CN110467810A - A kind of preparation method of the rat-and-ant proof PA environmentally-friendly plastic of high impact - Google Patents
A kind of preparation method of the rat-and-ant proof PA environmentally-friendly plastic of high impact Download PDFInfo
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- CN110467810A CN110467810A CN201910745653.5A CN201910745653A CN110467810A CN 110467810 A CN110467810 A CN 110467810A CN 201910745653 A CN201910745653 A CN 201910745653A CN 110467810 A CN110467810 A CN 110467810A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses a kind of preparation methods of the rat-and-ant proof PA environmentally-friendly plastic of high impact, each production raw material is in parts by mass, PA40-60 parts, ABS30-50 parts, PBE20-45 parts, 4-7 parts of fused alumina zirconia, 5-8 parts of ant proof mouse repellent agent, modified styrene-butadiene -10-15 parts of styrene triblock copolymer, 7-10 parts of polycarbodiimide, 5-8 parts of mica powder, 3-5 parts of dioctyl phthalate, 5-7 parts of potassium hydrogen tartrate, 5-8 parts of fiber, 2-5 parts of magnesium phosphate, the present invention relates to PA environmentally-friendly plastic technical fields.The preparation method of the rat-and-ant proof PA environmentally-friendly plastic of the high impact is in the preparation, rigid material and remaining additive can be added, the intensity and anti-impact force of plastics can be improved, and added with one or more kinds of fibers, the toughness of plastics can be improved, and plastics are in the preparation, ant proof mouse repellent agent can be added, the rat-and-ant proof performance that plastics can significantly be promoted, can prevent plastics to be destroyed when in use, the problem for causing the components of plastics inner impaired.
Description
Technical field
The present invention relates to PA environmentally-friendly plastic technical field, the rat-and-ant proof PA environmentally-friendly plastic of specially a kind of high impact
Preparation method.
Background technique
PA plastics are the resins for fiber, meet the lightweight of downstream industry product with substituted metal, reduce wanting for cost
It asks.PA has good comprehensive performance, including mechanical property, heat resistance, wear resistance, chemical resistance and self-lubrication,
And coefficient of friction is low, there is certain anti-flammability, and it is easy to process, it is suitable for using glass fibre and other filler filling enhancing modifieds, mentions
High-performance and expansion application range.The good fluidities of PA plastics, inprocess shrinkage range and shrinking percentage are big, and directionality is obvious, Yi Fa
Raw shrinkage cavity, deformation etc., PA plastics mainly apply with automobile manufacture in terms of, electric appliance and electronic is industrial, medical instrument instrument or remaining
Aspect.
Existing PA plastic strength is poor, and impact resistance is lower, in PA plastics in use, sometimes by mouse ant
Bait and destroy, the device of plastic wraps will expose the loss that will cause property in air, but mould in existing PA
Material does not have the step of rat-and-ant proof in production, causes the rat-and-ant proof performance of PA plastics poor.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of preparations of the rat-and-ant proof PA environmentally-friendly plastic of high impact
It is poor to solve existing PA plastic strength for method, and impact resistance is lower, in PA plastics in use, sometimes by
Mouse ant baiting and destroying, and the device of plastic wraps will expose the loss that will cause property in air, but existing
PA plastics do not have the step of rat-and-ant proof in production, the problem for causing the rat-and-ant proof performance of PA plastics poor.
(2) technical solution
In order to achieve the above object, the present invention is achieved by the following technical programs: a kind of rat-and-ant proof of high impact
The preparation method of PA environmentally-friendly plastic, method the following steps are included:
Step 1 prepares production raw material；Making raw material includes PA, ABS, PBS, fused alumina zirconia powder, ant proof mouse repellent agent, modification
Styrene-butadiene-styrene triblock copolymer, polycarbodiimide, mica powder, dioctyl phthalate, tartaric acid
Hydrogen potassium, fiber and magnesium phosphate, each to make raw material in parts by mass, PA40-60 parts, ABS30-50 parts, PBE20-45 parts, fused alumina zirconia
4-7 parts, 5-8 parts of ant proof mouse repellent agent, modified styrene-butadiene -10-15 parts of styrene triblock copolymer, poly- carbonization two
7-10 parts of imines, 5-8 parts of mica powder, 3-5 parts of dioctyl phthalate, 5-7 parts of potassium hydrogen tartrate, 5-8 parts of fiber, magnesium phosphate
2-5 parts；
Step 2, raw material crush；PA, ABS, PBS are crushed using pulverizer, it is straight that PA, ABS, PBS are crushed to 1cm
Diameter or 1cm diameter particle below, the feed particles by diameter greater than 1cm or more are filtered using filter screen, will be selected
Raw material science and technology afterwards reuses pulverizer and is processed, and repeats the above steps, until underproof feed particles are less than raw material
The accounting of gross mass 3%；
Step 3, additive formulations；Smashed PA, ABS, PBS are heated, its thawing is made, then by fused alumina zirconia
Powder, modified styrene-butadiene-styrene triblock copolymer, polycarbodiimide, mica powder, dioctyl phthalate,
Potassium hydrogen tartrate and magnesium phosphate are added in raw material, are then persistently stirred, and direct material is uniformly mixed with additive, then by glass
Glass fiber and ant proof mouse repellent agent are added to again in mixed raw material, are then stirred again；
Step 4, plastics make material molding；Mixed raw material after thawing is connect with double rod extruding machine, double rod extruding machine will be former
It after material squeezes out, is cooled down through cold water, raw material is cut using cutter device immediately then, it is made to become graininess modeling
Material, then sieves particular plastics, obtains the similar regular plastic particle of diameter.
Preferably, it is contour that glass fibre, bamboo fibre, nylon fiber or asbestos fibre can be used in the fiber in the step 1
Strength, and when adding fiber, the temperature of raw material is lower than 350 DEG C.
Preferably, the stirring position of the processing agitating device in the step 2 is provided with anti-creep rod structure, anti-pole-climbing knot
The structures such as bar, hangnail can be used down in structure.
Preferably, one Phenoxyphenyl-methyl -2 can be used in the ant proof mouse repellent agent in the step 1, and add Ah
Tie up rhzomorph, asarinin and Dihydrocapsaicin.
Preferably, the fused alumina zirconia powder in the step 3, modified styrene-butadiene-styrene triblock copolymer, poly-
Carbodiimides, mica powder, dioctyl phthalate, potassium hydrogen tartrate and magnesium phosphate need mixing equal before being added to raw material
It is even.
Preferably, the glass fibre in the step 3 and ant proof mouse repellent agent need to be separated in addition launches, and ant proof mouse becomes
It keeps away agent first to be launched, then launches glass fibre, the interval launched between ant proof mouse repellent agent and glass fibre is no more than
10min。
(3) beneficial effect
The present invention provides a kind of preparation methods of the rat-and-ant proof PA environmentally-friendly plastic of high impact.Have following beneficial to effect
Fruit: the preparation method of the rat-and-ant proof PA environmentally-friendly plastic of the high impact, by by fused alumina zirconia powder, modified phenylethylene-fourth two
Alkene-styrene triblock copolymer, polycarbodiimide, mica powder, dioctyl phthalate, potassium hydrogen tartrate and magnesium phosphate
It is added in raw material, then persistently stirs, direct material is uniformly mixed with additive, then walks quickly and keeps away glass fibre and ant proof mouse
Agent is added to again in mixed raw material, is then stirred again, and the stirring position of processing agitating device is provided with anti-
Pole-climbing structure, anti-creep rod structure can be used down the structures such as bar, hangnail, glass fibre and ant proof mouse repellent agent and need to separate in addition
It launches, ant proof mouse repellent agent is first launched, then launches glass fibre, launch between ant proof mouse repellent agent and glass fibre
Interval is no more than 10min, and the plastics in the present invention can add rigid material and remaining additive, modeling can be improved in the preparation
The intensity and anti-impact force of material, and added with one or more kinds of fibers, the toughness of plastics can be improved, and plastics are being made
When standby, ant proof mouse repellent agent can be added, the rat-and-ant proof performance of plastics can be significantly promoted, plastics can be prevented when in use
It is destroyed, the problem for causing the components of plastics inner impaired.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
The embodiment of the present invention provides a kind of technical solution: a kind of preparation side of the rat-and-ant proof PA environmentally-friendly plastic of high impact
Method, method include following embodiment:
Implementation column 1
Step 1 prepares production raw material；Making raw material includes PA, ABS, PBS, fused alumina zirconia powder, ant proof mouse repellent agent, modification
Styrene-butadiene-styrene triblock copolymer, polycarbodiimide, mica powder, dioctyl phthalate, tartaric acid
Hydrogen potassium, fiber and magnesium phosphate, each to make raw material in parts by mass, PA50 parts, ABS40 parts, PBE30 parts, 5 parts of fused alumina zirconia, ant proof
6 parts of mouse repellent agent, 11 parts of modified styrene-butadiene-styrene triblock copolymer, 8 parts of polycarbodiimide, mica powder 6
Part, 4 parts of dioctyl phthalate, 6 parts of potassium hydrogen tartrate, 7 parts of fiber, 5 parts of magnesium phosphate；
Step 2, raw material crush；PA, ABS, PBS are crushed using pulverizer, PA, ABS, PBS are crushed to diameter
For the particle of 8cm, the feed particles by diameter greater than 1cm or more are filtered using filter screen, the raw material science and technology after selecting
It reuses pulverizer to be processed, repeat the above steps, until underproof feed particles are accounting for for total mass of raw material 3%
Than；
Step 3, additive formulations；Smashed PA, ABS, PBS are heated, its thawing is made, then by fused alumina zirconia
Powder, modified styrene-butadiene-styrene triblock copolymer, polycarbodiimide, mica powder, dioctyl phthalate,
Potassium hydrogen tartrate and magnesium phosphate are added in raw material, fused alumina zirconia powder, modified styrene-butadiene-styrene triblock copolymer,
Polycarbodiimide, mica powder, dioctyl phthalate, potassium hydrogen tartrate and magnesium phosphate need to mix before being added to raw material
Uniformly, it then persistently stirs, the stirring position of processing agitating device is provided with anti-creep rod structure, and anti-creep rod structure can be used down
The structures such as bar, hangnail, direct material are uniformly mixed with additive, are then added to glass fibre and ant proof mouse repellent agent again
In mixed raw material, one Phenoxyphenyl-methyl -2 are can be used in ant proof mouse repellent agent, and add avermectin, asarum rouge
The high strength fibres such as glass fibre, bamboo fibre, nylon fiber or asbestos fibre can be used in element and Dihydrocapsaicin, fiber, and
When adding fiber, the temperature of raw material is 350 DEG C, is then stirred again, glass fibre and ant proof mouse repellent agent are being added
When need to separate and launch, ant proof mouse repellent agent first be launched, then launch glass fibre, ant proof mouse repellent agent and glass fibre it
Between launch between be divided into 10min；
Step 4, plastics make material molding；Mixed raw material after thawing is connect with double rod extruding machine, double rod extruding machine will be former
It after material squeezes out, is cooled down through cold water, raw material is cut using cutter device immediately then, it is made to become graininess modeling
Material, then sieves particular plastics, obtains the similar regular plastic particle of diameter.
Implementation column 2
Step 1 prepares production raw material；Making raw material includes PA, ABS, PBS, fused alumina zirconia powder, ant proof mouse repellent agent, modification
Styrene-butadiene-styrene triblock copolymer, polycarbodiimide, mica powder, dioctyl phthalate, tartaric acid
Hydrogen potassium, fiber and magnesium phosphate, each to make raw material in parts by mass, PA55 parts, ABS40 parts, PBE35 parts, 6 parts of fused alumina zirconia, ant proof
7 parts of mouse repellent agent, 14 parts of modified styrene-butadiene-styrene triblock copolymer, 10 parts of polycarbodiimide, mica powder 7
Part, 4 parts of dioctyl phthalate, 6 parts of potassium hydrogen tartrate, 8 parts of fiber, 4 parts of magnesium phosphate；
Step 2, raw material crush；PA, ABS, PBS are crushed using pulverizer, PA, ABS, PBS are crushed to diameter
For the particle of 0.8cm, the feed particles by diameter greater than 0.8cm or more are filtered using filter screen, by the raw material after selecting
Science and technology reuses pulverizer and is processed, and repeats the above steps, until underproof feed particles are total mass of raw material 2%
Accounting；
Step 3, additive formulations；Smashed PA, ABS, PBS are heated, its thawing is made, then by fused alumina zirconia
Powder, modified styrene-butadiene-styrene triblock copolymer, polycarbodiimide, mica powder, dioctyl phthalate,
Potassium hydrogen tartrate and magnesium phosphate are added in raw material, fused alumina zirconia powder, modified styrene-butadiene-styrene triblock copolymer,
Polycarbodiimide, mica powder, dioctyl phthalate, potassium hydrogen tartrate and magnesium phosphate need to mix before being added to raw material
Uniformly, it then persistently stirs, the stirring position of processing agitating device is provided with anti-creep rod structure, and anti-creep rod structure can be used down
The structures such as bar, hangnail, direct material are uniformly mixed with additive, are then added to glass fibre and ant proof mouse repellent agent again
In mixed raw material, one Phenoxyphenyl-methyl -2 are can be used in ant proof mouse repellent agent, and add avermectin, asarum rouge
The high strength fibres such as glass fibre, bamboo fibre, nylon fiber or asbestos fibre can be used in element and Dihydrocapsaicin, fiber, and
When adding fiber, the temperature of raw material is 300 DEG C, is then stirred again, glass fibre and ant proof mouse repellent agent are being added
When need to separate and launch, ant proof mouse repellent agent first be launched, then launch glass fibre, ant proof mouse repellent agent and glass fibre it
Between launch between be divided into 7min；
Step 4, plastics make material molding；Mixed raw material after thawing is connect with double rod extruding machine, double rod extruding machine will be former
It after material squeezes out, is cooled down through cold water, raw material is cut using cutter device immediately then, it is made to become graininess modeling
Material, then sieves particular plastics, obtains the similar regular plastic particle of diameter.
Implementation column 3
Step 1 prepares production raw material；Making raw material includes PA, ABS, PBS, fused alumina zirconia powder, ant proof mouse repellent agent, modification
Styrene-butadiene-styrene triblock copolymer, polycarbodiimide, mica powder, dioctyl phthalate, tartaric acid
Hydrogen potassium, fiber and magnesium phosphate, each to make raw material in parts by mass, PA41 parts, ABS32 parts, PBE25 parts, 4 parts of fused alumina zirconia, ant proof
6 parts of mouse repellent agent, 15 parts of modified styrene-butadiene-styrene triblock copolymer, 9 parts of polycarbodiimide, mica powder 5
Part, 4 parts of dioctyl phthalate, 5 parts of potassium hydrogen tartrate, 7 parts of fiber, 4 parts of magnesium phosphate；
Step 2, raw material crush；PA, ABS, PBS are crushed using pulverizer, PA, ABS, PBS are crushed to diameter
For the particle of 0.7cm, the feed particles by diameter greater than 0.7cm or more are filtered using filter screen, by the raw material after selecting
Science and technology reuses pulverizer and is processed, and repeats the above steps, until underproof feed particles are total mass of raw material 1%
Accounting；
Step 3, additive formulations；Smashed PA, ABS, PBS are heated, its thawing is made, then by fused alumina zirconia
Powder, modified styrene-butadiene-styrene triblock copolymer, polycarbodiimide, mica powder, dioctyl phthalate,
Potassium hydrogen tartrate and magnesium phosphate are added in raw material, fused alumina zirconia powder, modified styrene-butadiene-styrene triblock copolymer,
Polycarbodiimide, mica powder, dioctyl phthalate, potassium hydrogen tartrate and magnesium phosphate need to mix before being added to raw material
Uniformly, it then persistently stirs, the stirring position of processing agitating device is provided with anti-creep rod structure, and anti-creep rod structure can be used down
The structures such as bar, hangnail, direct material are uniformly mixed with additive, are then added to glass fibre and ant proof mouse repellent agent again
In mixed raw material, one Phenoxyphenyl-methyl -2 are can be used in ant proof mouse repellent agent, and add avermectin, asarum rouge
The high strength fibres such as glass fibre, bamboo fibre, nylon fiber or asbestos fibre can be used in element and Dihydrocapsaicin, fiber, and
When adding fiber, the temperature of raw material is 280 DEG C, is then stirred again, glass fibre and ant proof mouse repellent agent are being added
When need to separate and launch, ant proof mouse repellent agent first be launched, then launch glass fibre, ant proof mouse repellent agent and glass fibre it
Between launch between be divided into 5min；
Step 4, plastics make material molding；Mixed raw material after thawing is connect with double rod extruding machine, double rod extruding machine will be former
It after material squeezes out, is cooled down through cold water, raw material is cut using cutter device immediately then, it is made to become graininess modeling
Material, then sieves particular plastics, obtains the similar regular plastic particle of diameter.
Effect implementation column 1: after product is made using the plastics in the present invention in certain producer, the impact resistance of product in testing
Other plastic products can be apparently higher than, and in strength test, the data of detection are apparently higher than the data of remaining plastic products,
And in routine use, the service life of remaining plastic product is higher than using product service life made of plastics in the present invention, and
And product made of plastics of the present invention deforms smaller when in use, practicability is stronger.
Effect implementation column 2: certain is equipped with the machine of the machine of plastic products and ordinary plastic articles in the present invention, when long
Between after use, the machines of ordinary plastic articles by mouse ant destruction it is more, area is bigger, uses plastics in the present invention
The destruction by mouse ant, protecting effect be not more preferable for the machine of product.
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality
Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation
In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to
Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those
Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment
Intrinsic element.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (7)
1. a kind of preparation method of the rat-and-ant proof PA environmentally-friendly plastic of high impact, it is characterised in that: the method includes following
Step:
Step 1 prepares production raw material；Production raw material includes PA, ABS, PBS, fused alumina zirconia powder, ant proof mouse repellent agent, modified benzene second
Alkene-butadiene-styrene triblock copolymer, polycarbodiimide, mica powder, dioctyl phthalate, potassium hydrogen tartrate,
Fiber and magnesium phosphate；
Step 2, raw material crush；PA, ABS, PBS are crushed using pulverizer, PA, ABS, PBS are crushed to 0.5cm-1cm
Particle, diameter is filtered greater than the feed particles of 1cm using filter screen, the raw material science and technology after selecting reuses powder
Broken machine is processed, and is repeated the above steps, until underproof feed particles are the accounting of total mass of raw material 1%-3%；
Step 3, additive formulations；Smashed PA, ABS, PBS are heated using process equipment, make its thawing, then will
Fused alumina zirconia powder, modified styrene-butadiene-styrene triblock copolymer, polycarbodiimide, mica powder, phthalic acid
Dioctyl ester, potassium hydrogen tartrate and magnesium phosphate are added in raw material, are then persistently stirred using process equipment, direct material and addition
Agent is uniformly mixed, and then glass fibre and ant proof mouse repellent agent are added to again in mixed raw material, then carried out again
Stirring；
Step 4, plastics make material molding；Mixed raw material after thawing is connect with double rod extruding machine, double rod extruding machine squeezes raw material
It after out, is cooled down immediately through cold water, then raw material is cut using cutter device, it is made to become particular plastics, with
Particular plastics are sieved afterwards, obtain regular plastic particle.
2. a kind of preparation method of the rat-and-ant proof PA environmentally-friendly plastic of high impact according to claim 1, feature exist
One of glass fibre, bamboo fibre, nylon fiber or asbestos fibre or a variety of can be used in: the fiber in the step 1
Combination, and when adding fiber, the temperature of raw material is 280-350 DEG C.
3. a kind of preparation method of the rat-and-ant proof PA environmentally-friendly plastic of high impact according to claim 1, feature exist
: the stirring position of the processing agitating device in the step 2 is provided with anti-creep rod structure, anti-creep rod structure using fall bar,
The combination of one or both of hangnail.
4. a kind of preparation method of the rat-and-ant proof PA environmentally-friendly plastic of high impact according to claim 1, feature exist
In: one Phenoxyphenyl-methyl -2 can be used in the ant proof mouse repellent agent in the step 1, and add avermectin, asarum rouge
Element and Dihydrocapsaicin.
5. a kind of preparation method of the rat-and-ant proof PA environmentally-friendly plastic of high impact according to claim 1, feature exist
In: fused alumina zirconia powder, modified styrene-butadiene-styrene triblock copolymer, polycarbodiimide, cloud in the step 3
Female powder, dioctyl phthalate, potassium hydrogen tartrate and magnesium phosphate need to be uniformly mixed before being added to raw material.
6. a kind of preparation method of the rat-and-ant proof PA environmentally-friendly plastic of high impact according to claim 1, feature exist
In: glass fibre and ant proof mouse repellent agent in the step 3 need to be separated when adding to be launched, and ant proof mouse repellent agent first be thrown
It puts, then launches glass fibre, be divided into 5min-10min between launching between ant proof mouse repellent agent and glass fibre.
7. a kind of preparation method of the rat-and-ant proof PA environmentally-friendly plastic of high impact according to claim 1, feature exist
In parts by mass in: each production raw material in the step 1, PA40-60 parts, ABS30-50 parts, PBE20-45 parts, fused alumina zirconia 4-
7 parts, 5-8 parts of ant proof mouse repellent agent, modified styrene-butadiene -10-15 parts of styrene triblock copolymer, two Asia of poly- carbonization
7-10 parts of amine, 5-8 parts of mica powder, 3-5 parts of dioctyl phthalate, 5-7 parts of potassium hydrogen tartrate, 5-8 parts of fiber, magnesium phosphate 2-
5 parts.
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| CN201910745653.5A CN110467810A (en) | 2019-08-13 | 2019-08-13 | A kind of preparation method of the rat-and-ant proof PA environmentally-friendly plastic of high impact |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115785658A (en) * | 2022-12-28 | 2023-03-14 | 南京勇聚新材料科技有限公司 | Rat bite preventing nylon master batch and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103709586A (en) * | 2013-12-15 | 2014-04-09 | 上海悦萌环保科技有限公司 | Rat and termite prevention PA/ABS (polyamide/acrylonitrile-butadiene-styrene) environmentally-friendly plastic |
| CN103772785A (en) * | 2014-01-03 | 2014-05-07 | 山东省塑料研究开发中心 | Polyethylene master batch for preventing ant and rat bite from damaging plastic pipelines and preparation method thereof |
| CN105295358A (en) * | 2015-12-05 | 2016-02-03 | 淄博夸克医药技术有限公司 | Ratproof and anti-termite PA-ABS environment-friendly plastic |
-
2019
- 2019-08-13 CN CN201910745653.5A patent/CN110467810A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103709586A (en) * | 2013-12-15 | 2014-04-09 | 上海悦萌环保科技有限公司 | Rat and termite prevention PA/ABS (polyamide/acrylonitrile-butadiene-styrene) environmentally-friendly plastic |
| CN103772785A (en) * | 2014-01-03 | 2014-05-07 | 山东省塑料研究开发中心 | Polyethylene master batch for preventing ant and rat bite from damaging plastic pipelines and preparation method thereof |
| CN105295358A (en) * | 2015-12-05 | 2016-02-03 | 淄博夸克医药技术有限公司 | Ratproof and anti-termite PA-ABS environment-friendly plastic |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115785658A (en) * | 2022-12-28 | 2023-03-14 | 南京勇聚新材料科技有限公司 | Rat bite preventing nylon master batch and preparation method thereof |
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Application publication date: 20191119 |