CN103668985A - Ultraviolet-resistant three-proofing finishing agent - Google Patents

Ultraviolet-resistant three-proofing finishing agent Download PDF

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Publication number
CN103668985A
CN103668985A CN201310610487.0A CN201310610487A CN103668985A CN 103668985 A CN103668985 A CN 103668985A CN 201310610487 A CN201310610487 A CN 201310610487A CN 103668985 A CN103668985 A CN 103668985A
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Prior art keywords
parts
finishing agent
ultraviolet
resistant
proofing
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CN201310610487.0A
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CN103668985B (en
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朱卫强
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JIANGSU ZHONGXIN RESOURCES GROUP Co Ltd
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JIANGSU ZHONGXIN RESOURCES GROUP Co Ltd
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Abstract

The invention relates to an ultraviolet-resistant three-proofing finishing agent and belongs to the technical field of textile auxiliaries. The ultraviolet-resistant three-proofing finishing agent comprises the following components in parts by weight: 12-16 parts of fluorocarbon emulsion, 8-12 parts of trifluoropropylmethylcyclotrisiloxane, 2-5 parts of a coupling agent, 1-3 parts of citric acid, 4-7 parts of 2-hydroxyl-4-methoxybenzophenone, 2-5 parts of bis-(2,2,6,6-tetramethyl-4-piperidyl)sebate, 3-5 parts of fat acid polyethenoxy ester and 120-150 parts of deionized water. The system of the ultraviolet-resistant three-proofing finishing agent provided by the invention is stable, and the ultraviolet-resistant three-proofing finishing agent not only has good water-proofing, oil-proofing and fouling-proofing functions, but also has a good ultraviolet-resisting function, and is easy to popularize and apply; a fabric finished by the ultraviolet-resistant three-proofing finishing agent touches better.

Description

A kind of uvioresistant three-proof finishing agent
Technical field
The invention belongs to textile auxiliary technical field, be specifically related to a kind of uvioresistant three-proof finishing agent.
Background technology
Three-proof finishing agent is a kind of fabric that is applicable to the fabrics such as cotton, hair, silk, chemical fibre and blend fibre, gives the spinning post-finishing agent that it has super water and oil repellant and anti-pollution function.So-called three prevent being waterproof, grease proofing and antifouling.Fabric feeling after traditional three-proof finishing agent arranges is stiff, and does not have anti-ultraviolet function.Therefore how overcoming the deficiencies in the prior art is problems that current textile auxiliary technical field is needed solution badly.
Summary of the invention
The object of the invention is, in order to solve the deficiencies in the prior art, provides a kind of uvioresistant three-proof finishing agent, and this finishing agent not only has good waterproof, grease proofing and anti-pollution function, also has uvioresistant effect.
The technical solution used in the present invention is as follows:
A kind of uvioresistant three-proof finishing agent, comprise the following component according to parts by weight meter: 4 ~ 7 parts of 12 ~ 16 parts of fluorine carbon emulsions, 8 ~ 12 parts of trifluoro propyl methyl cyclotrisiloxane, 2 ~ 5 parts of coupling agents, 1 ~ 3 part of citric acid, ESCALOL 567, two (2,2,6,6-tetramethyl-4-piperidyl) 2 ~ 5 parts of sebacates, 3 ~ 5 parts of polyoxyethylene carboxylates, 120 ~ 150 parts of deionized waters.
Further preferably described coupling agent is silane coupler.
Further preferably described silane coupler is γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane.
The preparation method of above-mentioned uvioresistant three-proof finishing agent is by deionized water, fluorine carbon emulsion, trifluoro propyl methyl cyclotrisiloxane, ESCALOL 567, two (2,2,6,6-tetramethyl-4-piperidyl) sebacate and coupling agent be placed in stirrer for mixing evenly after, add again polyoxyethylene carboxylate and citric acid, continue to be stirred to and mix, obtain uvioresistant three-proof finishing agent of the present invention.
compared with prior art, its beneficial effect is in the present invention:uvioresistant finishing agent stable system of the present invention, not only has good waterproof, grease proofing and anti-pollution function, also has good anti-ultraviolet function, and the fabric feeling after arrangement is better, is easy to apply.
Specific embodiment
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment 1
A kind of uvioresistant three-proof finishing agent, comprise the following component according to parts by weight meter: 12 parts of fluorine carbon emulsions, 8 parts of trifluoro propyl methyl cyclotrisiloxane, γ-(2,3-epoxy the third oxygen) 4 parts of 2 parts of propyl trimethoxy silicanes, 1 part of citric acid, ESCALOL 567, two (2,2,6,6-tetramethyl-4-piperidyl) 2 parts of sebacates, 3 parts of polyoxyethylene carboxylates, 120 parts of deionized waters.
The preparation method of the uvioresistant three-proof finishing agent of the present embodiment is by deionized water, fluorine carbon emulsion, trifluoro propyl methyl cyclotrisiloxane, ESCALOL 567, two (2,2,6,6-tetramethyl-4-piperidyl) sebacate and γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane be placed in stirrer for mixing evenly after, add again polyoxyethylene carboxylate and citric acid, continue to be stirred to and mix, obtain the uvioresistant three-proof finishing agent of the present embodiment.
Embodiment 2
A kind of uvioresistant three-proof finishing agent, comprise the following component according to parts by weight meter: 16 parts of fluorine carbon emulsions, 12 parts of trifluoro propyl methyl cyclotrisiloxane, γ-(2,3-epoxy the third oxygen) 7 parts of 5 parts of propyl trimethoxy silicanes, 3 parts of citric acids, ESCALOL 567, two (2,2,6,6-tetramethyl-4-piperidyl) 5 parts of sebacates, 5 parts of polyoxyethylene carboxylates, 150 parts of deionized waters.
The preparation method of the uvioresistant three-proof finishing agent of the present embodiment is identical with the preparation method of the uvioresistant three-proof finishing agent of embodiment 1.
Embodiment 3
A kind of uvioresistant three-proof finishing agent, comprise the following component according to parts by weight meter: 14 parts of fluorine carbon emulsions, 10 parts of trifluoro propyl methyl cyclotrisiloxane, γ-(2,3-epoxy the third oxygen) 6 parts of 4 parts of propyl trimethoxy silicanes, 2 parts of citric acids, ESCALOL 567, two (2,2,6,6-tetramethyl-4-piperidyl) 3 parts of sebacates, 4 parts of polyoxyethylene carboxylates, 130 parts of deionized waters.
The preparation method of the uvioresistant three-proof finishing agent of the present embodiment is identical with the preparation method of the uvioresistant three-proof finishing agent of embodiment 1.
Adopt the white gauze of cotton to test, by in the uvioresistant three-proof finishing agent of the embodiment of the present invention 1 ~ 3 of the white gauze immersion of cotton 20 ~ 30g/L, pick-up is 70%, dry at 120 ℃, then according to the method for AATCC-22 and AATCC-118, it is refused water and refuses oily performance test, according to the method for GB-T 18830-2002, carry out anti-ultraviolet performance test, its test result is shown in Table 1 simultaneously.
The performance detection data of the uvioresistant three-proof finishing agent of table 1 embodiment 1 ~ 3
? Refuse water Refuse oil UPF T(UVA)av
Embodiment 1 95 6 62 <5%
Embodiment 2 100 4 60 <5%
Embodiment 3 100 5 61 <5%

Claims (3)

1. a uvioresistant three-proof finishing agent, it is characterized in that comprising the following component according to parts by weight meter: 4 ~ 7 parts of 12 ~ 16 parts of fluorine carbon emulsions, 8 ~ 12 parts of trifluoro propyl methyl cyclotrisiloxane, 2 ~ 5 parts of coupling agents, 1 ~ 3 part of citric acid, ESCALOL 567, two (2,2,6,6-tetramethyl-4-piperidyl) 2 ~ 5 parts of sebacates, 3 ~ 5 parts of polyoxyethylene carboxylates, 120 ~ 150 parts of deionized waters.
2. uvioresistant three-proof finishing agent according to claim 1, is characterized in that described coupling agent is silane coupler.
3. uvioresistant three-proof finishing agent according to claim 1, is characterized in that described silane coupler is γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane.
CN201310610487.0A 2013-11-27 2013-11-27 A kind of uvioresistant three-proof finishing agent Active CN103668985B (en)

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104452291A (en) * 2014-12-23 2015-03-25 常熟市华博毛纺织有限公司 Finishing process of wool fabric
CN105603743A (en) * 2016-02-26 2016-05-25 苏州三和开泰花线织造有限公司 Lasting efficient anti-ultraviolet finishing agent and preparation method thereof
CN105648776A (en) * 2016-04-01 2016-06-08 吴江市林旺纺织厂 Antibacterial and anti-ultraviolet finishing agent and method for preparing same
CN107604510A (en) * 2017-10-13 2018-01-19 江苏美恒纺织实业有限公司 One kind is breathed freely and uvioresistant fabrics and its manufacture method
CN107740217A (en) * 2017-10-13 2018-02-27 江苏美恒纺织实业有限公司 A kind of multifunctional fabric and its manufacture method
CN108505347A (en) * 2018-04-25 2018-09-07 肖玉杰 Breathable fabric
CN108589297A (en) * 2018-04-25 2018-09-28 肖玉杰 Ventilative comfortable women's dress and its processing technology
CN108729216A (en) * 2018-05-29 2018-11-02 安徽英士博纺织发展有限公司 A kind of rapid-curing cutback clothing fabric anti-ultraviolet finishing liquid
CN109056156A (en) * 2018-10-17 2018-12-21 南通薇星纺织科技有限公司 UV protection polyester cotton shell fabric and preparation method thereof
CN111434490A (en) * 2019-04-30 2020-07-21 浙江东进新材料有限公司 Foaming breathable film composite multifunctional fabric
CN112921444A (en) * 2021-03-09 2021-06-08 许玉华 Anti-ultraviolet functional fiber and preparation process thereof
CN114771074A (en) * 2022-05-23 2022-07-22 绍兴精绣布艺有限公司 Curtain fabric and preparation process thereof
CN115045106A (en) * 2022-05-10 2022-09-13 嘉兴元祯化工有限公司 Ultraviolet-proof three-proofing finishing agent for fabric, preparation method and use method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1763302A (en) * 2005-08-09 2006-04-26 西安华捷科技发展有限责任公司 Nano compound, multifunctional oil-resistant, waterproof ultraviolet-resistant textile finishing agent and preparation method thereof
CN101696548A (en) * 2009-10-15 2010-04-21 浙江理工大学 Wideband, uvioresistant and highly lightfast finishing agent as well as preparation method and application thereof
CN102585145A (en) * 2012-02-21 2012-07-18 黑龙江泰纳科技发展有限责任公司 Three-protection anti-microbial finishing agent and preparation method thereof
JP2013036136A (en) * 2011-08-08 2013-02-21 Komatsu Seiren Co Ltd Water and oil repellent fabric with stain release property
CN103102447A (en) * 2012-12-14 2013-05-15 常熟市琴达针织印染有限公司 Preparation method of water/alcohol/blood proof finishing agent for fabrics

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1763302A (en) * 2005-08-09 2006-04-26 西安华捷科技发展有限责任公司 Nano compound, multifunctional oil-resistant, waterproof ultraviolet-resistant textile finishing agent and preparation method thereof
CN101696548A (en) * 2009-10-15 2010-04-21 浙江理工大学 Wideband, uvioresistant and highly lightfast finishing agent as well as preparation method and application thereof
JP2013036136A (en) * 2011-08-08 2013-02-21 Komatsu Seiren Co Ltd Water and oil repellent fabric with stain release property
CN102585145A (en) * 2012-02-21 2012-07-18 黑龙江泰纳科技发展有限责任公司 Three-protection anti-microbial finishing agent and preparation method thereof
CN103102447A (en) * 2012-12-14 2013-05-15 常熟市琴达针织印染有限公司 Preparation method of water/alcohol/blood proof finishing agent for fabrics

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104452291A (en) * 2014-12-23 2015-03-25 常熟市华博毛纺织有限公司 Finishing process of wool fabric
CN105603743A (en) * 2016-02-26 2016-05-25 苏州三和开泰花线织造有限公司 Lasting efficient anti-ultraviolet finishing agent and preparation method thereof
CN105648776A (en) * 2016-04-01 2016-06-08 吴江市林旺纺织厂 Antibacterial and anti-ultraviolet finishing agent and method for preparing same
CN107604510A (en) * 2017-10-13 2018-01-19 江苏美恒纺织实业有限公司 One kind is breathed freely and uvioresistant fabrics and its manufacture method
CN107740217A (en) * 2017-10-13 2018-02-27 江苏美恒纺织实业有限公司 A kind of multifunctional fabric and its manufacture method
CN108589297A (en) * 2018-04-25 2018-09-28 肖玉杰 Ventilative comfortable women's dress and its processing technology
CN108505347A (en) * 2018-04-25 2018-09-07 肖玉杰 Breathable fabric
CN108729216A (en) * 2018-05-29 2018-11-02 安徽英士博纺织发展有限公司 A kind of rapid-curing cutback clothing fabric anti-ultraviolet finishing liquid
CN109056156A (en) * 2018-10-17 2018-12-21 南通薇星纺织科技有限公司 UV protection polyester cotton shell fabric and preparation method thereof
CN111434490A (en) * 2019-04-30 2020-07-21 浙江东进新材料有限公司 Foaming breathable film composite multifunctional fabric
CN111434490B (en) * 2019-04-30 2021-10-01 浙江东进新材料有限公司 Foaming breathable film composite multifunctional fabric
CN112921444A (en) * 2021-03-09 2021-06-08 许玉华 Anti-ultraviolet functional fiber and preparation process thereof
CN112921444B (en) * 2021-03-09 2023-02-03 无锡市世纪风服饰有限公司 Anti-ultraviolet functional fiber and preparation process thereof
CN115045106A (en) * 2022-05-10 2022-09-13 嘉兴元祯化工有限公司 Ultraviolet-proof three-proofing finishing agent for fabric, preparation method and use method
CN114771074A (en) * 2022-05-23 2022-07-22 绍兴精绣布艺有限公司 Curtain fabric and preparation process thereof

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