生化科技有限公司 | A kind of plant growth regualting composition, preparation and its application |
| WO2021214215A1 (en) * | 2020-04-23 | 2021-10-28 | Arch Uk Biocides Ltd | Synergistic biocide composition with a polyglycerol ester |
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Application publication date: 20140514 |