CN105670326A - Frosting plastic material with superior frosting performance - Google Patents
Frosting plastic material with superior frosting performance Download PDFInfo
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- CN105670326A CN105670326A CN201511035703.9A CN201511035703A CN105670326A CN 105670326 A CN105670326 A CN 105670326A CN 201511035703 A CN201511035703 A CN 201511035703A CN 105670326 A CN105670326 A CN 105670326A
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- frosted
- plastic material
- granule
- layer
- frosting
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
Abstract
The invention relates to a frosting plastic material with a superior frosting performance. The frosting plastic material comprises a plastic material and a plurality of frosting particles, wherein the melting point of the frosting particles is higher than the melting point and the processing temperature of the plastic material, and the frosting particles are uniformly distributed in the plastic material. The frosting plastic material has the advantages of very good frosting effect, no generation of a large amount of sewage in the production process, small pollution to environment, light weight, difficult fragmentation, difficult occurrence of safety accidents, and convenient transportation and storage.
Description
Technical field
The present invention relates to a kind of frosted plastic material that can apply to the fields such as building materials, lampshade, section bar, tubing.
Background technology
At present, abrasive material mainly includes ground glass material and frosted plastic material. Ground glass material obtains the method for frosted finish effect pickling processes and blasting treatment. Wherein, pickling processes, acid cleaning process can produce substantial amounts of sewage, it is easy to environment is affected greatly, and the optical property of wayward ground glass. And blasting treatment, then adopting compression air is power, promotes abrasive material to carry out the process processed to glass surface, after treatment, makes glass surface produce frosted stricture of vagina reason; The factor impacts such as the uniformity that the frosted finish effect of glass plate is vulnerable to speed that spray gun and the distance of surface of the work, spray gun move, spray gun shakes out, and what these factors were also difficult to control. Therefore, blasting treatment mode is also not easy to control the optical property of ground glass. Additionally, ground glass material there is also Heavy Weight, broken, easily produce security incident, not readily transportable with the shortcoming such as deposit.
Frosted plastic material is compared to ground glass material, although have lightweight and not broken, be not likely to produce security incident, transport and deposit the advantages such as convenient, but the mode of the frosted finish effect of frosted plastic material acquisition at present adopts rolling technology to obtain mostly, it is the physical arrangement by changing plastic material surface, makes plastic material surface frosted texture occur. But, in frosted plastic material subsequent applications, also tend to frosted plastic material to be stretched or the hot-working such as blowing, owing to frosted texture part is by rolling out at plastic material surface, so the composition of frosted texture and plastics material body are identical, it is being heated and is carrying out stretching or after blowing, frosted texture can deform along with the deformation of plastics material body, the frosted texture that can make plastic material surface is greatly reduced or disappears, thus being unable to reach intended frosted finish effect; Further, the application of rolling technology is extremely easily subject to shape (such as heterotypic material, the tubular material) restriction of plastic material so that narrower and application the facility of its range of application is had a greatly reduced quality.
Summary of the invention
It is an object of the invention to solve the problems referred to above and deficiency, the frosted plastic material of a kind of frosted superior performance is provided, the frosted finish effect that this frosted plastic material obtains is very good, physical arrangement is stable, large amount of sewage will not be produced in process of production, the pollution of environment is little, and also there is simple structure, easily realize, lightweight, not broken, be not likely to produce security incident, transport and deposit the advantages such as convenience, applied range.
The technical scheme is that and be achieved in that: the frosted plastic material of a kind of frosted superior performance, it is characterized in that and includes plastic material, some frosted granules, wherein the fusing point of frosted granule is higher than fusing point and the processing temperature of plastic material, and described each frosted granule is laid in a plastic material equably.
Further, the particle diameter of described frosted granule is 2 μm-200 μm.
Yet further, the refractive index of described frosted granule is 1.3-3.0.
On aforesaid basis, the concrete structure of plastic material be also proposed two kinds of designs by the present invention, and it is respectively as follows:
The first, described plastic material includes frosted top layer, basic unit, and wherein each frosted granule is laid in frosted top layer equably, and the fusing point of frosted granule is that stacking is arranged higher than fusing point and processing temperature, described frosted top layer and the basic unit of frosted top layer and basic unit.
The second, described plastic material includes frosted top layer, basic unit, frosted bottom, wherein each frosted granule is laid in frosted top layer and frosted bottom respectively equably, and the fusing point of frosted granule is higher than fusing point and the processing temperature of frosted top layer, frosted bottom and basic unit; Described frosted top layer and frosted bottom are respectively arranged on the surface of basic unit and bottom surface and cambium layer stacked configuration.
On the basis of aforementioned two kinds of plastic material schemes, described basic unit can be transparent plastic material layer, or can also be opaque plastics material layer; When adopting transparent plastic material layer, in order to promote the light diffusing energy of transparent plastic material layer in plastic material further, this transparent plastic material layer is further equally laid with some smooth diffusion particles.
Beneficial effects of the present invention: the frosted plastic material of frosted superior performance of the present invention includes plastic material and lays frosted granule in a plastic material equably, wherein the fusing point of frosted granule is higher than fusing point and the processing temperature of plastic material, and described frosted granule is put in plastic material when plastic material is in molten condition. owing to the Main Ingredients and Appearance of obtained frosted plastic material is plastics, so its lighter in weight, and not broken, without producing security incident, transport with deposit also more convenient. by aforementioned rational design, make frosted plastic material in subsequent applications, such as carry out stretching or during the heat treatment such as blowing, frosted granule simply there occurs mobile change in plastic material deformation process, both some only moved inside plastic material in this mobile change of frosted granule, also some has emerged the surface of plastic material, after making processing, there has been rough granular sensation surface on the surface of plastic material, but the quantity of frosted granule can't reduce, frosted granule is without melting or occurring physical features to change, frosted physical arrangement is sufficiently stable, thus avoiding the heat treatment of stretching or blowing that the frosted finish effect of plastic material finished product is produced impact, plastic material finished product is made to have good frosted finish effect, and frosted optical property controls very well, as long as controlling frosted granule addition in a plastic material and reasonably controlling the particle diameter of frosted granule. will not producing substantial amounts of sewage in the production process of frosted plastic material of the present invention, therefore it is only small to the pollution of environment simultaneously. frosted plastic material of the present invention can be applicable on building materials, lampshade, section bar, tubing, heterotypic material etc.
Accompanying drawing explanation
Fig. 1 is the structural representation of scheme one in the present invention.
Fig. 2 is the structural representation of scheme two in the present invention.
Fig. 3 is the structural representation of scheme three in the present invention.
Fig. 4 is the structure for amplifying schematic diagram of part A in Fig. 3 of the present invention.
Detailed description of the invention
As shown in Figure 1, the frosted plastic material of a kind of frosted superior performance of the present invention, including plastic material 1, some frosted granules 10 fusing point (melt temperature) higher than the fusing point (melt temperature) of plastic material 1 and processing temperature, described each frosted granule 10 is laid in plastic material 1 equably. in implementation process, plastic material 1 can make single layer structure, it is also possible to makes multiple structure. wherein, frosted granule 10 is plastic material 1 when being in molten condition, puts into or is distributed in plastic material 1, be then reprocessed into frosted plastic material. of course, raw material monomer when plastic polymer can also add frosted granule, then frosted plastic material it is reprocessed into, the effect of its acquisition is substantially the same, but this situation adding frosted granule in raw material monomer, is generally suitable only for the plastic material product of monolayer constructions will. it addition, the fusing point of frosted granule 10 (melt temperature) is higher than fusing point (melt temperature) and the processing temperature of raw material monomer equally. owing to the composition of plastic material 1 is mainly plastics, so after being processed into finished product (such as: lamellar sheet material, tubing, section bar etc.), its lighter in weight, and not broken, without producing security incident, transport with deposit also more convenient. in finished product subsequent applications, such as, frosted plastic material is stretched or during the heat treatment of blowing etc., frosted granule is simply in the deformation process of frosted plastic material, mobile change is there occurs along with the change of frosted plastic material shape, both some only moved inside plastic material in this mobile change of frosted granule, also some has emerged the surface of plastic material, after making processing, there has been rough granular sensation surface on the surface of plastic material, but the quantity of frosted granule can't reduce, frosted granule is without melting or occurring physical features to change, frosted physical arrangement is sufficiently stable, the simply slightly fraction of change of density of frosted granule, thus avoiding the heat treatment of stretching or blowing that the frosted finish effect of plastic material finished product is produced impact, sheet material is made to have good frosted finish effect. production process at the frosted plastic material of the present invention will not produce substantial amounts of sewage, and therefore it is substantially free of contamination to environment, very environmental protection. frosted plastic material of the present invention can be applicable on building materials, sheet material, lampshade, section bar, tubing, heterotypic material etc.
The particle diameter of described frosted granule 10 is 2 μm-200 μm, and described frosted granule 10 is resistant to elevated temperatures organic granular or inorganic particle, and wherein frosted granule 10 both can adopt nanotechnology to process, it is also possible to is not. It addition, in order to ensure that frosted granule 10 has preferably anaclasis effect, the refractive index of described frosted granule controls within the scope of 1.3-3.0, in other words, the organic material meeting this value range or inorganic material is selected to process.
On the basis of aforementioned schemes, the concrete structure of plastic material 1 is given two kinds of designs by the present invention, and it is respectively as follows:
The first, as in figure 2 it is shown, described plastic material 1 includes frosted top layer 2, basic unit 3, wherein each frosted granule 10 is laid in frosted top layer 2 equably, and the fusing point of frosted granule 10 is that stacking is arranged higher than fusing point and processing temperature, described frosted top layer 2 and the basic unit 3 of frosted top layer 2 and basic unit 3.
The second, as shown in Figure 3 and Figure 4, described plastic material 1 includes frosted top layer 2, basic unit 3, frosted bottom 4, wherein each frosted granule 10 is laid in frosted top layer 2 and frosted bottom 4 respectively equably, and the fusing point of frosted granule 10 is higher than fusing point and the processing temperature of frosted top layer 2, frosted bottom 4 and basic unit 3; Described frosted top layer 2 and frosted bottom 4 are respectively arranged on the surface of basic unit 3 and bottom surface and cambium layer stacked configuration.
Except above two scheme, it is also possible to as it is shown in figure 1, only the scheme of one layer of basic unit's structure is available for implementing, so make the present invention can effectively meet every profession and trade to frosted plastic materials application requirement.
On the basis of aforementioned two kinds of plastic material schemes, described basic unit 3 can be transparent plastic material layer, or can also be opaque plastics material layer. When adopting transparent plastic material layer, for promoting the light diffusing energy of transparent plastic material layer in plastic material further, this transparent plastic material layer is laid with some smooth diffusion particles 20 equably.
Additionally, described frosted top layer 2 is transparent plastic material layer or opaque plastics material layer, described frosted bottom 4 is transparent plastic material layer or opaque plastics material layer. Transparent plastic material layer mentioned here, had both comprised the situation of the plastic material layer of all-transparent shape, also comprised the situation of translucent plastic material layer. When transparent plastic material layered scheme selected by described frosted top layer 2, frosted bottom 4, for promoting the light diffusing energy of this transparent plastic material layer further, this transparent plastic material layer is further equally provided with some smooth diffusion particles 20. Various different product can be produced with this, be suitable for different application scenario needs.
Reasonably controlling frosted granule addition in a plastic material and reasonably controlling the particle diameter of frosted granule, it is possible to producing and meet the plastic material with frosted finish effect that industry-by-industry uses out. Such as, when producing a kind of plastic plate that frosted granular sensation is obvious, feel is strong or other shapes of plastics part, can select particle diameter is 30 μm-200 μm, hundred parts of ratios of quality account for the frosted granule of the 5%-30% of raw materials for plastics production, and having the scheme of frosted layer, hundred parts of ratios of quality account for the frosted granule of the raw-material 5%-30% of frosted layer. Again such as, produce that a kind of frosted is fine and smooth, the plastic plate of matte effect or during other shapes of plastics part, can select particle diameter is 2 μm-30 μm, hundred parts of ratios of quality account for the frosted granule of the 5%-30% of raw materials for plastics production, and having the scheme of frosted layer, hundred parts of ratios of quality account for the frosted granule of the raw-material 5%-30% of frosted layer. Described frosted granule can except on-demand selection except particle diameter, and the refractive index of frosted granule can also carry out selecting to use according to actual needs. Therefore, the present invention is compared with the frosted plastic material of the ground glass of pickling processes of the prior art or blasting treatment and rolling technology, technical scheme is all control very well in frosted granular sensation and frosted optical property, can produce into satisfied application convenient, simply and require that the abrasive material of parameter is come. Furthermore, it is possible to produce the plastics part of variously-shaped structure or special type structure, it does not have any limitation so that the occasion of present invention application is very extensive.
Claims (10)
1. the frosted plastic material of a frosted superior performance, it is characterized in that: include plastic material (1), some frosted granules (10), wherein the fusing point of frosted granule (10) is higher than fusing point and the processing temperature of plastic material (1), and described each frosted granule (10) is laid in plastic material (1) equably.
2. the frosted plastic material of frosted superior performance according to claim 1, it is characterised in that: the particle diameter of described frosted granule (10) is 2 μm-200 μm.
3. the frosted plastic material of frosted superior performance according to claim 1, it is characterised in that: the refractive index of described frosted granule (10) is 1.3-3.0.
4. the frosted plastic material of frosted superior performance according to claim 1, it is characterized in that: described plastic material (1) includes frosted top layer (2), basic unit (3), wherein each frosted granule (10) is laid in frosted top layer (2) equably, and the fusing point of frosted granule (10) is arranged in stacking higher than fusing point and processing temperature, described frosted top layer (2) and the basic unit (3) of frosted top layer (2) and basic unit (3).
5. the frosted plastic material of frosted superior performance according to claim 1, it is characterized in that: described plastic material (1) includes frosted top layer (2), basic unit (3), frosted bottom (4), wherein each frosted granule (10) is laid in frosted top layer (2) and frosted bottom (4) respectively equably, and the fusing point of frosted granule (10) is higher than fusing point and the processing temperature of frosted top layer (2), frosted bottom (4) and basic unit (3); Described frosted top layer (2) and frosted bottom (4) are respectively arranged on the surface of basic unit (3) and bottom surface and cambium layer stacked configuration.
6. the frosted plastic material of frosted superior performance according to claim 4 or 5, it is characterised in that: described frosted top layer (2) is transparent plastic material layer or opaque plastics material layer.
7. the frosted plastic material of frosted superior performance according to claim 5, it is characterised in that: described frosted bottom (4) is transparent plastic material layer or opaque plastics material layer.
8. the frosted plastic material of frosted superior performance according to claim 4 or 5, it is characterised in that: described basic unit (3) is transparent plastic material layer or opaque plastics material layer.
9. the frosted plastic material of frosted superior performance according to claim 8, it is characterised in that: described basic unit (3) is transparent plastic material layer, is laid with some smooth diffusion particles (20) in this transparent plastic material layer equably.
10. the frosted plastic material of frosted superior performance according to claim 5, it is characterized in that: described frosted top layer (2), frosted bottom (4) are transparent plastic material layer, this transparent plastic material layer is further equally provided with some smooth diffusion particles (20).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511035703.9A CN105670326A (en) | 2015-12-31 | 2015-12-31 | Frosting plastic material with superior frosting performance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511035703.9A CN105670326A (en) | 2015-12-31 | 2015-12-31 | Frosting plastic material with superior frosting performance |
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| Publication Number | Publication Date |
|---|---|
| CN105670326A true CN105670326A (en) | 2016-06-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511035703.9A Pending CN105670326A (en) | 2015-12-31 | 2015-12-31 | Frosting plastic material with superior frosting performance |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113022072A (en) * | 2021-04-12 | 2021-06-25 | 上海品诚控股集团有限公司 | Spraying-free hollow plate with texture on surface and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1358788A (en) * | 2002-01-18 | 2002-07-17 | 北京化工大学 | Method for preparing mother material from nano grade inorganic powder material |
| CN103625202A (en) * | 2013-12-13 | 2014-03-12 | 保定乐凯新材料股份有限公司 | Drawing decorative film with frosting effect |
| CN204009122U (en) * | 2013-11-26 | 2014-12-10 | 连平长荣塑胶有限公司 | A kind of plastic reflective sheet |
| KR20150075471A (en) * | 2013-12-26 | 2015-07-06 | 코오롱인더스트리 주식회사 | Polyester resin composition and polyester film using thereof |
-
2015
- 2015-12-31 CN CN201511035703.9A patent/CN105670326A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1358788A (en) * | 2002-01-18 | 2002-07-17 | 北京化工大学 | Method for preparing mother material from nano grade inorganic powder material |
| CN204009122U (en) * | 2013-11-26 | 2014-12-10 | 连平长荣塑胶有限公司 | A kind of plastic reflective sheet |
| CN103625202A (en) * | 2013-12-13 | 2014-03-12 | 保定乐凯新材料股份有限公司 | Drawing decorative film with frosting effect |
| KR20150075471A (en) * | 2013-12-26 | 2015-07-06 | 코오롱인더스트리 주식회사 | Polyester resin composition and polyester film using thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113022072A (en) * | 2021-04-12 | 2021-06-25 | 上海品诚控股集团有限公司 | Spraying-free hollow plate with texture on surface and preparation method thereof |
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Application publication date: 20160615 |
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