CN103651456A - Compound pesticidal composition containing ethiprole and tsumacide and application thereof - Google Patents
Compound pesticidal composition containing ethiprole and tsumacide and application thereof Download PDFInfo
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- CN103651456A CN103651456A CN201210323442.0A CN201210323442A CN103651456A CN 103651456 A CN103651456 A CN 103651456A CN 201210323442 A CN201210323442 A CN 201210323442A CN 103651456 A CN103651456 A CN 103651456A
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- tolyl
- mtmc
- methylcarbamate
- meta
- worm nitrile
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Abstract
The invention discloses a compound pesticidal composition containing ethiprole and tsumacide and application thereof. The compound pesticidal composition uses ethiprole and tsumacide as pesticidal active components, wherein the weight ratio of the ethiprole to the tsumacide is (0.1-80):(0.5-80). The pesticidal composition can generate higher synergic effect, overcomes and postpones the drug resistance of pests, has the advantages of high pesticidal speed and long duration time, lowers the pesticide cost, and has obviously better preventing and treating effects than a single agent. The composition can prevent and treat hemiptera pests on crops, especially can be used for preventing and treating rice planthoppers and aphids, and has obviously better effect than a single agent.
Description
Technical field
The invention belongs to the field of agricultural pesticide that contains heterocyclic compound, concrete body relates to a kind of compound pesticide compositions.
Background technology
Second worm nitrile (Ethiprole), chemical name: 1-(2,6-dichlor-4-trifluoromethyl phenyl)-3-cyano group-4-ethyl sulfinyl-5-amino-pyrazol.Molecular formula is: C
13h
9c
l2f
3n
4oS.
Second worm nitrile (Ethiprole) is the Insecticidal and acaricidal agent by rhone-poulenc is found, Beyer Co., Ltd develops, belong to effective to multiple chewing type and sucking pest under the low consumption of insecticide that the second generation acts on GABA, can be used for seed treatment and foliar spray, the lasting period reaches 21-28d.(be mainly used in preventing and treating thrips, stinkbug, curculionid, beet gelechiid, aphid, plant hopper and locust etc., some aleyrodid is also shown to activity (particularly the rice grub green rice bug of extremely difficult control being had to very strong activity).
Meta-tolyl-N-methylcarbamate (MTMC) is a kind of carbamate insecticide.Chemical name is: tolyl-N-methyl carbamate, and structural formula is:
Meta-tolyl-N-methylcarbamate (MTMC) has and tags and fumigation action insect, and the power of knocking down is strong, and holding effect is short.Can be used to prevent and treat towering like a mountain peak lice, leafhopper, cotten aphid, thrips, cotton bollworm etc.; Control rice fulgorid, rice leafhopper, rice thrips etc. have special efficacy.To people, animal moderate toxicity.
But rice fulgorid and aphid are under the condition of current long-term prescription, and resistance increases gradually, and agricultural chemicals single dose declines gradually to the effect of control of insect.Inventor finds after deliberation, and the synergistic complex of agricultural chemicals is expanding prevention spectrum and the effective measures that improve preventive effect, not yet finds up to now the Pesticidal combination of relevant second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC).
Summary of the invention
The object of this invention is to provide a kind of compound pesticide compositions containing second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC), this Pesticidal combination is the multifunctional insecticide composition of control Semiptera insect.
Another object of the present invention is to provide this Pesticidal combination and in preparation, prevents and treats the application on the insecticidal materials of resistance Semiptera insect, particularly the application on the insecticidal materials of preparation control plant hopper, aleyrodid or aphid.
The object of the invention is to be achieved through the following technical solutions:
Containing a compound pesticide compositions for second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC), it is active insecticidal components that this compound pesticide compositions be take second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC), and wherein, the weight ratio of second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) is 0.1 ~ 80:0.5 ~ 80.
In this compound pesticide compositions, the weight ratio of second worm nitrile (A) and S-sumicidin (B) is preferably 0.5 ~ 50:1 ~ 50.A kind of preferred scheme is that the two weight ratio of A and B is further 0.5 ~ 10:1 ~ 30, most preferably is 1～10:1～10.It is that the two weight ratio of A and B is 0.1～20:1 that another kind is preferably scheme, is further 0.1～10:1.
This compound pesticide compositions can only contain active component second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC), also can when using or prepare, in active component, add other components, and the effective ingredient in this Pesticidal combination can also synergy effective dose be present in composition.
In compound pesticide compositions of the present invention, the two weight percentage in this compound pesticide compositions of second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) is 3 ~ 80%.Be preferably 5 ~ 55%, most preferably 10 ~ 40%.
It is active component or main active ingredient that Pesticidal combination of the present invention be take second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC), be mixed with insecticides adjuvant and excipient any one formulation allowing on agricultural chemicals, described formulation is preferably missible oil, suspending agent, wetting powder, aqueous emulsion, microemulsion or water dispersion granule.
Aforementionedly can be applicable to the not special restriction of insecticides adjuvant of the present invention, include, but are not limited to calcium dodecyl benzene sulfonate, 600#, the rare block compound of polyoxyethylene polyoxy third (as agriculture breast 33
#), polyoxyethylene nonylphenol ether etc.Aforementionedly can be applicable to excipient of the present invention and be also not particularly limited, include, but are not limited to isopropyl alcohol, vegetable oil, solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient and other auxiliary material can alone or and use.
The multiple Semiptera insect that Pesticidal combination of the present invention easily produces resistance to rice fulgorid and aphid etc. has good preventive effect; And suppress insect the pesticide resistance of unitary agent (second worm nitrile or meta-tolyl-N-methylcarbamate (MTMC) are arbitrary) is produced.
Above-mentioned Pesticidal combination is prevented and treated the application on the insecticidal materials of resistance Semiptera insect in preparation, especially the effect on the insecticidal materials of preparation control aleyrodid, rice fulgorid or aphid is remarkable.
Beneficial effect of the present invention compared with prior art: (1) is compared with single dose, said composition antagonism Semiptera insect, as rice fulgorid, aphid etc. has obvious synergistic function, overcomes and has delayed pest resistance to insecticide, and expanding prevention is composed, desinsection speed is fast, has obviously improved control efficiency; (2) reduce control recruitment, drug cost; (3) alternative high-toxic pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with meta-tolyl-N-methylcarbamate (MTMC) single dose with second worm nitrile, produce and use cost reduction; (6) suppress Semiptera insect the resistance of agricultural chemicals is strengthened, its successful is used higher than its single dose.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but do not limit the present invention in any way.
Embodiment 1:
Take second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) 30g altogether, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, vegetable oil are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and is mixed with the second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) missible oil that main active ingredient weight percentage is 30%.Wherein the concrete ratio of second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) is in Table 1 and 2.
Adopt rice stem infusion process to carry out indoor synergy biologicall test, selecting resistant rice plant hopper is target pest, and every processing repeats 3 times, and every concentration is processed 60, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism rice fulgorid by probability value method
50, use LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 1:
Table 1 second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) is composite and the toxicity test of single dose antagonism rice fulgorid
As shown in Table 1, second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) are composite, and co-toxicity coefficient is all greater than 120, show good synergistic function.Wherein when second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) 1:1, synergistic effect is the most obvious.
Employing is soaked leaf dip method and is carried out indoor synergy biologicall test, and selecting resistance wheat aphid is target pest, and every processing repeats 3 times, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism rice fulgorid by probability value method
50, use LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 2:
Table 2 second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) is composite and the toxicity test of single dose antagonism wheat aphid
As shown in Table 2, second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) are composite, and the co-toxicity coefficient of wheat aphid is all greater than to 120, show good synergistic function.Wherein when second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) 1:1, synergistic effect is the most obvious.
Embodiment 2:
Take 5g second worm nitrile, 50g meta-tolyl-N-methylcarbamate (MTMC), phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33
#2g, 600#1g, vegetable oil 13g, adds water to 100g.The method of above raw material being prepared routinely to aqueous emulsion drops into the mixing of mixing kettle high speed, forms the second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) aqueous emulsion that main active ingredient weight percentage is 55%.
Embodiment 3:
Take 2g second worm nitrile, 18g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33
#2g, 600#1g, isopropyl alcohol 10g, adds water to 100g.The method that above raw material is prepared to microemulsion routinely drops in mixing kettle mixes, and forms the second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) microemulsion that main active ingredient weight percentage is 20%.
Embodiment 3 is prevented and treated to the Brown Planthopper test of pesticide effectiveness, and contrast medicament is 420% meta-tolyl-N-methylcarbamate (MTMC) EC(missible oil) and 20% second worm nitrile EW(aqueous emulsion), according to the extension rate of 3 li of forms, dilute, after medicine, look into 3 days, the result of 7 days, result is in Table 3:
The composite field test results to Brown Planthopper of table 3 second worm nitrile-meta-tolyl-N-methylcarbamate (MTMC)
Field efficacy result shows, second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) composition antagonism brown planthopper has good control efficiency, and control efficiency is all better than the direct acting effect of single dose kind.
Embodiment 3 is prevented and treated to wheat aphid field medicine effect test, and contrast medicament is 20% meta-tolyl-N-methylcarbamate (MTMC) EC(missible oil) and 20% second worm nitrile EW(aqueous emulsion), according to the extension rate of 3 li of forms, dilute, after medicine, look into 3 days, the result of 7 days, result is in Table 4:
The composite field test results to wheat aphid of table 4 second worm nitrile-meta-tolyl-N-methylcarbamate (MTMC)
Field efficacy result shows, second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) composition antagonism wheat aphid has good control efficiency, and control efficiency is all better than the direct acting effect of single dose kind.
Embodiment 4:
Take 1g second worm nitrile, 5g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, vegetable oil to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) missible oil that main active ingredient weight percentage is 6%.
Embodiment 5:
Take 50g second worm nitrile, 20g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) missible oil that main active ingredient weight percentage is 70%.
Embodiment 6:
Take 2g second worm nitrile, 40g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) missible oil that main active ingredient weight percentage is 42%.
Embodiment 7:
Take 0.2g second worm nitrile, 50g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g, vegetable oil are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) missible oil that main active ingredient weight percentage is 50.2%.
Embodiment 8:
Take 5g second worm nitrile, 0.5g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, vegetable oil are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) missible oil that main active ingredient weight percentage is 5.5%.
Embodiment 9:
Take 5g second worm nitrile, 30g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, vegetable oil are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms second worm nitrile-meta-tolyl-N-methylcarbamate (MTMC) missible oil that main active ingredient weight percentage is 35%.
Embodiment 10:
Take 20g second worm nitrile, 5g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, vegetable oil are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) missible oil that main active ingredient weight percentage is 25%.
Embodiment 11:
Take 30g second worm nitrile, 12g meta-tolyl-N-methylcarbamate (MTMC), the 2g of lignin salt, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, forms the second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) suspending agent that main active ingredient weight percentage is 42% under the effect of sand mill.
Embodiment 12:
Take 2g second worm nitrile, 5g meta-tolyl-N-methylcarbamate (MTMC), sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite 21g, forms by water dispersible granular agent method the second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) water dispersion granule that main active ingredient weight percentage is 14% by above raw material.
Embodiment 13:
Take 50g second worm nitrile, 3g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, vegetable oil are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) missible oil that main active ingredient weight percentage is 53%.
Embodiment 14:
Take 2g second worm nitrile, 18g meta-tolyl-N-methylcarbamate (MTMC), lignin 10g, naphthalene sulfonate 2g, with diatomite, add to 100g, above raw material is mixed in micronizer, form the second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) wetting powder that main active ingredient weight percentage is 20%.
Embodiment 15:
Take 7g second worm nitrile, 70g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) missible oil that main active ingredient weight percentage is 77%.
Embodiment 16:
Take 60g second worm nitrile, 5g meta-tolyl-N-methylcarbamate (MTMC), the 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin 13g, forms by water dispersible granular agent method the second worm nitrile Tsumacide water dispersible granule that main active ingredient weight percentage is 65% by above raw material.
Embodiment 17:
Take 20g second worm nitrile, 20g meta-tolyl-N-methylcarbamate (MTMC), nonyl phenol phosphate 5g, 600#4g, n-butanol 3g, 10g solvent naphtha and 20g pyrrolidones, 0.1g xanthans, all the other waters are supplied 100g, n-butanol and water-soluble solution form water, and all the other component mix and blends form oil phases, go in slowly water being added to oil phase under clipper effect, and continue to shear 10 ~ 30 minutes, form the second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) aqueous emulsion that main active ingredient weight percentage is 40%.
Embodiment 18:
Take 60g second worm nitrile, 1g meta-tolyl-N-methylcarbamate (MTMC), calcium dodecyl benzene sulfonate 5g, 600#4g, the solvent naphtha of 10g and the pyrrolidones of 15g, all the other waters are supplied 100g, above-mentioned former medicine, solvent, emulsifier, cosolvent mix and blend are formed to homogeneous phase transparent solution, finally slowly add water to stir and form clear solution, be the second worm nitrile meta-tolyl-N-methylcarbamate (MTMC) microemulsion that main active ingredient weight percentage is 61%.
Claims (10)
1. containing a compound pesticide compositions for second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC), it is characterized in that it is active insecticidal components that this compound pesticide compositions be take second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC), wherein, the weight ratio of second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) is 0.1 ~ 80:0.5 ~ 80.
2. the compound pesticide compositions containing second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) according to claim 1, is characterized in that described second worm nitrile and the weight ratio of meta-tolyl-N-methylcarbamate (MTMC) are 0.5 ~ 50:1 ~ 50.
3. the compound pesticide compositions containing second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) according to claim 2, is characterized in that described second worm nitrile and the weight ratio of meta-tolyl-N-methylcarbamate (MTMC) are 0.5 ~ 10:1 ~ 30.
4. the compound pesticide compositions containing second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) according to claim 3, is characterized in that described second worm nitrile and the weight ratio of meta-tolyl-N-methylcarbamate (MTMC) are 01 ~ 10:1 ~ 10.
5. the compound pesticide compositions containing second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) according to claim 1, is characterized in that the two weight percentage in this compound pesticide compositions of second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) is 3% ~ 80%.
6. the compound pesticide compositions containing second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) according to claim 5, is characterized in that the two weight percentage in this compound pesticide compositions of second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) is 5% ~ 55%.
7. the compound pesticide compositions containing second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) according to claim 1, is characterized in that this compound pesticide compositions take second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) and be mixed with the formulation allowing on agricultural chemicals as active insecticidal components and insecticides adjuvant and excipients.
8. the compound pesticide compositions containing second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) according to claim 7, is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersion granule.
9. the compound pesticide compositions containing second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) claimed in claim 1 is prevented and treated the application on the insecticidal materials of resistance Semiptera insect in preparation.
Compound pesticide compositions containing second worm nitrile and meta-tolyl-N-methylcarbamate (MTMC) according to claim 9 in preparation, anti-ly eliminate aphis, the application on the insecticidal materials of aleyrodid or rice fulgorid.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210323442.0A CN103651456A (en) | 2012-09-04 | 2012-09-04 | Compound pesticidal composition containing ethiprole and tsumacide and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210323442.0A CN103651456A (en) | 2012-09-04 | 2012-09-04 | Compound pesticidal composition containing ethiprole and tsumacide and application thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007085899A2 (en) * | 2005-07-06 | 2007-08-02 | Foamix Ltd. | Foamable arthropocidal composition for tropical application |
| WO2009012909A2 (en) * | 2007-07-23 | 2009-01-29 | Bayer Cropscience Ag | Insecticidal active substance combinations (genestein + insecticides) |
| CN101883488A (en) * | 2007-12-03 | 2010-11-10 | 拜尔农作物科学股份公司 | Pesticidal compound mixtures comprising ethiprole and specific carbamates |
| CN102414197A (en) * | 2009-04-27 | 2012-04-11 | 美国陶氏益农公司 | Insecticidal pyridine compounds |
-
2012
- 2012-09-04 CN CN201210323442.0A patent/CN103651456A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007085899A2 (en) * | 2005-07-06 | 2007-08-02 | Foamix Ltd. | Foamable arthropocidal composition for tropical application |
| WO2009012909A2 (en) * | 2007-07-23 | 2009-01-29 | Bayer Cropscience Ag | Insecticidal active substance combinations (genestein + insecticides) |
| CN101883488A (en) * | 2007-12-03 | 2010-11-10 | 拜尔农作物科学股份公司 | Pesticidal compound mixtures comprising ethiprole and specific carbamates |
| CN102414197A (en) * | 2009-04-27 | 2012-04-11 | 美国陶氏益农公司 | Insecticidal pyridine compounds |
Non-Patent Citations (1)
| Title |
|---|
| 农药科学与管理编辑部: ""乙虫腈"", 《农药科学与管理》, vol. 30, no. 5, 15 May 2009 (2009-05-15), pages 58 * |
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