CN103626286A - Manufacture method of water supply sludge composite filler and packed bed thereof - Google Patents

Manufacture method of water supply sludge composite filler and packed bed thereof Download PDF

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Publication number
CN103626286A
CN103626286A CN201310700033.2A CN201310700033A CN103626286A CN 103626286 A CN103626286 A CN 103626286A CN 201310700033 A CN201310700033 A CN 201310700033A CN 103626286 A CN103626286 A CN 103626286A
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China
Prior art keywords
bed
packings
sewage sludge
mud
manufacture method
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CN201310700033.2A
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CN103626286B (en
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魏东洋
洪雷
贺涛
许振成
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South China Institute of Environmental Science of Ministry of Ecology and Environment
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South China Institute of Environmental Science of Ministry of Ecology and Environment
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Publication of CN103626286A publication Critical patent/CN103626286A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention discloses a manufacture method of water supply sludge composite filler and a packed bed thereof. The manufacture method comprises following steps: taking a quantity of sludge, drying, then smashing and sieving; mixing the raw material sludge with anthracite at a weight ratio of 1:(0.2-0.5); adding a starch paste into the mixture, and mixing uniformly, wherein the quantity of the starch paste is 2-5wt% of the mixture; prilling and drying; roasting the dried particles at 300-600 DEG C; steeping the roasted particles in a 5-10% aluminum polychlorid solution; uniformly mixing the steeped particles with sponge iron at a weight ratio of 1:(0.2-0.5). The granular water supply sludge composite filler is the material capable of dephosphorizing and fixing nitrogen efficiently.

Description

A kind of manufacture method and bed of packings thereof of giving sewage sludge compounded mix
Technical field
The invention belongs to technical field of sewage, relate in particular to a kind of manufacture method and bed of packings thereof to sewage sludge compounded mix.
Background technology
Rural decentralized wastewater is because amount is little wide, and centralized collection is difficult, and large amount of sewage is failed to be effectively addressed and discharged environment, and in the southern network of waterways, gather district and water conservation district, easily cause body eutrophication and serious threat drinking water source.
Existing treatment technology substantially all adopts the method for the ecologies such as artificial swamp to be processed, but that these facilities are limited to floor space is large, and degree for the treatment of is low, and investment, compared with large and difficult large scale application, causes dispersion face source sewage difficulty to be effectively addressed.
Adopt the treatment effect of feedwater sludge treatment sewage good, utilize feedwater sludge treatment sewage not also to be widely adopted, substantially in the experimental study stage, that in experimental study, uses lays for block individual layer to sewage sludge, wastewater treatment efficiency is bad, and the sewage after processing can not reach the sewage drainage standard of national regulation.
Summary of the invention
In order to solve above technical problem, the invention provides a kind of manufacture method and bed of packings thereof to sewage sludge compounded mix.
A manufacture method of giving sewage sludge compounded mix, is characterized in that: get mud some, crushed after being dried is sieved, and obtains mud raw material; Mud raw material is mixed according to 1:0.2 ~ 0.5 weight ratio with hard coal, obtain compound; In compound, add starch paste, wherein starch paste consumption is the 2-5% of compound weight, and mixing and stirring, obtains mud mixture; By mixture, granulation, dry; Temperature roasting by dried particle with 300 ~ 600 ℃; The polymeric aluminum chlorides solution that is 5 ~ 10% by concentration by the particle after roasting soaks; The particle soaking is mixed according to 1:0.2 ~ 0.5 weight ratio with sponge iron.
Optionally, described in to get mud some, comprise the mud of choosing in the settling tank of waterworks.
What the manufacture method of giving sewage sludge compounded mix described in a kind of basis was manufactured is granular to sewage sludge compounded mix.
The bed of packings of giving sewage sludge compounded mix described in a kind of employing, it is characterized in that: described bed of packings is comprised of multistage, each section forms by small particle size layer and large particle diameter layer, small particle size layer is layed on large particle diameter layer, small particle size layer comprises granular to sewage sludge compounded mix, large particle diameter layer comprises gas concrete brick grain, presses the anti-granularity of different-grain diameter layers of material for every section and lays.
Optionally, in described large particle diameter layer, lay ventpipe.
Optionally, the bed of packings the superiors, plantation wetland plant.
The invention has the beneficial effects as follows: the high-efficiency environment friendly material that utilizes waterworks waste processing to sewage sludge of the present invention, pollution-free, expense is low, through chemical modification and heat modification, granulates, and it has good phosphor-removing effect.Dephosphorization efficiency by using is high, and nitrogen is also had to certain adsorptive power, has nitrogen fixation.
The paving mode of bed of packings of the present invention can be brought into play the granular adsorptive power to sewage sludge of the present invention to greatest extent.
Accompanying drawing explanation
Fig. 1 is the granular manufacture method schema to sewage sludge compounded mix of the present invention.
Fig. 2 is the granular bed of packings structural representation to sewage sludge compounded mix of the present invention.
Embodiment
Below in conjunction with accompanying drawing, the preferred embodiment of invention is described in detail, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that, protection scope of the present invention is made to more explicit defining.
The moiety of sewage sludge compounded mix of giving of the present invention comprises: mud, hard coal, starch, polymerize aluminum chloride and sponge iron.To sewage sludge, through chemical modification and heat modification, granulate, it has good phosphor-removing effect.
Concrete preparation flow is as follows:
S101: get mud some, this mud is preferably the mud of waterworks settling tank, and the mud of waterworks settling tank itself has certain soil removability, and it is low to obtain expense.By mud seasoning, after being dried, utilize pulverizer to pulverize, the mud after pulverizing is sieved, remove the foreign material such as rubble, fragment of brick, obtain mud raw material.
S102: mud raw material is mixed according to 1:0.2 ~ 0.5 weight ratio with hard coal, obtain compound;
S103: add starch paste in compound, wherein starch paste consumption is the 2-5% of compound weight, and mixing and stirring, obtains mud mixture;
S104: by mixture, by granulator granulation, be dried after granulation is complete;
S105: the temperature roasting for some time by dried particle with 300 ~ 600 ℃, this time is preferably 3 hours, roasting can be carried out in retort furnace;
S106: the polymeric aluminum chlorides solution that is 5 ~ 10% by concentration by the particle after roasting soaks for some time, soaks into completely to particle, and this time can be 12 hours, by the immersion particles of about 12 hours, can soak into completely;
S107: the particle soaking and sponge iron are mixed to get of the present invention to sewage sludge compounded mix according to 1:0.2 ~ 0.5 weight ratio.
The high-efficiency environment friendly material of utilizing waterworks waste processing to sewage sludge compounded mix of the present invention, pollution-free, expense is low, through chemical modification and heat modification, granulates, and it has good phosphor-removing effect.Dephosphorization efficiency by using is high, and nitrogen is also had to certain adsorptive power, has nitrogen fixation.
In order to make the granular sewage sludge compounded mix of giving of the present invention reach better wastewater treatment efficiency, the granular anti-granularity of sewage sludge compounded mix layering of giving of the present invention can be layed in bed of packings, this laying method can be brought into play the granular adsorptive power to sewage sludge compounded mix of the present invention to greatest extent.Particularly.
As shown in Figure 2, bed of packings is pressed the anti-granularity of different-grain diameter layers of material and is laid, and the bed of packings in Fig. 2 is divided into three sections, but those skilled in the art should understand, the number of segmentation can be less than or more than three sections, the present invention is not intended to limit segmentation number, only usings three sections as schematically illustrating.
Each section of bed of packings forms by small particle size layer 1 and large particle diameter layer 2, small particle size layer 1 is layed on large particle diameter layer 2, small particle size layer 1 is comprised of the granular sewage sludge compounded mix of giving of the present invention, large particle diameter layer 2 can be comprised of gas concrete brickbat grain, and the section of each after filling is all that particle diameter is ascending from top to bottom like this.
Further, in order to improve sewage treatment capacity, improve organic degree of degradation, can lay ventpipe 3 at large particle diameter layer 2, carry out aeration, water inlet adopts intermittent loading mode, in bed of packings three sections different time sections in whole bed of packings forms respectively the filtering layer of using aerobic-anoxia-aerobic-anerobic-aerobic-anerobic like this, in whole bed of packings, form the A/O conversion zone of multistage, form multistage biological nitration-denitrification process, carry out biological denitrificaion.
Further, can be in the bed of packings the superiors, plantation wetland plant, can beautify the environment so on the one hand, can also absorb on the other hand the materials such as nitrogen phosphorus in sewage, improves wastewater treatment efficiency.Sewage after handling is discharged by being arranged at the rising pipe 4 of bed of packings bottom.
Like this, adopt the granular sewage sludge compounded mix of giving of the present invention by above paving mode, the sewage of handling, can reach discharging standards.
The above, be only the specific embodiment of the present invention, but protection scope of the present invention is not limited to this, and any variation of expecting without creative work or replacement, within all should being encompassed in protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.

Claims (6)

1. give a manufacture method for sewage sludge compounded mix, it is characterized in that:
Get mud some, crushed after being dried is sieved, and obtains mud raw material;
Mud raw material is mixed according to 1:0.2 ~ 0.5 weight ratio with hard coal, obtain compound;
In compound, add starch paste, wherein starch paste consumption is the 2-5% of compound weight, and mixing and stirring, obtains mud mixture;
By mixture, granulation, dry;
Temperature roasting by dried particle with 300 ~ 600 ℃;
The polymeric aluminum chlorides solution that is 5 ~ 10% by concentration by the particle after roasting soaks;
The particle soaking is mixed according to 1:0.2 ~ 0.5 weight ratio with sponge iron.
2. manufacture method according to claim 1, is characterized in that: described in to get mud some, comprise the mud of choosing in the settling tank of waterworks.
3. the manufacture of the manufacture method to sewage sludge compounded mix according to claim 1 is granular to sewage sludge compounded mix.
4. one kind adopts the granular bed of packings to sewage sludge compounded mix claimed in claim 3, it is characterized in that: described bed of packings is comprised of multistage, each section forms by small particle size layer and large particle diameter layer, small particle size layer is layed on large particle diameter layer, small particle size layer comprises granular to sewage sludge compounded mix, large particle diameter layer comprises gas concrete brick grain, presses the anti-granularity of different-grain diameter layers of material for every section and lays.
5. bed of packings according to claim 4, is characterized in that: in described large particle diameter layer, lay ventpipe.
6. bed of packings according to claim 4, is characterized in that: the bed of packings the superiors, plantation wetland plant.
CN201310700033.2A 2013-12-19 2013-12-19 A kind of manufacture method of copper water-supply pipe compounded mix and bed of packings thereof Expired - Fee Related CN103626286B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104528902A (en) * 2014-12-16 2015-04-22 上海交通大学 Novel polymeric aluminum chloride dephosphorizing filler and preparation method thereof
CN105776763A (en) * 2016-04-27 2016-07-20 中国科学院水生生物研究所 Novel composite substrate for vertical flow artificial wetlands

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101229945A (en) * 2007-01-22 2008-07-30 大连理工大学 Biological aerated filter filler using waste material as raw material and preparation method thereof
CN102161527A (en) * 2010-12-22 2011-08-24 兰州交通大学 Sponge iron-AT (Attapulgite)-PVF (Polyvinyl Fluoride) composite filler and application thereof on water treatment
CN102616921A (en) * 2012-04-09 2012-08-01 河海大学 Composite ecological fillers and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101229945A (en) * 2007-01-22 2008-07-30 大连理工大学 Biological aerated filter filler using waste material as raw material and preparation method thereof
CN102161527A (en) * 2010-12-22 2011-08-24 兰州交通大学 Sponge iron-AT (Attapulgite)-PVF (Polyvinyl Fluoride) composite filler and application thereof on water treatment
CN102616921A (en) * 2012-04-09 2012-08-01 河海大学 Composite ecological fillers and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104528902A (en) * 2014-12-16 2015-04-22 上海交通大学 Novel polymeric aluminum chloride dephosphorizing filler and preparation method thereof
CN105776763A (en) * 2016-04-27 2016-07-20 中国科学院水生生物研究所 Novel composite substrate for vertical flow artificial wetlands
CN105776763B (en) * 2016-04-27 2020-05-22 中国科学院水生生物研究所 Novel vertical-flow constructed wetland combined matrix

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