CN103740105A - Rat-proof and ant-proof PA/PPS environmental protection plastic - Google Patents
Rat-proof and ant-proof PA/PPS environmental protection plastic Download PDFInfo
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- CN103740105A CN103740105A CN201310687760.XA CN201310687760A CN103740105A CN 103740105 A CN103740105 A CN 103740105A CN 201310687760 A CN201310687760 A CN 201310687760A CN 103740105 A CN103740105 A CN 103740105A
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Abstract
The invention discloses a rat-proof and ant-proof PA/PPS environmental protection plastic, which comprises the following components by weight: 30 parts of PA, 55 parts of PPS, 8-12 parts of compatilizer SEBS-g-MAH and 3-5 parts of biological rat-proof and ant-proof agent. The rat-proof and ant-proof PA/PPS environmental protection plastic has the advantages of strong impact toughness and excellent rat-proof and ant-proof performance.
Description
Technical field
The present invention relates to a kind of plastic material, relate in particular to a kind of rat-and-ant proof PA/PPS environmentally-friendly plastic.
Background technology
Mouse extensively lives in each area in the world as a kind of reproductivity and the very strong rodent of vitality, because its front tooth is very flourishing and constantly growth, so muroid has the object of nibbling to keep the habit that its tooth is sharp, the distinctive smell of plastics makes plastics become the muroid object that often bites.
Termite also claims that worm is luxuriant, is in the streets commonly called as flood ant (because conventionally occur, hence obtaining one's name) before raining, the general name of isoptera insect, approximately kind more than 2000.For the paurometabola of incomplete metamorphosis and be social insect, the termite individuality in each termitarium can reach more than 1,000,000.Termite damage building construction, reservoir dam, mountain forest orchard, vehicle ship etc., cause very large loss to national economy.The distinctive smell of plastics makes plastics become the termite object that often bites.
Existing plastic material in order to realize rat-and-ant proof, adds the poisoning agents such as Niran, aldrin conventionally in plastics, has very large environmental pollution, and very harmful to HUMAN HEALTH, not environmental protection of the utmost point.
Summary of the invention
For above shortcomings in prior art, technical problem to be solved by this invention is to provide a kind of rat-and-ant proof PA/PPS environmentally-friendly plastic.
Technical problem to be solved by this invention is achieved by the following technical solution:
A kind of rat-and-ant proof PA/PPS environmentally-friendly plastic, consists of by weight following component: 30 parts of PA, 55 parts of PPS, 8-12 part compatilizer SEBS-g-MAH, the biological rat-and-ant proof agent of 3-5 part.
Described biological rat-and-ant proof agent, consists of by weight following component: 10-30 part 11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, 10-30 part Triptonide, 10-30 part N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide.
11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone, Triptonide, N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide are uniformly mixed, and can make biological rat-and-ant proof agent.
Can adopt industry universal method to be prepared rat-and-ant proof PA/PPS environmentally-friendly plastic of the present invention, for example: by proportioning, take each component, after mixing, melting mixing, extruding pelletization, obtain described rat-and-ant proof PA/PPS environmentally-friendly plastic.
Concrete, can be for to take each component by proportioning, in mixing machine, under room temperature, control rotating speed at 300-400 rev/min, mix 2-10 minute, after taking-up, proceed in screw extrusion press, extruding pelletization at 180-200 ℃ of temperature, obtains described rat-and-ant proof PA/PPS environmentally-friendly plastic.
Polyphenylene sulfide English is abbreviated as PPS, is a kind of novel high-performance thermoplastic resin, has that physical strength is high, high temperature resistant, an advantage such as chemical proofing, difficult combustion, Heat stability is good, electrical property are good.At electronics, automobile, machinery and chemical field, be all widely used.
Rat-and-ant proof PA/PPS environmentally-friendly plastic of the present invention, impelling strength is strong, has excellent preventing from being eaten by ant and mouse performance.
Embodiment
Embodiment 1
According to corresponding embodiment 1-4 data in table 1, take each raw material.Each component is joined in high-speed mixer, control rotating speed at 320 revs/min under room temperature, mix 8 minutes, proceed in screw extrusion press after taking-up, extruding pelletization at 200 ℃ of temperature, obtains rat-and-ant proof PA/PPS environmentally-friendly plastic.
Table 1: rat-and-ant proof PA/PPS environmentally-friendly plastic formula table unit: kilogram
| ? | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| PA resin | 30 | 30 | 30 | 30 |
| PPS resin | 55 | 55 | 55 | 55 |
| Compatilizer SEBS-g-MAH | 10.2 | 10.2 | 10.2 | 10.2 |
| 11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone | 1.6 | 2.4 | 2.4 | / |
| Triptonide | 1.6 | 2.4 | / | 2.4 |
| N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide | 1.6 | / | 2.4 | 2.4 |
11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone, No. CAS: 6882-66-2.Triptonide, No. CAS: 38647-11-9.N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide, No. CAS: 19408-84-5.
PA resin is selected the PA66 resin of the trade mark 101L of du pont company; PPS resin is selected the PPS resin of the trade mark A503 of toray company.
Test case 1
Adopt GB/T2951.38-1986 electric wire termite test method, knock down method test.
Test piece: 50mm × 50mm × 1mm.
Table 2: anti-ant performance test table
| ? | Termite is knocked down time KT50, min |
| Embodiment 1 | 162 |
| Embodiment 2 | 176 |
| Embodiment 3 | 180 |
| Embodiment 4 | 170 |
Visible, by 11,12, composite use, synergy are carried out in 13,14-, tetra-dehydrogenation matridinde-15-ketone, Triptonide, N-(4-hydroxyl-3-methoxybenzy)-biological rat-and-ant proof agent of three kinds of 8-methyl pelargonamides, the termite time of knocking down obviously reduces, and anti-ant performance is good.
Test case 2
Adopt GB/T2951.38-1986 electric wire termite test method, the rat-and-ant proof PA/PPS environmentally-friendly plastic of embodiment 1 is carried out to Colony test test.Test piece: 80mm × 25mm × 1mm.
Test result: termite moth erosion grade is 1 grade.
Test case 3
Test materials film-making: sample is made to the test piece that specification is 150mm × 20mm × 3mm according to GB/T8815-2002 pilot scale piece preparation method.
Testing installation and experimental animal: weight 250-300 gram of SD male rat PP plastics casing stainless steel square mouse cage, mouse cage specification is high 250mm, long is 600mm, wide is 400mm, at the bottom of mouse cage and wall be PP plastics, top is stainless steel square, and is furnished with waterer.
Testing sequence: choose SD male rat, mouse cage is put in stochastic sampling, 5, every cage; Test piece is stretched in cage from mouse cage top, with thin copper wire tightly colligation at the stainless (steel) wire near feeding place, covering, the part that test piece is exposed at beyond mouse cage is no more than 20mm, a cage hangs three test pieces, test piece is evenly arranged on mouse cage width, and interval is approximately 80mm.Rat is at duration of test regular supply drink ArsenazoⅢ (be that every day changed clear water by waterer, feeding place has remained food).Observe the activity of rat and diet situation and test period every day and finish the situation that rear sample is bitten by rat.Test period is 7 days.
The rat-and-ant proof PA/PPS environmentally-friendly plastic of embodiment 1: the area that bites is less than 5%.
Claims (2)
1. a rat-and-ant proof PA/PPS environmentally-friendly plastic, is characterized in that, following component, consists of by weight: 30 parts of PA, 55 parts of PPS, 8-12 part compatilizer SEBS-g-MAH, the biological rat-and-ant proof agent of 3-5 part.
2. rat-and-ant proof PA/PPS environmentally-friendly plastic as claimed in claim 1, it is characterized in that, described biological rat-and-ant proof agent, by following component, formed by weight: 10-30 part 11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone, 10-30 part Triptonide, 10-30 part N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310687760.XA CN103740105B (en) | 2013-12-15 | 2013-12-15 | Rat-and-ant proof PA/PPS environmentally-friendly plastic |
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| CN201310687760.XA CN103740105B (en) | 2013-12-15 | 2013-12-15 | Rat-and-ant proof PA/PPS environmentally-friendly plastic |
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| CN103740105A true CN103740105A (en) | 2014-04-23 |
| CN103740105B CN103740105B (en) | 2016-10-19 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105238048A (en) * | 2015-10-27 | 2016-01-13 | 江门市道生工程塑料有限公司 | High-performance insulating insect/mouse-resistant modified PPS material and preparation method therefor |
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| CN1306750A (en) * | 2000-01-28 | 2001-08-08 | 武长安 | Herbal pesticide |
| CN102396564A (en) * | 2010-09-14 | 2012-04-04 | 陈银华 | Compound rodenticide |
| CN102746547A (en) * | 2012-04-23 | 2012-10-24 | 深圳市鑫康沃科技开发有限公司 | Capillary penetration micro irrigation material and preparation method thereof |
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| CN103371169A (en) * | 2012-04-16 | 2013-10-30 | 上海韬鸿化工科技有限公司 | Sophoramine insect-preventing missible oil, sophoramine insect-preventing fabric and preparation method of fabric |
| CN103371171A (en) * | 2012-04-16 | 2013-10-30 | 上海韬鸿化工科技有限公司 | Biogenic emulsifiable insecticide and method for preparing same |
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2013
- 2013-12-15 CN CN201310687760.XA patent/CN103740105B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1306750A (en) * | 2000-01-28 | 2001-08-08 | 武长安 | Herbal pesticide |
| CN102396564A (en) * | 2010-09-14 | 2012-04-04 | 陈银华 | Compound rodenticide |
| CN103371169A (en) * | 2012-04-16 | 2013-10-30 | 上海韬鸿化工科技有限公司 | Sophoramine insect-preventing missible oil, sophoramine insect-preventing fabric and preparation method of fabric |
| CN103371171A (en) * | 2012-04-16 | 2013-10-30 | 上海韬鸿化工科技有限公司 | Biogenic emulsifiable insecticide and method for preparing same |
| CN102746547A (en) * | 2012-04-23 | 2012-10-24 | 深圳市鑫康沃科技开发有限公司 | Capillary penetration micro irrigation material and preparation method thereof |
| CN103351616A (en) * | 2013-07-15 | 2013-10-16 | 上海秋橙新材料科技有限公司 | Aging-resistant PA (Polyamide) -PPS (Polyphenylene Sulfide) plastic alloy |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105238048A (en) * | 2015-10-27 | 2016-01-13 | 江门市道生工程塑料有限公司 | High-performance insulating insect/mouse-resistant modified PPS material and preparation method therefor |
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| CN103740105B (en) | 2016-10-19 |
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Inventor after: Gu Wei Inventor before: Ding Yonghua |
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Effective date of registration: 20170605 Address after: 226601 Jiangsu city of Nantong Province Economic and Technological Development Zone Branch Road No. 1-1 Patentee after: Nantong leveling macromolecule New Material Co., Ltd. Address before: 201107 Shanghai city Minhang District Minhang Road 88 Lane No. 1-30 building twenty-second room T157 Patentee before: Shanghai Yuemeng Environmental Protection Technology Co., Ltd. |