CN108902267A - One kind is based on consumption animal collagen casing and preparation method thereof - Google Patents
One kind is based on consumption animal collagen casing and preparation method thereof Download PDFInfo
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- CN108902267A CN108902267A CN201810992426.8A CN201810992426A CN108902267A CN 108902267 A CN108902267 A CN 108902267A CN 201810992426 A CN201810992426 A CN 201810992426A CN 108902267 A CN108902267 A CN 108902267A
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- collagen
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- A—HUMAN NECESSITIES
- A22—BUTCHERING; MEAT TREATMENT; PROCESSING POULTRY OR FISH
- A22C—PROCESSING MEAT, POULTRY, OR FISH
- A22C13/00—Sausage casings
- A22C13/0013—Chemical composition of synthetic sausage casings
- A22C13/0016—Chemical composition of synthetic sausage casings based on proteins, e.g. collagen
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Abstract
The invention belongs to casing to produce and process technical field, more specifically, more particularly to it is a kind of be based on consumption animal collagen casing, the edible collagen casing include by weight below component：Moisture 10-15%, chitosan 50-55%, collagen 30-32.5%, plasticizer 1-3%, crosslinking agent 0.1-0.3% and emulsifier 0.1-0.2%；The crosslinking agent is cinnamamide；The chitosan is modification of chitosan, which is modified acquisition by the following method；Using the integrality for keeping tropocollagen molecule chain to the maximum extent simultaneously, so that material micelle easy to form after auxiliary material addition is mixed and rubbed；The selected auxiliary material for being equipped with addition simultaneously not only improves the color and viscosity of micelle, and the ductility and intensity of micelle are further strengthened, to obtain, plasticity is more preferable, is more conducive to the micelle of extrusion molding, crosslinked modified, final obtained Collagent casing for sausages tensile strength is strong, resistance to hot-working.
Description
Technical field
The invention belongs to casing to produce and process technical field, more specifically, more particularly to it is a kind of based on consumption animal
Collagent casing for sausages.Meanwhile the invention further relates to a kind of preparation methods based on consumption animal collagen casing.
Background technique
The large and small intestines of domestic animal are through livestock products made of striking.It is mainly used as filling and presenting the coat of sausage and bowel lavage；Sheep casing is also
It can be made into gutstring, for production tennis racket line, bowstring and surgical sutures etc..Casing by poultry other point have hog intestine, sheep casing and
Beef casing.There are big casing, small casing by position point.Intestines are divided into mucous membrane, submucosa, muscle layer and 4 layers of serous coat from inside to outside.According to
Poultry does not require with the different of processing finished product, and the processing to four layers above is also different.Casing best in quality should be tough and tensile semi-transparent
Bright.
Domestic animal and fish protein have good filming performance and the performances such as degradable, resistance oxygen, anti-oxidant, but existing
Casing intensity is low, poor flexibility, intolerant to boiling, add chitosan in the manufacturing process of collagen film, press down mattress to improve its
Property and tensile strength, but the chitosan of different chitosan additive amount and different Degree of Enzymatic Hydrolysis is to the biocidal property and tension of composite membrane
The influence of intensity, larger to the biocidal property and intensity effect of collagen composite membrane, the additional amount of chitosan must limit
In relatively low range, the casing product of performance needed for meeting can not be obtained in the case where improving chitosan content, thus
The exploitation of casing is caused to be greatly limited.
Summary of the invention
The purpose of the present invention is to solve disadvantage existing in the prior art, structure designs advantages of simple, manufacturing cost
Low, energy conservation and environmental protection, fire and water repellency is good, and anticorrosive ageing resistance is strong, and caking property easy to use is high, applied widely, favorably
In promotion and popularization, and the one kind proposed is based on consumption animal collagen casing.
To achieve the above object, the present invention provides the following technical solutions：One kind being based on consumption animal collagen casing,
The edible collagen casing include by weight below component：Moisture 10-15%, chitosan 50-55%, collagen
30-32.5%, plasticizer 1-3%, crosslinking agent 0.1-0.3% and emulsifier 0.1-0.2%；The crosslinking agent is cinnamamide；
The chitosan is modification of chitosan, which is modified acquisition by the following method：Chitosan is placed in and is had
It is ground in the milling apparatus of temperature control sleeve, grinding temperature is 60-65 DEG C, milling time 4h.
Preferably, the edible collagen casing include by weight below component：Moisture 15-20%, chitosan
55-60%, collagen 32.5-35%, plasticizer 3-5%, crosslinking agent 0.3-0.5%, emulsifier 0.2-0.3%.
Preferably, the edible collagen casing also include the sodium carboxymethylcellulose of raw material weight 10~15%, 1~
3% hydroxypropyl PASELLI EASYGEL and 1~5% sodium tripolyphosphate.
Preferably, the film forming agent is mucedin.
Preferably, the plasticizer is sorbierite, Portugal's hexitol or glucomannans, and the emulsifier is polyoxyethylene mistake
Water Span.
The present invention also provides a kind of preparation methods based on consumption animal collagen casing, include the following steps：
Include the following steps：
S1, modification of chitosan is dissolved in the glacial acetic acid aqueous solution that glacial acetic acid concentration is 2.0% weight, is sufficiently stirred,
The concentration of modification of chitosan is 2.0% weight, adds the desired amount of plasticizer and emulsifier, and modification of chitosan solution is made；
S2, the collagen that animal cladding is extracted from the acetic acid of 0.5mol/L, are then concentrated by evaporation to collagen egg
White concentration is 6.0-9.0% weight, and collagen solution is made；
S3, by collagen solution made from modification of chitosan solution made from step S1 and step S2 so that shell is poly-
The ratio that sugar and collagen solution meet required product constituent content is uniformly mixed, and crosslinking agent is then added, then sufficiently
Homogenizing；
Dietary fiber element or the derivative element of dietary fiber element, oil is added in S4, the solution heating stirring by step S3 while stirring
Fat liquor controls pH value and water content, collagen group is mixed evenly into；The freezing of collagen group squeezes and sprays tube, dry,
Curing agent and plasticizer processing is added, while plasticizer is added, removes bubble, is then formed a film using the tape casting, film is placed in Sheng
In the drier for having saturation magnesium nitrate solution, relative humidity 48%-52% is kept at normal temperature, and dry 24 as a child up to edible
Property Collagent casing for sausages.
Preferably, wherein mucedin is added in step (3).
Preferably, any one or more of the animal cladding in pigskin, ox-hide, sheepskin and fish-skin.
Technical effect and advantage of the invention：One kind provided by the invention is based on consumption animal collagen casing, with
Traditional consumption animal collagen casing is compared, since chitosan can only be dissolved in partially acidic solution, while chitosan point
Containing a large amount of hydrophilic radicals in son, these can generate many adverse effects in the casing preparation comprising chitosan and application aspect,
Various conventional chemical modifications can bring new ingredient to casing again, be added to sodium carboxymethylcellulose, two starch phosphate of hydroxypropyl
Ester, sodium tripolyphosphate auxiliary material, using the integrality for keeping tropocollagen molecule chain to the maximum extent simultaneously, so that material is added in auxiliary material
It is mixed to rub rear micelle easy to form；The selected auxiliary material for being equipped with addition simultaneously not only improves the color and viscosity of micelle, and micelle
Ductility and intensity be further strengthened, to obtain that plasticity is more preferable, is more conducive to the micelle of extrusion molding, crosslinked modification
Afterwards, final obtained Collagent casing for sausages tensile strength is strong, resistance to hot-working, is able to satisfy daily bowel lavage requirement, guarantees product quality,
It is applied widely, be conducive to popularize.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.Based on the embodiments of the present invention, those of ordinary skill in the art are not before making creative work
Every other embodiment obtained is put, shall fall within the protection scope of the present invention.
Embodiment 1
The edible collagen casing include by weight below component：Moisture 10-15%, chitosan 50-55%,
Collagen 30-32.5%, plasticizer 1-3%, crosslinking agent 0.1-0.3% and emulsifier 0.1-0.2%；Crosslinking agent is cortex cinnamomi
Amide；Chitosan is modification of chitosan, which is modified acquisition by the following method：Chitosan is placed in and is had
It is ground in the milling apparatus of temperature control sleeve, grinding temperature is 60-65 DEG C, milling time 4h, the edible collagen
Casing also includes the hydroxypropyl PASELLI EASYGEL and 1~5% of the sodium carboxymethylcellulose of raw material weight 10~15%, 1~3%
Sodium tripolyphosphate, film forming agent is mucedin, and plasticizer is sorbierite, Portugal's hexitol or glucomannans, and emulsifier is poly-
Ethylene oxide sorbitan fatty acid ester.
The present invention also provides a kind of preparation methods based on consumption animal collagen casing, include the following steps：
S1, modification of chitosan is dissolved in the glacial acetic acid aqueous solution that glacial acetic acid concentration is 2.0% weight, is sufficiently stirred,
The concentration of modification of chitosan is 2.0% weight, adds the desired amount of plasticizer and emulsifier, and modification of chitosan solution is made；
S2, the collagen that animal cladding is extracted from the acetic acid of 0.5mol/L, are then concentrated by evaporation to collagen egg
White concentration is 6.0-9.0% weight, and collagen solution is made；
S3, by collagen solution made from modification of chitosan solution made from step S1 and step S2 so that shell is poly-
The ratio that sugar and collagen solution meet required product constituent content is uniformly mixed, and crosslinking agent is then added, then sufficiently
Homogenizing；
Dietary fiber element or the derivative element of dietary fiber element, oil is added in S4, the solution heating stirring by step S3 while stirring
Fat liquor controls pH value and water content, collagen group is mixed evenly into；The freezing of collagen group squeezes and sprays tube, dry,
Curing agent and plasticizer processing is added, while plasticizer is added, removes bubble, is then formed a film using the tape casting, film is placed in Sheng
In the drier for having saturation magnesium nitrate solution, relative humidity 48%-52% is kept at normal temperature, and dry 24 as a child up to edible
Property Collagent casing for sausages.
Embodiment 2
The edible collagen casing include by weight below component：Moisture 15-20%, chitosan 55-60%,
Collagen 32.5-35%, plasticizer 3-5%, crosslinking agent 0.3-0.5%, emulsifier 0.2-0.3%, crosslinking agent are cinnamamide；Shell
Glycan is modification of chitosan, which is modified acquisition by the following method：Chitosan is placed in temperature control set
It is ground in the milling apparatus of cylinder, grinding temperature is 60-65 DEG C, milling time 4h, and the edible collagen casing is also
Sodium carboxymethylcellulose comprising raw material weight 10~15%, 1~3% hydroxypropyl PASELLI EASYGEL and 1~5% trimerization
Sodium phosphate, film forming agent are mucedin, and plasticizer is sorbierite, Portugal's hexitol or glucomannans, and emulsifier is polyoxyethylene
Sorbitan fatty acid ester.
The present invention also provides a kind of preparation methods based on consumption animal collagen casing, include the following steps：
S1, modification of chitosan is dissolved in the glacial acetic acid aqueous solution that glacial acetic acid concentration is 2.0% weight, is sufficiently stirred,
The concentration of modification of chitosan is 2.0% weight, adds the desired amount of plasticizer and emulsifier, and modification of chitosan solution is made；
S2, the collagen that animal cladding is extracted from the acetic acid of 0.5mol/L, are then concentrated by evaporation to collagen egg
White concentration is 6.0-9.0% weight, and collagen solution is made；
S3, by collagen solution made from modification of chitosan solution made from step S1 and step S2 so that shell is poly-
The ratio that sugar and collagen solution meet required product constituent content is uniformly mixed, and crosslinking agent is then added, then sufficiently
Homogenizing；
Dietary fiber element or the derivative element of dietary fiber element, oil is added in S4, the solution heating stirring by step S3 while stirring
Fat liquor controls pH value and water content, collagen group is mixed evenly into；The freezing of collagen group squeezes and sprays tube, dry,
Curing agent and plasticizer processing is added, while plasticizer is added, removes bubble, is then formed a film using the tape casting, film is placed in Sheng
In the drier for having saturation magnesium nitrate solution, relative humidity 48%-52% is kept at normal temperature, and dry 24 as a child up to edible
Property Collagent casing for sausages.
Embodiment 3
The edible collagen casing include by weight below component：Moisture 15%, chitosan 55%, collagen
32.5%, plasticizer 3%, crosslinking agent 0.3%, emulsifier 0.2%, crosslinking agent is cinnamamide；Chitosan is modification of chitosan,
The modification of chitosan is modified acquisition by the following method：Chitosan is placed in the milling apparatus with temperature control sleeve and is carried out
Grinding, grinding temperature are 60-65 DEG C, milling time 4h, which also includes raw material weight 12%
Sodium carboxymethylcellulose, 2% hydroxypropyl PASELLI EASYGEL and 3% sodium tripolyphosphate, film forming agent are mucedin, plasticising
Agent is sorbierite, and emulsifier is polyoxyethylene sorbitan fatty acid ester.
The present invention also provides a kind of preparation methods based on consumption animal collagen casing, include the following steps：
S1, modification of chitosan is dissolved in the glacial acetic acid aqueous solution that glacial acetic acid concentration is 2.0% weight, is sufficiently stirred,
The concentration of modification of chitosan is 2.0% weight, adds the desired amount of plasticizer and emulsifier, and modification of chitosan solution is made；
S2, the collagen that animal cladding is extracted from the acetic acid of 0.5mol/L, are then concentrated by evaporation to collagen egg
White concentration is 8.2% weight, and collagen solution is made；
S3, by collagen solution made from modification of chitosan solution made from step S1 and step S2 so that shell is poly-
The ratio that sugar and collagen solution meet required product constituent content is uniformly mixed, and crosslinking agent is then added, then sufficiently
Homogenizing；
Dietary fiber element or the derivative element of dietary fiber element, oil is added in S4, the solution heating stirring by step S3 while stirring
Fat liquor controls pH value and water content, collagen group is mixed evenly into；The freezing of collagen group squeezes and sprays tube, dry,
Curing agent and plasticizer processing is added, while plasticizer is added, removes bubble, is then formed a film using the tape casting, film is placed in Sheng
In the drier for having saturation magnesium nitrate solution, relative humidity 48%-52% is kept at normal temperature, and dry 24 as a child up to edible
Property Collagent casing for sausages.
To sum up：It is provided by the invention a kind of based on consumption animal collagen casing, with traditional consumption animal glue
Collagen albumen sausage casing is compared, and since chitosan can only be dissolved in partially acidic solution, while containing a large amount of hydrophilic groups in chitosan molecule
Group, these can generate many adverse effects in the casing preparation comprising chitosan and application aspect, and various conventional chemical modifications are again
New ingredient can be brought to casing, be added to sodium carboxymethylcellulose, hydroxypropyl PASELLI EASYGEL, sodium tripolyphosphate auxiliary material,
Using the integrality for keeping tropocollagen molecule chain to the maximum extent simultaneously, so that material glue easy to form after auxiliary material addition is mixed and rubbed
Group；The selected auxiliary material for being equipped with addition simultaneously not only improves the color and viscosity of micelle, and the ductility of micelle and intensity obtain
To further strengthening, thus obtain that plasticity is more preferable, is more conducive to the micelle of extrusion molding, crosslinked modified, final glue obtained
Collagen albumen sausage casing tensile strength is strong, resistance to hot-working, is able to satisfy daily bowel lavage requirement, guarantees product quality, applied widely, favorably
In promotion and popularization.
Finally it should be noted that：The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features,
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention
Within protection scope.
Claims (8)
1. one kind is based on consumption animal collagen casing, it is characterised in that：The edible collagen casing includes with weight
Component below meter：Moisture 10-15%, chitosan 50-55%, collagen 30-32.5%, plasticizer 1-3%, crosslinking agent
0.1-0.3% and emulsifier 0.1-0.2%；The crosslinking agent is cinnamamide；The chitosan is modification of chitosan, this changes
Property chitosan is modified acquisition by the following method：Chitosan is placed in the milling apparatus with temperature control sleeve and is ground
Mill, grinding temperature are 60-65 DEG C, milling time 4h.
2. according to claim 1 a kind of based on consumption animal collagen casing, it is characterised in that：The edibility glue
Collagen albumen sausage casing include by weight below component：Moisture 15-20%, chitosan 55-60%, collagen 32.5-35%, plasticising
Agent 3-5%, crosslinking agent 0.3-0.5%, emulsifier 0.2-0.3%.
3. according to claim 1 a kind of based on consumption animal collagen casing, it is characterised in that：The edibility glue
Collagen albumen sausage casing also include the sodium carboxymethylcellulose of raw material weight 10~15%, 1~3% hydroxypropyl PASELLI EASYGEL and
1~5% sodium tripolyphosphate.
4. according to claim 1 a kind of based on consumption animal collagen casing, it is characterised in that：The film forming agent
For mucedin.
5. according to claim 1 or 2 a kind of based on consumption animal collagen casing, it is characterised in that：The increasing
Modeling agent is sorbierite, Portugal's hexitol or glucomannans, and the emulsifier is polyoxyethylene sorbitan fatty acid ester.
6. a kind of preparation method described in claim 1 based on consumption animal collagen casing, it is characterised in that：Including
Following steps：
S1, modification of chitosan is dissolved in the glacial acetic acid aqueous solution that glacial acetic acid concentration is 2.0% weight, is sufficiently stirred, it is modified
The concentration of chitosan is 2.0% weight, adds the desired amount of plasticizer and emulsifier, and modification of chitosan solution is made；
S2, the collagen that animal cladding is extracted from the acetic acid of 0.5mol/L, are then concentrated by evaporation dense to collagen
Degree is 6.0-9.0% weight, and collagen solution is made；
S3, by collagen solution made from modification of chitosan solution made from step S1 and step S2 so that chitosan and
The ratio that collagen solution meets required product constituent content is uniformly mixed, and crosslinking agent, then sufficiently homogenizing is then added；
Dietary fiber element or the derivative element of dietary fiber element, grease cream is added in S4, the solution heating stirring by step S3 while stirring
Liquid controls pH value and water content, collagen group is mixed evenly into；The freezing of collagen group squeezes and sprays tube, dry, is added
Curing agent and plasticizer processing, while being added plasticizer, remove bubble, then formed a film using the tape casting, film is placed in fill it is full
In the drier of magnesium nitrate solution, relative humidity 48%-52% is kept at normal temperature, and dry 24 as a child up to edibility glue
Collagen albumen sausage casing.
7. a kind of preparation method based on consumption animal collagen casing according to claim 6, it is characterised in that：
Mucedin is wherein added in step (3).
8. a kind of preparation method based on consumption animal collagen casing according to claim 6, it is characterised in that：
Any one or more of the animal cladding in pigskin, ox-hide, sheepskin and fish-skin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810992426.8A CN108902267A (en) | 2018-08-29 | 2018-08-29 | One kind is based on consumption animal collagen casing and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810992426.8A CN108902267A (en) | 2018-08-29 | 2018-08-29 | One kind is based on consumption animal collagen casing and preparation method thereof |
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| CN108902267A true CN108902267A (en) | 2018-11-30 |
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| CN201810992426.8A Pending CN108902267A (en) | 2018-08-29 | 2018-08-29 | One kind is based on consumption animal collagen casing and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112262876A (en) * | 2020-09-28 | 2021-01-26 | 青岛明月海藻集团有限公司 | Alginate co-extrusion casing glue, preparation method thereof and obtained co-extrusion casing |
| CN112450260A (en) * | 2020-10-30 | 2021-03-09 | 浙江波拉波拉食品股份有限公司 | Preparation method of Taiwan flavor sausage convenient to preserve |
| CN114766537A (en) * | 2022-05-24 | 2022-07-22 | 河南工业大学 | High-temperature-resistant chicken skin collagen edible casing film and preparation method thereof |
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| CN101300992A (en) * | 2008-07-09 | 2008-11-12 | 梧州神冠蛋白肠衣有限公司 | Middle and small diameter collagen protein casing and preparation thereof |
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| US3408917A (en) * | 1965-05-19 | 1968-11-05 | Tee Pak Inc | Iron tanning of edible collagen casings |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112262876A (en) * | 2020-09-28 | 2021-01-26 | 青岛明月海藻集团有限公司 | Alginate co-extrusion casing glue, preparation method thereof and obtained co-extrusion casing |
| CN112450260A (en) * | 2020-10-30 | 2021-03-09 | 浙江波拉波拉食品股份有限公司 | Preparation method of Taiwan flavor sausage convenient to preserve |
| CN114766537A (en) * | 2022-05-24 | 2022-07-22 | 河南工业大学 | High-temperature-resistant chicken skin collagen edible casing film and preparation method thereof |
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