CN103709508B - Rat-and-ant proof PP/HDPE environmentally-friendly plastic - Google Patents
Rat-and-ant proof PP/HDPE environmentally-friendly plastic Download PDFInfo
- Publication number
- CN103709508B CN103709508B CN201310687716.9A CN201310687716A CN103709508B CN 103709508 B CN103709508 B CN 103709508B CN 201310687716 A CN201310687716 A CN 201310687716A CN 103709508 B CN103709508 B CN 103709508B
- Authority
- CN
- China
- Prior art keywords
- rat
- hdpe
- ant proof
- environmentally
- friendly plastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
Abstract
The invention discloses a kind of rat-and-ant proof PP/HDPE environmentally-friendly plastic, be made up of by weight following component: 50 parts of PP, 30 parts of HDPE, 12 20 parts of EPDM, 35 parts of biological rat-and-ant proof agent.The rat-and-ant proof PP/HDPE environmentally-friendly plastic of the present invention, has higher impact strength and hot strength, and has the preventing from being eaten by ant and mouse performance of excellence.
Description
Technical field
The present invention relates to a kind of plastic material, particularly relate to a kind of rat-and-ant proof PP/HDPE environmentally-friendly plastic.
Background technology
Mouse extensively lives in each area in the world as the rodent that a kind of reproductive capacity and vitality are the strongest, by
The most flourishing in its front tooth and can constantly grow, so muroid has object of nibbling to be kept the habit that its tooth is sharp, plastics are peculiar
Abnormal smells from the patient make plastics become muroid often to bite object.
It is luxuriant that Coptotermes formosanus Shtrari. is also known as worm, is in the streets commonly called as flood ant (because generally occurring before raining, hence obtain one's name), isoptera insect
General name, about kind more than 2000.For incomplete metamorphosis manometavola and be social insect, Coptotermes formosanus Shtrari. in each termitarium is individual
Up to more than million.Termite damage building construction, reservoir dam, mountain forest orchard, vehicle ship etc., cause very national economy
Big loss.The distinctive abnormal smells from the patient of plastics makes plastics become Coptotermes formosanus Shtrari. often to bite object.
Existing plastic material, in order to realize rat-and-ant proof, adds the poisoning such as Niran, drinox the most in the plastic
, there is the biggest environmental pollution in agent, and very harmful to health, and pole is not environmentally.
Summary of the invention
For above-mentioned deficiency present in prior art, the technical problem to be solved is to provide a kind of rat-and-ant proof
PP/HDPE environmentally-friendly plastic.
The technical problem to be solved is achieved by the following technical solution:
A kind of rat-and-ant proof PP/HDPE environmentally-friendly plastic, is made up of by weight following component: 50 parts of PP, 30 parts of HDPE, 12-
20 parts of EPDM, 3-5 part biology rat-and-ant proof agent.
Described biological rat-and-ant proof agent, is made up of by weight following component: 10-15 part 11,12,13,14-tetra-dehydrogenation Radix Sophorae Flavescentis
Secondary alkali-15-ketone, 10-15 part Tripterygium wilfordii lactone ketone, 10-15 part N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide.
11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, Tripterygium wilfordii lactone ketone, N-(4-hydroxy-3-methoxy benzyl
Base)-8-methyl pelargonamide is uniformly mixed, and can be prepared by biological rat-and-ant proof agent.
Industry universal method can be used to be prepared the rat-and-ant proof PP/HDPE environmentally-friendly plastic of the present invention, such as: by joining
Ratio weighs each component, after mix homogeneously, and melting mixing, extruding pelletization, i.e. obtain described rat-and-ant proof PP/HDPE environmentally-friendly plastic.
Concrete, can be to weigh each component by proportioning, in mixer, control rotating speed under room temperature at 300-400 rev/min
Clock, mixes 2-10 minute, proceeds in screw extruder after taking-up, extruding pelletization at a temperature of 170-190 DEG C, i.e. obtains described anti-
Mus ant PP/HDPE environmentally-friendly plastic.
HDPE, high density polyethylene (HDPE), is a kind of degree of crystallinity thermoplastic resin high, nonpolar.PP, polypropylene, is by third
A kind of thermoplastic resin that alkene is polymerized and prepares.EPDM, ethylene propylene diene rubber, ethylene, propylene and the three of non-conjugated diene hydrocarbon
Membered copolymer.
The rat-and-ant proof PP/HDPE environmentally-friendly plastic of the present invention, has higher impact strength and hot strength, and has excellence
Preventing from being eaten by ant and mouse performance.
Detailed description of the invention
Embodiment 1
Each raw material is weighed according to embodiment 1-4 data corresponding in table 1.Each component is joined in high-speed mixer, room temperature
Lower control rotating speed, at 320 revs/min, mixes 8 minutes, proceeds in screw extruder after taking-up, extrude and make at a temperature of 185 DEG C
Grain, it is thus achieved that rat-and-ant proof PP/HDPE environmentally-friendly plastic.
Table 1: rat-and-ant proof PP/HDPE environmental-friendplastic plastic formula list position: kilogram
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| PP resin | 50 | 50 | 50 | 50 |
| HDPE resin | 30 | 30 | 30 | 30 |
| EPDM resin | 15.2 | 15.2 | 15.2 | 15.2 |
| 11,12,13,14-tetra-dehydrogenation matridinde-15-ketone | 1.6 | 2.4 | 2.4 | / |
| Tripterygium wilfordii lactone ketone | 1.6 | 2.4 | / | 2.4 |
| N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide | 1.6 | / | 2.4 | 2.4 |
11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, No. CAS: 6882-66-2.Tripterygium wilfordii lactone ketone, No. CAS:
38647-11-9.N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide, No. CAS: 19408-84-5.
Petrochemical industry Guangzhou petrochemical industry branch company trade mark J641 copolymerization PP resin in the selection of PP resin；HDPE resin selects Korea S SK public
The HDPE of department trade mark JK910.The EPDM resin of LG-DOW EPDM5565 selected by EPDM resin.
Test case 1
Use GB/T2951.38-1986 electric wire Coptotermes formosanus Shtrari. test method, carry out knocking down method test.
Test piece: 50mm × 50mm × 1mm.
Table 2: anti-ant performance test table
| Coptotermes formosanus Shtrari. knockdown time KT50, min | |
| Embodiment 1 | 144 |
| Embodiment 2 | 162 |
| Embodiment 3 | 170 |
| Embodiment 4 | 155 |
Visible, by 11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, Tripterygium wilfordii lactone ketone, N-(4-hydroxyl-3-methoxy
Base benzyl) the biological rat-and-ant proof agent of-8-methyl pelargonamide three kinds carries out compounding use, and Synergistic, Coptotermes formosanus Shtrari. knockdown time substantially drops
Low, anti-ant performance is good.
Test case 2
Use GB/T2951.38-1986 electric wire Coptotermes formosanus Shtrari. test method, the rat-and-ant proof PP/HDPE environmental protection to embodiment 1
Plastics carry out Colony test test.Test piece: 80mm × 25mm × 1mm.
Test result: Coptotermes formosanus Shtrari. moth erosion grade is 1 grade.
Test case 3
Test material film-making: by sample according to GB/T8815-2002 pilot scale piece preparation method make specification be 150mm ×
The test piece of 20mm × 3mm.
Testing equipment and experimental animal: weight 250-300 gram SD male rat PP plastic casing rustless steel square mouse cage, mouse cage
Specification is high 250mm, a length of 600mm, a width of 400mm, and at the bottom of mouse cage and four walls are PP plastics, top is rustless steel square, and joins
There is waterer.
Test procedure: choose SD male rat, stochastic sampling puts into mouse cage, 5, every cage；Test piece is stretched into from mouse cage top
In cage, with thin copper wire tightly colligation on the stainless (steel) wire lid at feeding, the part that test piece is exposed at beyond mouse cage is less than
20mm, a cage hangs three test pieces, and test piece is uniformly arranged on mouse cage width, and interval is about 80mm.Rat is in test
Period regular supply drinking-water and food (i.e. every day changed clear water by waterer, has remained food at feeding).Every day observes big
The activity of Mus and diet situation and test period terminate the situation that rear sample is bitten by rat.Test period is 7 days.
The rat-and-ant proof PP/HDPE environmentally-friendly plastic of embodiment 1: bite area 2%.
Claims (1)
1. a rat-and-ant proof PP/HDPE environmentally-friendly plastic, it is characterised in that be made up of by weight following component: 50 parts of PP, 30 parts
HDPE, 12-20 part EPDM, 3-5 part biology rat-and-ant proof agent；
Described biological rat-and-ant proof agent, is made up of by weight following component: 10-15 part 11,12,13,14-tetra-dehydrogenation Radix Sophorae Flavescentis
Alkali-15-ketone, 10-15 part Tripterygium wilfordii lactone ketone, 10-15 part N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310687716.9A CN103709508B (en) | 2013-12-15 | 2013-12-15 | Rat-and-ant proof PP/HDPE environmentally-friendly plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310687716.9A CN103709508B (en) | 2013-12-15 | 2013-12-15 | Rat-and-ant proof PP/HDPE environmentally-friendly plastic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103709508A CN103709508A (en) | 2014-04-09 |
| CN103709508B true CN103709508B (en) | 2016-11-23 |
Family
ID=50402885
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310687716.9A Active CN103709508B (en) | 2013-12-15 | 2013-12-15 | Rat-and-ant proof PP/HDPE environmentally-friendly plastic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103709508B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115521520A (en) * | 2022-10-21 | 2022-12-27 | 安徽电缆股份有限公司 | Termite-proof cable outer sheath material and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1301660A (en) * | 1999-12-29 | 2001-07-04 | 天津市农产品保鲜研究中心 | Special five-protective grain fresh keeping bag |
| CN1752131A (en) * | 2005-10-09 | 2006-03-29 | 广州市鹿山化工材料有限公司 | Special resin for exhaust pipe of moving air conditioner |
| CN1948388A (en) * | 2006-10-19 | 2007-04-18 | 广州华工百川自控科技有限公司 | Preparation method of ramie stem and plastic composite material |
| CN101161712A (en) * | 2007-09-03 | 2008-04-16 | 上海斯瑞聚合体科技有限公司 | Environment-friendly type ant-proof ratproof material for electric wire and cable |
| CN102649855A (en) * | 2012-05-29 | 2012-08-29 | 上海瀚氏模具成型有限公司 | Anti-ageing PP/HDPE (Polypropylene/High-Density Polyethylene) plastic for automobile interior and preparation method thereof |
| CN102775663A (en) * | 2012-08-02 | 2012-11-14 | 深圳市沃尔核材股份有限公司 | Ant- and rat-resistant radiation-crosslinked flame-retardant pyrocondensation material and manufacturing method thereof |
-
2013
- 2013-12-15 CN CN201310687716.9A patent/CN103709508B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1301660A (en) * | 1999-12-29 | 2001-07-04 | 天津市农产品保鲜研究中心 | Special five-protective grain fresh keeping bag |
| CN1752131A (en) * | 2005-10-09 | 2006-03-29 | 广州市鹿山化工材料有限公司 | Special resin for exhaust pipe of moving air conditioner |
| CN1948388A (en) * | 2006-10-19 | 2007-04-18 | 广州华工百川自控科技有限公司 | Preparation method of ramie stem and plastic composite material |
| CN101161712A (en) * | 2007-09-03 | 2008-04-16 | 上海斯瑞聚合体科技有限公司 | Environment-friendly type ant-proof ratproof material for electric wire and cable |
| CN102649855A (en) * | 2012-05-29 | 2012-08-29 | 上海瀚氏模具成型有限公司 | Anti-ageing PP/HDPE (Polypropylene/High-Density Polyethylene) plastic for automobile interior and preparation method thereof |
| CN102775663A (en) * | 2012-08-02 | 2012-11-14 | 深圳市沃尔核材股份有限公司 | Ant- and rat-resistant radiation-crosslinked flame-retardant pyrocondensation material and manufacturing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103709508A (en) | 2014-04-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106633704A (en) | Full-biodegradation mulch film for rice planting and production method thereof | |
| CN102850626A (en) | Degradable mulch film and preparation method thereof | |
| CN105885184A (en) | Foamed masterbatch used for polyolefin and preparation method thereof | |
| CN103709508B (en) | Rat-and-ant proof PP/HDPE environmentally-friendly plastic | |
| CN104341672A (en) | Special weeding film for fruit trees and preparation process of special weeding film | |
| CN103374173B (en) | Durable type mulch film | |
| CN103709586B (en) | Rat-and-ant proof PA/ABS environmentally-friendly plastic | |
| CN108276792A (en) | A kind of degradable Insulation Mulch Film and its manufacturing method containing cow dung | |
| CN106117750A (en) | Photodegradable plastics thin film | |
| CN103694668B (en) | Rat-and-ant proof PPO/PPS environmentally-friendly plastic | |
| CN103740105B (en) | Rat-and-ant proof PA/PPS environmentally-friendly plastic | |
| CN105001558A (en) | Farm-oriented anti-atomization polyvinyl chloride film and preparation method thereof | |
| CN103709706B (en) | Rat-and-ant proof PA/PC environmentally-friendly plastic | |
| CN101353455A (en) | Plastic film preventing cultivated crabs from escaping and preparation thereof | |
| CN103694661B (en) | Rat-and-ant proof PET/PC environmentally-friendly plastic | |
| CN104672709A (en) | Rat bite resistant environment-friendly cable formula | |
| CN103694678B (en) | Rat-and-ant proof PA/PAR environmentally-friendly plastic | |
| CN103709705B (en) | Rat-and-ant proof PC/HDPE environmentally-friendly plastic | |
| CN103709585B (en) | Rat-and-ant proof ABS/PC environmentally-friendly plastic | |
| CN103709707B (en) | Rat-and-ant proof PBT/PC environmentally-friendly plastic | |
| CN105084956A (en) | Method for manufacturing compound organic fertilizer through biological waste materials and organisms bred by biological waste materials | |
| CN106577704A (en) | Pyribencarb-containing fungicidal composition | |
| CN106046505A (en) | Photodegradable plastic film | |
| CN208754905U (en) | A kind of Ecocyclic cultivation system | |
| CN102239795B (en) | Bacteriostatic agricultural mulching film containing chilli powder |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170515 Address after: Tung Chung town Nansha District Guangzhou city Guangdong province 510000 Ho Chung east of the mouth Patentee after: GUANGZHOU TESHUAI HARDWARE & PLASTIC PRODUCTS CO.,LTD. Address before: 510000 unit 2414-2416, building, No. five, No. 371, Tianhe District, Guangdong, China Patentee before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Effective date of registration: 20170515 Address after: 510000 unit 2414-2416, building, No. five, No. 371, Tianhe District, Guangdong, China Patentee after: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Address before: 201107 Shanghai city Minhang District Minhang Road 88 Lane No. 1-30 building twenty-second room T157 Patentee before: SHANGHAI YUEMENG ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 510000 east side of haoyongkou, Dongyong Town, Nansha District, Guangzhou City, Guangdong Province Patentee after: Guangdong teshuai Technology Co.,Ltd. Address before: 510000 east side of haoyongkou, Dongyong Town, Nansha District, Guangzhou City, Guangdong Province Patentee before: GUANGZHOU TESHUAI HARDWARE & PLASTIC PRODUCTS CO.,LTD. |
|
| CP01 | Change in the name or title of a patent holder |