CN103665404A - Method for modifying natural emulsion adopting compound of sodium alginate and prolamine - Google Patents
Method for modifying natural emulsion adopting compound of sodium alginate and prolamine Download PDFInfo
- Publication number
- CN103665404A CN103665404A CN201310605715.5A CN201310605715A CN103665404A CN 103665404 A CN103665404 A CN 103665404A CN 201310605715 A CN201310605715 A CN 201310605715A CN 103665404 A CN103665404 A CN 103665404A
- Authority
- CN
- China
- Prior art keywords
- sodium alginate
- prolamine
- emulsion
- natural emulsion
- molten albumen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 239000000839 emulsion Substances 0.000 title claims abstract description 25
- 235000010413 sodium alginate Nutrition 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 title claims abstract description 14
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 229940005550 sodium alginate Drugs 0.000 title claims abstract description 12
- 239000000661 sodium alginate Substances 0.000 title claims abstract description 12
- 150000001875 compounds Chemical class 0.000 title abstract 5
- 108090000623 proteins and genes Proteins 0.000 claims abstract description 8
- 102000004169 proteins and genes Human genes 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 27
- 229910052708 sodium Inorganic materials 0.000 claims description 27
- 239000011734 sodium Substances 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 20
- 239000008267 milk Substances 0.000 claims description 16
- 210000004080 milk Anatomy 0.000 claims description 16
- 235000013336 milk Nutrition 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 12
- 239000012528 membrane Substances 0.000 claims description 11
- 108010010803 Gelatin Proteins 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 229920000159 gelatin Polymers 0.000 claims description 5
- 239000008273 gelatin Substances 0.000 claims description 5
- 235000019322 gelatine Nutrition 0.000 claims description 5
- 235000011852 gelatine desserts Nutrition 0.000 claims description 5
- 239000004816 latex Substances 0.000 claims description 5
- 229920000126 latex Polymers 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 229920002494 Zein Polymers 0.000 claims description 4
- 239000005019 zein Substances 0.000 claims description 4
- 229940093612 zein Drugs 0.000 claims description 4
- 108010061711 Gliadin Proteins 0.000 claims description 3
- 241000209140 Triticum Species 0.000 claims description 3
- 235000021307 Triticum Nutrition 0.000 claims description 3
- 206010020751 Hypersensitivity Diseases 0.000 abstract description 2
- 208000026935 allergic disease Diseases 0.000 abstract description 2
- 230000007815 allergy Effects 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract 1
- 230000008014 freezing Effects 0.000 abstract 1
- 238000007710 freezing Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000004073 vulcanization Methods 0.000 abstract 1
- 230000032683 aging Effects 0.000 description 2
- 230000003266 anti-allergic effect Effects 0.000 description 2
- HZWWPUTXBJEENE-UHFFFAOYSA-N 5-amino-2-[[1-[5-amino-2-[[1-[2-amino-3-(4-hydroxyphenyl)propanoyl]pyrrolidine-2-carbonyl]amino]-5-oxopentanoyl]pyrrolidine-2-carbonyl]amino]-5-oxopentanoic acid Chemical compound C1CCC(C(=O)NC(CCC(N)=O)C(=O)N2C(CCC2)C(=O)NC(CCC(N)=O)C(O)=O)N1C(=O)C(N)CC1=CC=C(O)C=C1 HZWWPUTXBJEENE-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003570 biosynthesizing effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
Landscapes
- Medicinal Preparation (AREA)
Abstract
A method for modifying a natural emulsion adopting a compound of sodium alginate and prolamine comprises the following steps: (1) preparing the protein compound of sodium alginate and prolamine: dissolving sodium alginate in water, adding prolamine into the solution, mixing uniformly, freezing, drying, and heating the frozen and dried product at 30 DEG C for 30 min to obtain the compound of sodium alginate and prolamine for later use; (2) preparing modified emulsion film: preparing a water solution of covalent compound of sodium alginate and prolamine, mixing the solution and the natural emulsion uniformly, performing emulsion film vulcanization treatment, concreting to form at 70 DEG C when the emulsion solution is stable and generates no bubbles to obtain the modified emulsion film. The natural emulsion prepared by the invention has age resistance and allergy resistance.
Description
technical field
The present invention relates to a kind of method of modifying of natural emulsion, particularly the method for the molten albumen composition modified natural emulsion of a kind of sodium alginate-ol, belongs to natural macromolecular material manufacture field.
technical background
Natural emulsion is a kind of through biosynthesizing, reproducible natural resources, is widely used in the products such as medical catheter, medical gloves and condom because of excellent over-all properties.But natural emulsion is because of containing unsaturated double-bond, make its oil-proofness, ageing resistance poor, micro-water-soluble protein wherein causes that human allergy reacts.
Summary of the invention
The object of this invention is to provide a kind of method of modifying of preparing the natural emulsion of ageing resistance, antiallergic property.
For realizing above object, the method for the molten albumen composition modified natural emulsion of a kind of sodium alginate-ol of the present invention, step is:
(1) preparation of the molten albumen composition of sodium alginate-ol: sodium alginate is dissolved in water, in solution, add prolamine, mix postlyophilization, then lyophilized products is placed at 30 ℃ and heats 30min, obtain the molten albumen covalent complex of sodium alginate-ol standby;
(2) preparation of modified milk glued membrane: the molten albumen covalent complex of the preparation sodium alginate-ol aqueous solution, with natural milk gelatin mixing and stirring, carry out latex film sulfidizing, after emulsion-stabilizing is without bubble, at 70 ℃, pour into a mould film forming, obtain modified milk glued membrane.
Preferably, prolamine is zein or wheat gliadin; The mass ratio of sodium alginate and prolamine is 10:1-20:1; The add-on of the molten albumen covalent complex of sodium alginate-ol is the 1%-3% of natural emulsion quality.
The beneficial effect that the present invention produces is that sodium alginate has good biocompatibility and biodegradability, has good affinity with human body skin.Prolamine has good biocompatibility, oxidation-resistance.Utilize various active group in sodium alginate and prolamine molecule to the protein cross sex change in natural emulsion, reduce water-soluble protein spillage, give modified milk glued membrane antiallergic property.
Embodiment
Embodiment 1:
A method for the molten albumen composition modified natural emulsion of sodium alginate-ol, step is:
(1) preparation of the molten protein mixture of sodium alginate-ol: 20 parts of sodium alginates are dissolved in water, in solution, add 2 parts of zein, mix postlyophilization, then lyophilized products is placed at 30 ℃ and heats 30min, obtain the molten albumen covalent complex of sodium alginate-ol standby;
(2) preparation of modified milk glued membrane: the molten albumen covalent complex of above-mentioned sodium alginate-ol is formulated as to the aqueous solution, with 2000 parts of natural milk gelatin mixing and stirring, carry out latex film sulfidizing, after emulsion-stabilizing is without bubble, at 70 ℃, pour into a mould film forming, obtain modified milk glued membrane.More than be weight part.
Embodiment 2:
A method for the molten albumen composition modified natural emulsion of sodium alginate-ol, step is:
(1) preparation of the molten protein mixture of sodium alginate-ol: 20 parts of sodium alginates are dissolved in water, in solution, add 2 portions of wheat gliadins, mix postlyophilization, then lyophilized products is placed at 30 ℃ and heats 30min, obtain the molten albumen covalent complex of sodium alginate-ol standby;
(2) preparation of modified milk glued membrane: the molten albumen covalent complex of above-mentioned sodium alginate-ol is formulated as to the aqueous solution, with 1500 parts of natural milk gelatin mixing and stirring, carry out latex film sulfidizing, after emulsion-stabilizing is without bubble, at 70 ℃, pour into a mould film forming, obtain modified milk glued membrane.More than be weight part.
Embodiment 3:
A method for the molten albumen composition modified natural emulsion of sodium alginate-ol, step is:
(1) preparation of the molten protein mixture of sodium alginate-ol: 20 parts of sodium alginates are dissolved in water, in solution, add 1 part of zein, mix postlyophilization, then lyophilized products is placed at 30 ℃ and heats 30min, obtain the molten albumen covalent complex of sodium alginate-ol standby;
(2) preparation of modified milk glued membrane: the molten albumen covalent complex of above-mentioned sodium alginate-ol is formulated as to the aqueous solution, with 800 parts of natural milk gelatin mixing and stirring, carry out latex film sulfidizing, after emulsion-stabilizing is without bubble, at 70 ℃, pour into a mould film forming, obtain modified milk glued membrane.More than be weight part.
Claims (4)
1. a method for the molten albumen composition modified natural emulsion of sodium alginate-ol, is characterized in that: step is:
The preparation of the molten protein mixture of sodium alginate-ol: sodium alginate is dissolved in water, in solution, add prolamine, mix postlyophilization, then lyophilized products is placed at 30 ℃ and heats 30min, obtain the molten albumen covalent complex of sodium alginate-ol standby;
The preparation of modified milk glued membrane: the molten albumen covalent complex of the preparation sodium alginate-ol aqueous solution, with natural milk gelatin mixing and stirring, carry out latex film sulfidizing, after emulsion-stabilizing is without bubble, at 70 ℃, pour into a mould film forming, obtain modified milk glued membrane.
2. the method for the molten albumen composition modified natural emulsion of a kind of sodium alginate-ol as claimed in claim 1, is characterized in that: described prolamine is zein or wheat gliadin.
3. the method for the molten albumen composition modified natural emulsion of a kind of sodium alginate-ol as claimed in claim 1, is characterized in that: the mass ratio of described sodium alginate and prolamine is 10:1-20:1.
4. the method for the molten albumen composition modified natural emulsion of a kind of sodium alginate-ol as claimed in claim 1, is characterized in that: the add-on of the molten albumen covalent complex of described sodium alginate-ol is the 1%-3% of natural emulsion quality.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310605715.5A CN103665404B (en) | 2013-11-26 | 2013-11-26 | A kind of method of modifying natural emulsion adopting compound of sodium alginate and prolamine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310605715.5A CN103665404B (en) | 2013-11-26 | 2013-11-26 | A kind of method of modifying natural emulsion adopting compound of sodium alginate and prolamine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103665404A true CN103665404A (en) | 2014-03-26 |
| CN103665404B CN103665404B (en) | 2016-10-19 |
Family
ID=50304249
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310605715.5A Active CN103665404B (en) | 2013-11-26 | 2013-11-26 | A kind of method of modifying natural emulsion adopting compound of sodium alginate and prolamine |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103665404B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111286038A (en) * | 2020-04-09 | 2020-06-16 | 武汉轻工大学 | Preparation method and application of polyglycerol-modified zein |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102093722A (en) * | 2011-01-17 | 2011-06-15 | 四川大学 | Edible collagen food packaging film and preparation method thereof |
-
2013
- 2013-11-26 CN CN201310605715.5A patent/CN103665404B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102093722A (en) * | 2011-01-17 | 2011-06-15 | 四川大学 | Edible collagen food packaging film and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111286038A (en) * | 2020-04-09 | 2020-06-16 | 武汉轻工大学 | Preparation method and application of polyglycerol-modified zein |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103665404B (en) | 2016-10-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105646951A (en) | Method for preparing functional soluble and edible compound membranes | |
| CN103961335B (en) | Pulullan polysaccharide soft capsule and preparation method thereof | |
| CN103724709A (en) | Method for modifying natural latex with pullulan oxide-sericin compound | |
| WO2018171630A1 (en) | Composite starch 3d printing material preparation and process | |
| HRP20220638T1 (en) | The method of obtaining the aqueous solution of chitosan, chitosan composition, chitosan aerosol, the method of producing the chitosan hydrogel membrane and the method of producing chitosan-protein biopolymer material | |
| CN100559959C (en) | A kind of composite modifying method of natural wheat protein and the application in starch food products | |
| CN103961334A (en) | Pulullan hollow hard capsule and preparation method thereof | |
| CN103642086B (en) | The method of the molten protein modified natural emulsion of a kind of pullulan oxide-ol | |
| CN103694489B (en) | The preparation method of the molten albumen of a kind of pulullan polysaccharide-ol and organic silicon composite modified natural emulsion | |
| CN106729728A (en) | A kind of Capsules plant amylum composition | |
| RU2013141169A (en) | GELATING COLLAGEN AND MEANS FOR PREPARING IT | |
| CN104262654B (en) | Preparation method of soybean protein isolate-modified zein composite film | |
| CN103665404A (en) | Method for modifying natural emulsion adopting compound of sodium alginate and prolamine | |
| CN102975321B (en) | Method for preparing condom by using polyisoprene rubber latex | |
| WO2017197774A1 (en) | Film-forming composition, soft- and hard-shelled capsule manufactured using the composition, and manufacturing method thereof | |
| CN103665466B (en) | The method of a kind of sodium alginate-silk gum mixture modified natural emulsion | |
| KR101602049B1 (en) | Method for production of double layer hydrogel mask pack | |
| CN108902267A (en) | One kind is based on consumption animal collagen casing and preparation method thereof | |
| CN102250368A (en) | Edible collagen-based food packaging film and preparation method thereof | |
| CN104151637A (en) | Foamed rubber | |
| JP2019518474A5 (en) | ||
| CN103877587B (en) | Medicinal enteric hard-shell capsule of a kind of vegetable polysaccharides and preparation method thereof | |
| CN103642085B (en) | The method of the molten albumen of a kind of sodium alginate-ol and organic-silicon-modified natural emulsion | |
| CN105638850A (en) | Freshness-retaining film for meat product and preparation method of freshness-retaining film | |
| CN105250235A (en) | Carrageenan plant soft capsule material and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Chen Hui Inventor before: Su Jianli |
|
| CB03 | Change of inventor or designer information | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170515 Address after: 510000 unit 2414-2416, building, No. five, No. 371, Tianhe District, Guangdong, China Patentee after: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Address before: 266061 Shandong, Laoshan, Hongkong East Road, No. Pioneering Park, biological park, room 248, No. 239 Patentee before: QINGDAO WINCHANCE TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170607 Address after: Baiyun District of Guangzhou City, Guangdong province 510000 Xicha step North Garden B2 block two layer ladder Patentee after: GUANGDONG SELLMAN ECONOMIC DEVELOPMENT CO.,LTD. Address before: 510000 unit 2414-2416, building, No. five, No. 371, Tianhe District, Guangdong, China Patentee before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210813 Address after: 215000 268 Jinfeng Road, Wuzhong District, Suzhou City, Jiangsu Province Patentee after: Han Gang Address before: 510000 2nd floor, North staircase, building B2, Shangbu garden, Xicha Road, Baiyun District, Guangzhou City, Guangdong Province Patentee before: GUANGDONG SELLMAN ECONOMIC DEVELOPMENT Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20221117 Address after: No. 39, Guishan Road, Xianning Hi tech Development Zone, Hubei 437100 Patentee after: Le Fusi Health Products Co.,Ltd. Address before: 215000 268 Jinfeng Road, Wuzhong District, Suzhou City, Jiangsu Province Patentee before: Han Gang |
|
| TR01 | Transfer of patent right |