CN103619902A - 半导体聚合物 - Google Patents

半导体聚合物 Download PDF

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Publication number
CN103619902A
CN103619902A CN201280028860.5A CN201280028860A CN103619902A CN 103619902 A CN103619902 A CN 103619902A CN 201280028860 A CN201280028860 A CN 201280028860A CN 103619902 A CN103619902 A CN 103619902A
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semiconducting polymer
polymer
alkyl
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Chinese (zh)
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俞陆平
H·J·孙
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University of Chicago
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University of Chicago
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/151—Copolymers
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    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/20—Carbon compounds, e.g. carbon nanotubes or fullerenes
    • H10K85/211—Fullerenes, e.g. C60
    • H10K85/215—Fullerenes, e.g. C60 comprising substituents, e.g. PCBM
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/14—Side-groups
    • C08G2261/141—Side-chains having aliphatic units
    • C08G2261/1412—Saturated aliphatic units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/14—Side-groups
    • C08G2261/142—Side-chains containing oxygen
    • C08G2261/1426—Side-chains containing oxygen containing carboxy groups (COOH) and/or -C(=O)O-moieties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/14—Side-groups
    • C08G2261/146—Side-chains containing halogens
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/324—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed
    • C08G2261/3243—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed containing one or more sulfur atoms as the only heteroatom, e.g. benzothiophene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/90—Applications
    • C08G2261/91—Photovoltaic applications
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    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/30—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising bulk heterojunctions, e.g. interpenetrating networks of donor and acceptor material domains
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/50—Photovoltaic [PV] devices
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Photovoltaic Devices (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
CN201280028860.5A 2011-04-15 2012-04-13 半导体聚合物 Pending CN103619902A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161517205P 2011-04-15 2011-04-15
US61/517,205 2011-04-15
PCT/US2012/033601 WO2012142469A1 (en) 2011-04-15 2012-04-13 Semiconducting polymers

Publications (1)

Publication Number Publication Date
CN103619902A true CN103619902A (zh) 2014-03-05

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CN201280028860.5A Pending CN103619902A (zh) 2011-04-15 2012-04-13 半导体聚合物

Country Status (6)

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US (1) US9153785B2 (enExample)
EP (1) EP2697283A4 (enExample)
JP (1) JP2014518562A (enExample)
KR (1) KR101545429B1 (enExample)
CN (1) CN103619902A (enExample)
WO (1) WO2012142469A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110317210A (zh) * 2018-03-30 2019-10-11 中国科学院化学研究所 平面茚并茚—二噻吩类光伏受体材料、其制备方法及应用
CN111269083A (zh) * 2020-02-24 2020-06-12 珠海市柏瑞医药科技有限公司 一种格尔伯特酸的合成方法

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014531493A (ja) * 2011-09-23 2014-11-27 オーシャンズ キング ライティング サイエンスアンドテクノロジー カンパニー リミテッド ジフルオロベンゾトリアゾリル太陽電池ポリマー材料、並びにその調製方法及び使用
US9006568B2 (en) 2012-02-15 2015-04-14 Phillips 66 Company Synthesis of photovoltaic conjugated polymers
US9691986B2 (en) 2012-12-03 2017-06-27 Solarmer Energy, Inc. Furan and selenophene derivatized benzo [1,2-b:4,5-b′] dithiophene-thienothiophene based conjugated polymers for high-efficiency organic solar cells
KR101563048B1 (ko) * 2013-05-10 2015-10-30 주식회사 엘지화학 광활성층, 이를 포함하는 유기 태양 전지 및 이의 제조 방법
CN103626976B (zh) * 2013-11-22 2016-08-17 武汉理工大学 苯并[2，1-b:3，4-b′]二硒吩类聚合物半导体材料及其应用
US10818849B2 (en) * 2015-12-29 2020-10-27 The University Of Chicago Electron acceptors based on alpha-position substituted PDI for OPV solar cells
JP2017149689A (ja) * 2016-02-25 2017-08-31 株式会社トクヤマ クロロプロパン類の製造方法
CN111349003B (zh) * 2018-12-20 2023-10-03 四川科瑞德制药股份有限公司 一种丙戊酸钠的制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101170161A (zh) * 2006-10-25 2008-04-30 施乐公司 电子器件
CN101343351A (zh) * 2007-07-13 2009-01-14 气体产品与化学公司 含有硒的导电性聚合物以及制备导电性聚合物的方法
WO2010008672A1 (en) * 2008-07-18 2010-01-21 University Of Chicago Semiconducting polymers

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7432340B2 (en) 2002-07-11 2008-10-07 Air Products And Chemicals, Inc. Fluorinated alkyl substituted-thieno[3,4-]thiophene monomers and polymers therefrom
US7071289B2 (en) 2002-07-11 2006-07-04 The University Of Connecticut Polymers comprising thieno [3,4-b]thiophene and methods of making and using the same
DE602004017550D1 (de) 2003-08-28 2008-12-18 Merck Patent Gmbh Mono-, Oligo- und Polythienoi2,3-b thiophene
DE602004024629D1 (de) 2003-10-15 2010-01-28 Merck Patent Gmbh Polybenzodithiophene
CN101495487A (zh) 2006-07-26 2009-07-29 默克专利有限公司 取代的苯并二噻吩和苯并二硒吩
US7834132B2 (en) 2006-10-25 2010-11-16 Xerox Corporation Electronic devices
US7982055B2 (en) * 2007-07-13 2011-07-19 Konarka Technologies, Inc. Heterocyclic fused selenophene monomers
US20090140219A1 (en) * 2007-07-13 2009-06-04 Air Products And Chemicals, Inc. Selenium Containing Electrically Conductive Polymers and Method of Making Electrically Conductive Polymers
JP5647121B2 (ja) * 2008-08-18 2014-12-24 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツングＭｅｒｃｋ Ｐａｔｅｎｔ Ｇｅｓｅｌｌｓｃｈａｆｔ ｍｉｔ ｂｅｓｃｈｒａｅｎｋｔｅｒ Ｈａｆｔｕｎｇ インダセノジチオフェンおよびインダセノジセレノフェンポリマーおよび有機半導体としてのそれらの使用
US8372945B2 (en) * 2009-07-24 2013-02-12 Solarmer Energy, Inc. Conjugated polymers with carbonyl substituted thieno[3,4-B]thiophene units for polymer solar cell active layer materials
KR101780083B1 (ko) 2009-12-02 2017-10-10 바스프 에스이 디티에노벤조-티에노［3,2-ｂ］티오펜 공중합체 및 고성능 용액 공정 가능한 반도체 중합체로서 이의 용도
WO2011156478A2 (en) 2010-06-08 2011-12-15 The University Of North Carolina At Chapel Hill Polymers with tunable band gaps for photonic and electronic applications

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101170161A (zh) * 2006-10-25 2008-04-30 施乐公司 电子器件
CN101343351A (zh) * 2007-07-13 2009-01-14 气体产品与化学公司 含有硒的导电性聚合物以及制备导电性聚合物的方法
WO2010008672A1 (en) * 2008-07-18 2010-01-21 University Of Chicago Semiconducting polymers

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
ASIT PATRA, ET AL.: ""Tuning the Band Gap of Low-Band-Gap Polyselenophenes and Polythiophenes: The Effect of the Heteroatom"", 《CHEM. MATER.》, vol. 23, no. 3, 11 January 2011 (2011-01-11), pages 896 - 906 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110317210A (zh) * 2018-03-30 2019-10-11 中国科学院化学研究所 平面茚并茚—二噻吩类光伏受体材料、其制备方法及应用
CN111269083A (zh) * 2020-02-24 2020-06-12 珠海市柏瑞医药科技有限公司 一种格尔伯特酸的合成方法
CN111269083B (zh) * 2020-02-24 2023-08-25 珠海市柏瑞医药科技有限公司 一种格尔伯特酸的合成方法

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EP2697283A1 (en) 2014-02-19
KR101545429B1 (ko) 2015-08-18
KR20140010156A (ko) 2014-01-23
US20140145119A1 (en) 2014-05-29
EP2697283A4 (en) 2015-12-16
WO2012142469A1 (en) 2012-10-18
JP2014518562A (ja) 2014-07-31
US9153785B2 (en) 2015-10-06

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Application publication date: 20140305