CN103625202A - Drawing decorative film with frosting effect - Google Patents
Drawing decorative film with frosting effect Download PDFInfo
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- CN103625202A CN103625202A CN201310681151.3A CN201310681151A CN103625202A CN 103625202 A CN103625202 A CN 103625202A CN 201310681151 A CN201310681151 A CN 201310681151A CN 103625202 A CN103625202 A CN 103625202A
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- parts
- wire drawing
- decorating film
- film according
- decorative film
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- 230000000694 effects Effects 0.000 title claims abstract description 29
- 239000010410 layer Substances 0.000 claims abstract description 47
- 239000011248 coating agent Substances 0.000 claims abstract description 36
- 238000000576 coating method Methods 0.000 claims abstract description 36
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920005989 resin Polymers 0.000 claims abstract description 18
- 239000011347 resin Substances 0.000 claims abstract description 18
- 229920008347 Cellulose acetate propionate Polymers 0.000 claims abstract description 13
- 239000011241 protective layer Substances 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000000758 substrate Substances 0.000 claims abstract description 9
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 8
- 239000003377 acid catalyst Substances 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 6
- 239000002904 solvent Substances 0.000 claims abstract description 6
- 239000002270 dispersing agent Substances 0.000 claims abstract description 5
- 238000005491 wire drawing Methods 0.000 claims description 56
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 39
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 26
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 24
- 239000012530 fluid Substances 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 17
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 13
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 13
- 238000002360 preparation method Methods 0.000 claims description 7
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical group CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 7
- 235000013312 flour Nutrition 0.000 claims description 5
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 3
- 239000012046 mixed solvent Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 abstract description 4
- 239000004033 plastic Substances 0.000 abstract description 3
- 238000005034 decoration Methods 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 abstract 2
- 239000004640 Melamine resin Substances 0.000 abstract 1
- 229920000877 Melamine resin Polymers 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 13
- -1 siloxanes Chemical class 0.000 description 9
- 238000001771 vacuum deposition Methods 0.000 description 6
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 238000001723 curing Methods 0.000 description 3
- 238000013007 heat curing Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000011247 coating layer Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 208000034189 Sclerosis Diseases 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- AVMNFQHJOOYCAP-UHFFFAOYSA-N acetic acid;propanoic acid Chemical compound CC(O)=O.CCC(O)=O AVMNFQHJOOYCAP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a drawing decorative film with the frosting effect. The decorative film is composed of a substrate, a release layer, a protective layer, a decorative layer and a bonding layer which are sequentially overlapped together. The release layer is formed by applying a coating liquid on the surface of the substrate through curing and drawing, wherein the coating liquid is prepared from the following materials in parts by weight: 20-30 parts of hex-methoxymethyl melamine resin, 5-10 parts of cellulose acetate propionate resin, 5-8 parts of organic silicon resin, 5-10 parts of an acid catalyst, 8-12 parts of silica powder, 2-4 parts of high-white aluminum silicate, 0.2-2 parts of a dispersing agent, 0.2-0.5 part of a flatting agent and 30-60 parts of a solvent. The frosting drawing texture of the decorative film is real, and the decorative film can be widely applied to surface decoration of high-grade plastic parts.
Description
Technical field
The present invention relates to a kind of decorating film, particularly a kind of wire drawing decorative film with frosted finish effect.
Background technology
Along with social development, the parts such as household electrical appliance, automobile, mobile phone have all adopted working of plastics in a large number, on working of plastics surface, adopt metal wire-drawing to decorate, and can show the decorative effect of high texture, meet its high-grade demand of decorating.
Application number is that 201210145622.4 Chinese patent discloses a kind of double-sided metal wire drawing decorative film for transparent plastic article, by to heat-curable coating wire drawing, the wire drawing mode of the curing aftershaping of UV is carried out wire drawing to coating, thereby forms the decorating film with two-sided wire-drawing effect.But this wire drawing decorative film does not have frosted texture, can not meet the decoration demand of frosted wire drawing.
Summary of the invention
The technical problem to be solved in the present invention is the weak point existing for prior art, and a kind of wire drawing decorative film with frosted finish effect is provided.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
A kind of wire drawing decorative film with frosted finish effect, described decorating film is comprised of superimposed preparation base material, release layer, protective layer, decorative layer and adhered layer together successively, and the coating fluid that described release layer is comprised of the material that contains following portions by weight is coated on substrate surface through solidifying and wire drawing forms: 20～30 parts of HMMM resins; 5～10 parts of cellulose acetate propionate resins; Organic siliconresin 5-8 part; 5～10 parts of acid catalysts; 8～12 parts of silica flours; 2～4 parts of high white alumina silicate; 0.2～2 part of dispersant; Levelling agent 0.2-0.5 part; 30～60 parts of solvents.
The above-mentioned wire drawing decorative film with frosted finish effect, described cellulose acetate propionate is the cellulose acetate propionate of hydroxyl.
The above-mentioned wire drawing decorative film with frosted finish effect, described organic siliconresin is polymethyl siloxane.
The above-mentioned wire drawing decorative film with frosted finish effect, described acid catalyst is p-methyl benzenesulfonic acid.
The above-mentioned wire drawing decorative film with frosted finish effect, described silica flour is that particle diameter is the aerosil of 2～8 microns.
The above-mentioned wire drawing decorative film with frosted finish effect, the particle diameter of the white alumina silicate of described height is 2～5 microns.
The above-mentioned wire drawing decorative film with frosted finish effect, described levelling agent is organosilicon levelling agent.
The above-mentioned wire drawing decorative film with frosted finish effect, described solvent is the mixed solvent of butanone, ethyl acetate, isopropyl alcohol.
The above-mentioned wire drawing decorative film with frosted finish effect, the thickness of described release layer is 2～5 microns.
Compared with prior art, the present invention processes by the interaction between the adjustment of the selection of various components in release layer, consumption, various component with to the curing and wire drawing of release layer, when guaranteeing to there is frosted and wire-drawing effect, improved on the one hand the heat resistance of decorating film, guaranteed that decorating film is indeformable in high temperature process process; While making on the other hand decorating film thermoprint be worked into frosting, there is again good wearability.
The specific embodiment
The Main Function of the HMMM resin in the present invention is that heat cure cross-linking reaction forms fine and close coating, guarantees that the silica and the Gao Bai alumina silicate that are dispersed in are wherein particle stabilized, thereby forms the release layer with matte surface.The effect of the cellulose acetate propionate of hydroxyl is the curing reaction that participates in HMMM resin, and reduce and react shrinkage factor, improve the attachment fastness of release layer and PET support, the good film forming of coating is provided, and guarantees the continuity of the physics differential wire drawing in drawing process process.The acetate propionate fiber that is applicable to hydroxyl of the present invention includes but not limited to CAP-504 of eastman chemical etc.
In order to improve surperficial release effect, in the present invention, used organic siliconresin, provide the release interface of coating surface, the preferred polymethyl siloxane of organic siliconresin using in the present invention.
The Main Function of the acid catalyst in the present invention is the reaction that promotes HMMM, guarantees to be solidified fully in coating solidification process, is applicable to the preferred p-methyl benzenesulfonic acid of acid catalyst of the present invention.
Silica flour in the present invention is mainly to provide surperficial sub-light frosted finish effect, and it is selected from particle diameter is the aerosil of 2～8 microns.
The effect of the white alumina silicate of height in the present invention is to improve frosted texture, and it is selected from particle diameter is the white alumina silicate of height of 2～5 microns.
Dispersant effect in the present invention is to improve silica and the stability of Gao Bai alumina silicate in formula, is applicable to the DC-3 that dispersant of the present invention includes but not limited to DOW CORNING, the BYK-P104 of Bi Ke chemistry etc.
Levelling agent in the present invention is organosilicon levelling agent, is applicable to organosilicon levelling agent of the present invention and includes but not limited to polyether polyester modified siloxane, as BYK-310 of Bi Ke chemistry etc.
Solvent in the present invention is comprised of butanone, ethyl acetate, isopropyl alcohol, adopts the solvent mixture.
Wire drawing in the present invention is processed and is adopted following operation: the frosted release layer with wire drawing roller after to heat cure carries out wire drawing processing, the rotation direction of wire drawing roller and the direction of rotation of support.
The thickness of the frosted wire drawing release layer in the present invention is 2～5 microns, if coating layer thickness is less than 2 microns, after wire drawing is processed, protective layer anti-wear performance can not meet the demands; If coating layer thickness is greater than 5 microns, coating surface frosted finish effect reduces, and glossiness obviously improves.
Wire drawing decorative film provided by the invention can be prepared by following method:
On PET base material, be coated with release layer, frosted release layer carries out wire drawing after heat cure is processed, and forms frosted wire drawing release layer, is coated with protective layer, vacuum coating on protective layer on frosted wire drawing release layer; On plated film, be coated with adhered layer, obtain frosted wire drawing decorative film,
During application, after described frosted wire drawing decorative film application processing, between protective layer and frosted wire drawing layer, depart from, frosted wire drawing release layer is stripped from together with support, and decorated surface is the protective layer with the sclerosis of frosted wire drawing pattern.
Below in conjunction with embodiment, the present invention will be further described.
Embodiment 1
The preparation of release layer coating fluid:
20 parts of HMMM resins
10 parts of cellulose acetate propionate resins
5 parts of polymethyl siloxanes
5 parts of P-TOLUENE SULFO ACID 99s
8 parts of aerosils (particle diameter is 3.5 microns)
2 parts of high white alumina silicate (particle diameter is 2 microns)
0.2 part of DC-3
0.2 part of BYK-310
30 parts of butanone
10 parts of isopropyl alcohols
9.6 parts, ethyl acetate.
In container, first add butanone, isopropyl alcohol, ethyl acetate, then add successively above-mentioned other each component, through high-speed stirred, disperse to obtain coating fluid, stand-by.
PET substrate surface at 20 μ m is coated with above-mentioned coating fluid, through heated drying, solidifies and wire drawing processes that to obtain thickness be the release layer of 2 microns; On release layer, coating thickness is the protective layer of 1.5 microns, and then vacuum coating and coating adhered layer, obtain having the wire drawing decorative film of frosted finish effect.
The wire drawing decorative film thermoprint obtaining, to ABS plastic part, is tested to properties.
Embodiment 2
The preparation of release layer coating fluid:
30 parts of HMMM resins
10 parts of cellulose acetate propionate resins
5 parts of polymethyl siloxanes
10 parts of p-methyl benzenesulfonic acid
12 parts of aerosils (particle diameter is 2 microns)
2 parts of high white alumina silicate (particle diameter is 3 microns)
0.2 part of BYK-104
0.2 part of BYK-310
20 parts of butanone
14 parts of isopropyl alcohols
6.6 parts, ethyl acetate.
In container, first add butanone, isopropyl alcohol, ethyl acetate, then add successively above-mentioned other each component, through high-speed stirred, disperse to obtain coating fluid, stand-by.
PET substrate surface at 25 μ m is coated with above-mentioned coating fluid, through heated drying, solidifies and wire drawing processes that to obtain thickness be the release layer of 4 microns; On release layer, coating thickness is the protective layer of 1.5 microns, and then vacuum coating and coating adhered layer, obtain having the wire drawing decorative film of frosted finish effect.The frosted wire drawing decorative film thermoprint obtaining, to ABS plastic part, is tested to properties.
Embodiment 3
The preparation of release layer coating fluid:
25 parts of HMMM resins
5 parts of cellulose acetate propionate resins
5 parts of polymethyl siloxanes
5 parts of p-methyl benzenesulfonic acid
10 parts of aerosils (particle diameter is 3.5 microns)
2 parts of high white alumina silicate (particle diameter is 2.5 microns)
0.2 part of DC-3
0.2 part of BYK-310
30 parts of butanone
12 parts of isopropyl alcohols
9.6 parts, ethyl acetate.
In container, first add butanone, isopropyl alcohol, ethyl acetate, then add successively above-mentioned other each component, through high-speed stirred, disperse to obtain coating fluid, stand-by.
PET substrate surface at 30 μ m is coated with above-mentioned coating fluid, through heated drying, solidifies and wire drawing processes that to obtain thickness be the release layer of 2 microns; On release layer, coating thickness is the protective layer of 1.5 microns, and then vacuum coating and coating adhered layer, obtain having the wire drawing decorative film of frosted finish effect.
The frosted wire drawing decorative film thermoprint obtaining, to ABS plastic part, is tested to properties.
Embodiment 4
The preparation of release layer coating fluid:
20 parts of HMMM resins
10 parts of cellulose acetate propionate resins
5 parts of polymethyl siloxanes
5 parts of p-methyl benzenesulfonic acid
8 parts of aerosils (3.5 microns of particle diameters)
4 parts of high white alumina silicate (particle diameter is 4.5 microns)
0.2 part of BYK-104
0.2 part of BYK-310
28 parts of butanone
10 parts of isopropyl alcohols
9.6 parts, ethyl acetate.
In container, first add butanone, isopropyl alcohol, ethyl acetate, then add successively above-mentioned other each component, through high-speed stirred, disperse to obtain coating fluid, stand-by.
PET substrate surface at 23 μ m is coated with above-mentioned coating fluid, through heated drying, solidifies and wire drawing processes that to obtain thickness be the release layer of 2 microns; On release layer, coating thickness is the protective layer of 1.5 microns, and then vacuum coating and coating adhered layer, obtain having the wire drawing decorative film of frosted finish effect.
The frosted wire drawing decorative film thermoprint obtaining, to ABS plastic part, is tested to properties.
Embodiment 5
The preparation of release layer coating fluid:
25 parts of HMMM resins
8 parts of cellulose acetate propionate resins
5 parts of organic siliconresins
5 parts of p-methyl benzenesulfonic acid
10 parts of aerosils (2 microns of particle diameters)
4 parts of high white alumina silicate (4.5 microns of particle diameters)
0.2 part of DC-3
0.2 part of BYK-310
20 parts of butanone
15 parts of isopropyl alcohols
7.6 parts, ethyl acetate.
In container, first add butanone, isopropyl alcohol, ethyl acetate, then add successively above-mentioned other each component, through high-speed stirred, disperse to obtain coating fluid, stand-by.
PET substrate surface at 25 μ m is coated with above-mentioned coating fluid, through heated drying, solidifies and wire drawing processes that to obtain thickness be the release layer of 2 microns; On release layer, coating thickness is the protective layer of 1.5 microns, and then vacuum coating and coating adhered layer, obtain having the wire drawing decorative film of frosted finish effect.
The frosted wire drawing decorative film thermoprint obtaining, to ABS plastic part, is tested to properties.
| Embodiment | Roughness | Glossiness | Case hardness | Wearability |
| 1 | 0.5 micron | 35-50 | 2H | 35 times |
| 2 | 0.5 micron | 35-50 | 3H | 40 times |
| 3 | 0.5 micron | 35-50 | 3H | 40 times |
| 4 | 0.4 micron | 35-50 | 2H | 38 times |
| 5 | 0.4 micron | 35-50 | 2H | 38 times |
?in table, the method for testing of properties is as follows:
1. roughness: roughmeter test;
2. glossiness: 60 degree angle Grossmeters tests;
3. case hardness: pencil hardometer;
4. wearability: RCA paper tape abrasion instrument.
Claims (9)
1. a wire drawing decorative film with frosted finish effect, it is characterized in that, described decorating film is comprised of superimposed preparation base material, release layer, protective layer, decorative layer and adhered layer together successively, and the coating fluid that described release layer is comprised of the material that contains following portions by weight is coated on substrate surface through solidifying and wire drawing forms: 20～30 parts of HMMM resins; 5～10 parts of cellulose acetate propionate resins; Organic siliconresin 5-8 part; 5～10 parts of acid catalysts; 8～12 parts of silica flours; 2～4 parts of high white alumina silicate; 0.2～2 part of dispersant; Levelling agent 0.2-0.5 part; 30～60 parts of solvents.
2. decorating film according to claim 1, is characterized in that, described cellulose acetate propionate is the cellulose acetate propionate of hydroxyl.
3. decorating film according to claim 2, is characterized in that, described organic siliconresin is polymethyl siloxane.
4. decorating film according to claim 3, is characterized in that, described acid catalyst is p-methyl benzenesulfonic acid.
5. decorating film according to claim 4, is characterized in that, described silica flour is that particle diameter is the aerosil of 2～8 microns.
6. decorating film according to claim 5, is characterized in that, the particle diameter of the white alumina silicate of described height is 2～5 microns.
7. decorating film according to claim 6, is characterized in that, described levelling agent is organosilicon levelling agent.
8. decorating film according to claim 7, is characterized in that, described solvent is the mixed solvent of butanone, ethyl acetate, isopropyl alcohol.
9. decorating film according to claim 1, is characterized in that, the thickness of described release layer is 2～5 microns.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310681151.3A CN103625202B (en) | 2013-12-13 | 2013-12-13 | A kind of wire drawing decorative film with frosted finish effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310681151.3A CN103625202B (en) | 2013-12-13 | 2013-12-13 | A kind of wire drawing decorative film with frosted finish effect |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103625202A true CN103625202A (en) | 2014-03-12 |
| CN103625202B CN103625202B (en) | 2016-09-14 |
Family
ID=50206805
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310681151.3A Active CN103625202B (en) | 2013-12-13 | 2013-12-13 | A kind of wire drawing decorative film with frosted finish effect |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103625202B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104985490A (en) * | 2015-06-05 | 2015-10-21 | 深圳市依诺威电子有限公司 | Wiredrawing machining method for hard aluminum alloy base materials |
| CN105670326A (en) * | 2015-12-31 | 2016-06-15 | 钟莉 | Frosting plastic material with superior frosting performance |
| CN109096513A (en) * | 2018-07-10 | 2018-12-28 | 温州新意特种纸业有限公司 | A kind of PET release film and its manufacturing method |
| CN113815340A (en) * | 2021-09-17 | 2021-12-21 | 邝国材 | Preparation process of pre-coated composite transfer membrane |
| CN114379276A (en) * | 2021-10-29 | 2022-04-22 | 邝国材 | Transfer printing process for precoating composite film |
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| JP2010275558A (en) * | 2010-07-16 | 2010-12-09 | Shin-Etsu Chemical Co Ltd | Liquid silicone rubber coating agent composition for curtain airbag, curtain airbag, and method for manufacturing the same |
| CN102417796A (en) * | 2011-08-31 | 2012-04-18 | 保定乐凯新材料股份有限公司 | Metal decorating film with hardened protective layer and preparation method thereof |
| CN102642440A (en) * | 2012-05-11 | 2012-08-22 | 保定乐凯新材料股份有限公司 | Double-faced drawing decorative film for transparent plastic component |
| CN102673287A (en) * | 2012-05-14 | 2012-09-19 | 保定乐凯新材料股份有限公司 | Non-halogen transfer type decoration film used for plastic surface decoration |
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| CN101417579A (en) * | 2008-12-03 | 2009-04-29 | 中国乐凯胶片集团公司 | Decorating film |
| JP2010275558A (en) * | 2010-07-16 | 2010-12-09 | Shin-Etsu Chemical Co Ltd | Liquid silicone rubber coating agent composition for curtain airbag, curtain airbag, and method for manufacturing the same |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104985490A (en) * | 2015-06-05 | 2015-10-21 | 深圳市依诺威电子有限公司 | Wiredrawing machining method for hard aluminum alloy base materials |
| CN105670326A (en) * | 2015-12-31 | 2016-06-15 | 钟莉 | Frosting plastic material with superior frosting performance |
| CN109096513A (en) * | 2018-07-10 | 2018-12-28 | 温州新意特种纸业有限公司 | A kind of PET release film and its manufacturing method |
| CN113815340A (en) * | 2021-09-17 | 2021-12-21 | 邝国材 | Preparation process of pre-coated composite transfer membrane |
| CN114379276A (en) * | 2021-10-29 | 2022-04-22 | 邝国材 | Transfer printing process for precoating composite film |
| CN114379276B (en) * | 2021-10-29 | 2022-11-29 | 腾锦(广东)新材料科技有限公司 | Transfer printing process for pre-coating composite film |
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|---|---|
| CN103625202B (en) | 2016-09-14 |
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