CN103694678A - Rat/termite resistant PA/PAR environment-friendly plastic - Google Patents
Rat/termite resistant PA/PAR environment-friendly plastic Download PDFInfo
- Publication number
- CN103694678A CN103694678A CN201310687752.5A CN201310687752A CN103694678A CN 103694678 A CN103694678 A CN 103694678A CN 201310687752 A CN201310687752 A CN 201310687752A CN 103694678 A CN103694678 A CN 103694678A
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- Prior art keywords
- rat
- par
- friendly plastic
- parts
- termite
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- 239000004033 plastic Substances 0.000 title claims abstract description 26
- 229920003023 plastic Polymers 0.000 title claims abstract description 26
- 241000256602 Isoptera Species 0.000 title abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- SWOVVKGLGOOUKI-ZHGGVEMFSA-N triptonide Chemical compound O=C1OCC([C@@H]2C3)=C1CC[C@]2(C)[C@]12O[C@H]1[C@@H]1O[C@]1(C(C)C)C(=O)[C@]21[C@H]3O1 SWOVVKGLGOOUKI-ZHGGVEMFSA-N 0.000 claims description 7
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 6
- 238000012360 testing method Methods 0.000 description 20
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000000463 material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000005453 pelletization Methods 0.000 description 3
- 230000003203 everyday effect Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- JRLTTZUODKEYDH-UHFFFAOYSA-N 8-methylquinoline Chemical group C1=CN=C2C(C)=CC=CC2=C1 JRLTTZUODKEYDH-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 101000983122 Rattus norvegicus Pancreatic prohormone Proteins 0.000 description 1
- 241000283984 Rodentia Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 238000010171 animal model Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000003197 gene knockdown Methods 0.000 description 1
- 150000005826 halohydrocarbons Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 230000029052 metamorphosis Effects 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- LCCNCVORNKJIRZ-UHFFFAOYSA-N parathion Chemical compound CCOP(=S)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 LCCNCVORNKJIRZ-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000011020 pilot scale process Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Catching Or Destruction (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a rat/termite resistant PA/PAR environment-friendly plastic which consists of the following components in parts by weight: 50 parts of PA, 40 parts of PAR, 5-7 parts of compatilizer PE-g-MAH and 3-5 parts of biological rat/termite resistant agent. The rat/termite resistant PA/PAR environment-friendly plastic disclosed by the invention has relatively high impact strength and thermal deformation temperature as well as excellent resistance against rat/termite damage.
Description
Technical field
The present invention relates to a kind of plastic material, relate in particular to a kind of rat-and-ant proof PA/PAR environmentally-friendly plastic.
Background technology
Mouse extensively lives in each area in the world as a kind of reproductivity and the very strong rodent of vitality, because its front tooth is very flourishing and constantly growth, so muroid has the object of nibbling to keep the habit that its tooth is sharp, the distinctive smell of plastics makes plastics become the muroid object that often bites.
Termite also claims that worm is luxuriant, is in the streets commonly called as flood ant (because conventionally occur, hence obtaining one's name) before raining, the general name of isoptera insect, approximately kind more than 2000.For the paurometabola of incomplete metamorphosis and be social insect, the termite individuality in each termitarium can reach more than 1,000,000.Termite damage building construction, reservoir dam, mountain forest orchard, vehicle ship etc., cause very large loss to national economy.The distinctive smell of plastics makes plastics become the termite object that often bites.
Existing plastic material in order to realize rat-and-ant proof, adds the poisoning agents such as Niran, aldrin conventionally in plastics, has very large environmental pollution, and very harmful to HUMAN HEALTH, not environmental protection of the utmost point.
Summary of the invention
For above shortcomings in prior art, technical problem to be solved by this invention is to provide a kind of rat-and-ant proof PA/PAR environmentally-friendly plastic.
Technical problem to be solved by this invention is achieved by the following technical solution:
A rat-and-ant proof PA/PAR environmentally-friendly plastic, consists of by weight following component: 50 parts of PA, 40 parts of PAR, 5-7 part compatilizer PE-g-MAH, the biological rat-and-ant proof agent of 3-5 part.
Described biological rat-and-ant proof agent, consists of by weight following component: 10-20 part 11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, 10-20 part Triptonide, 10-20 part N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide.
11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone, Triptonide, N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide are uniformly mixed, and can make biological rat-and-ant proof agent.
Can adopt industry universal method to be prepared rat-and-ant proof PA/PAR environmentally-friendly plastic of the present invention, for example: by proportioning, take each component, after mixing, melting mixing, extruding pelletization, obtain described rat-and-ant proof PA/PAR environmentally-friendly plastic.
Concrete, can be for take each component by proportioning, in mixing machine, under room temperature, control rotating speed at 300-400 rev/min, mix 2-10 minute, after taking-up, proceed in screw extrusion press, extruding pelletization at 170-180 ℃ of temperature, obtains described rat-and-ant proof PA/PAR environmentally-friendly plastic.
PAR, polyarylester, is that a kind of good heat resistance, use temperature are wider, can be at-70～+ 180 ℃ life-time service, the thermoplastic engineering plastic that flame retardant resistance is good.The softening temperature of polyarylester and heat decomposition temperature (443 ℃) differ far away, therefore can adopt easily injection, extrude, the working method of the heating and melting such as blowing.Its mechanical property and electrical property are excellent, have outstanding shock-resistance.Stable to general organic chemicals, lipid, the also general diluted acid of ability, but not resistance to ammoniacal liquor, the vitriol oil and alkali.Be soluble in halohydrocarbon and phenols.Difficult combustion, good weatherability.
Rat-and-ant proof PA/PAR environmentally-friendly plastic of the present invention, has higher shock strength and heat-drawn wire, and has excellent preventing from being eaten by ant and mouse performance.
Embodiment
Embodiment 1
According to corresponding embodiment 1-4 data in table 1, take each raw material.Each component is joined in high-speed mixer, control rotating speed at 320 revs/min under room temperature, mix 8 minutes, proceed in screw extrusion press after taking-up, extruding pelletization at 170 ℃ of temperature, obtains rat-and-ant proof PA/PAR environmentally-friendly plastic.
Table 1: rat-and-ant proof PA/PAR environmentally-friendly plastic formula table unit: kilogram
| ? | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| PA resin | 50 | 50 | 50 | 50 |
| PAR resin | 40 | 40 | 40 | 40 |
| Compatilizer PE-g-MAH | 5.2 | 5.2 | 5.2 | 5.2 |
| 11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone | 1.6 | 2.4 | 2.4 | / |
| Triptonide | 1.6 | 2.4 | / | 2.4 |
| N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide | 1.6 | / | 2.4 | 2.4 |
11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone, No. CAS: 6882-66-2.Triptonide, No. CAS: 38647-11-9.N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide, No. CAS: 19408-84-5.
PA resin is selected the PA66 resin of the trade mark 101L of du pont company; PAR resin is selected the polyarylester PAR of the Japanese trade mark E3000 of Asahi Kasei Corporation.
Test case 1
Adopt GB/T2951.38-1986 electric wire termite test method, knock down method test.
Test piece: 50mm * 50mm * 1mm.
Table 2: anti-ant performance test table
| ? | Termite is knocked down time KT50, min |
| Embodiment 1 | 150 |
| Embodiment 2 | 170 |
| Embodiment 3 | 177 |
| Embodiment 4 | 161 |
Visible, by 11,12, composite use, synergy are carried out in 13,14-, tetra-dehydrogenation matridinde-15-ketone, Triptonide, N-(4-hydroxyl-3-methoxybenzy)-biological rat-and-ant proof agent of three kinds of 8-methyl pelargonamides, the termite time of knocking down obviously reduces, and anti-ant performance is good.
Test case 2
Adopt GB/T2951.38-1986 electric wire termite test method, the rat-and-ant proof PA/PAR environmentally-friendly plastic of embodiment 1 is carried out to Colony test test.Test piece: 80mm * 25mm * 1mm.
Test result: termite moth erosion grade is 1 grade.
Test case 3
Test materials film-making: sample is made to the test piece that specification is 150mm * 20mm * 3mm according to GB/T8815-2002 pilot scale piece preparation method.
Testing installation and experimental animal: weight 250-300 gram of SD male rat PP plastics casing stainless steel square mouse cage, mouse cage specification is high 250mm, long is 600mm, wide is 400mm, at the bottom of mouse cage and wall be PP plastics, top is stainless steel square, and is furnished with waterer.
Testing sequence: choose SD male rat, mouse cage is put in stochastic sampling, 5, every cage; Test piece is stretched in cage from mouse cage top, with thin copper wire tightly colligation at the stainless (steel) wire near feeding place, cover, the part that test piece is exposed at beyond mouse cage is no more than 20mm, a cage hangs three test pieces, test piece is evenly arranged on mouse cage width, and interval is approximately 80mm.Rat is at duration of test regular supply drink ArsenazoⅢ (be that every day changed clear water by waterer, feeding place has remained food).Observe the activity of rat and diet situation and test period every day and finish the situation that rear sample is bitten by rat.Test period is 7 days.
The rat-and-ant proof PA/PAR environmentally-friendly plastic of embodiment 1: area 3% bites.
Claims (2)
1. a rat-and-ant proof PA/PAR environmentally-friendly plastic, is characterized in that, following component, consists of by weight: 50 parts of PA, 40 parts of PAR, 5-7 part compatilizer PE-g-MAH, the biological rat-and-ant proof agent of 3-5 part.
2. rat-and-ant proof PA/PAR environmentally-friendly plastic as claimed in claim 1, it is characterized in that, described biological rat-and-ant proof agent, by following component, formed by weight: 10-20 part 11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone, 10-20 part Triptonide, 10-20 part N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310687752.5A CN103694678B (en) | 2013-12-15 | 2013-12-15 | Rat-and-ant proof PA/PAR environmentally-friendly plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310687752.5A CN103694678B (en) | 2013-12-15 | 2013-12-15 | Rat-and-ant proof PA/PAR environmentally-friendly plastic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103694678A true CN103694678A (en) | 2014-04-02 |
| CN103694678B CN103694678B (en) | 2016-11-16 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310687752.5A Active CN103694678B (en) | 2013-12-15 | 2013-12-15 | Rat-and-ant proof PA/PAR environmentally-friendly plastic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103694678B (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1306750A (en) * | 2000-01-28 | 2001-08-08 | 武长安 | Herbal pesticide |
| CN102396564A (en) * | 2010-09-14 | 2012-04-04 | 陈银华 | Compound rodenticide |
| CN102746547A (en) * | 2012-04-23 | 2012-10-24 | 深圳市鑫康沃科技开发有限公司 | Capillary penetration micro irrigation material and preparation method thereof |
| CN103371169A (en) * | 2012-04-16 | 2013-10-30 | 上海韬鸿化工科技有限公司 | Sophoramine insect-preventing missible oil, sophoramine insect-preventing fabric and preparation method of fabric |
| CN103371171A (en) * | 2012-04-16 | 2013-10-30 | 上海韬鸿化工科技有限公司 | Biogenic emulsifiable insecticide and method for preparing same |
| CN103396662A (en) * | 2013-07-15 | 2013-11-20 | 上海秋橙新材料科技有限公司 | Anti-aging PA-PAR (polyamide-polyarylester) plastic alloy |
-
2013
- 2013-12-15 CN CN201310687752.5A patent/CN103694678B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1306750A (en) * | 2000-01-28 | 2001-08-08 | 武长安 | Herbal pesticide |
| CN102396564A (en) * | 2010-09-14 | 2012-04-04 | 陈银华 | Compound rodenticide |
| CN103371169A (en) * | 2012-04-16 | 2013-10-30 | 上海韬鸿化工科技有限公司 | Sophoramine insect-preventing missible oil, sophoramine insect-preventing fabric and preparation method of fabric |
| CN103371171A (en) * | 2012-04-16 | 2013-10-30 | 上海韬鸿化工科技有限公司 | Biogenic emulsifiable insecticide and method for preparing same |
| CN102746547A (en) * | 2012-04-23 | 2012-10-24 | 深圳市鑫康沃科技开发有限公司 | Capillary penetration micro irrigation material and preparation method thereof |
| CN103396662A (en) * | 2013-07-15 | 2013-11-20 | 上海秋橙新材料科技有限公司 | Anti-aging PA-PAR (polyamide-polyarylester) plastic alloy |
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| Publication number | Publication date |
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| CN103694678B (en) | 2016-11-16 |
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| GR01 | Patent grant | ||
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Inventor after: Xu Yuwen Inventor before: Ding Yonghua |
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| TR01 | Transfer of patent right |
Effective date of registration: 20180103 Address after: 529060 Guangdong province Jiangmen City Jianghai District of Wenchang Garden District 94 building 107 floor wenje Patentee after: Jiangmen City Kaisheng Engineering Plastics Co.,Ltd. Address before: 201107 Shanghai city Minhang District Minhang Road 88 Lane No. 1-30 building twenty-second room T157 Patentee before: SHANGHAI YUEMENG ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd. |
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Effective date of registration: 20200917 Address after: 061000 Hebei city of Cangzhou province Cangxian before Du Sheng Zhen Shi Lou Cun Patentee after: CANGZHOU GAODA HONGYE PLASTIC PRODUCTS Co.,Ltd. Address before: 529060 Guangdong province Jiangmen City Jianghai District of Wenchang Garden District 94 building 107 floor wenje Patentee before: Jiangmen City Kaisheng Engineering Plastics Co.,Ltd. |
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Denomination of invention: Anti rat and ant PA / par environmental protection plastic Effective date of registration: 20220420 Granted publication date: 20161116 Pledgee: Bank of China Limited by Share Ltd. Cangzhou branch Pledgor: CANGZHOU GAODA HONGYE PLASTIC PRODUCTS CO.,LTD. Registration number: Y2022990000220 |
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Denomination of invention: Anti rat and ant PA/PAR environment-friendly plastics Effective date of registration: 20220927 Granted publication date: 20161116 Pledgee: Bank of China Limited by Share Ltd. Cangzhou branch Pledgor: CANGZHOU GAODA HONGYE PLASTIC PRODUCTS CO.,LTD. Registration number: Y2022110000232 |
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