CN103691314B - A kind of deodorizing composition and application thereof - Google Patents
A kind of deodorizing composition and application thereof Download PDFInfo
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- CN103691314B CN103691314B CN201310745615.2A CN201310745615A CN103691314B CN 103691314 B CN103691314 B CN 103691314B CN 201310745615 A CN201310745615 A CN 201310745615A CN 103691314 B CN103691314 B CN 103691314B
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Abstract
The invention discloses a kind of deodorizing composition, it includes following components by weight: photocatalyst 3～15 parts, anion powder 3～10 parts, natural smell-removing material 1～10 parts, plant extract 0.5～2 parts, antibacterial 0.5～1 part, essence 0～1 part.The invention also discloses above-mentioned deodorizing composition in application.The deodorizing composition of the present invention can go to eliminate the unusual smell comprehensively, longer, and the present invention creatively by taste removal technology and paper technology, make cloth technology, granule adsorbent technology combines, above-mentioned deodorizing composition is applied to papermaking, makes in cloth and granule adsorbent field, obtain low price, easy to use, can the new indoor pollution control product of long-acting adsorption-decomposition function abnormal flavour.
Description
Technical field
The present invention relates to technical field of air purification, be specifically related to a kind of deodorizing composition and application thereof.
Background technology
At present, the product that indoor pollution is administered mainly has taste removal bag, aerosol type eliminating smell agent, air purifier and all kinds of placement
Type aromatising prods.Taste removal bag mainly utilizes activated carbon, bamboo charcoal, mineral etc. to have the function of adsorbing contaminant, with ventilative nonwoven
These adsorbing materials packed by cloth.Owing to different non-woven fabrics air permeable effects is also same, before the content ensureing packaging does not spills
Putting, even if using best non-woven fabrics, its air penetrability also only has 60%, so, the working substance in non-woven fabrics and air
In the contact range of odor molecules extremely limited, have impact on the effect of use.Aerosol type eliminating smell agent is to use the mode sprayed,
Action effect is direct, but belongs to instant taste removal product, and effect is without long-lasting, and the drop after being atomized during spraying stops
The most easily sucked by human body, affect the health of people.Air purifier is the main product of current indoor purifying, main
Dynamic purification, efficiency height, but air purifier is expensive, and need electric power, there is potential safety hazard during use,
Most of air purifiers also need to timing and change filter element, use trouble.Placed type aromatising prods mainly has gel-like, liquid
Volatilization class, the mode of this series products many employings flavouring carries out taste removal, can be effectively improved environmental odors acceptance, but can not be real
Go to eliminate the unusual smell.
In sum, in existing indoor pollution improvement field, lack a kind of cheap, can adsorption-decomposition function abnormal flavour, taste removal
Effect is direct, the simple long-acting taste removal product of occupation mode.
Summary of the invention
It is an object of the invention to overcome the defect of above-mentioned prior art, it is provided that a kind of deodorizing composition, this deodorizing composition energy
Enough adsorption-decomposition function abnormal flavour, taste removal effect is the most long-acting.
For achieving the above object, the present invention adopts the following technical scheme that
A kind of deodorizing composition, it includes following components by weight: photocatalyst 3～15 parts, anion powder 3～10
Part, natural smell-removing material 1～10 parts, plant extract 0.5～2 parts, antibacterial 0.5～1 part, essence 0～1 part.
Preferably, the deodorizing composition of the present invention includes following components by weight: photocatalyst 5～10 parts, anion
Powder 6～8 parts, natural smell-removing material 4～8 parts, plant extract 0.5～2 parts, antibacterial 0.5～1 part, essence 0～1
Part.
In the deodorizing composition of the present invention, anion powder is made up of tourmaline powder and lanthanide series, or tourmaline powder
With rare earth element composition, it is possible to make taste removal paper persistently produce anion, and dust in air and cigarette smoke mainly band are just
Electric charge, anion can be combined with these positive charges, thus play the effect of fresh air.
In the deodorizing composition of the present invention, described photocatalyst be preferably zinc oxide, titanium dioxide, titania-doped in
One or more mixing, these photocatalysts can degrade under conditions of having light natural smell-removing material absorption hydrogen sulfide, ammonia
The odor molecules such as gas, methanthiol, reaches the effect of long-acting taste removal.Photocatalyst is more preferably with doping N, Fe, Ag, Pt etc.
The titanium dioxide of element, the photocatalysis efficiency of the titanium dioxide optical catalyst that the mode of employing doping obtains is higher.
In the deodorizing composition of the present invention, described natural smell-removing material be Pulvis Talci, kieselguhr, active hargil, attapulgite,
One or more mixing in zeolite powder, silicon dioxide, these natural smell-removing materials can adsorption of hydrogen sulfide, ammonia, first sulfur
The odor molecules such as alcohol and antibacterial.
In the deodorizing composition of the present invention, described plant extract is preferably Folium Menthae extract, corn extract, Folium Camelliae sinensis extraction
One or more mixing in thing, containing compositions such as tea polyphenols, caffeine, aminoacid, menthols in these plant extracts,
These compositions can pass through the chemical reaction such as acid-base neutralization, complex reaction, oxidation reaction, decomposition reaction remove hydrogen sulfide, three
The smell substances such as methylamine.
The plant extract of the present invention can obtain by the following method: the plant extract used in the present invention uses supercritical extraction
Following the example of, supercritical extraction is the method utilizing supercritical fluid to carry out extract and separate as extractant, and supercritical fluid is temperature
Degree and pressure slightly above or by near-critical fluid between gas and liquid, such as: CO2, water etc..The present invention uses
Mainly CO2System.Method particularly includes: make supercritical CO under elevated pressure conditions2With plant contact to be extracted, and by control
Pressure and temperature makes to need extraction of substance to be dissolved in wherein, is then reducing supercritical CO by blood pressure lowering and intensification2Fluid close
Degree, allows extract separate out, thus completes extraction process.
In the deodorizing composition of the present invention, described antibacterial preferably with inorganic antiseptic, as silver ion inorganic antiseptic,
Containing zinc from inorganic antiseptic, the inorganic antiseptic of copper ions, that these inorganic antiseptics make deodorizing composition have is antibacterial
Fungicidal properties.
Another object of the present invention is to provide the application of above-mentioned deodorizing composition, this deodorizing composition is used for papermaking, nonwoven
Cloth manufactures and in solid odor absorber.
The deodorizing composition of the present invention is when papermaking, and its addition is calculated as 10%-35% by paper dry weight.
When the deodorizing composition of the present invention is used for manufacturing non-woven fabrics, its addition is the 5%-20% of fabric nonwoven cloth dry weight.
When the deodorizing composition of the present invention is used for manufacturing solid kind adsorbent, its addition accounts for the 10%-50% of adsorbent gross weight.
Compared with prior art, the invention has the beneficial effects as follows:
1, right smell-removing material and photocatalyst are combined by the deodorizing composition of the present invention, are adsorbed by natural smell-removing material
After the odor molecules such as hydrogen sulfide, ammonia, methanthiol and antibacterial, then by photocatalyst degrade under conditions of having light adsorb exist
The odor molecules such as the hydrogen sulfide of taste removal paper microcosmic surface, ammonia, methanthiol, formation absorption-decompose-adsorb again-decompose again
Long-acting taste removal mode, meanwhile, deodorizing composition adds plant extract, in plant extract containing tea polyphenols,
The compositions such as caffeine, aminoacid, menthol, these compositions can pass through acid-base neutralization, complex reaction, oxidation reaction, divide
Solve the chemical reactions such as reaction and remove the smell substance that hydrogen sulfide, trimethylamine etc. fail to be attracted by natural smell-removing material, so that
Deodorizing composition can go to eliminate the unusual smell comprehensively, longer.
2, deodorizing composition is applied in field of papermaking by the present invention, creatively taste removal technology has been combined with paper technology
Come, it is possible to obtain low price, easy to use, can the taste removal paper of long-acting adsorption-decomposition function abnormal flavour, be a kind of novel indoor
The product of pollution control.
3, deodorizing composition is applied in non-woven fabrics field by the present invention, creatively by taste removal technology with make cloth technology and be combined
Get up, it is thus achieved that low price, easy to use, can the taste removal cloth of long-acting adsorption-decomposition function abnormal flavour, be a kind of novel indoor dirty
Dye administers product.
4, deodorizing composition is applied in granule adsorbent field by the present invention, and preparing can long-acting adsorption-decomposition function abnormal flavour
Taste removal granule, is that a kind of novel indoor pollution administers product.
Detailed description of the invention
Below by being embodied as example, the present invention is described in further detail, in order to be clearly understood that the present invention is claimed
Technical scheme.
A kind of deodorizing composition, it includes following components by weight: photocatalyst 3～15 parts, anion powder 3～10
Part, natural smell-removing material 1～10 parts, plant extract 0.5～2 parts, antibacterial 0.5～1 part, essence 0～1 part.
Embodiment 1
A kind of deodorizing composition, it includes following components by weight: titanium dioxide 10 parts, anion powder 3 parts, Talcum
0.5 part of powder, 0.5 part of kieselguhr, tea extract 0.5 part, 0.5 part of Ag-carried antibacterial powder, 0.1 part of essence.
Described tea extract is to be prepared by the following: make supercritical CO under elevated pressure conditions2Contact with Folium Camelliae sinensis, and by control
Pressing pressure and temperature make to need extraction of substance, as tea polyphenols is dissolved in wherein, are then reducing super facing by blood pressure lowering and intensification
Boundary CO2The density of fluid, allows extract separate out, thus completes extraction process.
Embodiment 2
A kind of deodorizing composition, it includes following components by weight: titanium dioxide 3 parts, anion powder 6 parts, Talcum
5 parts of powder, attapulgite 5 parts, corn extract 0.5 part, 0.5 part of Ag-carried antibacterial powder.
Described corn extract is to obtain by the following method: make supercritical CO under elevated pressure conditions2With corn contact, and by control
Pressing pressure and temperature make to need extraction of substance, as aminoacid is dissolved in wherein, are then reducing super facing by blood pressure lowering and intensification
Boundary CO2The density of fluid, allows extract separate out, thus completes extraction process.
Embodiment 3
A kind of deodorizing composition, it includes following components by weight: titanium dioxide 5 parts, anion powder 8 parts, Talcum
2 parts of powder, 2 parts of kieselguhr, Folium Menthae extract 2 parts, 1 part of Ag-carried antibacterial powder, 0.1 part of essence.
Described Folium Menthae extract is to obtain by the following method: make supercritical CO under elevated pressure conditions2Contact with Herba Menthae, and by control
Pressing pressure and temperature make to need extraction of substance, as menthol is dissolved in wherein, are then reducing super facing by blood pressure lowering and intensification
Boundary CO2The density of fluid, allows extract separate out, thus completes extraction process.
Embodiment 4
A kind of deodorizing composition, it includes following components by weight: titanium dioxide 8 parts, anion powder 3 parts, activity
Hargil 5 parts, zeolite powder 5 parts, tea extract 1 part, 0.5 part of Ag-carried antibacterial powder, 1 part of essence.
Described tea extract is to obtain by the following method: make supercritical CO under elevated pressure conditions2Contact with Folium Camelliae sinensis, and by controlling
Pressure and temperature makes to need extraction of substance, as tea polyphenols is dissolved in wherein, is then reducing supercritical by blood pressure lowering and intensification
CO2The density of fluid, allows extract separate out, thus completes extraction process.
Embodiment 5
A kind of deodorizing composition, it includes titania-doped 15 parts of following components: N, anion powder 10 by weight
Part, active hargil 1 part, tea abstract 1 part, antibacterial 0.5 part, 0.5 part of essence.
Described tea extract is to obtain by the following method: make supercritical CO under elevated pressure conditions2Contact with Folium Camelliae sinensis, and by controlling
Pressure and temperature makes to need extraction of substance, as tea polyphenols is dissolved in wherein, is then reducing supercritical by blood pressure lowering and intensification
CO2The density of fluid, allows extract separate out, thus completes extraction process.
Embodiment 6
The deodorizing composition of embodiment 5 being applied in paper technology, preparing can the taste removal of adsorption-decomposition function abnormal flavour longer
Paper, concrete grammar is as follows:
1) by papermaking base material and paper making additive polishing pulping；
2) deodorizing composition of embodiment 5 is added；
3) dilute, makes paper pulp；
4) paper pulp sieves, surfs the Net, squeezes, dries；
5) batch, arrange, pack.
In above-mentioned papermaking process, the weight summation of papermaking base material and paper making additive with the weight ratio of deodorizing composition is
1.8-9:1.Described papermaking base material is natural plant fibre or synthetic fibers, preferably cotton fibre or containing cotton fibre
Old paper stock.Described paper making additive is polyacrylamide, cationic starch, high hygroscopicity fibre etc., hydroxymethyl cellulose,
One or more mixing in polyvinyl alcohol, fatty alcohol, polyoxyethylene ether methyl-monosilane.
Embodiment 7
The deodorizing composition of embodiment 3 being applied to during non-woven fabrics manufactures, preparing can the removing of adsorption-decomposition function abnormal flavour longer
Taste, concrete method is as follows: use wet method nonwoven fabric production technology to carry out.
1) fiber treatment, carry out non-woven fabrics fiber cutting off, dedusting, screening.
2) the deodorizing composition mixed pulp in fiber, auxiliary agent and example 3 after processing.
3) making beating, streaming, wet-laying, drying.
4) batch, arrange, pack.
In above-mentioned taste removal cloth production process, non-woven fabrics fiber and auxiliary agent account for the 80%-95% of total amount, and taste removal combination accounts for 5%-20%.
Described non-woven fabrics fiber is one or the combination of the synthetic fibers such as polyvinyl, polypropylene.Described auxiliary agent is dispersant polyacrylamide,
Wet reinforcing agent daiamid epoxy vinyl chloride and binder fibre, binder fibre is vinal or the one of ES fiber or group
Close.
Embodiment 8
By the taste removal combination application of embodiment 1 in solid absorption granule, preparing can the taste removal of long-acting adsorption-decomposition function abnormal flavour
Granule, concrete grammar is as follows:
1) attapulgite powder is prepared by rolling comminutor the bead of particle diameter 0.2-0.4cm, does nucleation substance.
2) taste removal in example 1 is added in combination in absorption attapulgite powder, mix homogeneously in mixer.
3) pelletize, adds nucleation substance and rolls in comminutor, add the powder body and water mixed, make glomerate taste removal
Granule
4) dry, prepared spherical taste removal granule is dried.
5) arrange, pack.
In the preparation method of above-mentioned solid taste removal granule, taste removal combination accounts for the 10%-50% of granule gross weight, and remaining is attapulgite
Powder body and water.
The announcement of book and teaching according to the above description, above-mentioned embodiment can also be entered by those skilled in the art in the invention
Row change and amendment.Therefore, the invention is not limited in detailed description of the invention disclosed and described above, to the present invention
A little modifications and changes should also be as falling in the scope of the claims of the present invention.Although additionally, this specification employing
Some specific terms, but these terms are merely for convenience of description, and the present invention does not constitute any restriction.
Claims (7)
1. a deodorizing composition, it is characterized in that including by weight following components: photocatalyst 3～15 parts, anion powder 3～10 parts, natural smell-removing material 1～10 parts, plant extract 0.5～2 parts, antibacterial 0.5～1 part, essence 0～1 part, described photocatalyst be zinc oxide, titanium dioxide, titania-doped in one or more mixing, described plant extract selects one or more mixing in Folium Camelliae sinensis, Semen Maydis, and described plant extract obtains by the following method: make supercritical CO under elevated pressure conditions2With plant contact to be extracted, and by control pressure and temperature make to need extraction of substance to be dissolved in wherein, then by blood pressure lowering and heat up reducing supercritical CO2The density of fluid, allows extract separate out, thus completes extraction process；Described natural smell-removing material is one or more mixing in Pulvis Talci, active hargil, attapulgite, silicon dioxide.
2. deodorizing composition as claimed in claim 1, it is characterised in that include following components by weight: photocatalyst 5～10 parts, anion powder 6～8 parts, natural smell-removing material 4～8 parts, plant extract 0.5～2 parts, antibacterial 0.5～1 part, essence 0～1 part.
3. deodorizing composition as claimed in claim 1 or 2, it is characterised in that: described antibacterial is inorganic antiseptic.
4. the application in papermaking, non-woven fabrics and granule adsorbent of the deodorizing composition described in claim 1.
Apply the most as claimed in claim 4, it is characterised in that: the described deodorizing composition 10%-35% that addition is paper dry weight when papermaking.
Apply the most as claimed in claim 4, it is characterised in that: described deodorizing composition addition in time manufacturing non-woven fabrics is 5%-20%.
Apply the most as claimed in claim 4, it is characterised in that: described deodorizing composition addition for time prepared by granule adsorbent is 10%-50%.
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