CN103709586B - Rat-and-ant proof PA/ABS environmentally-friendly plastic - Google Patents
Rat-and-ant proof PA/ABS environmentally-friendly plastic Download PDFInfo
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- CN103709586B CN103709586B CN201310738080.6A CN201310738080A CN103709586B CN 103709586 B CN103709586 B CN 103709586B CN 201310738080 A CN201310738080 A CN 201310738080A CN 103709586 B CN103709586 B CN 103709586B
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Abstract
The invention discloses a kind of rat-and-ant proof PA/ABS environmentally-friendly plastic, be made up of by weight following component: 25 parts of PA, 70 parts of ABS, 24 parts of compatilizer ABS g MAH, 35 parts of biological rat-and-ant proof agent.The rat-and-ant proof PA/ABS environmentally-friendly plastic of the present invention, has the preventing from being eaten by ant and mouse performance of excellence.
Description
Technical field
The present invention relates to a kind of plastic material, particularly relate to a kind of rat-and-ant proof PA/ABS environmentally-friendly plastic.
Background technology
Mouse as the rodent that a kind of reproductive capacity and vitality are the strongest extensively live in the world each
Area, owing to its front tooth is the most flourishing and can constantly grow, so muroid has object of nibbling to be kept its tooth
Sharp habit, the distinctive abnormal smells from the patient of plastics makes plastics become muroid often to bite object.
It is luxuriant that Coptotermes formosanus Shtrari. is also known as worm, is in the streets commonly called as flood ant (because generally occurring before raining, hence obtain one's name),
The general name of isoptera insect, about kind more than 2000.For incomplete metamorphosis manometavola and be social insect,
Coptotermes formosanus Shtrari. in each termitarium is individual up to more than million.Termite damage building construction, reservoir dam,
Mountain forest orchard, vehicle ship etc., cause the biggest loss to national economy.The distinctive abnormal smells from the patient of plastics makes to mould
Material becomes Coptotermes formosanus Shtrari. and often bites object.
Existing plastic material, in order to realize rat-and-ant proof, adds Niran, Emhorn the most in the plastic
, there is the biggest environmental pollution in the poisoning agents such as agent, and very harmful to health, and pole is not environmentally.
Summary of the invention
For above-mentioned deficiency present in prior art, the technical problem to be solved is to provide one
Plant rat-and-ant proof PA/ABS environmentally-friendly plastic.
The technical problem to be solved is achieved by the following technical solution:
A kind of rat-and-ant proof PA/ABS environmentally-friendly plastic, is made up of by weight following component: 25 parts of PA,
70 parts of ABS, 2-4 part compatilizer ABS-g-MAH, 3-5 part biology rat-and-ant proof agent.
Described biological rat-and-ant proof agent, is made up of by weight following component: 10-30 part 11,12,13,14-tetra-
Dehydrogenation matridinde-15-ketone, 10-30 part Tripterygium wilfordii lactone ketone, 10-30 part N-(4-hydroxy-3-methoxy benzyl
Base)-8-methyl pelargonamide.
11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, Tripterygium wilfordii lactone ketone, N-(4-hydroxy-3-methoxy
Benzyl)-8-methyl pelargonamide is uniformly mixed, and can be prepared by biological rat-and-ant proof agent.
Industry universal method can be used to be prepared the rat-and-ant proof PA/ABS environmentally-friendly plastic of the present invention,
Such as: weigh each component by proportioning, after mix homogeneously, melting mixing, extruding pelletization, i.e. obtain described
Rat-and-ant proof PA/ABS environmentally-friendly plastic.
Concrete, can be to weigh each component by proportioning, in mixer, control rotating speed under room temperature and exist
300-400 rev/min, mix 2-10 minute, proceed to after taking-up in screw extruder, at 180-200 DEG C
At a temperature of extruding pelletization, i.e. obtain described rat-and-ant proof PA/ABS environmentally-friendly plastic.
The rat-and-ant proof PA/ABS environmentally-friendly plastic of the present invention, has the preventing from being eaten by ant and mouse performance of excellence.
Detailed description of the invention
Embodiment 1
Each raw material is weighed according to embodiment 1-4 data corresponding in table 1.Each component is joined mixed at high speed
In machine, under room temperature, control rotating speed is at 320 revs/min, mixes 6 minutes, proceeds to screw extruder after taking-up
In, extruding pelletization at a temperature of 190 DEG C, it is thus achieved that rat-and-ant proof PA/ABS environmentally-friendly plastic.
Table 1: rat-and-ant proof PA/ABS environmental-friendplastic plastic formula list position: kilogram
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| PA resin | 25 | 25 | 25 | 25 |
| ABS resin | 70 | 70 | 70 | 70 |
| Compatilizer ABS-g-MAH | 3 | 3 | 3 | 3 |
| 11,12,13,14-tetra-dehydrogenation matridinde-15-ketone | 1.6 | 2.4 | 2.4 | / |
| Tripterygium wilfordii lactone ketone | 1.6 | 2.4 | / | 2.4 |
| N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide | 1.6 | / | 2.4 | 2.4 |
11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, No. CAS: 6882-66-2.Tripterygium wilfordii lactone ketone,
No. CAS: 38647-11-9.N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide, No. CAS:
19408-84-5。
The PA66 resin of du pont company trade mark 101L selected by PA resin；ABS resin selects Jilin
The ABS resin of petro-chemical corporation trade mark 0215A.
Test case 1
Use GB/T2951.38-1986 electric wire Coptotermes formosanus Shtrari. test method, carry out knocking down method test.
Test piece: 50mm × 50mm × 1mm.
Table 2: anti-ant performance test table
| Coptotermes formosanus Shtrari. knockdown time KT50, min | |
| Embodiment 1 | 168 |
| Embodiment 2 | 182 |
| Embodiment 3 | 186 |
| Embodiment 4 | 175 |
Visible, by 11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, Tripterygium wilfordii lactone ketone, N-(4-hydroxyl
-3-methoxy-benzyl) the biological rat-and-ant proof agent of-8-methyl pelargonamide three kinds carries out compounding use, Synergistic,
Coptotermes formosanus Shtrari. knockdown time substantially reduces, and anti-ant performance is good.
Test case 2
Use GB/T2951.38-1986 electric wire Coptotermes formosanus Shtrari. test method, the rat-and-ant proof to embodiment 1
PA/ABS environmentally-friendly plastic carries out Colony test test.Test piece: 80mm × 25mm × 1mm.
Test result: Coptotermes formosanus Shtrari. moth erosion grade is 1 grade.
Test case 3
Test material film-making: according to GB/T8815-2002 pilot scale piece preparation method, sample is made specification is
The test piece of 150mm × 20mm × 3mm.
Testing equipment and experimental animal: weight 250-300 gram SD male rat PP plastic casing stainless (steel) wire
Lid mouse cage, mouse cage specification is high 250mm, a length of 600mm, a width of 400mm, at the bottom of mouse cage and four walls
For PP plastics, top is rustless steel square, and is furnished with waterer.
Test procedure: choose SD male rat, stochastic sampling puts into mouse cage, 5, every cage；By test piece
Stretch in cage from mouse cage top, with thin copper wire tightly colligation on the stainless (steel) wire lid at feeding, examination
The part that sheet is exposed at beyond mouse cage hangs three test pieces less than 20mm, a cage, and test piece is at mouse cage width
Uniformly arranging on direction, interval is about 80mm.Rat is regular supply drinking-water and food during testing
(i.e. every day changed clear water by waterer, has remained food at feeding).Observe every day rat activity and
Diet situation and test period terminate the situation that rear sample is bitten by rat.Test period is 7 days.
The rat-and-ant proof PA/ABS environmentally-friendly plastic of embodiment 1: bite area 2.5%.
Claims (1)
1. a rat-and-ant proof PA/ABS environmentally-friendly plastic, it is characterised in that by following component group by weight
Become: 25 parts of PA, 70 parts of ABS, 2-4 part compatilizer ABS-g-MAH, 3-5 part biology rat-and-ant proof agent；
Described biological rat-and-ant proof agent, is made up of by weight following component: 10-30 part 11,12,13,14-tetra-
Dehydrogenation matridinde-15-ketone, 10-30 part Tripterygium wilfordii lactone ketone, 10-30 part N-(4-hydroxy-3-methoxy benzyl
Base)-8-methyl pelargonamide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310738080.6A CN103709586B (en) | 2013-12-15 | 2013-12-15 | Rat-and-ant proof PA/ABS environmentally-friendly plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310738080.6A CN103709586B (en) | 2013-12-15 | 2013-12-15 | Rat-and-ant proof PA/ABS environmentally-friendly plastic |
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| Publication Number | Publication Date |
|---|---|
| CN103709586A CN103709586A (en) | 2014-04-09 |
| CN103709586B true CN103709586B (en) | 2017-01-04 |
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| CN201310738080.6A Expired - Fee Related CN103709586B (en) | 2013-12-15 | 2013-12-15 | Rat-and-ant proof PA/ABS environmentally-friendly plastic |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105295358A (en) * | 2015-12-05 | 2016-02-03 | 淄博夸克医药技术有限公司 | Ratproof and anti-termite PA-ABS environment-friendly plastic |
| CN110467810A (en) * | 2019-08-13 | 2019-11-19 | 江门市凯生工程塑料有限公司 | A kind of preparation method of the rat-and-ant proof PA environmentally-friendly plastic of high impact |
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| JP3342283B2 (en) * | 1996-02-13 | 2002-11-05 | 矢崎総業株式会社 | Termite- and rat-resistant wire |
| CN101798417B (en) * | 2010-03-26 | 2011-12-07 | 华南理工大学 | Anti-termite and coloring functional master batch for plastic and preparation method thereof |
| CN103371169B (en) * | 2012-04-16 | 2014-10-22 | 上海韬鸿化工科技有限公司 | Sophoramine insect-preventing missible oil, sophoramine insect-preventing fabric and preparation method of fabric |
| CN103360719B (en) * | 2013-07-15 | 2015-11-25 | 上海秋橙新材料科技有限公司 | anti-aging PA-ABS plastic alloy |
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Effective date of registration: 20170510 Address after: Changning Lotus Village town of Chenghai District of Shantou city in Guangdong province 515800 Patentee after: SHANTOU GUANGLONG PLASTIC CO.,LTD. Address before: 201107 Shanghai city Minhang District Minhang Road 88 Lane No. 1-30 building twenty-second room T157 Patentee before: SHANGHAI YUEMENG ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd. |
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Granted publication date: 20170104 Termination date: 20211215 |