CN103613298B - Environment-friendly sugar-brown pigment for cement-based color facing mortar for internal wall of building, and preparation method and using method for pigment - Google Patents
Environment-friendly sugar-brown pigment for cement-based color facing mortar for internal wall of building, and preparation method and using method for pigment Download PDFInfo
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- CN103613298B CN103613298B CN201310586946.6A CN201310586946A CN103613298B CN 103613298 B CN103613298 B CN 103613298B CN 201310586946 A CN201310586946 A CN 201310586946A CN 103613298 B CN103613298 B CN 103613298B
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Abstract
The invention relates to an environment-friendly sugar-brown pigment for cement-based color facing mortar for an internal wall of a building, and a preparation method and a using method for the pigment. Color characteristics of waste liquor in a molasses alcohol production process are taken into full account, the waste liquor is subjected to concentration, adsorption (color extraction), drying, crushing, grinding and screening to obtain a pigment, and the pigment is applied to the cement-based color facing mortar for the internal wall of the building to produce the sugar-brown cement-based color facing mortar. According to the pigment, and the preparation method and the using method thereof, a means can be provided for the utilization of coloring matters in the waste liquor of molasses alcohol as resources; in addition, the sugar-brown pigment is used instead of cement, quartz sand, a pigment and a thickening component, so that the production cost of the sugar-brown cement-based color facing mortar is lowered, the color types of the color facing mortar are enriched, and the market competitiveness of the cement-based color facing mortar is improved; moreover, the pigment is free of heavy metals, and is a plant pigment, so that the prepared color facing mortar is environment-friendly.
Description
Technical field
The invention belongs to building materials field, be specifically related to a kind of environment-friendly type building interior wall cement based colored finish mortar sugar brown pigments, preparation method and using method thereof.
Background technology
Cement based colored finish mortar is a kind of important material of construction.Compare with ceramic tile with other wall facing material such as pigment, cement-based mortar decorative effect nature.In addition, the thickness of cement-based finishing mortar and easy working quality can give architect larger imagination space.The use of cement makes it have and compares larger price advantage with pigment with ceramic tile.Therefore, cement based colored finish mortar is used widely in developed countries such as America and Europes as building outer wall decorative material.Usually, in the production process of colored finish mortar, in order to adjust the use color of facing mortar, the pigment of various different colours need be added.According to chemical property, these pigment can be divided into two classes.One is pigment dyestuff, and it two is mineral dye.Pigment dyestuff has stronger tinting strength, but price is higher.Mineral dye obtains the favor that mortar is produced because having lower cost and better weather resistance.In addition, mineral dye is less on mortar performance impact.But because of the tinctorial property that mineral dye is more weak, the volume of usual mineral dye in cement-based finishing mortar is comparatively large, and generally the volume of inorganic color in cement based colored finish mortar is 3% to 6% of cement amount.Therefore, every cube of m
3the mineral dye adding tens kilograms is needed in cement based colored finish mortar.But, about the usual per kilogram of these mineral dyes needs dozens of yuan.Therefore, the cost nearly hundred yuan of pigment in cement based colored finish mortar.The production cost of further reduction cement based colored finish mortar, significant for its competitive edge of lifting.In addition, normal containing a small amount of heavy metal or micro-radiation element in mineral dye, use at inner wall of building, there is the potential risk affecting HUMAN HEALTH.In addition, building industry, as the target of utilization of waste as resource, is not only conducive to the saving of resource and the consumption of the energy, and has the variation of construction industry product and the reduction of cost.Therefore, the interior wall R&D and production of cement-based finishing mortar pigment of cheapness, environmental protection, has great importance to the development of colored finish mortar.
Molasses are as the main raw material of alcohol, and the mode that molasses utilize again, in molasses-spirit production process, produce a large amount of waste liquid, and containing a large amount of sugared brown plant pigments in waste liquid, directly discharge will bring serious environmental problems.Therefore, before discharge, waste liquid needs desolventing technology.The decolouring of current molasses alcohol waste liquid is main it is considered that decolorizing efficiency, to eliminate containing the impact of pigment discharging of waste liquid on environment, eliminates the consideration that in waste liquid, pigment resourceization utilizes.Therefore, the recycling of pigment in waste liquid in molasses-spirit production process, for molasses as raw material, the sustainable development producing alcohol has positive effect.
Summary of the invention
The object of the present invention is to provide a kind of environment-friendly type building interior wall cement based colored finish mortar sugar brown pigments, preparation method and using method thereof.Simultaneously by molasses-spirit production process in generation waste liquid the recycling of sugared brown pigment a kind of approach is provided.
A kind of environment-friendly type building interior wall cement based colored finish mortar sugar brown pigments proposed in the present invention, the waste liquid produced in being produced by molasses-spirit obtains through concentrating, adsorbing or getting look, mummification, pulverizing, grinding and screening successively, its particle diameter is less than or equal to 40 orders, and size distribution is normal distribution.
The preparation method of a kind of environment-friendly type building interior wall cement based colored mortar sugar brown cure that the present invention proposes, concrete steps are as follows:
(1) adopt temperature not higher than any heat of 100 DEG C or the physical concentration mode of machinery, the waste liquid produced in concentrated molasses-spirit production process;
(2) carclazyte is adopted to adsorb step (1) gained concentrated solution or get look;
(3) mode of any mummification is adopted, not higher than at the temperature of 100 DEG C, the sugared brown pigment mixture of mummification carclazyte and absorption;
(4) adopt the mode of any pulverizing, not higher than at the temperature of 100 DEG C, the carclazyte after mummification and sugared brown pigment mixture are pulverized;
(5) adopt any milling equipment, not higher than at the temperature of 100 DEG C, carry out grinding by via the carclazyte pulverized and sugared brown pigment mixture;
(6) any equipment that can carry out being less than 40 order mechanical gradings is adopted to sieve;
Through said process, required a kind of environment-friendly type building interior wall cement based colored finish mortar sugar brown pigments can be obtained.
The using method of a kind of environment-friendly type building interior wall cement based colored finish mortar sugar brown pigments that the present invention proposes, at environment-friendly type building interior wall with in cement based colored finish mortar, described environment-friendly type building interior wall cement based colored finish mortar sugar brown pigments incorporation is 20 ~ 60% of total colored finish mortar quality.
In the present invention, described environment-friendly type building interior wall cement based colored finish mortar substitutes sugared brown facing mortar pigment, aggregate, gelling material and water-keeping thickening group component simultaneously and is respectively 100%, 10 ~ 40%, 20 ~ 30%, 10 ~ 50%.
In the present invention, environment protecting cement-base facing mortar sugar brown pigments is mainly used in the cement based colored finish mortar of inner wall of building, substitute during inner wall of building cement based colored finish mortar is produced the pigment used completely, Some substitute aggregate and thickener component, have aggregate, adjustment color and water-keeping thickening effect.The sugared brown of the following particle diameter of grinding to 40 order and the mixture of carclazyte, have certain gelling because of carclazyte, can play the effect of gelling material and the effect of filler aggregate; Because presenting sugared brown containing sugared brown pigment, the sugared brown pigments in cement based colored finish mortar can be substituted; Because carclazyte has stronger water sorption, water-keeping thickening effect can be played.
The multiduty approach of Realization of Product prepared by the present invention is: utilize sugared brown pigment to play the effect of pigment; Utilize the gelling that carclazyte is certain, play pectisation; By the water sorption of carclazyte, in use play water-keeping thickening effect.
beneficial effect of the present invention is:
The present invention adopts via concentrated, absorption (getting look), mummification, pulverize, grinding and the sugared brown pigment sieved in molasses alcohol waste liquid, carclazyte and sugared brown pigment mixture, final obtained sugared brown inner wall of building cement based colored finish mortar sugar brown pigments, pigment required in the production of colour cement facing mortar can be substituted completely, aggregates, gelling material and thickener component, except the cost that can reduce cement based colored finish mortar, improve the competitive power of cement based colored finish mortar, enrich the kind of cement based colored finish mortar, can be the recycling of pigment in molasses alcohol waste liquid and an approach is provided.In addition, sugared brown pigment derives from plant, makes it be prepared into cement based colored finish mortar and has good environmental protection effect.
Embodiment
The present invention is further illustrated below by embodiment.
Embodiment 1
The present invention is a kind of environment-friendly type building interior wall cement based colored finish mortar multi-usage sugar brown pigments, its preparation process obtains via concentrated, absorption (getting look), mummification, pulverizing, grinding and screening, particle diameter is less than 40 orders, the sugared brown powder in normal distribution.Pigment of the present invention is joined in cement based colored finish mortar preparation process with total colored finish mortar 20%, substitute pigment completely, substitute 20% aggregate, gelling material and thickener component, add the water that mass percentage is 27%, carry out physical and mechanical property test, test result is as shown in table 1:
Table 1 real an ancient swallowtailed flag example 1 physical and mechanical property test result
Embodiment 2
The present invention is a kind of environment-friendly type building interior wall cement based colored finish mortar multi-usage sugar brown pigments, its preparation process obtains via concentrated, absorption (getting look), mummification, pulverizing, grinding and screening, particle diameter is less than 40 orders, the sugared brown powder in normal distribution.Pigment of the present invention is joined in cement based colored finish mortar preparation process with total colored finish mortar 60%, substitute pigment completely, substitute 30% aggregate, 20% gelling material and 40% thickener component, add the water that mass percentage is 41%, according to JC/T 1024-2007 wall facing mortar standard, carry out physical and mechanical property test, test result is as shown in table 2:
Table 2 embodiment 2 physical and mechanical property test result
This shows, the performance of embodiment 1 and 2 all meets national JC/T 1024-2007 wall facing mortar standard.The preparation process of environment-friendly type inner wall cement based colored finish mortar multi-usage sugar brown pigments of the present invention is feasible, and effect is effective.
Claims (4)
1. an environment-friendly type building interior wall cement based colored finish mortar multi-usage sugar brown pigments, it is characterized in that described multi-usage sugar brown pigments adopts the waste liquid in molasses-spirit production process, obtain via concentrating, adsorbing or get look, mummification, pulverizing, grinding and screening, its size is normal distribution for being greater than 40 orders.
2. a preparation method for environment-friendly type building interior wall cement based colored finish mortar multi-usage sugar brown pigments as claimed in claim 1, is characterized in that concrete steps are as follows:
(1) adopt temperature not higher than any heat of 100 DEG C or the physical concentration mode of machinery, the waste liquid produced in concentrated molasses-spirit production process;
(2) carclazyte is adopted to adsorb step (1) gained concentrated solution or get look;
(3) mode of any mummification is adopted, not higher than at the temperature of 100 DEG C, the sugared brown pigment mixture of mummification carclazyte and absorption;
(4) adopt the mode of any pulverizing, not higher than at the temperature of 100 DEG C, the carclazyte after mummification and sugared brown pigment mixture are pulverized;
(5) adopt any milling equipment, not higher than at the temperature of 100 DEG C, carry out grinding by via the carclazyte pulverized and sugared brown pigment mixture;
(6) any equipment that can carry out being less than 40 order mechanical gradings is adopted to sieve;
Through said process, required a kind of environment-friendly type building interior wall cement based colored finish mortar sugar brown pigments can be obtained.
3. the using method of an a kind of environment-friendly type building interior wall cement based colored finish mortar multi-usage sugar brown pigments as claimed in claim 1, it is characterized in that in environment-friendly type building interior wall cement based colored finish mortar, described environment-friendly type building interior wall cement based colored finish mortar sugar brown pigments incorporation is 20 ~ 60% of total colored finish mortar quality.
4. a using method for environment-friendly type building interior wall cement based colored finish mortar multi-usage sugar brown pigments as claimed in claim 1, is characterized in that described environment-friendly type building interior wall cement based colored finish mortar sugar brown pigments substitutes pigment, aggregate, gelling material and water-keeping thickening group component and is respectively 100%, 10 ~ 40%, 20 ~ 30%, 10 ~ 50%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310586946.6A CN103613298B (en) | 2013-11-20 | 2013-11-20 | Environment-friendly sugar-brown pigment for cement-based color facing mortar for internal wall of building, and preparation method and using method for pigment |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310586946.6A CN103613298B (en) | 2013-11-20 | 2013-11-20 | Environment-friendly sugar-brown pigment for cement-based color facing mortar for internal wall of building, and preparation method and using method for pigment |
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| CN103613298A CN103613298A (en) | 2014-03-05 |
| CN103613298B true CN103613298B (en) | 2015-04-08 |
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| CN201310586946.6A Expired - Fee Related CN103613298B (en) | 2013-11-20 | 2013-11-20 | Environment-friendly sugar-brown pigment for cement-based color facing mortar for internal wall of building, and preparation method and using method for pigment |
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| CN112707751B (en) * | 2021-01-15 | 2022-02-18 | 杭州左纳实业有限公司 | Method for preparing cement floor color paste and cement curing reinforcing agent from dye residual paste and application |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| EP0582008A1 (en) * | 1992-08-04 | 1994-02-09 | Municipal Services Corporation | Fixation and utilization of ash residue from the incineration of municipal solid waste |
| US5900051A (en) * | 1997-05-20 | 1999-05-04 | Solomon Grind-Chem Service, Inc. | Compositions and method for conditioning mineral oxide pigment |
| CN101508542B (en) * | 2009-03-30 | 2012-07-04 | 上海英硕聚合材料股份有限公司 | Colorful mortar for wall face |
| CN101560077B (en) * | 2009-05-11 | 2012-08-08 | 常熟佳发化学有限责任公司 | Epoxy resin mortar composite used for plate type fragment-free track |
| CN101648793A (en) * | 2009-09-17 | 2010-02-17 | 苏州同济材料科技有限公司 | Colored mortar |
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