CN103589207A - Coated sheet glass/sapphire/ceramic and manufacturing method thereof - Google Patents

Coated sheet glass/sapphire/ceramic and manufacturing method thereof Download PDF

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Publication number
CN103589207A
CN103589207A CN201310487877.3A CN201310487877A CN103589207A CN 103589207 A CN103589207 A CN 103589207A CN 201310487877 A CN201310487877 A CN 201310487877A CN 103589207 A CN103589207 A CN 103589207A
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Prior art keywords
sapphire
sheet glass
pottery
glass
former sheet
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CN201310487877.3A
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Chinese (zh)
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CN103589207B (en
Inventor
黄涛
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Chongqing Aureavia Hi Tech Glass Co Ltd
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Individual
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Priority to CN201310487877.3A priority Critical patent/CN103589207B/en
Priority to PCT/CN2013/088203 priority patent/WO2015054948A1/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48Macromolecular compounds
    • C04B41/483Polyacrylates
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/32Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/82Coating or impregnation with organic materials
    • C04B41/83Macromolecular compounds

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Surface Treatment Of Glass (AREA)
  • Laminated Bodies (AREA)
  • Chemically Coating (AREA)

Abstract

The invention is applicable to the technical field of glass/sapphire/ceramic protection, and provides a coated sheet glass/sapphire/ceramic which can not be damaged in the process of transportation and is suitable for deep processing, and a manufacturing method thereof. At least one surface of the coated sheet glass/sapphire/ceramic is coated with a water soluble polymer coating layer; and the coating layer is a polymer obtained after a coating solution containing resins and additives is cured. According to the coated sheet glass/sapphire/ceramic provided by the invention, because an adhesive force between the protective coating layer and a glass substrate/sapphire/ceramic is extremely excellent, and the protective coating layer and the glass substrate/sapphire/ceramic are similar in mechanical characteristics, the protective coating layer and the glass substrate/sapphire/ceramic can adapt to the mechanical process and chemical environment of a glass/sapphire/ceramic machining link, and no demoulding situation occurs. When the water soluble polymer coating layer is removed, the water soluble polymer coating layer can be removed just through soaking the water soluble polymer coating layer in an aqueous solution at a certain temperature, therefore, no additional damage is caused on the surface of the glass/sapphire/ceramic.

Description

A kind of plated film former sheet glass/sapphire/pottery and preparation method thereof
Technical field
The invention belongs to glass/sapphire/ceramic resist technology field; relate to a kind of can be in transportation plated film former sheet glass/sapphire/pottery injury-free and applicable deep processing and preparation method thereof, be particularly useful for the ultra-thin sapphire sheet with aluminosilicate glass, soda glass substrate and the twin polishing of the capacitive touch screen panel of protection coatings.
Background technology
Glass is the core material of capacitive touch screen panel, in order to meet high-quality touch-control and display effect, conventionally face glass adopts the mode of " overflow down draw " to produce, this mode glass surface in the process of glass ware forming does not contact any object, thereby the glass of producing has " two air surface, minute surface " effect.
After glass substrate melting, moulding, need to arrive panel manufacturing firm through shelving, transport (as sea-freight, land transportation), in follow-up deep processing processing procedure, also need the operation through a plurality of deep processings, such as: scribing, sliver, edging, boring etc.First in the process of shelving, transporting, in order to prevent that between glass and glass, relative scuffing and the collision in transportation producing that rub, slide causes surface bad, conventionally can between naked glass and naked glass, put into feeding spaced papers or paste plastic protective film for plastics at glass surface; And itself also contain a lot of solid particulates in feeding spaced papers, inevitably can cause certain surface damage to glass; Protective membrane one side cost is high, not environmental protection, and the mechanical characteristics of protective membrane and glass is too wide in the gap on the other hand, when doing glass deep processing, after necessarily protective membrane need to being removed, just can carry out.Moreover, in deep-processing process, each operation can produce a lot of tiny glass fines, these cullet can directly damage glass surface, during disposable processing multiple pieces of glass, also may produce cut due to the relatively sliding between glass and glass, cause the defects such as scuffing, impression, therefore, the good article rate of glass deep processing only has 50% left and right conventionally; Bad for the surface producing, conventionally can only adopt rare earth material to carry out polishing and reprocess, and the cost that these are reprocessed is very high, not environmental protection, be unfavorable for saving social resources.
In order to improve glass deep processing yield, to have people first to come protective glass surface in glass surface printing a kind of " alkali-soluble polymer " protection coatings, just then start to do follow-up processing.But the problem of this method maximum is: " alkali-soluble polymer " protection coatings is after finishing using; must could " alkali-soluble polymer " protection coatings peel off from glass surface by " alkaline solution "; in this process; " alkaline solution " also can produce corrosion to glass surface, causes the scuffing of 10% left and right.Therefore, this method can only be the problem that solves to a certain extent glass protection, can not thoroughly solve the problem of glass protection.
Therefore be necessary the product existing way of current original sheet glass to be optimized, with protective glass in transportation and injury-free in deep-processing process.
In addition, at present because electric terminal slimming has become trend, due to the consideration of structural strength, a lot of fields adopt ultra-thin sapphire to replace glass to use.Because the industry of LED is risen, the minute surface sapphire of twin polishing has become usual production.No matter current sapphire does not all adopt sfgd. in transportation or deep processing process segment, and in tediously long transportation, mechanical processing process, minute surface sapphire surface can be scratched, damage, thereby has caused higher condemnation factor and lower good article rate.Therefore be necessary the sapphire product existing way of the minute surface of current twin polishing to be optimized, with protective glass surface sapphire in transportation and injury-free in deep-processing process.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of plated film former sheet glass/sapphire/pottery, be intended to transportation and deep-processing process in protective glass surface is injury-free better.
The present invention is achieved in that the former sheet glass/sapphire/pottery of a kind of plated film, and at least one side of described plated film former sheet glass/sapphire/pottery is coated with high molecular weight water soluble polymer coatings; The polymkeric substance that described coatings is served as reasons and obtained after the coating liquid that comprises resin, auxiliary agent solidifies.
Further, described resin comprises at least one in epoxy resin, esters of acrylic acid, polyurethanes, swollen resin.
Further, described auxiliary agent comprises light trigger, dispersion agent, wetting agent, smooth dose, solidifying agent, solvent, on-slip agent.
Further, the coating liquid of described coatings by following weight percent proportioning obtains after solidifying: 10-30% epoxy resin, 20-50% acrylate, 0-20% urethane, 0-10% swollen resin, 0-10% light trigger, 0-10% dispersion agent, 0-10% wetting agent, smooth dose of 0-10%, 0-10% solidifying agent, 0-10% on-slip agent, 0-10% look female, 0-10% solvent.
The present invention also provides the making method of a kind of plated film former sheet glass/sapphire/pottery, comprises the steps:
Former sheet glass/sapphire/pottery is provided;
High molecular weight water soluble polymer coating liquid is coated with at least one side that is contained in described former sheet glass/sapphire/pottery;
Described high molecular weight water soluble polymer coating liquid is solidified in described former sheet glass/sapphire/ceramic surface, obtain the former sheet glass/sapphire/pottery of plated film.
Further, described high molecular weight water soluble polymer coating liquid comprises 10-30% epoxy resin, 20-50% acrylate, 0-20% urethane, 0-10% swollen resin, 0-10% light trigger, 0-10% dispersion agent, 0-10% wetting agent, smooth dose of 0-10%, 0-10% solidifying agent, 0-10% on-slip agent, 0-10% look mother, 0-10% solvent.
Further, described high molecular weight water soluble polymer coating liquid carries out application by coating or mode of printing.
Further, described high molecular weight water soluble polymer coating liquid passes through ultraviolet, infrared or type of heating curing.
Former sheet glass/sapphire/the pottery of plated film provided by the present invention, because the sticking power between coatings and glass substrate/sapphire/pottery itself is very outstanding, mechanical features is similar, therefore can adapt to mechanical process and the chemical environment in glass/sapphire/ceramic processing link, can not produce the situation of demoulding.And when removing high molecular weight water soluble polymer coatings, only need the aqueous solution soaking of certain temperature to remove, therefore can not cause extra damage to glass/sapphire/ceramic surface.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearer, below in conjunction with drawings and Examples, the present invention is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
At least one side of plated film provided by the present invention former sheet glass/sapphire/pottery is coated with high molecular weight water soluble polymer coatings, the polymkeric substance that this coatings is served as reasons and obtained after the coating liquid that comprises resin, auxiliary agent solidifies, and this coating liquid can also comprise look mother.Wherein, resin can be selected from one or more the mixing of arbitrary proportion of epoxy resin, esters of acrylic acid, polyurethanes, swollen resin, and auxiliary agent can comprise light trigger, dispersion agent, wetting agent, smooth dose, solidifying agent, on-slip agent.
Preferably, above-mentioned coatings is cured the rear weight percent proportioning that obtains by the coating liquid of following weight percent proportioning: 10-30% epoxy resin, 20-50% acrylate, 0-20% urethane, 0-10% swollen resin, 0-10% light trigger, 0-10% dispersion agent, 0-10% wetting agent, smooth dose of 0-10%, 0-10% solidifying agent, 0-10% on-slip agent, 0-10% look mother, 0-10% solvent.
Sticking power between above-mentioned coatings and glass substrate/sapphire/pottery itself is very outstanding, and mechanical features is similar, therefore can adapt to mechanical process and the chemical environment in glass processing link, can not produce the situation of demoulding.After deep-processing process finishes; the aqueous solution that only coated glass/sapphire/pottery need to be put into the clear water of certain temperature or contained permeate agent; the protection coatings of glass surface can be in the aqueous solution from the perk of glass/sapphire/ceramic surface and depart from glass surface, can recover glass/sapphire/pottery " two air surface, minute surface " effect originally.Experimental data shows; " for the former sheet glass/sapphire/pottery of plated film of deep processing " that this patent provides can reach 99% at the straight-through yield of deep-processing process; and the straight-through yield of the former sheet glass/sapphire/pottery that is coated with alkaline solution protection coatings in deep-processing process only has 90%, the straight-through yield of the common former sheet glass/sapphire/pottery that is not coated with any protection coatings in deep-processing process only has 75% especially.
The present invention also provides the making method of above-mentioned plated film former sheet glass/sapphire/pottery, comprises the steps:
Steps A, provides former sheet glass/sapphire/pottery.This original sheet glass can be aluminosilicate glass, soda glass or sapphire.
Step B, is coated with high molecular weight water soluble polymer coating liquid at least one side that is contained in described former sheet glass/sapphire/pottery in modes such as coating or printings.
This high molecular weight water soluble polymer coating liquid comprises 10-30% epoxy resin, 20-50% acrylate, 0-20% urethane, 0-10% swollen resin, 0-10% light trigger, 0-10% dispersion agent, 0-10% wetting agent, smooth dose of 0-10%, 0-10% solidifying agent, 0-10% on-slip agent, 0-10% look mother, 0-10% solvent.
Step C, solidifies described high molecular weight water soluble polymer coating liquid in described former sheet glass/sapphire/ceramic surface, obtains the former sheet glass/sapphire/pottery of plated film.
According to the difference of resin and auxiliary agent, can use the modes such as UV-light, infrared light or heating to be solidificated in glass surface.Generally speaking, if the resin using is thermosetting resin, need thermofixation or infrared curing; If the resin using, for the curing resin of burst of ultraviolel, needs ultraviolet light polymerization; If comprising bi-material, the resin using needs simultaneously.And some swollen resins need certain temperature to excite and just can start working, need first infrared ultraviolet again.
Former sheet glass/sapphire/the pottery of plated film provided by the present invention, because the sticking power between coatings and glass substrate/sapphire/pottery itself is very outstanding, mechanical features is similar, therefore can adapt to mechanical process and the chemical environment in glass/sapphire/ceramic processing link, can not produce the situation of demoulding.And when removing high molecular weight water soluble polymer coatings, only need the aqueous solution soaking of certain temperature to remove, therefore can not cause extra damage to glass/sapphire/ceramic surface.In addition, in auxiliary agent, add on-slip agent, make coatings there is on-slip characteristic, will make glass/sapphire/pottery can not produce slip in transportation, better protective glass/sapphire/pottery, thus avoid extra damage; When deep processing, owing to thering is on-slip characteristic, can adopt the mode that multi-disc glass/sapphire/pottery is superimposed to carry out mechanical workout, further can enhance productivity.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any modifications of doing within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.

Claims (9)

1. the former sheet glass/sapphire/pottery of plated film, is characterized in that, at least one side of described plated film former sheet glass/sapphire/pottery is coated with high molecular weight water soluble polymer coatings; The polymkeric substance that described coatings is served as reasons and obtained after the coating liquid that comprises resin, auxiliary agent solidifies.
2. the former sheet glass/sapphire/pottery of plated film as claimed in claim 1, is characterized in that, described resin comprises at least one in epoxy resin, esters of acrylic acid, polyurethanes, swollen resin.
3. the former sheet glass/sapphire/pottery of plated film as claimed in claim 1, is characterized in that, described auxiliary agent comprises light trigger, dispersion agent, wetting agent, smooth dose, solidifying agent, on-slip agent.
4. the former sheet glass/sapphire/pottery of plated film as claimed in claim 1, is characterized in that, described coatings also comprises look mother.
5. the former sheet glass/sapphire/pottery of plated film as claimed in claim 4, it is characterized in that, after the coating liquid of described coatings by following weight percent proportioning solidifies, obtain: 10-30% epoxy resin, 20-50% acrylate, 0-20% urethane, 0-10% swollen resin, 0-10% light trigger, 0-10% dispersion agent, 0-10% wetting agent, smooth dose of 0-10%, 0-10% solidifying agent, 0-10% on-slip agent, 0-10% look female, 0-10% solvent.
6. a making method for plated film former sheet glass/sapphire/pottery, is characterized in that, comprises the steps:
Former sheet glass/sapphire/pottery is provided;
High molecular weight water soluble polymer coating liquid is coated with at least one side that is contained in described former sheet glass/sapphire/pottery;
Described high molecular weight water soluble polymer coating liquid is solidified in described former sheet glass/sapphire/ceramic surface, obtain the former sheet glass/sapphire/pottery of plated film.
7. making method as claimed in claim 6, it is characterized in that, described high molecular weight water soluble polymer coating liquid comprises 10-30% epoxy resin, 20-50% acrylate, 0-20% urethane, 0-10% swollen resin, 0-10% light trigger, 0-10% dispersion agent, 0-10% wetting agent, smooth dose of 0-10%, 0-10% solidifying agent, 0-10% on-slip agent, 0-10% look mother, 0-10% solvent.
8. making method as claimed in claim 6, is characterized in that, described high molecular weight water soluble polymer coating liquid carries out application by coating or mode of printing.
9. making method as claimed in claim 6, is characterized in that, described high molecular weight water soluble polymer coating liquid passes through ultraviolet, infrared or type of heating curing.
CN201310487877.3A 2013-10-17 2013-10-17 Coated sheet glass/sapphire/ceramic and manufacturing method thereof Active CN103589207B (en)

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CN201310487877.3A CN103589207B (en) 2013-10-17 2013-10-17 Coated sheet glass/sapphire/ceramic and manufacturing method thereof
PCT/CN2013/088203 WO2015054948A1 (en) 2013-10-17 2013-11-29 Coated sheet glass/sapphire/ceramic and preparing method therefor

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CN103589207B CN103589207B (en) 2017-02-15

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104123524B (en) * 2014-07-02 2017-07-07 厦门润晶光电集团有限公司 A kind of sapphire screen cover glass and its preparation method
CN109896742A (en) * 2019-04-23 2019-06-18 蚌埠中光电科技有限公司 A kind of film plating process of TFT-LCD base plate glass
CN110577367A (en) * 2018-08-13 2019-12-17 蓝思科技(长沙)有限公司 glass protection processing technology, glass and equipment
CN112876116A (en) * 2021-01-27 2021-06-01 上海无想新材料科技有限公司 Colored expanded vermiculite and preparation method and application thereof

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CN1268491A (en) * 1999-02-16 2000-10-04 肖特玻璃制造厂 Method for protecting glass basic surface
WO2003029372A2 (en) * 2001-10-03 2003-04-10 3M Innovative Properties Company Dry-peelable temporary protective coatings
CN101166584A (en) * 2005-04-29 2008-04-23 康宁股份有限公司 Methods for protecting glass
CN101463217A (en) * 2009-01-15 2009-06-24 方刚 Preparation of water-soluble acrylic ester coating
CN103059688A (en) * 2011-10-20 2013-04-24 展辰涂料集团股份有限公司 Waterborne two-component anti-radiation glass paint

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CN102134437B (en) * 2011-02-28 2012-08-22 上虞市佑谦特种材料有限公司 UV (ultraviolet)-curing glass coating paint
CN102503164B (en) * 2011-09-28 2014-03-12 奇瑞汽车股份有限公司 Preparation method of wear-resistant hydrophobic glass
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Publication number Priority date Publication date Assignee Title
CN1268491A (en) * 1999-02-16 2000-10-04 肖特玻璃制造厂 Method for protecting glass basic surface
WO2003029372A2 (en) * 2001-10-03 2003-04-10 3M Innovative Properties Company Dry-peelable temporary protective coatings
CN101166584A (en) * 2005-04-29 2008-04-23 康宁股份有限公司 Methods for protecting glass
CN101463217A (en) * 2009-01-15 2009-06-24 方刚 Preparation of water-soluble acrylic ester coating
CN103059688A (en) * 2011-10-20 2013-04-24 展辰涂料集团股份有限公司 Waterborne two-component anti-radiation glass paint

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104123524B (en) * 2014-07-02 2017-07-07 厦门润晶光电集团有限公司 A kind of sapphire screen cover glass and its preparation method
CN110577367A (en) * 2018-08-13 2019-12-17 蓝思科技(长沙)有限公司 glass protection processing technology, glass and equipment
CN109896742A (en) * 2019-04-23 2019-06-18 蚌埠中光电科技有限公司 A kind of film plating process of TFT-LCD base plate glass
CN112876116A (en) * 2021-01-27 2021-06-01 上海无想新材料科技有限公司 Colored expanded vermiculite and preparation method and application thereof

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