CN103563953A - Composite insecticidal composition containing methoxyfenozide and chlorfluazuron and application thereof - Google Patents
Composite insecticidal composition containing methoxyfenozide and chlorfluazuron and application thereof Download PDFInfo
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- CN103563953A CN103563953A CN201210276349.9A CN201210276349A CN103563953A CN 103563953 A CN103563953 A CN 103563953A CN 201210276349 A CN201210276349 A CN 201210276349A CN 103563953 A CN103563953 A CN 103563953A
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- methoxyfenozide
- fluorine pyridine
- pyridine urea
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Abstract
The invention discloses a composite insecticidal composition containing methoxyfenozide and chlorfluazuron and an application thereof. The insecticidal composition takes methoxyfenozide and chlorfluazuron as main active ingredients, wherein the weight ratio of methoxyfenozide to chlorfluazuron is (0.1-80):(0.5-80). The insecticidal composition can generate relatively high synergistic effect, overcomes and delays the drug resistance of insects, and realizes high insecticidal speed and long duration while the application cost is reduced and the prevention effect is obviously better than that of using a single agent. The insecticidal composition disclosed by the invention can prevent lepidoptera, hemiptera, coleoptera, hymenoptera, diptera and mite insects on crops and particularly realizes a special effect on the insects such as lepidoptera plutella xylostella, cotton bollworm and beet armyworm, thysanoptera thrips and mites and the like, and the effect is obviously better than that of using a single agent.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of compound pesticide compositions containing methoxyfenozide and fluorine pyridine urea and uses thereof.
Background technology
Methoxyfenozide, chemical name: the N-tert-butyl group-N'-(3-methoxyl group-2-methyl benzoyl)-3,5-dimethyl benzene formylhydrazine.Structural formula is:
Sterling is white powder, fusing point 202-205 ℃.Water solubility < 1mg/L in the time of 20 ℃.Solvability in other solvents: dimethyl sulfoxide (DMSO) 11g/L, cyclohexanone 9.9g/L, acetone 9g/L.Stable storage at 25 ℃, 25 ℃, PH=5,7,9 times hydrolysis.
Methoxyfenozide preparation low toxicity, rat acute LD50 of passing through mouth is 5000mg/kg, acute through skin LD50>2000mg/kg.
Methoxyfenozide is a kind of of insect growth regulator, IGR, is mainly that the normal growth of interference insect is grown, though insect molting and dead, and can suppress to ingest.This product is strong to controlling object selectivity, is mainly used in the control of lepidoptera pest.
Fluorine pyridine urea (chlorfluazuron) has another name called and presses down hooligan, determines worm urea, 1-(3,5-bis-chloro-4 (the chloro-5-trifluoromethyl-2-of 3-pyridine oxygen base) phenyl)-3-(2,6-difluoro benzoyl) urea; Structural formula is:
It is nineteen eighty-two by a kind of benzoyl area kind chitin inhibitor of Japanese Shi Yuan company exploitation.It has very high insecticidal activity, be a kind of efficient, low toxicity, with the pesticide species of environmentally compatible, will become one of high malicious insecticide principal item of the current use of replacement.
Physicochemical property: white crystals, 226.5 ℃ of fusing points (decomposition), vapour pressure <1 * 10
-10pa (20 ℃), in the time of 20 ℃, solvability is: water 0.01mg/L, hexane 0.01 g/L, n-octyl alcohol 1 g/L, solvent naphtha 2.5 g/L, methyl alcohol 2.5 g/L, toluene 6.6 g/L, isopropyl alcohol 7g/L, carrene 22 g/L, acetone 55 g/L, cyclohexanone 110 g/L are stable under light and heat.
Benzoyl area kind insect growth regulator, IGR.Take stomach poison function as main, have stronger action of contace poison concurrently, permeability is poor, without systemic action.Insecticidal mechanism is to suppress chitin to form, and hinders insect and normally casts off a skin, and makes that ovum is incubated, larval molting, kidney developmental deformity and adult eclosion, lays eggs and be obstructed, thereby reach the effect of desinsection.This medicament activity is high, and speed of action is slower, longer at larva Half-life in vivo.This medicament is broad spectrum insecticide, effective to multiple lepidoptera pest and diptera, orthoptera, Hymenoptera insect.Insect on vegetables is had to tall and erect effect, also can be used for preventing and treating the various pests on wild cabbage, cotton, tea tree, fruit tree.
But diamond-back moth, cotton bollworm and thrips are under the condition of current long-term prescription, and resistance increases gradually, and agricultural chemicals single dose declines gradually to the effect of control of insect.Inventor finds after deliberation, and the synergistic complex of agricultural chemicals is expanding prevention spectrum and the effective measures that improve preventive effect, not yet finds up to now the Pesticidal combination of relevant methoxyfenozide and fluorine pyridine urea.
Summary of the invention
The object of this invention is to provide a kind of compound pesticide compositions containing methoxyfenozide and fluorine pyridine urea, this Pesticidal combination is control Lepidoptera, Semiptera, coleoptera, orthoptera, Hymenoptera, diptera, thrips and mite pest multifunctional insecticide composition.
Another object of the present invention is to provide this compound pesticide compositions and prevents and treats the application on the insecticidal materials of any one or a few insect in resistance Lepidoptera, Semiptera, coleoptera, orthoptera, Hymenoptera, diptera, thrips and mite class in preparation, the particularly application on the insecticidal materials of any one or a few insect in preparation control diamond-back moth, cotton bollworm, beet armyworm, thrips and mite class.
The object of the invention is to be achieved through the following technical solutions:
Containing a compound pesticide compositions for methoxyfenozide and fluorine pyridine urea, it is main active ingredient that this Pesticidal combination be take methoxyfenozide and fluorine pyridine urea, and wherein, the weight ratio of methoxyfenozide and fluorine pyridine urea is 0.1 ~ 80:0.5 ~ 80.Be preferably 0.5 ~ 50:2 ~ 50, more preferably 0.5 ~ 10:4 ~ 30.In this Pesticidal combination, effective ingredient is present in composition with synergy effective dose.
In compound pesticide compositions of the present invention, the two weight percentage in this compound pesticide compositions of methoxyfenozide and fluorine pyridine urea is 3% ~ 80%.Be preferably 5% ~ 55%, most preferably 10% ~ 40%.
Compound pesticide compositions of the present invention be take methoxyfenozide and fluorine pyridine urea and is mixed with any one formulation allowing on agricultural chemicals, the preferred missible oil of described formulation, suspending agent, wetting powder, aqueous emulsion, microemulsion or water dispersible granules as main active ingredient and insecticides adjuvant and excipient.
Auxiliary agent can adopt calcium dodecyl benzene sulfonate, agriculture breast 600#, the rare block compound of polyoxyethylene polyoxy third (as agriculture breast 33
#), polyoxyethylene nonylphenol ether etc., excipient comprises cyclohexanone, solvent naphtha, solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient and other auxiliary material can alone or and use.
Compound pesticide compositions containing methoxyfenozide and fluorine pyridine urea of the present invention preparation prevent and treat resistance Lepidoptera, Semiptera, coleoptera, orthoptera,, application in diptera, thrips and mite class on the insecticidal materials of any one or a few insect.Especially in preparation control diamond-back moth, cotton bollworm, beet armyworm, thrips and mite class, the effect on the insecticidal materials of any one or a few insect is remarkable.And suppress insect the pesticide resistance of unitary agent (methoxyfenozide or fluorine pyridine urea are arbitrary) is produced.
Beneficial effect of the present invention compared with prior art:
(1) compare with single dose, said composition antagonism lepidoptera pest, as diamond-back moth and thrips insect thrips etc. has obvious synergistic function, overcomes and has delayed pest resistance to insecticide, expanding prevention spectrum, and desinsection speed is fast, has obviously improved control efficiency; (2) reduce control recruitment, drug cost; (3) alternative high-toxic pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with fluorine pyridine urea single dose with methoxyfenozide, produce and use cost reduction; (6) suppress lepidoptera pest, Hymenoptera, thrips and mite pest the resistance of agricultural chemicals is strengthened, its successful is used higher than its single dose.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
Embodiment 1:
Taking methoxyfenozide, fluorine pyridine urea adopts conventional formulation method to be mixed with by different proportion the methoxyfenozide 5 percent of hexaflumuron emulsifiable concentrate that main active ingredient weight percentage is 30%.Concrete ratio is in Table 1,2.
Adopt leaf dipping method to carry out indoor synergy biologicall test, selecting resistance diamond-back moth is target pest, and every processing repeats 3 times, and every concentration is processed 60, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism diamond-back moth by probability value method
50, use LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 1:
The toxicity test of the composite and single dose antagonism diamond-back moth of table 1 methoxyfenozide and fluorine pyridine urea
As shown in Table 1, methoxyfenozide and fluorine pyridine urea are composite, and co-toxicity coefficient is all greater than 120, shows good synergistic function.
Adopt leaf dipping method to carry out indoor synergy biologicall test, selection resistant bollworm is target pest, and every processing repeats 3 times, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism cotton bollworm by probability value method
50, use LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 2:
The toxicity test of the composite and single dose antagonism cotton bollworm of table 2 methoxyfenozide and fluorine pyridine urea
As shown in Table 2, methoxyfenozide and fluorine pyridine urea are composite, and the co-toxicity coefficient of cotton bollworm is all greater than to 120, show good synergistic function.
Embodiment 2:
Take 5g methoxyfenozide, 50g fluorine pyridine urea, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33
#2g, agriculture breast 600# 1g, solvent naphtha 13g, adds water to 100g.The method of above raw material being prepared routinely to aqueous emulsion drops into the mixing of mixing kettle high speed, forms the methoxyfenozide fluorine pyridine urea aqueous emulsion that main active ingredient weight percentage is 55%.
Embodiment 3:
Take 2g methoxyfenozide, 18g fluorine pyridine urea, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33
#2g, agriculture breast 600# 1g, cyclohexanone 10g, adds water to 100g.The method that above raw material is prepared to microemulsion routinely drops in mixing kettle mixes, and forms the methoxyfenozide fluorine pyridine urea microemulsion that main active ingredient weight percentage is 20%.
Embodiment 3 is prevented and treated to the vegetables diamond-back moth test of pesticide effectiveness, according to the consumption medication in form 3, every mu of ground medication 20g, 30g, contrast medicament is 40% fluorine pyridine urea EC(missible oil) 30g/ mu and 15% methoxyfenozide EC30g/ mu, with clear water, do blank, the result of looking into 3 days, 7 days, 14 days and 28 days after medicine, result is in Table 3:
Table 3: the composite field test results to vegetables diamond-back moth of methoxyfenozide fluorine pyridine urea
Field efficacy result shows, methoxyfenozide fluorine pyridine urea compositions antagonism diamond-back moth has good control efficiency, and control efficiency is all better than the effect that single dose kind is better than direct each single product of while.
Embodiment 3 is prevented and treated to cotton cotton bollworm field medicine effect test, according to the consumption medication in form 4, every mu of ground medication 20g, 30g, contrast medicament is 40% fluorine pyridine urea EC(missible oil) 30g/ mu and 15% methoxyfenozide EC 30g/ mu, with clear water, do blank, after medicine, look into 3 days, the result of 7 days, 14 days and 28 days, result is in Table 4:
Table 4: the composite field test results to cotton bollworm of methoxyfenozide fluorine pyridine urea
Field efficacy result shows, methoxyfenozide fluorine pyridine urea compositions antagonism cotton bollworm has good control efficiency, and control efficiency is all better than the effect that single dose kind is better than direct each single product of while.
Embodiment 4:
Take 1g methoxyfenozide, 5g fluorine pyridine urea, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the methoxyfenozide 5 percent of hexaflumuron emulsifiable concentrate that main active ingredient weight percentage is 6%.
Embodiment 5:
Take 50g methoxyfenozide, 20g fluorine pyridine urea, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the methoxyfenozide 5 percent of hexaflumuron emulsifiable concentrate that main active ingredient weight percentage is 70%.
Embodiment 6:
Take 2g methoxyfenozide, 40g fluorine pyridine urea, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the methoxyfenozide 5 percent of hexaflumuron emulsifiable concentrate that main active ingredient weight percentage is 42%.
Embodiment 7:
Take 0.2g methoxyfenozide, 50g fluorine pyridine urea, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the methoxyfenozide 5 percent of hexaflumuron emulsifiable concentrate that main active ingredient weight percentage is 50.2%.
Embodiment 8:
Take 5g methoxyfenozide, 0.5g fluorine pyridine urea, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the methoxyfenozide 5 percent of hexaflumuron emulsifiable concentrate that main active ingredient weight percentage is 5.5%.
Embodiment 9:
Take 5g methoxyfenozide, 30g fluorine pyridine urea, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the methoxyfenozide 5 percent of hexaflumuron emulsifiable concentrate that main active ingredient weight percentage is 35%.
Embodiment 10:
Take 20g methoxyfenozide, 5g fluorine pyridine urea, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the methoxyfenozide 5 percent of hexaflumuron emulsifiable concentrate that main active ingredient weight percentage is 25%.
Embodiment 11:
Take 30g methoxyfenozide, 12g fluorine pyridine urea, sodium lignin sulfonate 2g, alkyl phenol (or fatty alcohol) polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, forms the methoxyfenozide fluorine pyridine urea suspending agent that main active ingredient weight percentage is 42% under the effect of sand mill.
Embodiment 12:
Take 2g methoxyfenozide, 5g fluorine pyridine urea, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite 21g, forms by water dispersible granular agent method the methoxyfenozide fluorine pyridine urea water dispersible granules that main active ingredient weight percentage is 14% by above raw material.
Embodiment 13:
Take 50g methoxyfenozide, 3g fluorine pyridine urea, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the methoxyfenozide 5 percent of hexaflumuron emulsifiable concentrate that main active ingredient weight percentage is 53%.
Embodiment 14:
Take 2g methoxyfenozide, 18g fluorine pyridine urea, sodium lignin sulfonate 10g, Negel 2g, with diatomite, add to 100g, above raw material is mixed in micronizer, form the methoxyfenozide fluorine pyridine urea wetting powder that main active ingredient weight percentage is 20%.
Embodiment 15:
Take 7g methoxyfenozide, 70g fluorine pyridine urea, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the methoxyfenozide 5 percent of hexaflumuron emulsifiable concentrate that main active ingredient weight percentage is 77%.
Embodiment 16:
Take 60g methoxyfenozide, 5g fluorine pyridine urea, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin 13g, forms by water dispersible granular agent method the methoxyfenozide fluorine pyridine urea water dispersible granules that main active ingredient weight percentage is 65% by above raw material.
Claims (10)
1. containing a compound pesticide compositions for methoxyfenozide and fluorine pyridine urea, it is characterized in that it is main active ingredient that this Pesticidal combination be take methoxyfenozide and fluorine pyridine urea, wherein, the weight ratio of methoxyfenozide and fluorine pyridine urea is 0.1 ~ 80:0.5 ~ 80.
2. the compound pesticide compositions containing methoxyfenozide and fluorine pyridine urea according to claim 1, is characterized in that described methoxyfenozide and the weight ratio of fluorine pyridine urea are 0.5 ~ 50:2 ~ 50.
3. the compound pesticide compositions containing methoxyfenozide and fluorine pyridine urea according to claim 2, is characterized in that described methoxyfenozide and the weight ratio of fluorine pyridine urea are 0.5 ~ 10:4 ~ 30.
4. the compound pesticide compositions containing methoxyfenozide and fluorine pyridine urea according to claim 1, is characterized in that the two weight percentage in this compound pesticide compositions of methoxyfenozide and fluorine pyridine urea is 3% ~ 80%.
5. the compound pesticide compositions containing methoxyfenozide and fluorine pyridine urea according to claim 4, is characterized in that the two weight percentage in this compound pesticide compositions of methoxyfenozide and fluorine pyridine urea is 5% ~ 55%.
6. the compound pesticide compositions containing methoxyfenozide and fluorine pyridine urea according to claim 5, is characterized in that the two weight percentage in this compound pesticide compositions of methoxyfenozide and fluorine pyridine urea is 10% ~ 40%.
7. the compound pesticide compositions containing methoxyfenozide and fluorine pyridine urea according to claim 1, is characterized in that this compound pesticide compositions take methoxyfenozide and fluorine pyridine urea and be mixed with any one formulation allowing on agricultural chemicals as main active ingredient and insecticides adjuvant, excipients.
8. the compound pesticide compositions containing methoxyfenozide and fluorine pyridine urea according to claim 7, is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersible granules.
9. the compound pesticide compositions containing methoxyfenozide and fluorine pyridine urea claimed in claim 1 is prevented and treated the application on the insecticidal materials of any one or a few insect in resistance Lepidoptera, Semiptera, coleoptera, orthoptera, Hymenoptera, diptera, thrips and mite class in preparation.
10. the application on the insecticidal materials that is applied as this compound pesticide compositions any one or a few insect in preparation control diamond-back moth, cotton bollworm, beet armyworm, thrips and mite class according to claim 9.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210276349.9A CN103563953A (en) | 2012-08-05 | 2012-08-05 | Composite insecticidal composition containing methoxyfenozide and chlorfluazuron and application thereof |
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| CN201210276349.9A CN103563953A (en) | 2012-08-05 | 2012-08-05 | Composite insecticidal composition containing methoxyfenozide and chlorfluazuron and application thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110583653A (en) * | 2019-10-15 | 2019-12-20 | 中国农业科学院棉花研究所 | Insecticidal composition and application thereof |
| CN111066785A (en) * | 2019-12-26 | 2020-04-28 | 安徽农业大学 | Application of DMNT in preparation of lepidoptera pest insecticide |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0602794A2 (en) * | 1992-11-23 | 1994-06-22 | Rohm And Haas Company | Insecticidal N'-substituted-N, N'-diacylhydrazines |
| CN1399876A (en) * | 2001-07-31 | 2003-03-05 | 马韵升 | Tebufenozide pesticide composition |
| CN101647434A (en) * | 2009-07-06 | 2010-02-17 | 东莞市瑞德丰生物科技有限公司 | Pesticide composition having synergistic function and application thereof |
-
2012
- 2012-08-05 CN CN201210276349.9A patent/CN103563953A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0602794A2 (en) * | 1992-11-23 | 1994-06-22 | Rohm And Haas Company | Insecticidal N'-substituted-N, N'-diacylhydrazines |
| CN1399876A (en) * | 2001-07-31 | 2003-03-05 | 马韵升 | Tebufenozide pesticide composition |
| CN101647434A (en) * | 2009-07-06 | 2010-02-17 | 东莞市瑞德丰生物科技有限公司 | Pesticide composition having synergistic function and application thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110583653A (en) * | 2019-10-15 | 2019-12-20 | 中国农业科学院棉花研究所 | Insecticidal composition and application thereof |
| CN111066785A (en) * | 2019-12-26 | 2020-04-28 | 安徽农业大学 | Application of DMNT in preparation of lepidoptera pest insecticide |
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Application publication date: 20140212 |