CN103526634A - Paper printing environmental-friendly UV gloss paint and preparation method thereof - Google Patents
Paper printing environmental-friendly UV gloss paint and preparation method thereof Download PDFInfo
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- CN103526634A CN103526634A CN201310457178.4A CN201310457178A CN103526634A CN 103526634 A CN103526634 A CN 103526634A CN 201310457178 A CN201310457178 A CN 201310457178A CN 103526634 A CN103526634 A CN 103526634A
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Abstract
The invention relates to a paper printing environmental-friendly UV (ultraviolet) gloss paint which is prepared from the following raw materials in parts by weight: 55 to 60 parts of epoxy acrylate, 3 to 4 parts of methacrylate, 20 to 24 percent of vinyl ether carbamate, 8 to 10 parts of photoinitiator 184, 20 to 30 parts of 1,6-hexanediol diacrylate, 1 to 2 parts of cellulose acetate butyrate, 1 to 2 parts of sodium hexametaphosphate, 5 to 8 parts of ethylene glycol, 2 to 3 parts of tributyl phosphate, 1 to 2 parts of dibutyl phthalate and 4 to 5 parts of dispersing auxiliary. The paper printing environmental-friendly UV gloss paint uses epoxy acrylate, has a high curing speed, has the advantages of excellent water resistance, hot-water resistance, drug resistance, cohesiveness, toughness, high gloss, good wear resistance, low content of volatile matter, energy saving and environmental-friendliness, difficulty in yellowing, low cost and stable product quality, and has a good decorative effect.
Description
Technical field
The invention belongs to paint field, relate in particular to a kind of paper printing environmental-friendly UV (Ultraviolet) gloss oil and preparation method thereof.
Background technology
Development along with market economy, there is great variety in paint field, wherein UV coating has the advantages such as curing rate is fast, energy-conservation, normal temperature cure, superior performance, environmental protection, on it, ray velocity is fast, rete brightness is high, and dry rear face is firm heat-resisting, and refractive power is effective, make ground produce strong main body sense, be widely used in the fields such as chemical industry, machinery, electronics light industry, communication.Due to its environment-friendly advantage, UV solidifies and to have obtained the strong support of relevant environment rules and the close attention of industrial quarters, and UV radiation curing material is in market demand rapid growth, and UV Radiation-curing system is just with multiple technologies combination, to overcome some defect, meet actual application.Now in printing industry; the packing that can make UV obtains some special effects: high gloss, good ink protection feature, the slipping that can add control and rub resistance, low smell or do not have smell, low extract maybe cannot detect extract, and the protective effect to ink.
Current UV curing materials is various, but still in various degree exist some problems, such as: Organic Pollution, xanthochromia, explosive look, not low temperature resistant, the series of problems such as cost is high, corrosion-resistant, all need to continue improvement for different purposes, reduce production costs, expand purposes.
Summary of the invention
The object of the present invention is to provide paper printing environmental-friendly UV (Ultraviolet) gloss oil of a kind of strong adhesion, high glaze, environmental protection and energy saving and preparation method thereof.
Technical scheme of the present invention is as follows:
A kind of paper printing environmental-friendly UV (Ultraviolet) gloss oil, it is characterized in that being made by the raw material of following weight portion: epoxy acrylate 55-60, methacrylate 3-4, vinyl ethers type carbamate 20-24, light trigger 184 8-10,1,6-hexanediyl ester 20-30, acetylbutyrylcellulose 1-2, calgon 1-2, ethylene glycol 5-8, tributyl phosphate 2-3, dibutyl phthalate 1-2, dispersing aid 4-5;
Described dispersing aid is made by the raw material of following weight portion: diatomite 5-7, jade 3-4, Rosa Damascana 1-2, anilinomethyl triethoxysilane 1-2, sodium selenite 1-2, morpholine 2-3, pentaerythritol triacrylate 2-3, alcohol ester 12 5-6, methyl laurate 1-2, butyl acetate 22-25; Preparation method puts into calcining furnace by diatomite, jade, at 620-650 ℃, calcines 3-4 hour, takes out, and puts into 10-15% hydrochloric acid solution and is ground to 20-40 μ m slurry, and the material pH value of sizing mixing is for neutral, and spraying is dry; Other residual components is mixed, be heated to 50-55 ℃, stir 40-50 minute; Continue to be warming up to 70-80 ℃, add diatomite, jade powder, stirring reaction 1-2 hour, obtains.
The preparation method of described paper printing environmental-friendly UV (Ultraviolet) gloss oil, it is characterized in that comprising the following steps: other composition except light trigger 184 is mixed, be warming up to 30-40 ℃, under 500-600 rev/min, stir 15-20 minute, cool to 25 ℃ and add again below light trigger 184, continue to stir 10-15 minute, obtain.
Beneficial effect of the present invention
The present invention has used epoxy acrylate, curing rate is fast, have excellent resistance to water, hot water resistance, resistance physical property, caking property, toughness, high glaze, ABRASION RESISTANCE good, low volatile content, energy-conserving and environment-protective, inhibited from yellowing, cost is low, the advantage of constant product quality, good decorating effect.
The specific embodiment
A kind of paper printing environmental-friendly UV (Ultraviolet) gloss oil, by following weight portion (kilogram) raw material make: epoxy acrylate 57, methacrylate 3, vinyl ethers type carbamate 22, light trigger 184 9,1,6-hexanediyl ester 26, acetylbutyrylcellulose 1.5, calgon 1.5, ethylene glycol 6, tributyl phosphate 2, dibutyl phthalate 1, dispersing aid 4;
Described dispersing aid by following weight portion (kilogram) raw material make: diatomite 6, jade 3, Rosa Damascana 1.4, anilinomethyl triethoxysilane 1.5, sodium selenite 1.5, morpholine 2.5, pentaerythritol triacrylate 2.6, alcohol ester 12, methyl laurate 1.6, butyl acetate 24; Preparation method puts into calcining furnace by diatomite, jade, calcines 3.6 hours at 640 ℃, takes out, and puts into 13% hydrochloric acid solution and is ground to 30 μ m slurries, and the material pH value of sizing mixing is for neutral, and spraying is dry; Other residual components is mixed, be heated to 53 ℃, stir 45 minutes; Continue to be warming up to 75 ℃, add diatomite, jade powder, stirring reaction 1.5 hours, obtains.
The preparation method of described paper printing environmental-friendly UV (Ultraviolet) gloss oil, comprises the following steps: other composition except light trigger 184 is mixed, be warming up to 35 ℃, under 560 revs/min, stir 18 minutes, cool to 20 ℃ and add again light trigger 184, continue to stir 13 minutes, obtain.
This paper printing environmental-friendly UV (Ultraviolet) gloss oil can adopt the form of construction work of roller coating, showering, spraying to construct.The gloss oil painting making by above scheme is contained in adhesive force on plank and is all better than secondary, resistance to 75% ethanol is more than 24 hours, alkaline-resisting 24 hours above, acidproof more than 48 hours, the cold cycling that tolerates subzero 40 degree and 40 degree does not ftracture for 10 times, resistance to 15% saline solution is more than 60 hours, hardness can regulate between 3H at 2HB, and abrasion resistance index turns above 2800.
Claims (2)
1. a paper printing environmental-friendly UV (Ultraviolet) gloss oil, it is characterized in that being made by the raw material of following weight portion: epoxy acrylate 55-60, methacrylate 3-4, vinyl ethers type carbamate 20-24, light trigger 184 8-10,1,6-hexanediyl ester 20-30, acetylbutyrylcellulose 1-2, calgon 1-2, ethylene glycol 5-8, tributyl phosphate 2-3, dibutyl phthalate 1-2, dispersing aid 4-5;
Described dispersing aid is made by the raw material of following weight portion: diatomite 5-7, jade 3-4, Rosa Damascana 1-2, anilinomethyl triethoxysilane 1-2, sodium selenite 1-2, morpholine 2-3, pentaerythritol triacrylate 2-3, alcohol ester 12 5-6, methyl laurate 1-2, butyl acetate 22-25; Preparation method puts into calcining furnace by diatomite, jade, at 620-650 ℃, calcines 3-4 hour, takes out, and puts into 10-15% hydrochloric acid solution and is ground to 20-40 μ m slurry, and the material pH value of sizing mixing is for neutral, and spraying is dry; Other residual components is mixed, be heated to 50-55 ℃, stir 40-50 minute; Continue to be warming up to 70-80 ℃, add diatomite, jade powder, stirring reaction 1-2 hour, obtains.
2. the preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil according to claim 1, it is characterized in that comprising the following steps: other composition except light trigger 184 is mixed, be warming up to 30-40 ℃, under 500-600 rev/min, stir 15-20 minute, cool to 25 ℃ and add again below light trigger 184, continue to stir 10-15 minute, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310457178.4A CN103526634A (en) | 2013-09-30 | 2013-09-30 | Paper printing environmental-friendly UV gloss paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310457178.4A CN103526634A (en) | 2013-09-30 | 2013-09-30 | Paper printing environmental-friendly UV gloss paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103526634A true CN103526634A (en) | 2014-01-22 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310457178.4A Pending CN103526634A (en) | 2013-09-30 | 2013-09-30 | Paper printing environmental-friendly UV gloss paint and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101775254A (en) * | 2010-01-27 | 2010-07-14 | 吴江友鑫高分子材料科技有限公司 | Light reflection-preventing ultraviolet curing coating for plastic surface |
| CN102199375A (en) * | 2010-03-26 | 2011-09-28 | 东莞市佩琦涂料有限公司 | Ultraviolet (UV) paint solidified by ultraviolet light |
| CN103073989A (en) * | 2012-12-19 | 2013-05-01 | 青岛海诺水务科技股份有限公司 | Ultraviolet-cured paint |
| CN103087626A (en) * | 2013-01-31 | 2013-05-08 | 安徽蓝柯复合材料有限公司 | UV (Ultraviolet) varnish and preparation method thereof |
-
2013
- 2013-09-30 CN CN201310457178.4A patent/CN103526634A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101775254A (en) * | 2010-01-27 | 2010-07-14 | 吴江友鑫高分子材料科技有限公司 | Light reflection-preventing ultraviolet curing coating for plastic surface |
| CN102199375A (en) * | 2010-03-26 | 2011-09-28 | 东莞市佩琦涂料有限公司 | Ultraviolet (UV) paint solidified by ultraviolet light |
| CN103073989A (en) * | 2012-12-19 | 2013-05-01 | 青岛海诺水务科技股份有限公司 | Ultraviolet-cured paint |
| CN103087626A (en) * | 2013-01-31 | 2013-05-08 | 安徽蓝柯复合材料有限公司 | UV (Ultraviolet) varnish and preparation method thereof |
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| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20140122 |