CN103694678B - Rat-and-ant proof PA/PAR environmentally-friendly plastic - Google Patents
Rat-and-ant proof PA/PAR environmentally-friendly plastic Download PDFInfo
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- CN103694678B CN103694678B CN201310687752.5A CN201310687752A CN103694678B CN 103694678 B CN103694678 B CN 103694678B CN 201310687752 A CN201310687752 A CN 201310687752A CN 103694678 B CN103694678 B CN 103694678B
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- rat
- par
- ant proof
- environmentally
- friendly plastic
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- 239000004033 plastic Substances 0.000 title claims abstract description 24
- 229920003023 plastic Polymers 0.000 title claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 241000830536 Tripterygium wilfordii Species 0.000 claims description 6
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 6
- -1 lactone ketone Chemical class 0.000 claims description 6
- 235000015398 thunder god vine Nutrition 0.000 claims description 6
- 238000012360 testing method Methods 0.000 description 18
- 241001509962 Coptotermes formosanus Species 0.000 description 8
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000005453 pelletization Methods 0.000 description 3
- 229920001230 polyarylate Polymers 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 241000256602 Isoptera Species 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 2
- 230000003203 everyday effect Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000035943 smell Effects 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 101000983122 Rattus norvegicus Pancreatic prohormone Proteins 0.000 description 1
- 241000283984 Rodentia Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000010171 animal model Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000029052 metamorphosis Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- LCCNCVORNKJIRZ-UHFFFAOYSA-N parathion Chemical compound CCOP(=S)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 LCCNCVORNKJIRZ-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000011020 pilot scale process Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001850 reproductive effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- SWOVVKGLGOOUKI-ZHGGVEMFSA-N triptonide Chemical compound O=C1OCC([C@@H]2C3)=C1CC[C@]2(C)[C@]12O[C@H]1[C@@H]1O[C@]1(C(C)C)C(=O)[C@]21[C@H]3O1 SWOVVKGLGOOUKI-ZHGGVEMFSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Catching Or Destruction (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of rat-and-ant proof PA/PAR environmentally-friendly plastic, be made up of by weight following component: 50 parts of PA, 40 parts of PAR, 57 parts of compatilizer PE g MAH, 35 parts of biological rat-and-ant proof agent.The rat-and-ant proof PA/PAR environmentally-friendly plastic of the present invention, has higher impact strength and heat distortion temperature, and has the preventing from being eaten by ant and mouse performance of excellence.
Description
Technical field
The present invention relates to a kind of plastic material, particularly relate to a kind of rat-and-ant proof PA/PAR environmentally-friendly plastic.
Background technology
Mouse as the rodent that a kind of reproductive capacity and vitality are the strongest extensively live in the world each
Area, owing to its front tooth is the most flourishing and can constantly grow, so muroid has object of nibbling to be kept its tooth
Sharp habit, the distinctive abnormal smells from the patient of plastics makes plastics become muroid often to bite object.
It is luxuriant that Coptotermes formosanus Shtrari. is also known as worm, is in the streets commonly called as flood ant (because generally occurring before raining, hence obtain one's name),
The general name of isoptera insect, about kind more than 2000.For incomplete metamorphosis manometavola and be social insect,
Coptotermes formosanus Shtrari. in each termitarium is individual up to more than million.Termite damage building construction, reservoir dam,
Mountain forest orchard, vehicle ship etc., cause the biggest loss to national economy.The distinctive abnormal smells from the patient of plastics makes to mould
Material becomes Coptotermes formosanus Shtrari. and often bites object.
Existing plastic material, in order to realize rat-and-ant proof, adds Niran, Emhorn the most in the plastic
, there is the biggest environmental pollution in the poisoning agents such as agent, and very harmful to health, and pole is not environmentally.
Summary of the invention
For above-mentioned deficiency present in prior art, the technical problem to be solved is to provide one
Plant rat-and-ant proof PA/PAR environmentally-friendly plastic.
The technical problem to be solved is achieved by the following technical solution:
A kind of rat-and-ant proof PA/PAR environmentally-friendly plastic, is made up of by weight following component: 50 parts of PA, 40
Part PAR, 5-7 part compatilizer PE-g-MAH, 3-5 part biology rat-and-ant proof agent.
Described biological rat-and-ant proof agent, is made up of by weight following component: 10-20 part 11,12,13,14-tetra-
Dehydrogenation matridinde-15-ketone, 10-20 part Tripterygium wilfordii lactone ketone, 10-20 part N-(4-hydroxy-3-methoxy benzyl
Base)-8-methyl pelargonamide.
11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, Tripterygium wilfordii lactone ketone, N-(4-hydroxy-3-methoxy
Benzyl)-8-methyl pelargonamide is uniformly mixed, and can be prepared by biological rat-and-ant proof agent.
Industry universal method can be used to be prepared the rat-and-ant proof PA/PAR environmentally-friendly plastic of the present invention,
Such as: weigh each component by proportioning, after mix homogeneously, melting mixing, extruding pelletization, i.e. obtain described
Rat-and-ant proof PA/PAR environmentally-friendly plastic.
Concrete, can be to weigh each component by proportioning, in mixer, control rotating speed under room temperature and exist
300-400 rev/min, mix 2-10 minute, proceed to after taking-up in screw extruder, at 170-180 DEG C
At a temperature of extruding pelletization, i.e. obtain described rat-and-ant proof PA/PAR environmentally-friendly plastic.
PAR, polyarylate, it is that one is heat-resist, uses temperature relatively wide, can grow at-70～+180 DEG C
Phase uses, the thermoplastic engineering plastic that anti-flammability is good.The softening temperature of polyarylate and heat decomposition temperature
(443 DEG C) differ farther out, thus can use easily injection, extrude, blowing etc. adds the processing side of heat fusing
Method.Its mechanical performance and excellent electrical property, have prominent resistance to impact.To general organic chemical, oil
Lipid is stable, is also resistant to general diluted acid, but is weak to ammonia, concentrated sulphuric acid and alkali.It is soluble in halogenated hydrocarbons and phenol
Class.Difficult combustion, good weatherability.
The rat-and-ant proof PA/PAR environmentally-friendly plastic of the present invention, has higher impact strength and heat distortion temperature, and
There is the preventing from being eaten by ant and mouse performance of excellence.
Detailed description of the invention
Embodiment 1
Each raw material is weighed according to embodiment 1-4 data corresponding in table 1.Each component is joined mixed at high speed
In machine, under room temperature, control rotating speed is at 320 revs/min, mixes 8 minutes, proceeds to screw extruder after taking-up
In, extruding pelletization at a temperature of 170 DEG C, it is thus achieved that rat-and-ant proof PA/PAR environmentally-friendly plastic.
Table 1: rat-and-ant proof PA/PAR environmental-friendplastic plastic formula list position: kilogram
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| PA resin | 50 | 50 | 50 | 50 |
| PAR resin | 40 | 40 | 40 | 40 |
| Compatilizer PE-g-MAH | 5.2 | 5.2 | 5.2 | 5.2 |
| 11,12,13,14-tetra-dehydrogenation matridinde-15-ketone | 1.6 | 2.4 | 2.4 | / |
| Tripterygium wilfordii lactone ketone | 1.6 | 2.4 | / | 2.4 |
| N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide | 1.6 | / | 2.4 | 2.4 |
11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, No. CAS: 6882-66-2.Tripterygium wilfordii lactone ketone,
No. CAS: 38647-11-9.N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide, No. CAS:
19408-84-5。
The PA66 resin of du pont company trade mark 101L selected by PA resin；Japan selected by PAR resin
The polyarylate PAR of Asahi Kasei Corporation trade mark E3000.
Test case 1
Use GB/T2951.38-1986 electric wire Coptotermes formosanus Shtrari. test method, carry out knocking down method test.
Test piece: 50mm × 50mm × 1mm.
Table 2: anti-ant performance test table
| Coptotermes formosanus Shtrari. knockdown time KT50, min | |
| Embodiment 1 | 150 |
| Embodiment 2 | 170 |
| Embodiment 3 | 177 |
| Embodiment 4 | 161 |
Visible, by 11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, Tripterygium wilfordii lactone ketone, N-(4-hydroxyl
-3-methoxy-benzyl) the biological rat-and-ant proof agent of-8-methyl pelargonamide three kinds carries out compounding use, Synergistic,
Coptotermes formosanus Shtrari. knockdown time substantially reduces, and anti-ant performance is good.
Test case 2
Use GB/T2951.38-1986 electric wire Coptotermes formosanus Shtrari. test method, the rat-and-ant proof to embodiment 1
PA/PAR environmentally-friendly plastic carries out Colony test test.Test piece: 80mm × 25mm × 1mm.
Test result: Coptotermes formosanus Shtrari. moth erosion grade is 1 grade.
Test case 3
Test material film-making: according to GB/T8815-2002 pilot scale piece preparation method, sample is made specification is
The test piece of 150mm × 20mm × 3mm.
Testing equipment and experimental animal: weight 250-300 gram SD male rat PP plastic casing stainless (steel) wire
Lid mouse cage, mouse cage specification is high 250mm, a length of 600mm, a width of 400mm, at the bottom of mouse cage and four walls
For PP plastics, top is rustless steel square, and is furnished with waterer.
Test procedure: choose SD male rat, stochastic sampling puts into mouse cage, 5, every cage；By test piece
Stretch in cage from mouse cage top, with thin copper wire tightly colligation on the stainless (steel) wire lid at feeding, examination
The part that sheet is exposed at beyond mouse cage hangs three test pieces less than 20mm, a cage, and test piece is at mouse cage width
Uniformly arranging on direction, interval is about 80mm.Rat is regular supply drinking-water and food during testing
(i.e. every day changed clear water by waterer, has remained food at feeding).Observe every day rat activity and
Diet situation and test period terminate the situation that rear sample is bitten by rat.Test period is 7 days.
The rat-and-ant proof PA/PAR environmentally-friendly plastic of embodiment 1: bite area 3%.
Claims (1)
1. a rat-and-ant proof PA/PAR environmentally-friendly plastic, it is characterised in that by following component group by weight
Become: 50 parts of PA, 40 parts of PAR, 5-7 part compatilizer PE-g-MAH, 3-5 part biology rat-and-ant proof agent；
Described biological rat-and-ant proof agent, is made up of by weight following component: 10-20 part 11,12,13,14-tetra-
Dehydrogenation matridinde-15-ketone, 10-20 part Tripterygium wilfordii lactone ketone, 10-20 part N-(4-hydroxy-3-methoxy benzyl
Base)-8-methyl pelargonamide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310687752.5A CN103694678B (en) | 2013-12-15 | 2013-12-15 | Rat-and-ant proof PA/PAR environmentally-friendly plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310687752.5A CN103694678B (en) | 2013-12-15 | 2013-12-15 | Rat-and-ant proof PA/PAR environmentally-friendly plastic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103694678A CN103694678A (en) | 2014-04-02 |
| CN103694678B true CN103694678B (en) | 2016-11-16 |
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|---|---|---|---|
| CN201310687752.5A Active CN103694678B (en) | 2013-12-15 | 2013-12-15 | Rat-and-ant proof PA/PAR environmentally-friendly plastic |
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| Country | Link |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1306750A (en) * | 2000-01-28 | 2001-08-08 | 武长安 | Herbal pesticide |
| CN102396564A (en) * | 2010-09-14 | 2012-04-04 | 陈银华 | Compound rodenticide |
| CN102746547A (en) * | 2012-04-23 | 2012-10-24 | 深圳市鑫康沃科技开发有限公司 | Capillary penetration micro irrigation material and preparation method thereof |
| CN103371171A (en) * | 2012-04-16 | 2013-10-30 | 上海韬鸿化工科技有限公司 | Biogenic emulsifiable insecticide and method for preparing same |
| CN103371169A (en) * | 2012-04-16 | 2013-10-30 | 上海韬鸿化工科技有限公司 | Sophoramine insect-preventing missible oil, sophoramine insect-preventing fabric and preparation method of fabric |
| CN103396662A (en) * | 2013-07-15 | 2013-11-20 | 上海秋橙新材料科技有限公司 | Anti-aging PA-PAR (polyamide-polyarylester) plastic alloy |
-
2013
- 2013-12-15 CN CN201310687752.5A patent/CN103694678B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1306750A (en) * | 2000-01-28 | 2001-08-08 | 武长安 | Herbal pesticide |
| CN102396564A (en) * | 2010-09-14 | 2012-04-04 | 陈银华 | Compound rodenticide |
| CN103371171A (en) * | 2012-04-16 | 2013-10-30 | 上海韬鸿化工科技有限公司 | Biogenic emulsifiable insecticide and method for preparing same |
| CN103371169A (en) * | 2012-04-16 | 2013-10-30 | 上海韬鸿化工科技有限公司 | Sophoramine insect-preventing missible oil, sophoramine insect-preventing fabric and preparation method of fabric |
| CN102746547A (en) * | 2012-04-23 | 2012-10-24 | 深圳市鑫康沃科技开发有限公司 | Capillary penetration micro irrigation material and preparation method thereof |
| CN103396662A (en) * | 2013-07-15 | 2013-11-20 | 上海秋橙新材料科技有限公司 | Anti-aging PA-PAR (polyamide-polyarylester) plastic alloy |
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| CN103694678A (en) | 2014-04-02 |
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Inventor after: Xu Yuwen Inventor before: Ding Yonghua |
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Effective date of registration: 20180103 Address after: 529060 Guangdong province Jiangmen City Jianghai District of Wenchang Garden District 94 building 107 floor wenje Patentee after: Jiangmen City Kaisheng Engineering Plastics Co.,Ltd. Address before: 201107 Shanghai city Minhang District Minhang Road 88 Lane No. 1-30 building twenty-second room T157 Patentee before: SHANGHAI YUEMENG ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd. |
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Effective date of registration: 20200917 Address after: 061000 Hebei city of Cangzhou province Cangxian before Du Sheng Zhen Shi Lou Cun Patentee after: CANGZHOU GAODA HONGYE PLASTIC PRODUCTS Co.,Ltd. Address before: 529060 Guangdong province Jiangmen City Jianghai District of Wenchang Garden District 94 building 107 floor wenje Patentee before: Jiangmen City Kaisheng Engineering Plastics Co.,Ltd. |
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Denomination of invention: Anti rat and ant PA / par environmental protection plastic Effective date of registration: 20220420 Granted publication date: 20161116 Pledgee: Bank of China Limited by Share Ltd. Cangzhou branch Pledgor: CANGZHOU GAODA HONGYE PLASTIC PRODUCTS CO.,LTD. Registration number: Y2022990000220 |
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Date of cancellation: 20220926 Granted publication date: 20161116 Pledgee: Bank of China Limited by Share Ltd. Cangzhou branch Pledgor: CANGZHOU GAODA HONGYE PLASTIC PRODUCTS CO.,LTD. Registration number: Y2022990000220 |
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Denomination of invention: Anti rat and ant PA/PAR environment-friendly plastics Effective date of registration: 20220927 Granted publication date: 20161116 Pledgee: Bank of China Limited by Share Ltd. Cangzhou branch Pledgor: CANGZHOU GAODA HONGYE PLASTIC PRODUCTS CO.,LTD. Registration number: Y2022110000232 |
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Date of cancellation: 20231109 Granted publication date: 20161116 Pledgee: Bank of China Limited by Share Ltd. Cangzhou branch Pledgor: CANGZHOU GAODA HONGYE PLASTIC PRODUCTS CO.,LTD. Registration number: Y2022110000232 |