CN103493830A - Pesticide composition containing cycloxaprid and chlorfenapyr - Google Patents
Pesticide composition containing cycloxaprid and chlorfenapyr Download PDFInfo
- Publication number
- CN103493830A CN103493830A CN201310471584.6A CN201310471584A CN103493830A CN 103493830 A CN103493830 A CN 103493830A CN 201310471584 A CN201310471584 A CN 201310471584A CN 103493830 A CN103493830 A CN 103493830A
- Authority
- CN
- China
- Prior art keywords
- capillary
- cycloxaprid
- pesticidal combination
- pest
- combination according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a pesticide composition containing cycloxaprid and chlorfenapyr, relating to the field of agricultural insecticide techniques and particularly relates to a dualistically-compounded composition having the insecticidal activity and containing active components including the cycloxaprid and the chlorfenapyr and a use method of the composition. The pesticide composition is characterized by comprising the active components including the cycloxaprid and the chlorfenapyr, wherein the weight ratio of the cycloxaprid to the chlorfenapyr is (50:1)-(1:50). According to the pesticide composition which contains the cycloxaprid and the chlorfenapyr and is used for being applied to plants or growth environments of the plants, and a method for preventing or controlling pests by applying the pesticide composition, the composition having the insecticidal activity has a synergistic insecticidal action. The method for protecting the plants comprises the step of contacting the plants with the composition having the insecticidal activity.
Description
Technical field
A kind of Pesticidal combination containing cycloxaprid and capillary of the present invention relates to agriculture insecticidal technology field, in particular a kind of compoistion and method of use with insecticidal activity that comprises active component cycloxaprid and capillary binary built.
Background technology
Homoptera (Homoptera) comprises cicada, froghopper, leafhopper, horned frog, plant hopper, plant hopper, wood louse, aleyrodid, aphid and coccid, be a monoid larger in Insecta, metamorphosis is larger, the mouthpart pierce-suck type, fore wing quality identical (corresponding with Semiptera), therefore claim Homoptera.Homoptera insect all be take water as food, and wherein numerous species can be propagated the viroses of plant, is important pest.Some kind can be secreted wax, glue, or forms insect gall, produces gall nut, is important industrial resources insect.The song of cicada is melodized, and the form of plant hopper, horned frog is special, be people loved by all view and admire insect.
The known Homoptera in the world has kind more than 45000, is distributed widely in all over the world.China is known a kind more than 3000.Its feature can be summarized as: the fore wing homogeneity, beak is nearby sufficient under lifting one's head, leafhopper plant hopper aphid and a red-spotted lizard, often harmful agricultural and fruits and vegetables.
Homoptera comprises Cicadomorpha, Psyllomorpha, Aphidomorpha, Aleyrodomorpha and 5 suborders of Coccinea.
Cicadomorpha, beak and was given birth to before clavicula; The feeler setiform; Fore wing has obvious calvus; Digitus 3 joints.Active kind the jumping, the ability of circling in the air is strong, and many male worms can pronounce.
Psyllomorpha, small-sized, active kind the jumping.Feeler 10 joints, thread, the end bifurcated, the place ahead of giving birth at compound eye.Simple eye 3; Beak 3 joints bear between clavicula.Digitus 2 joints, the metapedes base pitch has verruca, tibia end spinosity.Nymph has wax gland more, can secrete wax protection thing, some formation insect galls, and some generation honeydews, often have ant to follow.Adult nymph thorn is inhaled the juice of plant, is agriculture and forestry injurious insect, and some also propagates the viroses of plant.This suborder only comprises 1 section, i.e. Psyllidae domesticly common are Psylla Chinesis Yang Et, oranges and tangerines wood louse etc.
Aphidomorpha, small-sized polymorphic insect, of the same race has aptery and alate.Feeler 3-6 joint, have primary and secondary two kinds of different perceptrons.Digitus 2 joints, the 1st joint is very short.Belly often has cornical, and minor details backboard and web form respectively cauda and tailgate.If any wing, fore wing is larger than hind wing, and fore wing has pterostigma.The mode of reproduction of aphid has bisexual reproduction and parthenogenesis, oviparity or ovoviviparity.The aphid thorn is inhaled water, causes that development of plants is bad, and the excretion honeydew, cause that mould grows, and can propagate the viroses of plant, is one of most important agriculture and forestry injurious insect monoid.The insect gall gall nut of times aphid is important industry and medicinal raw material.The known kind more than 4000 in the world, be classified as 2 Superfamily 13 sections.
Aleyrodomorpha, feeler 7 joints, the 2nd joint expands.Digitus 2 joints, wait large.Both sexes all have wing, adularescent wax powder on wing.There is [Dan at nymph, the adult abdomen end back side.Thorn is inhaled water, is the primary pest of cultivated plant in the woody plant such as oranges and tangerines and greenhouse, common are Aleurocanthus spiniferus, greenhouse whitefly etc.
Coccinea, be commonly referred to as coccid, Peculiar Forms, asyngamy.Male worm has 1 pair of film wing, and hind wing deteriorates to halter.Digitus 1 joint.Female worm is aptery, digitus 1-2 joint, and the normal healing of 3 individual section, the cephalothorax boundary is unclear, and some bellies also merogenesis are unclear.The secretion of wax, colloid is often arranged, or special a red-spotted lizard shell protection is arranged.Multiparasitism, in woody plant or herbaceos perennial, is important gardening and forest pest.Some coccid secretion wax, glue, pigment, become important industrial resources and medicine resource insect.The known kind more than 5000 in the world, annual also have novel species to find.
Lepidoptera is second large order in Insecta, comprises all butterflies and moth, and the whole world approximately has 200,000 kinds, and there is kind more than 8000 in China.Wherein the moth class is 6000 kinds, 2000 kinds of butterfly classes.The lepidoptera pest kind is extremely many, and almost each crops all is subject to the wherein harm of one or more insects.The Lepidoptera distribution is extremely wide, the abundantest with tropical kind.The larva of the most kinds all kinds of cultivated plants of causing harm, the normal food of bodily form the greater is blade or bore moth limb to the greatest extent.Bodily form smaller often leaf roll, sew leaf, knot sheath, weaving silk to knot or pierce plant tissue takes food and causes harm.Adult is mainly with nutrition as a supplement such as nectar, or mouthpart degenerates and no longer take food, and generally do not cause direct harm.Lepidoptera is the order that agriculture and forestry injurious insect is maximum, the yield and quality of its serious harm agricultural product.Telson moth, rice leaf roll snout moth's larva as paddy rice; The insect pests such as the chilo infuscatellus of the wild snout moth's larva of the beans of vegetables, melon thin,tough silk snout moth's larva and sugarcane and bar snout moth's larva.
Chemical control is an important means of the upper prevention of agricultural and Control pests.Yet current, due to kind, the existence characteristic of insect etc., the reasons such as the weak effect that living environment etc. cause, repellence prosperity can not effectively be prevented and kill off sometimes.Particularly, for the pest of Lepidoptera, coleoptera, diptera, Homoptera, Semiptera, Hymenoptera, thrips, arachnids and Nematoda etc., utilize conventional dose to carry out prevention and control and just become increasingly difficult.Therefore, for can effectively prevent and kill off can not prevent and kill off or prevent and kill off difficult pest and seek a kind of new means and method.
Capillary (Chlorfenapyr), have another name called eliminate, chlorfenapyr, capillary is a kind of new type heterocycle class desinsection of being succeeded in developing by American Cyanamid Company, kills mite, nematocide.Chemical name is bromo-2-(4-chlorphenyl)-1-ethoxyl methyl-5-trifluoromethyl pyrpole-3-nitrile, and its chemical formula is:
Capillary is the new pyrrole compounds, acts on the mitochondria of insect bodies inner cell, by the mixed-functional oxidase in insect bodies, works, and mainly suppresses the conversion of adenosine diphosphate (ADP) to adenosine triphosphate (ATP).And adenosine triphosphate storage cell maintains the necessary energy of its vital functions.As a kind of preinsecticide, itself to insect without the poisoning effect.After insect's food-taking or contact capillary, in insect bodies, capillary changes concrete insecticidal active compound under the effect of mixed-functional oxidase, and its target is the mitochondria in the insect bodies cell.Cell is synthesized and because lacking energy, stop vital functions, after laxative, pest activity dies down, and spot occurs, and color changes, and activity stops, and stupor is weak and limp, finally causes death.
This medicament has following characteristics: broad spectrum insecticide, have stomach toxicity and action of contace poison concurrently, with other insecticides, medium residual activity arranged without cross resistance, on crop, in nutrient solution through the selective systemic activity of Root Absorption, medium to the mammal Oral toxicity, lower, the effective formulation rate of percutaneous toxicity low (100g active ingredient/hm2).The capillary insecticidal spectrum is wide, through land for growing field crops, test for many years and practical application shows, 70 various pests in the orders such as Lepidoptera, Homoptera, coleoptera are had to fabulous preventive effect, especially to special efficacys such as the diamond-back moth in the vegetables resistant insect, beet armyworm, prodenia litura, Americal rice leaf miner, the wild snout moth's larva of beans, thrips, two spotted spider mite.Belong to bionic pesticide, toxicity is low, and desinsection speed is fast, and medication gets final product kill pests in 1 hour, and the same day, preventive effect reached more than 85%.Capillary can break up resistance, and mechanism of action uniqueness is different from other insecticide mechanism of action, and without cross resistance, the insect that the antagonism property of medicine is serious is efficient equally.Especially insect and the mite class of organic phosphor, carbamate, chrysanthemum ester, chitin synthesis inhibitor insecticides generation resistance are had to good effect.The capillary lasting period is long especially, on the control resistant insect, can control 15-20 days, and the control two spotted spider mite longevity of residure reaches 35 days, can thoroughly remove the hard work of vegetable grower's " three days one time medicine ".Capillary is applied widely, can be used for vegetables, fruit tree, ornamental plants etc., can be widely used in insect and mite class on the various crop such as control cotton, vegetables, citrus, grape and soybean, and drug effect than the high 4-16 of the conventional dose such as Methomyl, orthene doubly.Also can be used for control termites.The capillary permeability is strong, foliar spray, and effective ingredient is permeable to blade back, and desinsection is more thorough.Capillary is environmentally friendly machine, for the pyroles material of natural screening, fool proof to human body and livestock.Be particluarly suitable for exported product, the use of high-quality product.Each big city, the whole nation is chosen to be bromine worm eyeball in the first-selected agricultural chemicals of pollution-free vegetable.Although it is higher that the capillary a drug drops into, wide because of insecticidal spectrum, thoroughly, the control time is long in control, presses every mu of cumulative cost still than worthwhile with other insecticides.
Capillary has certain ovicidal action, and in conjunction with the prediction work of insect, suggestion is incubated peak at the product of insect, or ovum is incubated peak spraying and can be played good control efficiency.There is good local conductivity due to capillary in plant corpus, can conduct to another side from the one side infiltration of blade, therefore the back side of the blade that insect is taken food also can obtain same effect.Preventive effect 90-100% in 1-3 days after medicine, after medicine, 15 days drug effects still can be stabilized in 90%, recommend mu consumption 30-40 milliliter, safety interval 15-20 days.General antagonism insect is as diamond-back moth, 30 milliliters of conventional sprayings of every mu of use of nocturnal moth class, to advanced age tiger should increase consumption.
Cycloxaprid (Cycloxaprid), be called for short QS, is a kind of novel anabasine insecticide.Cycloxaprid is the antagonist of first nAChR in the world, very likely becomes the new class insecticide that has in the world material impact power, and its activity significantly is better than Imidacloprid.All efficient to Brown Planthopper, white-backed planthopper, small brown rice planthopper, cabbage aphid and cucumber aphid are also had to good preventive effect, rice leaf roller is had to the anti-effect of holding concurrently preferably, cotton field Bemisia tabaci activity is significantly higher than to Imidacloprid.Structural formula is:
Cycloxaprid is fully different from the capillary mechanism of action, there is no at present the people about cycloxaprid and the composite composition with insecticidal activity of capillary and application and reports.
Summary of the invention
The present invention seeks to for above-mentioned weak point, a kind of Pesticidal combination containing cycloxaprid and capillary is provided.
The present invention finds: not only can bring the additive property for insecticidal spectrum to improve cycloxaprid and the combination of capillary reactive compound, but also realize amazing synergy.
Term used herein " synergy " refers to that the combination of reactive compound of the present invention or the insecticidal effect of composition are greater than each activating agent effect sum, and in other words, its effect is superadditivity.
Based on above situation, the object of the present invention is to provide a kind of Pesticidal combination containing cycloxaprid and capillary.
A kind of Pesticidal combination of the present invention is achieved through the following technical solutions:
A kind of Pesticidal combination containing cycloxaprid and capillary, comprise cycloxaprid and capillary as active component.
A kind of Pesticidal combination containing cycloxaprid and capillary, wherein the weight ratio of cycloxaprid and capillary be or 50:1 to 1:50.
A kind of Pesticidal combination containing cycloxaprid and capillary, wherein the weight ratio of cycloxaprid and capillary is that 25:1 is to 1:25.
A kind of Pesticidal combination containing cycloxaprid and capillary, wherein the weight ratio of cycloxaprid and capillary be or 10:1 to 1:10.
A kind of Pesticidal combination containing cycloxaprid and capillary, wherein the weight ratio of cycloxaprid and capillary be or 5:1 to 1:5.
A kind of Pesticidal combination containing cycloxaprid and capillary, is characterized in that the weight of described cycloxaprid and capillary accounts for described composition 5%-90% by weight altogether.
A kind of Pesticidal combination containing cycloxaprid and capillary, is characterized in that described cycloxaprid and capillary account for described composition 10%-80% by weight altogether.
A kind of Pesticidal combination containing cycloxaprid and capillary, is characterized in that described cycloxaprid and capillary account for described composition 20%-60% by weight altogether.
Described a kind of Pesticidal combination, also comprises surfactant and/or extender containing cycloxaprid and capillary.
Described a kind of Pesticidal combination containing cycloxaprid and capillary, formulation is missible oil, suspending agent, seed coat agent, water dispersible granules, wetting powder, suspension emulsion, extrudes granule, coated granule, aerosol, aqueous emulsion, microcapsule suspending agent, microemulsion, microcapsule suspension-suspending agent, microemulsion.
A kind of Pesticidal combination containing cycloxaprid and capillary, wherein said composition also comprises one or more other active components.
On the other hand, the present invention also provides the purposes of a kind of Pesticidal combination containing cycloxaprid and capillary for prevention or control pest.
On the other hand, the present invention also provides a kind of prevention or has controlled the method for pest, a kind of Pesticidal combination containing cycloxaprid and capillary is acted on to the propagating materials of target useful plant, target pest or its environment, target useful plant.Described plant propagation material is seedling, rhizome, garden seedling, cutting or seed.
A kind of cover crop in case the method for pest invasion and attack comprise crop contacted with the Pesticidal combination that contains cycloxaprid and capillary.
A kind of method of prevention or control pest, comprise separately, use successively or simultaneously cycloxaprid, capillary.
Another object of the present invention is to provide a kind of kit for prevention or Control pests, and it comprises cycloxaprid and capillary.
A kind of prevention or control the method for pest, is characterized in that, wherein cycloxaprid and capillary each naturally through the form of compositions formulated.
The described Pesticidal combination containing cycloxaprid and capillary is for the treatment of the purposes of seed.
A kind of cover crop in case the method for pest invasion and attack it is characterized in that, comprise crop contacted with the Pesticidal combination that contains cycloxaprid and capillary.
A kind of Pesticidal combination containing cycloxaprid and capillary of the present invention, take cycloxaprid and capillary as active ingredient, composition synergistic effect with insecticidal activity is obvious, have synergistic function, can reduce the dosage of two active ingredients, both mechanisms of action are fully different, pest because of with a kind of Pesticide Exposure wherein after poisoning, resistance to another kind of agricultural chemicals will descend, and more easily kill, thereby delay the generation of resistance.
Embodiment
The present invention seeks to as solving above-mentioned at least one problem or its at least one aspect, in particular for effectively controlling pest, through the large number of biological test screen, but the unexpected discovery cycloxaprid of the inventor and capillary combination are for effectively preventing or control pest.Surprisingly, the activity of the combination of reactive compound of the present invention control pest is much higher than independent active ingredient physical performance summation.This unexpected effect is real synergistic effect, and be not only active add and.
The invention provides a kind of cycloxaprid and capillary agricultural insecticide composition as active component that comprises.
The invention provides a kind of cycloxaprid and capillary agricultural insecticide composition as active component that comprises, wherein cycloxaprid and capillary weight ratio be 50:1 to 1:50, preferably 25:1 is to 1:25, more preferably or 10:1 to 1:10, more preferred 5:1 is to 1:5.
In the present composition, the total amount of active compound component can be selected according to material elements, to realize desired effect.Described factor for example, formulation, object to be administered, application process etc.Cycloxaprid and capillary altogether account for described composition by weight 5% to 90%, preferably 10% to 80%, more preferably 20% to 50%.
Composition of the present invention optionally comprises acceptable surfactant or extender on agronomy.Preferably, described auxiliary element is a kind of or mixture in dispersant, wetting agent, antifreeze, thickener, defoamer, disintegrant, binding agent, assistant carrier.
According to the present invention, term " filler " refers to can be combined with reactive compound or for example combine, so that it is easier to be administered to the natural or synthetic organic or inorganic compound of object (plant, crop or careless class).Therefore, described carrier is preferably inertia, at least should be agronomically acceptablely.Described filler can be solid or liquid.
In the present invention, operable inactive filler can be both that solid can be also liquid, can be used as for example having that the solid-filling agent used: the phyteral powdery type (particle of soybean meal, starch, grain dust, wood powder, bark powder, sawdust, walnut shell powder, wheat bran, cellulose powder, coconut husk, corncob and tobacco stem for example, extract residue after plant essence etc.), paper, sawdust, pulverize synthesized polymer body, clay class (such as kaolin, bentonite, acid china clay etc.), the talcum powder class of synthetic resin etc.Silica (for example diatomite, silica sand, mica, moisture silicic acid, calcium silicates), chemical fertilizer, the clay fertilizer of active carbon, natural mineral matter class (float stone, attapulgite and zeolite etc.), the inorganic mineral powder of firing diatomite, sand, plastics medium etc. (such as polyethylene, polypropylene, polyvinylidene chloride etc.), potassium chloride, calcium carbonate, calcium phosphate etc., ammonium sulfate, ammonium phosphate, urea, ammonium chloride etc., these materials can be used separately or two or more is mixed.
Can be used as can selecting of liquid filling agent use in following material, water for example, alcohol type (methyl alcohol for example, ethanol, isopropyl alcohol, butanols, ethylene glycol etc.), ketone (acetone for example, methyl ethyl ketone, isobutyrone, cyclohexanone etc.), ethers (ether for example, dioxanes, methylcellulose, oxolane etc.), aliphatic hydrocarbon class (kerosene for example, the mineral wet goods), aromatic hydrocarbons class (benzene for example, toluene, dimethylbenzene, solvent naphtha, Fluhyzon, chlorinated aromatic hydrocarbons, chlorinated aliphatic hydrocarbon, chlorobenzene, Deng), the halogenated hydrocarbon class, amide-type, the sulfone class, dimethyl sulfoxide (DMSO), mineral and vegetable oil, the animal wet goods.
For making the emulsification of active ingredient compound, disperse, solubilization, and/or wetting can use surfactant for example can enumerate fatty alcohol-polyoxyethylene ether, polyoxyethylene alkylaryl ether, the polyoxyethylene high-grade aliphatic ester, the phosphate of polyoxyethylene alcohol or phenol, the fatty acid ester of polyalcohol, the naphthalene sulfonic acids polymer, lignosulfonates, a shape copolymer of macromolecule comb shape, butyl naphthalene sulfonate, alkylaryl sulfonates, the alkyl sodium sulfosuccinate, grease, fatty alcohol and ethylene oxide condensate, the polyacrylate of alkyltaurate, protein hydrolysate.Suitable oligosaccharide thing or polymer, for example combination of the vinyl monomer based on independent, acrylic acid, polyoxyethylene and/or polyoxypropylene or itself and for example (polynary) alcohol or (polynary) amine.
For making the dispersion of active ingredient compound, stabilisation, adhering to, can use such as adjuvants such as xanthans, aluminium-magnesium silicate, gelatin, starch, methyl cellulose, polyvinyl alcohol, polyvinyl acetate and natural phospholipid (as cephalin and lecithin) and synthetic phospholipid, bentonite, sodium lignin sulfonates.
The optional spent glycol of antifreezing agent wherein, propane diols, glycerine, sorbierite.Deflocculant as the suspension product can be used the adjuvant such as naphthalene sulfonic acids polymer, polymeric phosphate etc.Can use silicone defoaming agent as defoamer.For the mobility of improvement solid product, can use adjuvants such as paraffin, stearate, alkylphosphonate.
Operable colouring agent, inorganic pigment for example, as iron oxide, titanium oxide and Prussian blue; And organic pigment/dyestuff: alizarin dyes, azo dyes and metal phthalocyanine dyestuff; And trace element, for example molysite, manganese salt, boron salt, mantoquita, cobalt salt, molybdenum salt and zinc salt.
Optionally, also can comprise other annexing ingredient, for example protecting colloid, adhesive, thickener, thixotropic agent, bleeding agent, stabilizing agent, screening agent.
The formulation of described a kind of composition pesticide containing cycloxaprid and capillary is: missible oil, aerosol, suspending agent, the micro-capsule granula, granula subtilis, concentrate can flow, the ready to use solution agent, aqueous emulsion, oil emu, fine granule, the oil dispersion powder, the miscible mobility concentrate of oil, the miscible liquid of oil, foaming agent, paste, suspending concentrate, suspension emulsion, solubility concentrates thing, soluble powder, granule, water dispersible granules, water-soluble granular and/or tablet, water solube powder, wetting powder, natural or synthetic material through the reactive compound dipping, microcapsules in polymeric material and water-dispersible granule.
In preferred embodiments, described agricultural insecticide composition is missible oil, suspending agent, seed coat agent, water dispersible granules, wetting powder, suspension emulsion, extrudes granule, coated granule, aerosol, aqueous emulsion, microcapsule suspending agent, microemulsion, microcapsule suspension-suspending agent, microemulsion.
Described preparation of the present invention can mix described reactive compound to prepare with conventional additives by known way.Described conventional additives is as conventional extender and solvent or thinner, emulsifier, dispersant and/or adhesive or fixative, wetting agent, waterproofing agent, if necessary, can also comprise drier and colouring agent, stabilizing agent, pigment, defoamer, preservative, thickener, water and other processing aid.
These compositions not only comprise and can be applicable to immediately pending object as spraying or dusting equipment by suitable equipment, but also be included in to be applied to before object, need the concentrated business composition diluted.
Composition of the present invention can be made the preparation that is suitable for using with the form of the composition of its active compound component, also can use with the form of the combination of the commodity preparation of its suitable dosage.
Composition of the present invention can also be co-administered with other active component, such as fungicide, bactericide, attractant, insecticide, miticide, nematocide, growth regulator, weed killer herbicide, safener, fertilizer or semiochemical etc. of described other active component.
On the other hand, the present invention also provides the purposes of a kind of agricultural insecticide composition containing cycloxaprid and capillary for prevention or control animal pest, and animal pest is insect, acarid and nematode.Show the tolerance good to plant simultaneously, to the hypotoxicity of homoiothermy species and good Environmental compatibility.With kind resistance, activity is arranged to normal sensitivity, there is to activity all or special developmental stage.Above-mentioned animal pest comprises:
From Isopoda, damp worm (Oniscus aselluse) for example, pillworm (Armadillidium vulgare), and spot pillworm (Porcellio scaber).
From Diplopoda, Blaniuus guttulatus for example.
From chilopoda, for example centipede (Geophilus carpophagus) and common house centipede dragonfly (Scutigera spp.).
From Symphyla, clean symphilid (Scutigerella immaculate) for example.
From Thysanoptera, silverfiss (Lepisma saccharina) for example.
From Collembola, Onychiurus arcticus (Onychiurus armatus) for example.
From orthoptera, house cricket found in a kitchen (Acheta domesticus) for example, Gryllotalpa spp (Gryllotalpa spp.), torrid zone migratory locusts (Locusta migratoria migratorioides), the negative locust of long volume belongs to (Melanoplus spp.), and desert locust (Schistocerca gregaria).
From Blattaria, oriental cockroach (Blatta orientalis) for example, American cockroach (Periplaneta Americana), leucophaea maderae (Leucophaea maderae), Groton bug (Blattella germanica).
From Dermaptera, European earwig (Forficula auricularia) for example.
From Isoptera, Reticulitermes for example.
From Anoplura, body louse (Pediculus humanus corporis) for example, blind lice belongs to, and long volume lice genus, Trichodectes, Damalinia.
From thrips, greenhouse Hercinothrips spp (Hercinothrips femoralis) for example, cotton thrips (Thrips tabaci), Thrips palmi and Frankliniella accidentalis.
From Heteroptera, for example Eurygasterspp belongs to, middle red cotton bug (Dysdercus intermedius), and beet is intended lace bug (Piesma quadrata), the smelly stinkbug in temperate zone (Cimex lectularius), red abdomen is hunted stinkbug (Rhodnius prolixus) and Triatoma.
From Homoptera, wild cabbage aleyrodid (Aleurodes brassicae) for example, Bemisia tabaci (Bemisia tabaci), Trialeurodes vaporariorum Westwood (Trialeurodes vaporariorum), cotten aphid (Aphis gossypii), cabbage aphid (Brevicoryne brassicae), the hidden knurl volume of tea deer aphid (Cryptomyzus ribis), black bean aphid (Brevicoryne brassicae), apple aphid (Aphispomi), apple aphid (Eriosoma lanigerum), mealy plum aphid (Hyalopterus arundinis), grape phylloxera (Phylloxera vastatrix), , Pemphigus, English grain aphid (Macrosiphum avenae), knurl volume Aphis, hops knurl volume aphid (Phorodon humuli), grain Rhopalosiphum spp (Rhopalosiphum padi), leafhopper belongs to, Euscelisbilobatus, rice leafhopper (Nephotettix cincticeps), brown apricot scale (Lecaniumcorni), olive helmet (Saissetia oleae), rice small brown rice planthopper (Laodelphaxstriatellus), brown back rice plant hopper (Nilaparvata lugens), California red scale (Aonidiel1a aurantii), sweet-scented oleander circle a red-spotted lizard (Aspidiotus hederae), mealybug belongs to and Psylla spp.
From Lepidoptera, pink bollworm (Pectinophora gossypiella) for example, loose looper (Bupalus piniarius), winter geometrid moth (Chemimatobia brumata), Lithoclletis blancardela, cherry ermine moth (Hyponomeuta padella), diamond-back moth (Plutella xylostel1a), tent caterpillar (Malacosoma neustria), pornography and drug moth (Euproctis chrysorrhoea), Euproctis, cotton shot hole of leaf lyonetid (Bucculatrix thurberiella), tangerine leaf miner (Phyllocnis tiscitrella), Agrotis, root eating insect belongs to, brown Noctua, earias insulana (Eariasinsulana), Noctua, tomato moth (Mamestra brassicae), small noctuid (Panolis flammea), Noctua, cabbage looper (Trichoplusiani), codling moth (Carpocapsa pomonella), Pier, snout moth's larva belongs to Pyrausta nubilalis, Anagasta kuehniella (Ephestia kuehniella), rheum officinale snout moth's larva (Galleriamellonel1a), bag casemaking clothes moth (Tineola bisselliella), etting moth (Tineapell ionel1a), brown oecophorid (Hofmannophila pseudospretella), yellow tail leaf roller (Cacoecia podana), Capua reticulana, choristoneura fumigerana (Choristoneura fumiferana), grape codling moth (Clysia ambiguella) (Clysia ambiguel1a), tea yellow leaf curl moth (Homona magnanima), the green leaf roller of oak (Tortrix viridana), the volume snout moth's larva belongs to, Oulema oryzae (Oulema oryzae).
From coleoptera, furniture death watch beetle (Anobium punctatum) for example, lesser grain borer (Rhizopertha dominica), Bruchidius obtectus, common bean weevil (Acanthoscelides obtectus), house longhorn beetle (Hylotrupes bajulus), the purple flea beetle (Agelastica alni) of alder, colorado potato beetle (Leptinotarsadecemlineata), horseradish ape chrysomelid (Phaedon cochleariae), chrysomelid genus, the blue flea beetle (Psylliodes chrysocephala) of rape, mexican bean ladybird (Epi1achna varivestis), hidden wing first belongs to, saw chest ostomatid (Oryzaephilus surinamensis), weevil belongs to, Sitophilus, the vine black ear resembles (Otiorrhynchus sulcatus), banana spider base weevil (Cosmopolites sordidus), wild cabbage English weevil (Ceuthorrhynchusassimilis), alfalfa weevil (Hypera postica), khapra beetle belongs to, the spot khapra beetle belongs to, Anthrenus, hair is moth-eaten to be belonged to, powder is moth-eaten to be belonged to, pollen beetle (Meligethes aeneus), Ptinus, golden yellow ptinid (Niptus hololeucus), wheat ptinid (Gibbiumpsylloides), Tribolium, bloom first (Tenebrio molitor), click beetle belongs to, the acupuncture needle Eimeria, angle cockchafer (Melolontha melolontha), chafer in June (Amphimallon solstitialis), brown New Zealand's rib wing angle cockchafer (Costelytrazealandica) and rice water resemble (Lissorhoptrus oryzophilus).
From Hymenoptera, for example Neodiprion spp belongs to, tenthredinidae, and the field ant belongs to, MonomoriumMayr (Monomorium pharaonis) and Vespa.
From diptera, Aedes for example, the spot Anopheles, Culex, drosophila yellow gorilla (Drosophila melanogaster), Musca, the male servant fly belongs to, calliphora erythrocephala (Calliphoraerythrocephala), lucilia sericata belongs to, Carysomyia, cuterbrid belongs to, Gasterophilus, Hippobosca, the chela fly belongs to, the nose fly belongs to, Hypoderma, Pituophis, Tannia belongs to, Bibio hortulanus, Sweden's wheat stem chloropid fly (Oscinella frit), the wheat fly belongs to, spinach leaf miner (Pegomyiahyoscyami), Mediterranean fruitfly (Ceratitis capitata), dacus oleae (Dacusoleae) and European daddy-longlegs (Tipula paludosa), Hylemyia, and Hippelates.
From Siphonaptera, for example Xenopsyllacheopis (Xenopsylla cheopis) and angle leaf lice mouse.
From arachnids, scorpion (Scorpio maurus) for example, black widow (Latrodectus mactans), Acarus siro (Acarus siro), Dermanyssus gallinae (Dermanyssys gallinae), tea deer goitre mite (Eriophyesribis), citrus rust mite (Phyllocoptruta oleivora), Boophilus, carrapato belongs to, Amblyomma, glass eye tick belongs to, and hard tick belongs to, Acarus tritici belongs to, the ginger mite belongs to, and itch mite belongs to, the line genus of wriggling, Bryobia praetiosa (Bryobia praetiosa), two spotted spider mite belongs to, red autumnal leaves are wriggled genus, sharp tenthredinidae, short whisker Acarapis.
The parasitic plant nematode comprises that for example Pratylenchidae belongs to, similar similes thorne (Radopholus similis), fuller's teasel stem eelworm (Ditylenchus dipsaci), the nematode of partly puncturing (Tylenchulus semipenetrans), Heterodera, the ball Heterodera, Meloidogyne, Aphelenchoides, the minute hand Turbatrix, Xiphinema, and burr Turbatrix, remote spring dragonfly genus.
A kind of Pesticidal combination containing cycloxaprid and capillary of the present invention is specially adapted to control " biting " insect, and these insects specifically comprise following insect:
From Lepidoptera, pink bollworm (Pectinophora gossypiella) for example, loose looper (Bupalus piniarius), winter geometrid moth (Cheimatobia brumata), Lithocolletis blancardel1a, cherry ermine moth (Hyponomeuta padella), diamond-back moth (Plutella xylostella), tent caterpillar (Malacosoma neustria), pornography and drug moth (Euproctis chrysorrhoea), Euproctis, cotton shot hole of leaf lyonetid (Bucculatrix thurberlella), tangerine leaf miner (Phyllocnistiscitrella), Agrotis, root eating insect belongs to, brown Noctua, Egyptian complete just bored (Eariasinsulana), Noctua, tomato moth (Mamestra brassicae), small noctuid (Panolisflammea), Noctua, powder pattern moth (Trichoplusiani), codling moth (Carpocapsa pomonella), Pier, snout moth's larva belongs to, Pyrausta nubilalis, Anagasta kuehniella (Ephestia kuehniella), rheum officinale snout moth's larva (Gal1eriamellonella), bag casemaking clothes moth (Tineola bisselliella), etting moth (Tineapellionella), brown oecophorid (Hofmannophila pseudospretella), yellow tail leaf roller (Cacoecia podana), Capua reticulana, choristoneura fumigerana (Choristoneura fumiferana), grape is stayed moth-eaten moth (Clysia ambiguella), tea yellow leaf curl moth (Homona magnanima), the green leaf roller of oak (Tortrix viridana), the volume snout moth's larva belongs to, Oulema oryzae (Oulema oryzae).
From coleoptera, furniture death watch beetle (Anobium punctatum) for example, lesser grain borer (Rhizopertha dominica), Bruchidius obtectus, common bean weevil (Acanthoscelides obtectus), house longhorn beetle (Hylotrupes bajulus), the purple flea beetle (Agelastica alni) of alder, colorado potato beetle (Leptinotarsa decemlineata), horseradish ape chrysomelid (Phaedon cochleariae), chrysomelid genus, the blue flea beetle (Psylliodes chrysocephala) of rape, mexican bean ladybird (Epilachnavarivestis), hidden wing first belongs to, saw chest ostomatid (Oryzaephilus surinamensis), weevil belongs to, Sitophilus, during vine black ear beak (Otiorrhynchus sulcatus), banana spider base weevil (Cosmopolites sordidus), wild cabbage English weevil (Ceuthorrhynchus assimilis), alfalfa weevil (Hypera postica), khapra beetle belongs to, the spot khapra beetle belongs to, Anthrenus, hair is moth-eaten to be belonged to, powder is moth-eaten to be belonged to, pollen beetle (Meligethes aeneus), Ptinus, golden yellow ptinid (Niptus hololeucus), wheat ptinid (Gibbium psylloides), Tribolium, bloom first (Tenebrio molitor), click beetle belongs to, the acupuncture needle Eimeria, angle cockchafer (Melolontha melolontha), chafer in June (Amphimallon solstitialis), brown New Zealand's rib wing angle cockchafer (Costelytra zealandica) and rice water resemble (Lissorhoptrus oryzophilus).
A kind of Pesticidal combination containing cycloxaprid and capillary of the present invention also is applicable to control " sucking " insect, and these insects specifically comprise following insect:
From Homoptera, wild cabbage aleyrodid (Aleurodes brassicae) for example, Bemisia tabaci (Bemisia tabaci), Trialeurodes vaporariorum Westwood (Trialeurodes vaporariorum), cotten aphid (Aphis gossypii), cabbage aphid (Brevicoryne brassicae), the hidden knurl volume of tea deer aphid (Cryptomyzus ribis), black bean aphid (Aphis fabae), apple aphid (Aphispomi), apple aphid (Eriosoma lanigerum), mealy plum aphid (Hyalopterusarundinis), grape phylloxera (Phylloxera vastatrix), the goitre cotten aphid belongs to, English grain aphid (Macrosiphum avenae), knurl volume Aphis, hops knurl volume aphid (Phorodonhumuli), grain Rhopalosiphum spp (Rhopalosiphum padi), leafhopper belongs to, Euscelisbilobatus, rice leafhopper (Nephotettix cincticeps), brown apricot scale (Lecaniumcorni), olive helmet (Saissetia oleae), rice small brown rice planthopper (Laodel phaxstriatellus), brown back rice plant hopper (Nilaparvata lugens), California red scale (Aonidiella aurantii), sweet-scented oleander circle a red-spotted lizard (Aspidiotus hederae), mealybug belongs to and Psylla spp.
On the other hand, the present invention also provides a kind of prevention or has controlled the method for animal pest, a kind of agricultural insecticide composition containing cycloxaprid and capillary is acted on to the propagating materials of target useful plant, target animal insect or its environment, target useful plant.Described plant propagation material is seedling, rhizome, garden seedling, cutting or seed.
Described common processing method as by pouring (dipping), drip irrigation, spraying, evaporation, atomization, broadcast sowing, the modes such as dusting, foaming, coating; Perhaps as solvable pulvis, liquid agent, slurry for seed or rice shoot processing; And by dry treatment, slurry processing, liquid handling.Also can use described compound by the ultra low volume method, or described compound or composition itself are injected to soil.
Method of the present invention also provides with separately, successively or the described reactive compound of simultaneous system combined administration.
It is common with favourable that Pesticidal combination of the present invention is used with following dosage usually:
-for leaf section, process: 0.1-10000 g/ha, preferably 10-1000g/ha, more preferably 50-300g/ha; For dipping or, for instiling and using, described dosage even also can reduce, particularly when using inert base as asbestos or perlite;
-for seed treatment: 2-200 g/100kg seed, preferably 3-150g/100kg seed;
-for soil treatment: 0.1-10000g/ha, preferred 1-5000g/ha.
Above-mentioned dosage is only general exemplary dose, and during actual using, those skilled in the art can, according to actual conditions and needs, especially adjust rate of application according to character and the insect pest situation of pending plant or crop.
Pesticidal combination of the present invention has good plant compatibility, is suitable for Control pests, particularly insect, acarid, nematode, and fungi, rodent, microorganism etc., and it is preferably used for the composition that leaf processing, soil treatment and seed, rice shoot are processed.
According to the present invention, can process the each several part of all plant and plant.Plant this be interpreted as meaning all plants and plant population as desired with undesirable wild plant or crop (crop that comprises spontaneous growth).Crop can be the plant obtained by conventional breeding and optimum seeking method; the plant that perhaps combination by biotechnology and genetic engineering method or these methods obtains, comprise genetically modified plants and comprise the plant cultivation kind that can or can not be protected by plant breeder's certificate.The plant each several part is interpreted as meaning that all grounds and under ground portion and plant organ are as seedling, leaf, Hua Hegen, and the example that can mention is leaf, pin, stem, dry, flower, fruit body, fruit and seed and root, stem tuber and rhizome.The part of plant also comprises plant and vegetative propagation and the sexual propagation material after results, for example seedling, stem tuber, rhizome, transplant and seed.
As mentioned above, can process all plants and part thereof according to the present invention.In preferred embodiments, those plant varieties and the part thereof having processed wild plant kind and plant cultivation kind or obtained as hybridization or protoplast fusion by conventional Biology Breeding method.In a more preferred embodiment, processed by genetic engineering (genetically modified plants and plant cultivation kind and the part thereof that obtain in conjunction with conventional method (Genetically Modified Organisms) in case of necessity.
According to the present invention, particularly preferably be processing in all cases available on market or use in the plant of plant cultivation kind.
According to plant variety or plant cultivation kind, its position and growth conditions (soil, weather, vegetative period, food), also can produce to surpass to add with (" according to processing of the present invention and work in coordination with ") effect.So, for example reduce consumption and/or widen activity profile and/or increase activity according to the spendable material of the present invention and composition, better plant growth, strengthen tolerance to high temperature or low temperature, strengthen to dry early, the tolerance of water or soil salt content, increase the performance of blooming, be easier to results, hasting of maturity, higher harvest yield, better quality and/or results product higher nutritive value, better the machinability of storage stability and/or results product all becomes possibility, this has exceeded the effect of actual desired.
Pesticidal combination of the present invention also is applicable to prevent and treat the animal pest of enclosure space, particularly insect, spider and acarid, and described enclosure space is as house, factory floor, office, cabin etc.They can be used for preventing and treating these insects in family expenses desinsection product, and they have activity to sensitivity and kind resistance with to all developmental stage.These insects comprise:
Scorpionida, for example clamp scorpion (Buthus occitanus).
Acarina, for example adobe tick, stick up edge sharp-edged tick, Bryobia, Dermanyssus gallinae, the sweet mite of family's food, tampan tick, brown dog tick, trombiculid (Trombicula alfreddugesi), Neutrombicula autumnalis, dermatophagoides pteronyssinus, dust mite.
Araneida, for example cockle spider section, justify spider section.
Opiliones, for example intend scorpion class (Pseudoscorpiones chelifer), Pseudoscorpiones cheiridium, Opiliones phalangium.
Isopoda, damp worm for example, pillworm.
Sufficient order doubly, for example have a zebra land, mountain cricket Eimeria.
Lip foot order, for example Scolopendra.
Zygentoma order, for example comb silverfish genus, Taiwan silverfish, Lepismodes inquilinus.
Blattaria, for example oriental cockroach, Groton bug, Blatella (Bl a t t el1a asahinai), leucophaea maderae, angle abdomen Lian genus, wooden Lian genus, Australian cockroach, American cockroach, the large Lian of foxiness, Peroplaneta fluligginosa, long palpus blattaria.
Saltatoria, for example Shuai of family.
Dermaptera, for example European earwig.
Isoptera, for example kalotermitid belongs to, Reticulitermes.
The worm order, for example Lepinatus belongs to, powder is breathed heavily Eimeria.
Coleoptera, Anthrenus for example, fur is moth-eaten to be belonged to, and khapra beetle belongs to, a long lesser grain borer, hidden instep cuckoo Eimeria, Ptinus, lesser grain borer, grain weevil, rice weevil, corn weevil, Stegobium paniceum.
Diptera, Aedes aegypti for example, aedes albopictus, Aedes taeniorhynchus, Anopheles, calliphora erythrocephala, the great number sarcophagid, Culex quinquefasciatus, northern house, Culex tarsalis, slow-witted fly belongs to, Fannia canicularis, housefly, Bai Ling belongs to, sarcophagid (Sarcophaga carnaria), Simulium, male servant chela fly, daddy-longlegs (Tipula paludosa).
Lepidoptera, lesser wax-moth for example, galleria mellonella waxmoth, the ancient phycitid of India, rain moth, bag rain moth, curtain rain moth.
Siphonaptera, the first lice of dog comb for example, Ctenocephalides felis felis, humanlice, chigo, Xanthopsyllacheopis.
Hymenoptera, for example blazon hunchbacked ant, bright hair ant, and the black wool ant, Lasius umbratus, MonomoriumMayr, Paravespula belongs to, Pavement Ant.
Anoplura, head louse for example, body louse, crab louse.
Heteroptera, cimex hemipterus for example, bed bug, phodnius prolixus, invade and harass vertebra and hunt stinkbug.
Pesticidal combination of the present invention can be used as aerosol, the with no pressure spray product for example pump spraying and atomizer spray, automatically mist formation system, fogger, foam, gel, evaporator product, liquid evaporator, gel and film evaporator with evaporating plate that cellulose or polymer make, evaporator that screw drives, do not consume energy or the passive type vapo(u)rization system, catch moth paper, catch moth bag and insect-catching glue, as drawing agent or pulvis, for bait formulation or the bait formulation position of spraying use.
Any technical characterictic that it should be pointed out that any embodiment of the present invention or embodiment can be independently and any other embodiment combination with one another of the present invention.That is to say, one or more technical characterictics of any embodiment of the present invention all can reconfigure with any other technical characterictic.Technical characterictic reconfigures and the technical characterictic that forms is disclosed in herein thus, and it is documented in the same especially herein.
It is obvious that the composition synergistic effect with insecticidal activity that cycloxaprid and capillary be active ingredient is take in the present invention, can reduce the dosage of two compositions, both mechanisms of action are fully different, pest because of with a kind of Pesticide Exposure wherein after poisoning, resistance to another kind of agricultural chemicals will descend, more easily kill, thereby delayed the generation of resistance.
Example of formulations
Embodiment 1:50% cycloxaprid+1% capillary suspending agent
Cycloxaprid 50%
Capillary 1%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Ratio by each components such as active component, dispersant, wetting agent and water according to formula mixes, and after grinding and/or high speed shear, obtains 50% cycloxaprid+1% capillary suspending agent.
Embodiment 2 25% cycloxaprids+1% capillary wetting powder
Cycloxaprid 4%
Capillary 20%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Ratio composition by active component, various auxiliary agent and filler etc. in formula mixes, and after ultra-fine pulverizer disintegrating, obtains 25% cycloxaprid+1% capillary wetting powder.
Embodiment 3 20% cycloxaprids+2% capillary aqueous emulsion
Cycloxaprid 20%
Capillary 2%
1-METHYLPYRROLIDONE 15%
Calcium dodecyl benzene sulfonate 5%
Agriculture breast 600# 5%
Water complements to 100%
Former medicine, solvent, emulsifier are added together, make to be dissolved into even oil phase; Water-soluble component and water mixing are made to water; Under high-speed stirred, oil phase is mixed with water, make 20% cycloxaprid+2% capillary aqueous emulsion.
Embodiment 4 1.5% cycloxaprids+3.5% acarid nitrile water dispersion granula
Cycloxaprid 1.5%
Capillary 3.5%
Sodium lignin sulfonate 4%
Lauryl sodium sulfate 5%
Urea 5%
Kaolin complements to 100%
Ratio by active component, dispersant, wetting agent, disintegrant and filler in formula mixes, and through air-flow crushing, becomes wetting powder, then adds a certain amount of water mixing extruding to make material.Obtain 1.5% cycloxaprid+3.5% acarid nitrile water dispersion granula after the drying screening.
Embodiment 5 10% cycloxaprids+20% capillary suspending agent
Cycloxaprid 10%
Capillary 20%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Ratio by each components such as active component, dispersant, wetting agent and water according to formula mixes, and after grinding and/or high speed shear, obtains 10% cycloxaprid+20% capillary suspending agent.
Embodiment 6 2.5% cycloxaprids+7.5% capillary suspending agent
Cycloxaprid 2.5%
Capillary 7.5%
Methyl naphthalene sulfonate formaldehyde condensate 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Ratio by each components such as active component, dispersant, wetting agent and water according to formula mixes, and after grinding and/or high speed shear, obtains 2.5% cycloxaprid+7.5% capillary suspending agent.
Embodiment 7 1% cycloxaprids+10% capillary wetting powder
Cycloxaprid 1%
Capillary 10%
Lauryl sodium sulfate 10%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Said components is mixed in proportion, and grind, pulverize, be prepared into wetting powder.
Embodiment 8 1% cycloxaprids+50% capillary suspending agent
Cycloxaprid 1%
Capillary 50%
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Ratio by each components such as active component, dispersant, wetting agent and water according to formula mixes, and after grinding and/or high speed shear, obtains 1% cycloxaprid+50% capillary suspending agent.
Embodiment 9 15% cycloxaprids+5% capillary aqueous emulsion
Oil phase:
Cycloxaprid 15%
Capillary 5%
Methyl oleate 38%
Polystyrene 3.7%
Water:
Xanthans 0.07%
The sodium salt 1% of the naphthalene sulfonic acids-formaldehyde condensation products of sulfonation
Bactericide 0.2%
Water complements to 100%
Cycloxaprid and capillary are dissolved in methyl oleate, add polystyrene to obtain oil phase; Mix and obtain water according to the component in formula; Under agitation add water to obtain aqueous emulsion oil phase.
Embodiment 10 20% cycloxaprids+30% capillary wetting powder
Cycloxaprid 20%
Capillary 30%
Sodium lignin sulfonate 4%
NaLS 2%
The silicic acid 1% of high degree of dispersion
Kaolin complements to 100%
Said components is mixed in proportion, and grind, pulverize, be prepared into wetting powder.
Embodiment 11 1% cycloxaprids+25% capillary coated granule
Cycloxaprid 1%
Capillary 25%
Polyethylene glycol 3%
The silicic acid 1% of high degree of dispersion
Calcium carbonate complements to 100%
In blender, levigate active component evenly is applied on the carrier soaked by polyethylene glycol.Can obtain dustless coated granule in this way.
Embodiment 12 30% cycloxaprids+60% capillary wetting powder
Cycloxaprid 30%
Capillary 60%
Lauryl sodium sulfate 1%
Sodium lignin sulfonate 1%
White carbon 1%
Kaolin complements to 100%
Said components is mixed in proportion, and grind, pulverize, be prepared into wetting powder.
Embodiment 13 20% cycloxaprids+60% capillary is extruded granule
Cycloxaprid 20%
Capillary 60%
Sodium lignin sulfonate 4%
Carboxymethyl cellulose 2%
Kaolin complements to 100%
Active component is mixed with auxiliary agent and ground, the mixture water-wet.This mixture is extruded, then dry in air stream.
Embodiment 14 50% cycloxaprids+10% capillary suspending agent
Cycloxaprid 50%
Capillary 10%
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Ratio by each components such as active component, dispersant, wetting agent and water according to formula mixes, and after grinding and/or high speed shear, obtains 50% cycloxaprid+10% capillary suspending agent.
Embodiment 15 5% cycloxaprids+15% capillary ZC
Atlox 4913 4%
Citric acid 0.05%
Catalyzer 0.1%
Water 13%
Cycloxaprid 5%
PAPI 1.35%
Solvesso 200 10%
Atlox4913 16%
Dispersant LFH 0.3%
Defoamer 0.16%
Urea 8.4%
Capillary 15%
Water complements to 100%
By PAPI, the oil phase that capillary and Solvesso 100 form adds in the aqueous solution containing Atlox4913, forms emulsion.Then heat and be incubated 50
oadd catalyst reaction under C 2 hours.Obtain the microcapsules of capillary after cooling.
Atlox 4913, dispersant LFH, and defoamer, urea, cycloxaprid and water mix in proportion, and, through sand milling, are prepared into suspending agent.
The microcapsules of the capillary that obtains is added in the aqueous suspension agent of cycloxaprid, stir and obtain 5% cycloxaprid+15% capillary ZC.
Embodiment 16 10% cycloxaprids+50% capillary suspended emulsion
Cycloxaprid 10%
Capillary 50%
Solvesso 200 10%
Ethoxylated castor oil 4%
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Cycloxaprid is dissolved in Solvesso 200, adds ethoxylated castor oil, obtain the missible oil of cycloxaprid;
By capillary, fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium, above-mentioned each component mixes in proportion, and, through sand milling, is prepared into suspending agent.
To join in the suspending agent containing capillary containing the oil phase of cycloxaprid, obtain suspended emulsion.
Embodiment 17 10% cycloxaprids+10% capillary missible oil
Cycloxaprid 10%
Capillary 10%
Ethoxylated castor oil 5%
Calcium dodecyl benzene sulfonate 3%
Solvesso100 complements to 100%
Above-mentioned each component is mixed, be stirred to and obtain transparent homogeneous phase.
Embodiment 18 5% cycloxaprids+10% capillary suspension seed-coating agent
Cycloxaprid 5%
Capillary 10%
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
PVP-K30 1%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and, through sand milling, be prepared into suspension seed-coating agent.
The biological test example
When the effect of active compound combinations surpasses the summation of the effect when each reactive compound is used separately, there are collaborative desinsection and acaricidal action.The predictive role of the particular combination of two kinds of reactive compounds can be used so-called " Colby formula " (referring to S.R. Colby, " Calculating Synergistic and Antagonistic Responses of Herbicide Combinations ", Weeds 1967,15,20-22) following calculating: if
X is the kill ratio when using consumption for m g/ha or the concentration reactive compound A that is m ppm, is expressed as the percentage that accounts for untreated control,
Y is the kill ratio when using consumption for n g/ha or the concentration reactive compound B that is nppm, is expressed as the percentage that accounts for untreated control,
E is the kill ratio when using consumption for m and n g/ha or the concentration reactive compound A that is m and n ppm and B, is expressed as the percentage that accounts for untreated control,
So
If actual desinsection lethality rate surpasses calculated value, the lethal effect of composition be super add and, have synergy.In this case, the kill ratio that actual observation is arrived must surpass the value of the expection kill ratio value (E) of using above-mentioned formula to calculate.
The 1 rice fulgorid test of biological test example
Solvent: the dimethyl formamide of 7 weight portions
Emulsifier: the alkylaryl polyglycol ether of 2 weight portions
For preparing suitable active agent preparations, the reactive compound of 1 weight portion is mixed with solvent and the emulsifier of described amount, and described dope is diluted with water to desired concn.
The rice leaf that will seriously be infected by rice fulgorid (rice planthopper) is processed by the reactive compound that immerses desired concn.
After required time, determine the lethality in %.100% means that whole rice fulgorids are killed; 0% means do not have rice fulgorid to be killed.By definite lethality substitution Colby formula.
In this test, for example, the application's following active compound combinations is compared with the reactive compound of using separately, shows the collaborative activity improved:
The rice fulgorid test
The 2 tea lesser leafhopper tests of biological test example
Solvent: the dimethyl formamide of 7 weight portions
Emulsifier: the alkylaryl polyglycol ether of 2 weight portions
For preparing suitable active agent preparations, the reactive compound of 1 weight portion is mixed with solvent and the emulsifier of described amount, and described dope is diluted with water to desired concn.
The blade pass that will seriously be infected by smaller green leaf hopper is crossed the active agent preparations that immerses desired concn and is processed.
After required time, determine the lethality in %.100% means that whole smaller green leaf hoppers kill; 0% means do not have smaller green leaf hopper to be killed.By definite lethality substitution Colby formula.
In this test, for example, the application's following active agent combinations is compared with the reactive compound of using separately, shows the collaborative activity improved:
The smaller green leaf hopper test
Biological test 3 beet armyworm tests
Solvent: the dimethyl formamide of 7 weight portions
Emulsifier: the alkylaryl polyglycol ether of 2 weight portions
For preparing suitable active agent preparations, the reactive compound of 1 weight portion is mixed with solvent and the emulsifier of described amount, and described dope is diluted with water to desired concn.
Cabbage leaves is processed by the active agent preparations of spraying desired concn, and the garden beet noctuid is inoculated when blade is still moist.
After required time, determine the lethality in %.100% means that whole beet armyworms are killed; 0% means do not have beet armyworm to be killed.Definite lethality substitution Colby formula is calculated.
In this test, for example, the application's following active agent combinations is compared with the reactive compound of using separately, shows the collaborative activity improved:
The 4 cotten aphid tests of biological test example
Solvent: the dimethyl formamide of 7 weight portions
Emulsifier: the alkylaryl polyglycol ether of 2 weight portions
For preparing suitable active agent preparations, the reactive compound of 1 weight portion is mixed with solvent and the emulsifier of described amount, and described dope is diluted with water to desired concn.
By the described active agent preparations that sprays desired concn, cotton leaf is processed, and with cotten aphid, cotton leaf is inoculated when blade is still wetting.
Through after required time, determine the Death Level meaned with %.100% refer to that all cotten aphids all are killed herein; 0% refers to do not have cotten aphid to be killed.The lethality substitution Colby formula recorded is calculated.
The 5 panonychus citri tests of biological test example
Solvent: the dimethyl formamide of 7 weight portions
Emulsifier: the alkylaryl polyglycol ether of 2 weight portions
For preparing suitable active agent preparations, the reactive compound of 1 weight portion is mixed with solvent and the emulsifier of described amount, and described dope is diluted with water to desired concn.
By the described active agent preparations that sprays desired concn, the oranges and tangerines leaf is processed, and with panonychus citri, the oranges and tangerines leaf is inoculated when blade is still wetting.
Through after required time, determine the Death Level meaned with %.100% refer to that all panonychus citris all are killed herein; 0% refers to do not have panonychus citri to be killed.The lethality substitution Colby formula recorded is calculated.
Can find out that in above-mentioned experimental data Insecticidal combinations that the present invention contains cycloxaprid and capillary obtained the effect of cooperative gain on insecticidal effect.
Claims (20)
1. the Pesticidal combination containing cycloxaprid and capillary, is characterized in that, comprises cycloxaprid and capillary as active component.
2. Pesticidal combination according to claim 1, is characterized in that, the weight ratio of described cycloxaprid and capillary be or 50:1 to 1:50.
3. Pesticidal combination according to claim 1, is characterized in that, the weight ratio of described cycloxaprid and capillary be or 25:1 to 1:25.
4. Pesticidal combination according to claim 1, is characterized in that, the weight ratio of described cycloxaprid and capillary be or 10:1 to 1:10.
5. Pesticidal combination according to claim 1, is characterized in that, the weight ratio of described cycloxaprid and capillary be or 5:1 to 1:5.
6. Pesticidal combination according to claim 1, is characterized in that, the weight of described cycloxaprid and capillary accounts for described composition 5%-90% by weight altogether.
7. Pesticidal combination according to claim 1, is characterized in that, described cycloxaprid and capillary account for described composition 10%-80% by weight altogether.
8. Pesticidal combination according to claim 1, is characterized in that, described cycloxaprid and capillary account for described composition 20%-60% by weight altogether.
9. Pesticidal combination according to claim 1, is characterized in that, also comprises surfactant and/or extender.
10. Pesticidal combination according to claim 1, it is characterized in that, formulation is missible oil, suspending agent, seed coat agent, water dispersible granules, wetting powder, suspension emulsion, extrudes granule, coated granule, aerosol, aqueous emulsion, microcapsule suspending agent, microemulsion, microcapsule suspension-suspending agent, microemulsion.
11. Pesticidal combination according to claim 1, is characterized in that, also comprises one or more other active components.
12. Pesticidal combination claimed in claim 1 is for the purposes of prevention or control pest.
13. the method for preventing or controlling pest, is characterized in that, the propagating materials by the Pesticidal combination of claim 1 for target useful plant, target pest or its environment, target useful plant.
14. the method for a kind of prevention according to claim 13 or control pest is characterized in that described plant propagation material is seedling, rhizome, garden seedling, cutting or seed.
15. the method for a kind of prevention according to claim 13 or control pest is characterized in that described pest is selected from Insecta, arachnids and Nematoda.
16. the method for a kind of prevention according to claim 13 or control pest is characterized in that described pest is selected from Lepidoptera, homoptera pest.
17. the method for a kind of prevention according to claim 13 or control pest, is characterized in that, comprises separately, uses successively or simultaneously cycloxaprid and capillary.
18. a kind of prevention according to claim 13 or control the method for pest, is characterized in that, wherein cycloxaprid and capillary each naturally through the form of compositions formulated.
19. Pesticidal combination claimed in claim 1 is for the treatment of the purposes of seed.
20. a cover crop in case the method for pest invasion and attack it is characterized in that, comprise crop contacted with Pesticidal combination claimed in claim 1.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510628139.5A CN105123716B (en) | 2013-10-11 | 2013-10-11 | A kind of Pesticidal combination containing cycloxaprid and capillary |
| CN201310471584.6A CN103493830A (en) | 2013-10-11 | 2013-10-11 | Pesticide composition containing cycloxaprid and chlorfenapyr |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310471584.6A CN103493830A (en) | 2013-10-11 | 2013-10-11 | Pesticide composition containing cycloxaprid and chlorfenapyr |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510628139.5A Division CN105123716B (en) | 2013-10-11 | 2013-10-11 | A kind of Pesticidal combination containing cycloxaprid and capillary |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103493830A true CN103493830A (en) | 2014-01-08 |
Family
ID=49859171
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310471584.6A Pending CN103493830A (en) | 2013-10-11 | 2013-10-11 | Pesticide composition containing cycloxaprid and chlorfenapyr |
| CN201510628139.5A Active CN105123716B (en) | 2013-10-11 | 2013-10-11 | A kind of Pesticidal combination containing cycloxaprid and capillary |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510628139.5A Active CN105123716B (en) | 2013-10-11 | 2013-10-11 | A kind of Pesticidal combination containing cycloxaprid and capillary |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN103493830A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102405918A (en) * | 2011-12-25 | 2012-04-11 | 上海生农生化制品有限公司 | Cycloxaprid water dispersible tablets and preparation method thereof |
| CN103238609A (en) * | 2012-02-09 | 2013-08-14 | 陕西美邦农药有限公司 | Cycloxaprid-containing insecticidal composition |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004269479A (en) * | 2003-03-12 | 2004-09-30 | Otsuka Chemical Co Ltd | Acaricide composition |
| JP2005047847A (en) * | 2003-07-28 | 2005-02-24 | Otsuka Chemical Co Ltd | Acaricide |
| CN101401576B (en) * | 2008-11-18 | 2012-01-25 | 深圳诺普信农化股份有限公司 | Composition for killing acarid |
-
2013
- 2013-10-11 CN CN201310471584.6A patent/CN103493830A/en active Pending
- 2013-10-11 CN CN201510628139.5A patent/CN105123716B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102405918A (en) * | 2011-12-25 | 2012-04-11 | 上海生农生化制品有限公司 | Cycloxaprid water dispersible tablets and preparation method thereof |
| CN103238609A (en) * | 2012-02-09 | 2013-08-14 | 陕西美邦农药有限公司 | Cycloxaprid-containing insecticidal composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105123716A (en) | 2015-12-09 |
| CN105123716B (en) | 2017-07-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104285988A (en) | Acaricide active agent combinations | |
| CN101489387A (en) | Active ingredient combinations with insecticidal and acaricidal properties | |
| CN102986719B (en) | Insecticide composition containing bifenthrin and pyriproxyfen and applications thereof | |
| CN103461333A (en) | Pesticide composition containing flubendiamide and methoxyfenozide | |
| CN105309465B (en) | A kind of Fungicidal insecticidal composition | |
| CN105794831B (en) | A kind of Pesticidal combination and application thereof | |
| CN103518733B (en) | A kind of Pesticidal combination containing ethyl pleocidin and bromine cyanogen insect amide | |
| CN105794813B (en) | A kind of Pesticidal combination and its method for controlling agricultural pests | |
| CN103461376B (en) | A kind of agricultural insecticide composition containing fipronil bisamide and pyridaphethione | |
| CN103535371B (en) | A kind of Pesticidal combination containing ethyl pleocidin and gamma cyhalothrin | |
| CN103535363B (en) | Pesticide insecticidal composition containing flubendiamide and teflubenzuron | |
| CN103503910B (en) | A kind of Pesticidal combination containing the pyridine of piperazine worm and fenpropathrin | |
| CN105265468B (en) | A kind of Fungicidal insecticidal composition | |
| CN107751202A (en) | A kind of Pesticidal combination | |
| CN103503908B (en) | Insecticidal composition containing Paichongding (1-((6-chloropyridine-3-group) methyl-5-propoxy-7-methyl-8-nitryl-1,2,3,5,6,7-hexahydroimidazo[1,2-a] pyridine) and efficient cyhalothrin | |
| CN103503909B (en) | A kind of Pesticidal combination containing the pyridine of piperazine worm and cypermethrin | |
| CN103503905B (en) | Insecticidal composition containing Paichongding (1-((6-chloropyridine-3-group) methyl-5-propoxy-7-methyl-8-nitryl-1,2,3,5,6,7-hexahydroimidazo[1,2-a] pyridine) and bifenthrin | |
| CN105123716B (en) | A kind of Pesticidal combination containing cycloxaprid and capillary | |
| CN103503907B (en) | Insecticidal composition containing 1-((6-chloropyridine-3-yl) methyl)-5-propoxy-7-methyl-8-nitryl-1,2,3,5,6,7-hexahydroimidazo[1,2-alpha] pyridine) and deltamethrin | |
| CN103461337B (en) | A kind of agricultural insecticide composition containing fipronil bisamide and thiocyclam | |
| CN105794787A (en) | Insecticidal composition and agricultural insect control method | |
| CN105309443B (en) | A kind of Fungicidal insecticidal composition | |
| CN105265469B (en) | A kind of Fungicidal insecticidal composition | |
| CN103478130A (en) | Insecticidal composition containing fipronil bisamide and bisultap | |
| CN107318882A (en) | A kind of Pesticidal combination |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140108 |