CN103589207B - Coated sheet glass/sapphire/ceramic and manufacturing method thereof - Google Patents
Coated sheet glass/sapphire/ceramic and manufacturing method thereof Download PDFInfo
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- CN103589207B CN103589207B CN201310487877.3A CN201310487877A CN103589207B CN 103589207 B CN103589207 B CN 103589207B CN 201310487877 A CN201310487877 A CN 201310487877A CN 103589207 B CN103589207 B CN 103589207B
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- sapphire
- glass
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- pottery
- sheet glass
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- 229910052594 sapphire Inorganic materials 0.000 title claims abstract description 60
- 239000010980 sapphire Substances 0.000 title claims abstract description 60
- 239000005357 flat glass Substances 0.000 title claims abstract description 34
- 239000000919 ceramic Substances 0.000 title claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 239000011521 glass Substances 0.000 claims abstract description 61
- 239000011248 coating agent Substances 0.000 claims abstract description 23
- 238000000576 coating method Methods 0.000 claims abstract description 23
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract description 22
- 239000011347 resin Substances 0.000 claims abstract description 21
- 229920005989 resin Polymers 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 19
- 229920000642 polymer Polymers 0.000 claims abstract description 7
- 239000007864 aqueous solution Substances 0.000 claims abstract description 4
- 238000007747 plating Methods 0.000 claims description 26
- 239000007788 liquid Substances 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 239000012748 slip agent Substances 0.000 claims description 11
- 239000012752 auxiliary agent Substances 0.000 claims description 10
- 239000002270 dispersing agent Substances 0.000 claims description 10
- 238000007711 solidification Methods 0.000 claims description 10
- 230000008023 solidification Effects 0.000 claims description 10
- 239000000080 wetting agent Substances 0.000 claims description 10
- 239000003822 epoxy resin Substances 0.000 claims description 9
- 229920000647 polyepoxide Polymers 0.000 claims description 9
- 239000004595 color masterbatch Substances 0.000 claims description 8
- 229920002635 polyurethane Polymers 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 5
- 241001062009 Indigofera Species 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000010437 gem Substances 0.000 claims description 2
- 229910001751 gemstone Inorganic materials 0.000 claims description 2
- 230000000149 penetrating effect Effects 0.000 claims description 2
- 238000007639 printing Methods 0.000 claims description 2
- 239000004925 Acrylic resin Substances 0.000 claims 4
- 229920000178 Acrylic resin Polymers 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 2
- 239000010426 asphalt Substances 0.000 claims 1
- 239000004744 fabric Substances 0.000 claims 1
- 238000012545 processing Methods 0.000 abstract description 18
- 239000000758 substrate Substances 0.000 abstract description 8
- 239000000853 adhesive Substances 0.000 abstract description 4
- 230000001070 adhesive effect Effects 0.000 abstract description 4
- 238000010297 mechanical methods and process Methods 0.000 abstract description 4
- 230000005226 mechanical processes and functions Effects 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 238000002791 soaking Methods 0.000 abstract description 3
- 238000003754 machining Methods 0.000 abstract description 2
- 239000000243 solution Substances 0.000 abstract description 2
- 239000011247 coating layer Substances 0.000 abstract 5
- 239000010410 layer Substances 0.000 abstract 3
- 239000011253 protective coating Substances 0.000 abstract 3
- 239000000654 additive Substances 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 description 6
- 208000027418 Wounds and injury Diseases 0.000 description 4
- 208000014674 injury Diseases 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- 238000012805 post-processing Methods 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000005354 aluminosilicate glass Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000003854 Surface Print Methods 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000010675 chips/crisps Nutrition 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007688 edging Methods 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 238000011416 infrared curing Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/483—Polyacrylates
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/82—Coating or impregnation with organic materials
- C04B41/83—Macromolecular compounds
Abstract
The invention is applicable to the technical field of glass/sapphire/ceramic protection, and provides a coated sheet glass/sapphire/ceramic which can not be damaged in the process of transportation and is suitable for deep processing, and a manufacturing method thereof. At least one surface of the coated sheet glass/sapphire/ceramic is coated with a water soluble polymer coating layer; and the coating layer is a polymer obtained after a coating solution containing resins and additives is cured. According to the coated sheet glass/sapphire/ceramic provided by the invention, because an adhesive force between the protective coating layer and a glass substrate/sapphire/ceramic is extremely excellent, and the protective coating layer and the glass substrate/sapphire/ceramic are similar in mechanical characteristics, the protective coating layer and the glass substrate/sapphire/ceramic can adapt to the mechanical process and chemical environment of a glass/sapphire/ceramic machining link, and no demoulding situation occurs. When the water soluble polymer coating layer is removed, the water soluble polymer coating layer can be removed just through soaking the water soluble polymer coating layer in an aqueous solution at a certain temperature, therefore, no additional damage is caused on the surface of the glass/sapphire/ceramic.
Description
Technical field
The invention belongs to glass/sapphire/pottery resist technology field, being related to one kind can be injury-free in transportation
Sheet glass/sapphire/pottery former with the plated film of suitable deep processing and preparation method thereof, is particularly suited for protection film plating layer
The ultra-thin sapphire sheet of the aluminosilicate glass of capacitive touch screen panel, soda glass substrate and twin polishing.
Background technology
Glass is the core material of capacitive touch screen panel, in order to meet touch-control and the display effect of high-quality, generally
Face glass to be produced by the way of " overflow down draw ", and this mode glass surface during glass molding does not contact appoints
What object, thus the glass produced has " double air surface, minute surface " effect.
After glass substrate melting, molding, need through shelving, transporting（As sea-freight, land transportation）Reach panel manufacturing plant man,
The operation through multiple deep processings is also needed to, for example in follow-up deep processing processing procedure：Scribing, sliver, edging, boring etc..Exist first
During shelving, transporting, in order to prevent Relative friction between glass and glass, slide in the scuffing producing and transportation
Collision cause surface bad it will usually put between naked glass and naked glass feeding spaced papers or glass surface paste plastics protect
Cuticula；And itself also contain a lot of solid particles in feeding spaced papers, inevitably glass is caused with certain surface damage；Protect
Cuticula one side high cost, not environmentally, another aspect protecting film is too wide in the gap with the mechanical property of glass, is doing glass post-processing
When, after necessarily needing to remove protecting film, just can carry out.Furthermore, in deep-processing process, each operation can produce very
How tiny glass fines, these chipss of glass directly can damage glass surface, be likely to during disposable processing multiple pieces of glass due to
Relative slip between glass and glass and produce cut, cause the defects such as scuffing, impression, therefore, usual glass post-processing
Yields only has 50% about；Bad for the surface producing, it is typically only capable to be polished reprocessing using rare earth material, and these
The cost reprocessed is very high, not environmentally, be unfavorable for saving social resources.
In order to improve glass post-processing yield, someone is first in glass surface printing a kind of " alkali-soluble polymer " protection plating
Film layer comes protective glass surface, then just starts to do follow-up processing.But the maximum problem of this method is：" alkali solubility gathers
Compound " protection film plating layer using after finishing it is necessary to could " alkali-soluble polymer " protection be plated by " aqueous slkali "
Film layer is peeled off from glass surface, and in this process, " aqueous slkali " also can produce corrosion to glass surface, causes 10% left side
Right scuffing.Therefore, this method can only be to solve the problems, such as glass protection to a certain extent it is impossible to thoroughly solve glass protection
Problem.
It is therefore desirable to being optimized to the product existing way of current original sheet glass, with protective glass in transportation
Injury-free in neutralization deep-processing process.
In addition, at present because electric terminal slimming has become trend, due to the consideration of structural strength, a lot of fields adopt
Ultra-thin sapphire come to replace glass use.Industry due to LED is risen, and the minute surface sapphire of twin polishing has become common product
Product.No matter current sapphire is all provided without protective measure in transport or deep processing process segment, adds in tediously long transport, machinery
During work, minute surface sapphire surface can be scratched, damage, thus causing higher scrappage and relatively low yields.Cause
This is necessary the minute surface sapphire product existing way of current twin polishing is optimized, and is existed with protective glass surface sapphire
In transportation and injury-free in deep-processing process.
Content of the invention
The technical problem to be solved is to provide a kind of former sheet glass/sapphire/pottery of plated film it is intended to transport
Injury-free with preferably protective glass surface in deep-processing process.
The present invention is achieved in that a kind of former sheet glass/sapphire/pottery of plated film, and the former sheet glass/indigo plant of described plated film is precious
At least one side of stone/pottery is coated with high molecular weight water soluble polymer film plating layer；Described film plating layer is by comprising resin, auxiliary agent
The polymer obtaining after coating liquid solidification.
Further, described resin comprise epoxy resin, esters of acrylic acid, polyurethaness, in swollen resin at least
A kind of.
Further, described auxiliary agent comprise light trigger, dispersant, wetting agent, flat dose, firming agent, solvent, on-slip
Agent.
Further, described film plating layer is obtained after the coating liquid solidification of following percentage by weight proportioning：10-30% ring
Oxygen tree fat, 20-50% acrylate, 0-20% polyurethane, 0-10% swollen resin, 0-10% light trigger, 0-10% dispersant, 0-
Flat dose of 10% wetting agent, 0-10%, 0-10% firming agent, 0-10% on-slip agent, 0-10% color masterbatch, 0-10% solvent.
Present invention also offers a kind of manufacture method of the former sheet glass/sapphire/pottery of plated film, comprise the steps：
Former sheet glass/sapphire/pottery is provided；
High molecular weight water soluble polymer coating liquid is painted at least one side of described former sheet glass/sapphire/pottery；
Described high molecular weight water soluble polymer coating liquid is solidified on described former sheet glass/sapphire/ceramic surface, obtains
Former sheet glass/sapphire/the pottery of plated film.
Further, described high molecular weight water soluble polymer coating liquid comprises 10-30% epoxy resin, 20-50% acrylic acid
Ester, 0-20% polyurethane, 0-10% swollen resin, 0-10% light trigger, 0-10% dispersant, 0-10% wetting agent, 0-10% are flat
Agent, 0-10% firming agent, 0-10% on-slip agent, 0-10% color masterbatch, 0-10% solvent.
Further, described high molecular weight water soluble polymer coating liquid carries out application by coating or mode of printing.
Further, described high molecular weight water soluble polymer coating liquid passes through ultraviolet, infrared or mode of heating solidification.
Former sheet glass/sapphire/the pottery of plated film provided by the present invention, due to film plating layer and glass substrate/sapphire/pottery
Adhesive force between porcelain itself is very outstanding, and mechanical featuress are similar to, and are therefore adapted to glass/sapphire/Ceramic manufacturing link
In mechanical process and chemical environment, the situation of demoulding will not be produced.And when removing high molecular weight water soluble polymer film plating layer,
The aqueous solution soaking only needing to uniform temperature can remove, and causes extra damage thus without to glass/sapphire/ceramic surface
Bad.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, below in conjunction with drawings and Examples, right
The present invention is further elaborated.It should be appreciated that specific embodiment described herein is only in order to explain the present invention, and
It is not used in the restriction present invention.
At least one side of the former sheet glass/sapphire/pottery of plated film provided by the present invention is coated with water soluble polymer and gathers
Compound film plating layer, this film plating layer is by the polymer obtaining after the coating liquid solidification comprising resin, auxiliary agent, and this coating liquid is acceptable
Comprise color masterbatch.Wherein, resin be selected from epoxy resin, esters of acrylic acid, polyurethaness, one or more of swollen resin
The mixing of arbitrary proportion, auxiliary agent can comprise light trigger, dispersant, wetting agent, flat dose, firming agent, on-slip agent.
Preferably, obtain weight hundred after after above-mentioned film plating layer is solidified by the coating liquid of following percentage by weight proportioning
Divide and compare proportioning：10-30% epoxy resin, 20-50% acrylate, 0-20% polyurethane, 0-10% swollen resin, 0-10% are light-initiated
Agent, 0-10% dispersant, 0-10% wetting agent, flat dose of 0-10%, 0-10% firming agent, 0-10% on-slip agent, 0-10% color masterbatch, 0-
10% solvent.
Adhesive force between above-mentioned film plating layer and glass substrate/sapphire/pottery itself is very outstanding, mechanical featuress class
Seemingly, therefore it is adapted to the mechanical process in glass processing link and chemical environment, the situation of demoulding will not be produced.In deep processing
It is only necessary to coated glass/sapphire/pottery is put into the clear water of uniform temperature or water-soluble containing penetrating agent after process terminates
In liquid, the protection film plating layer of glass surface can tilt from glass/sapphire/ceramic surface in aqueous and depart from glass table
Face, you can to recover glass/sapphire/pottery " double air surface, minute surface " effect originally.Experimental data shows, this patent provides
" for the former sheet glass/sapphire/pottery of plated film of deep processing " straight-through yield in deep-processing process can reach 99%,
And be coated with aqueous slkali and protect the straight-through yield in deep-processing process for the former sheet glass/sapphire/pottery of film plating layer to only have 90%,
Straight-through yield in deep-processing process for the common former sheet glass/sapphire/pottery not being coated with any protection film plating layer is even more
Only 75%.
Present invention also offers the manufacture method of the former sheet glass/sapphire/pottery of above-mentioned plated film, comprise the steps：
Step A, provides former sheet glass/sapphire/pottery.This original sheet glass can be aluminosilicate glass, soda glass or indigo plant
Gem.
Step B, by high molecular weight water soluble polymer coating liquid be coated with or the mode such as print be painted on described former sheet glass/
At least one side of sapphire/pottery.
This high molecular weight water soluble polymer coating liquid comprises 10-30% epoxy resin, 20-50% acrylate, the poly- ammonia of 0-20%
Ester, 0-10% swollen resin, 0-10% light trigger, 0-10% dispersant, 0-10% wetting agent, flat dose of 0-10%, 0-10% solidification
Agent, 0-10% on-slip agent, 0-10% color masterbatch, 0-10% solvent.
Step C, described high molecular weight water soluble polymer coating liquid is solidified on described former sheet glass/sapphire/ceramic watch
Face, obtains the former sheet glass/sapphire/pottery of plated film.
Difference according to resin and auxiliary agent, it is possible to use the mode such as ultraviolet light, infrared light or heating is solidificated in glass surface.
If in general, the resin using is thermosetting resin, needing heat cure or infrared curing；If the resin using swashs for ultraviolet
Send out the resin of solidification, then need ultraviolet light polymerization；If the resin using comprises bi-material, simultaneously need to.And some expansion trees
Fat, needs uniform temperature just can start working to excite, then need first infrared ultraviolet again.
Former sheet glass/sapphire/the pottery of plated film provided by the present invention, due to film plating layer and glass substrate/sapphire/pottery
Adhesive force between porcelain itself is very outstanding, and mechanical featuress are similar to, and are therefore adapted to glass/sapphire/Ceramic manufacturing link
In mechanical process and chemical environment, the situation of demoulding will not be produced.And when removing high molecular weight water soluble polymer film plating layer,
The aqueous solution soaking only needing to uniform temperature can remove, and causes extra damage thus without to glass/sapphire/ceramic surface
Bad.In addition, adding on-slip agent in auxiliary agent so that film plating layer has on-slip characteristic, glass/sapphire/pottery will be made in transport
During will not produce slip, more preferable protective glass/sapphire/pottery, thus avoid extra damage；In deep processing,
Due to having on-slip characteristic, machining can be carried out in the way of being superimposed using divided glass/sapphire/pottery, enter
One step can be with improve production efficiency.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.
Claims (4)
1. a kind of former sheet glass/sapphire/pottery of plated film is it is characterised in that described plated film former sheet glass/sapphire/pottery
At least one side is coated with high molecular weight water soluble polymer film plating layer to protect described glass/sapphire/pottery；Described film plating layer is
By the polymer obtaining after the coating liquid solidification comprising resin, auxiliary agent；Described resin comprises epoxy resin, acrylic resin
In at least one；Described auxiliary agent comprise light trigger, dispersant, wetting agent, flat dose, firming agent, on-slip agent；
Described film plating layer also comprises color masterbatch；
Described film plating layer is obtained after the coating liquid solidification of following percentage by weight proportioning：10-30% epoxy resin, 20-
50% acrylic resin, 0-20% polyurethane, 0-10% light trigger, 0-10% dispersant, 0-10% wetting agent, 0-
10% flat dose, 0-10% firming agent, 0-10% on-slip agent, 0-10% color masterbatch, 0-10% solvent.
2. a kind of manufacture method of the former sheet glass/sapphire/pottery of plated film is it is characterised in that comprise the steps：
Former sheet glass/sapphire/pottery is provided；
High molecular weight water soluble polymer coating liquid is painted at least one side of described former sheet glass/sapphire/pottery；
Described high molecular weight water soluble polymer coating liquid is solidified on described former sheet glass/sapphire/ceramic surface, former in plated film
Film plating layer is obtained on sheet glass/sapphire/pottery；
Film plating layer glass/sapphire/pottery is placed in the aqueous solution containing penetrating agent makes described film plating layer from glass/indigo plant by described
Gem/ceramic surface departs from；
Described film plating layer is by the polymer obtaining after the coating liquid solidification comprising resin, auxiliary agent；Described resin comprises asphalt mixtures modified by epoxy resin
At least one in fat, acrylic resin；Described auxiliary agent comprises light trigger, dispersant, wetting agent, flat dose, solidification
Agent, on-slip agent；
Described high molecular weight water soluble polymer coating liquid is by the material composition of following percentage by weight：10-30% epoxy resin,
20-50% acrylic resin, 0-20% polyurethane, 0-10% light trigger, 0-10% dispersant, 0-10% wetting agent,
Flat dose of 0-10%, 0-10% firming agent, 0-10% on-slip agent, 0-10% color masterbatch, 0-10% solvent.
3. manufacture method as claimed in claim 2 is it is characterised in that described high molecular weight water soluble polymer coating liquid passes through to apply
Cloth or mode of printing carry out application.
4. manufacture method as claimed in claim 2 is it is characterised in that described high molecular weight water soluble polymer coating liquid passes through purple
Outward, infrared or mode of heating solidifies.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310487877.3A CN103589207B (en) | 2013-10-17 | 2013-10-17 | Coated sheet glass/sapphire/ceramic and manufacturing method thereof |
| PCT/CN2013/088203 WO2015054948A1 (en) | 2013-10-17 | 2013-11-29 | Coated sheet glass/sapphire/ceramic and preparing method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310487877.3A CN103589207B (en) | 2013-10-17 | 2013-10-17 | Coated sheet glass/sapphire/ceramic and manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103589207A CN103589207A (en) | 2014-02-19 |
| CN103589207B true CN103589207B (en) | 2017-02-15 |
Family
ID=50079540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310487877.3A Active CN103589207B (en) | 2013-10-17 | 2013-10-17 | Coated sheet glass/sapphire/ceramic and manufacturing method thereof |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN103589207B (en) |
| WO (1) | WO2015054948A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104123524B (en) * | 2014-07-02 | 2017-07-07 | 厦门润晶光电集团有限公司 | A kind of sapphire screen cover glass and its preparation method |
| CN110577367B (en) * | 2018-08-13 | 2022-03-22 | 蓝思科技（长沙）有限公司 | Glass protection processing technology, glass and equipment |
| CN109896742A (en) * | 2019-04-23 | 2019-06-18 | 蚌埠中光电科技有限公司 | A kind of film plating process of TFT-LCD base plate glass |
| CN112876116A (en) * | 2021-01-27 | 2021-06-01 | 上海无想新材料科技有限公司 | Colored expanded vermiculite and preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19906333C2 (en) * | 1999-02-16 | 2002-09-26 | Schott Glas | Process for protecting the surface of glass substrates and use of the process for producing display glass |
| US20030072948A1 (en) * | 2001-10-03 | 2003-04-17 | 3M Innovative Properties Company | Dry-peelable temporary protective coatings |
| US20060246302A1 (en) * | 2005-04-29 | 2006-11-02 | Brady Michael D | Methods for protecting glass |
| CN101463217B (en) * | 2009-01-15 | 2012-03-07 | 方刚 | Preparation of water-soluble acrylic ester coating |
| CN102134437B (en) * | 2011-02-28 | 2012-08-22 | 上虞市佑谦特种材料有限公司 | UV (ultraviolet)-curing glass coating paint |
| CN102503164B (en) * | 2011-09-28 | 2014-03-12 | 奇瑞汽车股份有限公司 | Preparation method of wear-resistant hydrophobic glass |
| CN103059688B (en) * | 2011-10-20 | 2015-10-14 | 展辰涂料集团股份有限公司 | A kind of aqueous double-component radiation shielding glass paint |
| CN102786839B (en) * | 2012-07-31 | 2014-07-09 | 佛山市三求电子材料有限公司 | Glass protecting ink and preparation method thereof |
-
2013
- 2013-10-17 CN CN201310487877.3A patent/CN103589207B/en active Active
- 2013-11-29 WO PCT/CN2013/088203 patent/WO2015054948A1/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| WO2015054948A1 (en) | 2015-04-23 |
| CN103589207A (en) | 2014-02-19 |
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