CN105123716A - Insecticidal composition containing cycloxaprid and chlorfenapyr - Google Patents

Abstract

The invention provides an insecticidal composition containing cycloxaprid and chlorfenapyr, relates to the technical field of agricultural insecticides, and in particular relates to a binary composite composition containing active components such as the cycloxaprid and the chlorfenapyr and having insecticidal activity and an application method of the composition. A method of preventing or controlling panonychus citri comprises a step that the insecticidal composition is applied to target useful plants, target pests or environment thereof, and propagative materials of the target useful plants; the insecticidal composition comprises the cycloxaprid and the chlorfenapyr as the active components, the weight ratio of the cycloxaprid and the chlorfenapyr is 5:1 to 1:5. The invention relates to the insecticidal composition containing the cycloxaprid and the chlorfenapyr and applied to plants or growth environment thereof and a method for preventing or controlling the pests by applying the insecticidal composition, wherein the composition with insecticidal activity has a synergies insecticidal effect. The method of preventing the plants comprises a step that the plants contact with the composition with the insecticidal activity.

Description

A kind of Pesticidal combination containing cycloxaprid and capillary

The application is application number is 201310471584.6, and the applying date is on October 11st, 2013, and denomination of invention is the divisional application of " a kind of Pesticidal combination containing cycloxaprid and capillary ".

Technical field

A kind of Pesticidal combination containing cycloxaprid and capillary of the present invention relates to agricultural insecticidal technical field, in particular a kind of compoistion and method of use with insecticidal activity comprising active component cycloxaprid and capillary binary built.

Background technology

Homoptera (Homoptera) comprises cicada, froghopper, leafhopper, horned frog, plant hopper, plant hopper, wood louse, aleyrodid, aphid and coccid, be a monoid larger in Insecta, metamorphosis is comparatively large, mouthpart pierce-suck type, fore wing quality identical (corresponding with Semiptera), therefore claim Homoptera.Homoptera insect is all food with water, and wherein numerous species can propagate the viroses of plant, is important pest.Some kind can secrete wax, glue, or forms insect gall, and producing gall nut, is important industrial resources insect.The song of cicada is melodized, and the form of plant hopper, horned frog is special, is people's enjoyable insects loved by all.

Known Homoptera has kind more than 45000 in the world, is distributed widely in all over the world.China there will be a known kind more than 3000.Its feature can be summarized as: fore wing homogeneity, and beak is nearby sufficient under lifting one's head, leafhopper plant hopper aphid and a red-spotted lizard, the agricultural of normal evil and fruits and vegetables.

Homoptera comprises Cicadomorpha, Psyllomorpha, Aphidomorpha, Aleyrodomorpha and Coccinea 5 suborders.

Cicadomorpha, beak raw before clavicula; Feeler setiform; Fore wing has obvious calvus; Digitus 3 saves.Active kind jumping, ability of circling in the air is strong, and many male worms can pronounce.

Psyllomorpha, small-sized, active kind jumping.Feeler 10 saves, thread, end furcations, raw in the front of compound eye.Simple eye 3; Beak 3 saves, and bears between clavicula.Digitus 2 saves, and metapedes base pitch has verruca, tibia end spinosity.Nymph has wax gland more, can secrete wax protection, some formation insect galls, and some generation honeydews often have ant adjoint.Adult nymph thorn inhales the juice of plant, and be agriculture and forestry injurious insect, some also propagates the viroses of plant.This suborder only comprises 1 section, i.e. Psyllidae, domesticly common are Psylla Chinesis Yang Et, diaphorina citri etc.

Aphidomorpha, small-sized polymorphic insect, of the same race has aptery and alate.Feeler 3-6 saves, and has primary and secondary two kinds of different perceptrons.Digitus 2 saves, and Section 1 is very short.Belly often has cornical, and minor details backboard and web form cauda and tailgate respectively.If any wing, then fore wing is larger than hind wing, and fore wing has pterostigma.The mode of reproduction of aphid has bisexual reproduction and parthenogenesis, oviparity or ovoviviparity.Aphid thorn inhales water, causes development of plants bad, and excretion honeydew, causing mould to grow, and can propagate the viroses of plant, is one of most important agriculture and forestry injurious insect monoid.The insect gall gall nut of times aphid is important industry and medicinal raw material.The known kind more than 4000 in the world, is classified as 2 Superfamily 13 sections.

Aleyrodomorpha, feeler 7 saves, and Section 2 is expanded.Digitus 2 saves, and waits large.Both sexes all have wing, adularescent wax powder on wing.Nymph, the adult abdomen end back side have tubulus.Thorn inhales water, is the primary pest of cultivated plant in the woody plants such as oranges and tangerines and greenhouse, common are Aleurocanthus spiniferus, greenhouse whitefly etc.

Coccinea, is commonly referred to as coccid, Peculiar Forms, asyngamy.Male worm has 1 pair of film wing, and hind wing deteriorates to halter.Digitus 1 saves.Female worm is aptery, and digitus 1-2 saves, and 3 individual sections often heal, and cephalothorax boundary is unclear, and some bellies also merogenesis are unclear.Often there is the secretion of wax, colloid, or had special a red-spotted lizard shell protection.Multiparasitism, in woody plant or herbaceos perennial, is important gardening and forest pest.Some coccid secretion wax, glue, pigment, become important industrial resources and medicine resource insect.The known kind more than 5000 in the world, annual also have novel species to find.

Lepidoptera is second large order in Insecta, and comprise all butterflies and moth, the whole world about has 200,000 kinds, and there is kind more than 8000 in China.Wherein moth class 6000 kinds, butterfly class 2000 kinds.Lepidoptera pest kind is extremely many, and almost each crops is all subject to the harm of wherein one or more insects.Lepidoptera distribution is extremely wide, the abundantest with tropical kind.The larva of most kind is caused harm all kinds of cultivated plant, and bodily form the greater is often eaten most blade or bored moth limb.Bodily form smaller often leaf roll, sew leaf, knot sheath, weave silk and knot or pierce plant tissue and take food and cause harm.Adult is mainly with nutrition as a supplement such as nectar, or mouthpart degeneration no longer takes food, and does not generally cause direct harm.Lepidoptera is the order that agriculture and forestry injurious insect is maximum, the yield and quality of its serious harm agricultural product.As telson moth, the rice leaf roll snout moth's larva of paddy rice; The insect pests such as the chilo infuscatellus of the wild snout moth's larva of the beans of vegetables, pathogenicity test and sugarcane and bar snout moth's larva.

Chemical control is an important means of agriculturally prevention and corntrol insect.But current, due to kind, the living nature of insect etc., the reasons such as the weak effect that living environment etc. cause, repellence are flourishing can not effectively be prevented and kill off sometimes.Particularly for the pest of Lepidoptera, coleoptera, diptera, Homoptera, Semiptera, Hymenoptera, thrips, arachnids and Nematoda etc., utilize conventional dose to carry out prevention and control and just become increasingly difficult.Therefore, in order to can effectively prevent and kill off can not prevent and kill off or prevent and kill off difficulty pest and seek a kind of new means and method.

Capillary (Chlorfenapyr), have another name called eliminate, chlorfenapyr, capillary be succeeded in developing by American Cyanamid Company a kind of new type heterocycle class desinsection, kill mite, nematocide.Chemical name is bromo-2-(4-chlorphenyl)-1-ethoxyl methyl-5-trifluoromethyl pyrpole-3-nitrile, and its chemical formula is:

Capillary is new pyrrole compounds, acts on the mitochondria of insect bodies inner cell, is worked by the mixed-functional oxidase in insect bodies, mainly suppresses adenosine diphosphate (ADP) to the conversion of adenosine triphosphate (ATP).And adenosine triphosphate stored cells maintains the necessary energy of its vital functions.As a kind of preinsecticide, itself to insect without toxic action.Insect's food-taking or contact capillary after in insect bodies, capillary changes concrete insecticidal active compound under the effect of mixed-functional oxidase, and its target is the mitochondria in insect bodies cell.Cell is synthesized and stops vital functions because lacking energy, after laxative, pest activity dies down, and occur spot, color changes, movable stopping, and stupor is weak and limp, finally causes death.

This medicament has following characteristics: broad spectrum insecticide, have stomach toxicity and action of contace poison concurrently, with other insecticides without cross resistance, on crop, have medium residual activity, in nutrient solution through the selective systemic activity of Root Absorption, medium to mammal Oral toxicity, lower, the effective formulation rate of percutaneous toxicity low (100g active ingredient/hm2).Capillary insecticidal spectrum is wide, to test for many years through land for growing field crops and practical application shows, fabulous preventive effect is had, especially to the special efficacy such as the diamond-back moth in vegetables resistant insect, beet armyworm, prodenia litura, Americal rice leaf miner, beans wild snout moth's larva, thrips, two spotted spider mite to 70 various pests in the orders such as Lepidoptera, Homoptera, coleoptera.Belong to bionic pesticide, toxicity is low, and desinsection speed is fast, and medication gets final product kill pests in 1 hour, and the same day, namely preventive effect reached more than 85%.Capillary can break up resistance, and the mechanism of action is unique, different from other insecticide mechanism of action, and without cross resistance, the insect that the antagonism property of medicine is serious is efficient equally.Especially to organic phosphor, carbamate, chrysanthemum ester, chitin synthesis inhibitor insecticides produces the insect of resistance and mite class has good effect.The capillary lasting period is long especially, can control 15-20 days on control resistant insect, and the control two spotted spider mite longevity of residure reaches 35 days, thoroughly can remove the hard work of vegetable grower's " three days one time medicine ".Capillary is applied widely, can be used for vegetables, fruit tree, ornamental plants etc., and can be widely used in the insect in the various crop such as control cotton, vegetables, citrus, grape and soybean and mite class, drug effect than the conventional dose such as Methomyl, orthene height 4-16 doubly.Also can be used for control termites.Capillary permeability is strong, and foliar spray, effective ingredient is permeable to blade back, and desinsection is more thorough.Capillary is environmentally friendly machine, is the azoles of natural screening, to human body and livestock fool proof.Be particluarly suitable for exported product, high-quality product uses.Bromine worm eyeball is chosen to be the first-selected agricultural chemicals of pollution-free vegetable by each big city, the whole nation.Although capillary a drug drops into higher, because insecticidal spectrum is wide, thoroughly, the control time is long, by every mu of cumulative cost still than worthwhile with other insecticides in control.

Capillary has certain ovicidal action, in conjunction with the prediction work of insect, advises incubating peak at the product of insect, or ovum incubate peak spraying can play good control efficiency.Because capillary has good local conductivities in plant corpus, another side can be conducted to from the one side infiltration of blade, therefore also can obtain same effect to the back side of the blade of pests.Preventive effect 90-100% in 1-3 days after medicine, after medicine 15 days drug effects still Absorbable organic halogens 90%, recommend mu consumption 30-40 milliliter, safety interval 15-20 days.General antagonism insect is as diamond-back moth, and the spraying of nocturnal moth class every mu use 30 milliliters routine, should increase consumption to tiger at advanced age.

Cycloxaprid (Cycloxaprid), being called for short QS, is a kind of novel anabasine insecticide.Cycloxaprid is the antagonist of first nAChR in the world, and very likely become the new class insecticide in the world with material impact power, its activity is significantly better than Imidacloprid.All efficient to Brown Planthopper, white-backed planthopper, small brown rice planthopper, also there is good preventive effect to cabbage aphid and Cucumber blight, have to rice leaf roller anti-effect of holding concurrently preferably, Imidacloprid is significantly higher than to cotton field Bemisia tabaci activity.Structural formula is:

Cycloxaprid is completely different from the capillary mechanism of action, about cycloxaprid and the composite composition with insecticidal activity of capillary and apply and there is no people at present and reported.

Summary of the invention

The present invention seeks to for above-mentioned weak point, a kind of Pesticidal combination containing cycloxaprid and capillary is provided.

The present invention finds: the additive property for insecticidal spectrum not only can be brought to improve cycloxaprid and capillary active compound, but also realize amazing synergy.

Term used herein " synergy " refers to that the combination of reactive compound of the present invention or the insecticidal effect of composition are greater than each activating agent effect sum, and in other words, its effect is superadditivity.

Based on above situation, the object of the present invention is to provide a kind of Pesticidal combination containing cycloxaprid and capillary.

A kind of Pesticidal combination of the present invention is achieved through the following technical solutions:

Containing a Pesticidal combination for cycloxaprid and capillary, comprise cycloxaprid and capillary as active component.

Contain a Pesticidal combination for cycloxaprid and capillary, wherein the weight ratio of cycloxaprid and capillary is or 50:1 to 1:50.

Contain a Pesticidal combination for cycloxaprid and capillary, wherein the weight ratio of cycloxaprid and capillary is 25:1 to 1:25.

Contain a Pesticidal combination for cycloxaprid and capillary, wherein the weight ratio of cycloxaprid and capillary is or 10:1 to 1:10.

Contain a Pesticidal combination for cycloxaprid and capillary, wherein the weight ratio of cycloxaprid and capillary is or 5:1 to 1:5.

Contain a Pesticidal combination for cycloxaprid and capillary, it is characterized in that the weight of described cycloxaprid and capillary accounts for described composition 5%-90% by weight altogether.

Contain a Pesticidal combination for cycloxaprid and capillary, it is characterized in that described cycloxaprid and capillary account for described composition 10%-80% by weight altogether.

Contain a Pesticidal combination for cycloxaprid and capillary, it is characterized in that described cycloxaprid and capillary account for described composition 20%-60% by weight altogether.

Described a kind of Pesticidal combination, also comprises surfactant and/or extender containing cycloxaprid and capillary.

Described a kind of Pesticidal combination containing cycloxaprid and capillary, formulation is missible oil, suspending agent, seed coat agent, water dispersible granules, wetting powder, suspension emulsion, extrude granule, coated granule, aerosol, aqueous emulsion, microcapsule suspending agent, microemulsion, microcapsule suspension-suspendinagent agent, microemulsion.

Contain a Pesticidal combination for cycloxaprid and capillary, wherein said composition also comprises one or more other active components.

On the other hand, present invention also offers a kind of Pesticidal combination containing cycloxaprid and capillary for preventing or control the purposes of pest.

On the other hand, present invention also offers a kind of prevention or control the method for pest, a kind of Pesticidal combination containing cycloxaprid and capillary being acted on the propagating materials of target useful plant, object noxious livings or its environment, target useful plant.Described plant propagation material is seedling, rhizome, garden seedling, cutting or seed.

Cover crop, in case a method for pest infestation, comprises and crop is contacted with the Pesticidal combination of capillary with containing cycloxaprid.

A method for prevention or control pest, comprises separately, uses cycloxaprid, capillary successively or simultaneously.

Another object of the present invention is to provide a kind of for preventing or the kit of Control pests, and it comprises cycloxaprid and capillary.

A method for prevention or control pest, is characterized in that, wherein cycloxaprid and capillary are respectively naturally through the form of compositions formulated.

The described purposes of Pesticidal combination for the treatment of seed containing cycloxaprid and capillary.

Cover crop, in case a method for pest infestation, is characterized in that, comprises and crop is contacted with the Pesticidal combination of capillary with containing cycloxaprid.

A kind of Pesticidal combination containing cycloxaprid and capillary of the present invention, with cycloxaprid and capillary for active ingredient, the composition synergistic effect with insecticidal activity is obvious, have synergistic function, can reduce the dosage of two active ingredients, both mechanisms of action are completely different, pest because of with wherein a kind of Pesticide Exposure after poisoning, to decline to the resistance of another kind of agricultural chemicals, more easily kill, thus delay the generation of resistance.

Embodiment

The present invention seeks to as solving at least one problem above-mentioned or its at least one aspect, especially effectively control pest, through large number of biological test screen, the unexpected discovery of the present inventor cycloxaprid and capillary combination can be used for effectively prevention or controls pest.Surprisingly, the activity of the combination control pest of reactive compound of the present invention is much higher than independent active ingredient physical performance summation.This unexpected effect is real synergistic effect, and be not only active add and.

The invention provides and a kind ofly comprise cycloxaprid and the capillary agricultural insecticide composition as active component.

The invention provides and a kind ofly comprise cycloxaprid and the capillary agricultural insecticide composition as active component, wherein cycloxaprid and capillary weight ratio are 50:1 to 1:50, preferred 25:1 to 1:25, more preferably or 10:1 to 1:10, more preferred 5:1 to 1:5.

In the present composition, the total amount of active compound component can be selected according to material elements, to realize desired effect.Described factor such as, formulation, object to be administered, application process etc.Cycloxaprid and capillary altogether account for described composition by weight 5% to 90%, preferably 10% to 80%, more preferably 20% to 50%.

Composition of the present invention optionally comprises acceptable surfactant or extender on agronomy.Preferably, described auxiliary element is one in dispersant, wetting agent, antifreeze, thickener, defoamer, disintegrant, binding agent, assistant carrier or mixture.

According to the present invention, term " filler " refers to can be combined with reactive compound or combine to make it be easier to the organic or inorganic compound being administered to the natural of object (such as plant, crop or careless class) or synthesizing.Therefore, described carrier is preferably inertia, at least should be agronomically acceptable.Described filler can be solid or liquid.

In the present invention, operable inactive filler both can be solid also can be liquid, what can use as solid-filling agent has such as: phyteral powdery type (the such as particle of soybean meal, starch, grain dust, wood powder, bark powder, sawdust, walnut shell powder, wheat bran, cellulose powder, coconut husk, corncob and tobacco stem, extract the residue etc. after plant essence), paper, sawdust, pulverize synthesized polymer body, clay class (such as kaolin, bentonite, acid china clay etc.), the talcum powder class of synthetic resin etc.Silica (such as diatomite, silica sand, mica, moisture silicic acid, calcium silicates), active carbon, natural mineral matter class (float stone, attapulgite and zeolite etc.), fire chemical fertilizer, the clay fertilizer of inorganic mineral powder, ammonium sulfate, ammonium phosphate, urea, ammonium chloride etc. of diatomite, sand, plastics medium etc. (such as polyethylene, polypropylene, polyvinylidene chloride etc.), potassium chloride, calcium carbonate, calcium phosphate etc., these materials can be used alone or two or more is used with.

What can use as liquid filling agent can select in llowing group of materials, such as water, alcohol type (such as methyl alcohol, ethanol, isopropyl alcohol, butanols, ethylene glycol etc.), ketone (such as acetone, methyl ethyl ketone, isobutyrone, cyclohexanone etc.), ethers (such as ether, dioxanes, methylcellulose, oxolane etc.), aliphatic hydrocarbon class (such as kerosene, mineral wet goods), aromatic hydrocarbons class (such as benzene, toluene, dimethylbenzene, solvent naphtha, Fluhyzon, chlorinated aromatic hydrocarbons, chlorinated aliphatic hydrocarbon, chlorobenzene, Deng), halogenated hydrocarbon class, amide-type, sulfone class, dimethyl sulfoxide (DMSO), mineral and vegetable oil, animal wet goods.

For making the emulsification of active ingredient compound, dispersion, solubilized, and/or wetting surfactant can be used such as can to enumerate fatty alcohol-polyoxyethylene ether, polyoxyethylene alkylaryl ether, polyoxyethylene higher fatty acid esters, the phosphate of polyoxyethylene alcohol or phenol, the fatty acid ester of polyalcohol, naphthalene sulfonic acid polymer, lignosulfonates, a shape copolymer of macromolecule comb shape, butyl naphthalene sulfonate, alkylaryl sulfonates, sodium alkylsulfosuccinates, grease, fatty alcohol and ethylene oxide condensate, the polyacrylate of alkyltaurate, protein hydrolysate.Suitable oligosaccharide thing or polymer, such as, based on the combination of independent vinyl monomer, acrylic acid, polyoxyethylene and/or polyoxypropylene or itself and such as (polynary) alcohol or (polynary) amine.

For making the dispersion of active ingredient compound, stabilisation, attachment, such as xanthans, aluminium-magnesium silicate, gelatin, starch, methyl cellulose, polyvinyl alcohol, polyvinyl acetate and the adjuvant such as natural phospholipid (as cephalin and lecithin) and synthetic phospholipid, bentonite, sodium lignin sulfonate can be used.

The wherein optional spent glycol of antifreezing agent, propane diols, glycerine, sorbierite.Deflocculant as suspension product can use the adjuvant of such as naphthalene sulfonic acid polymer, polymeric phosphate etc.Silicone defoaming agent can be used as defoamer.For improveing the mobility of solid product, the adjuvants such as such as paraffin, stearate, alkylphosphonate can be used.

Operable colouring agent, such as inorganic pigment, as iron oxide, titanium oxide and Prussian blue; And organic pigment/dyestuff: alizarin dyes, azo dyes and metallized phthalocyanine dye; And trace element, such as molysite, manganese salt, boron salt, mantoquita, cobalt salt, molybdenum salt and zinc salt.

Optionally, also can comprise other annexing ingredient, such as protecting colloid, adhesive, thickener, thixotropic agent, bleeding agent, stabilizing agent, screening agent.

Described a kind of formulation containing the composition pesticide of cycloxaprid and capillary is: missible oil, aerosol, suspending agent, microcapsulated granule, granula subtilis, can be flowed concentrate, ready to use solution agent, aqueous emulsion, oil emu, fine granule, oil dispersion pulvis, the miscible mobility concentrate of oil, oil miscible liquids, foaming agent, paste, suspending concentrate, suspension emulsion, solubility concentrate, soluble powder, granule, water dispersible granules, water-soluble granular and/or tablet, water solube powder, wetting powder, through the natural or synthetic material of reactive compound dipping, microcapsules in polymeric material and water-dispersible granule.

In preferred embodiments, described agricultural insecticide composition is missible oil, suspending agent, seed coat agent, water dispersible granules, wetting powder, suspension emulsion, extrudes granule, coated granule, aerosol, aqueous emulsion, microcapsule suspending agent, microemulsion, microcapsule suspension-suspendinagent agent, microemulsion.

Described reactive compound mixes with conventional additives by known way and prepares by described preparation of the present invention.Described conventional additives is as conventional extender and solvent or thinner, emulsifier, dispersant and/or adhesive or fixative, wetting agent, waterproofing agent, if needed, drier and colouring agent, stabilizing agent, pigment, defoamer, preservative, thickener, water and other processing aid can also be comprised.

These compositions not only comprise can by suitable equipment as spraying or dusting equipment be applicable to pending object immediately, but also be included in be applied to object before need the concentrated commercial composition that carries out diluting.

Composition of the present invention can make with the form of the composition of its active compound component the preparation being suitable for using, and also can use with the form of the combination of the commercial preparation of its suitable dosage.

Composition of the present invention can also be used with other active ingredient combination, other active component described such as fungicide, bactericide, attractant, insecticide, miticide, nematocide, growth regulator, weed killer herbicide, safener, fertilizer or semiochemical etc.

On the other hand, present invention also offers a kind of agricultural insecticide composition containing cycloxaprid and capillary for preventing or control the purposes of animal pest, animal pest is insect, acarid and nematode.Show to the good tolerance of plant, to the hypotoxicity of warm blooded species and good Environmental compatibility simultaneously.There is activity to kind that is normal responsive and resistance, have activity to all or special developmental stage.Above-mentioned animal pest comprises:

From Isopoda, such as damp worm (Oniscusaselluse), pillworm (Armadillidiumvulgare), and spot pillworm (Porcellioscaber).

From Diplopoda, such as Blaniuusguttulatus.

From chilopoda, such as centipede (Geophiluscarpophagus) and common house centipede dragonfly (Scutigeraspp.).

From Symphyla, such as clean symphilid (Scutigerellaimmaculate).

From Thysanoptera, such as silverfiss (Lepismasaccharina).

From Collembola, such as Onychiurus arcticus (Onychiurusarmatus).

From orthoptera, such as house cricket found in a kitchen (Achetadomesticus), Gryllotalpa spp (Gryllotalpaspp.), tropical migratory locusts (Locustamigratoriamigratorioides), long volume is born locust and is belonged to (Melanoplusspp.), and desert locust (Schistocercagregaria).

From Blattaria, such as oriental cockroach (Blattaorientalis), American cockroach (PeriplanetaAmericana), leucophaea maderae (Leucophaeamaderae), Groton bug (Blattellagermanica).

From Dermaptera, such as European earwig (Forficulaauricularia).

From Isoptera, such as Reticulitermes.

From Anoplura, such as body louse (Pediculushumanuscorporis), blind lice belongs to, and long volume lice belongs to, Trichodectes, Damalinia.

From thrips, such as greenhouse Hercinothrips spp (Hercinothripsfemoralis), cotton thrips (Thripstabaci), Thripspalmi and Frankliniellaaccidentalis.

From Heteroptera, such as Eurygasterspp belongs to, middle red cotton bug (Dysdercusintermedius), and lace bug (Piesmaquadrata) intended by beet, and the smelly stinkbug in temperate zone (Cimexlectularius), red abdomen hunts stinkbug (Rhodniusprolixus) and Triatoma.

From Homoptera, such as wild cabbage aleyrodid (Aleurodesbrassicae), Bemisia tabaci (Bemisiatabaci), Trialeurodes vaporariorum Westwood (Trialeurodesvaporariorum), cotten aphid (Aphisgossypii), cabbage aphid (Brevicorynebrassicae), tea deer hidden knurl volume aphid (Cryptomyzusribis), black bean aphid (Brevicorynebrassicae), apple aphid (Aphispomi), apple aphid (Eriosomalanigerum), mealy plum aphid (Hyalopterusarundinis), grape phylloxera (Phylloxeravastatrix), , Pemphigus, English grain aphid (Macrosiphumavenae), knurl volume Aphis, hops knurl volume aphid (Phorodonhumuli), grain Rhopalosiphum spp (Rhopalosiphumpadi), leafhopper belongs to, Euscelisbilobatus, rice leafhopper (Nephotettixcincticeps), brown apricot scale (Lecaniumcorni), olive helmet (Saissetiaoleae), rice small brown rice planthopper (Laodelphaxstriatellus), brown back rice plant hopper (Nilaparvatalugens), California red scale (Aonidiel1aaurantii), sweet-scented oleander circle a red-spotted lizard (Aspidiotushederae), mealybug belongs to and Psylla spp.

From Lepidoptera, such as pink bollworm (Pectinophoragossypiella), loose looper (Bupaluspiniarius), winter geometrid moth (Chemimatobiabrumata), Lithoclletisblancardela, cherry ermine moth (Hyponomeutapadella), diamond-back moth (Plutellaxylostel1a), tent caterpillar (Malacosomaneustria), pornography and drug moth (Euproctischrysorrhoea), Euproctis, cotton shot hole of leaf lyonetid (Bucculatrixthurberiella), tangerine leaf miner (Phyllocnistiscitrella), Agrotis, root eating insect belongs to, brown Noctua, earias insulana (Eariasinsulana), Noctua, tomato moth (Mamestrabrassicae), small noctuid (Panolisflammea), Noctua, cabbage looper (Trichoplusiani), codling moth (Carpocapsapomonella), Pier, snout moth's larva belongs to Pyraustanubilalis, Anagasta kuehniella (Ephestiakuehniella), rheum officinale snout moth's larva (Galleriamellonel1a), bag casemaking clothes moth (Tineolabisselliella), etting moth (Tineapellionel1a), brown oecophorid (Hofmannophilapseudospretella), yellow tail leaf roller (Cacoeciapodana), Capuareticulana, choristoneura fumigerana (Choristoneurafumiferana), grape codling moth (Clysia ambiguella) (Clysiaambiguel1a), tea yellow leaf curl moth (Homonamagnanima), the green leaf roller of oak (Tortrixviridana), volume snout moth's larva belongs to, Oulema oryzae (Oulemaoryzae).

From coleoptera, such as furniture death watch beetle (Anobiumpunctatum), lesser grain borer (Rhizoperthadominica), Bruchidiusobtectus, common bean weevil (Acanthoscelidesobtectus), house longhorn beetle (Hylotrupesbajulus), the purple flea beetle (Agelasticaalni) of alder, colorado potato beetle (Leptinotarsadecemlineata), horseradish ape chrysomelid (Phaedoncochleariae), chrysomelid genus, the blue flea beetle (Psylliodeschrysocephala) of rape, mexican bean ladybird (Epi1achnavarivestis), hidden wing first belongs to, saw chest ostomatid (Oryzaephilussurinamensis), weevil belongs to, Sitophilus, vine black ear resembles (Otiorrhynchussulcatus), banana spider base weevil (Cosmopolitessordidus), wild cabbage English weevil (Ceuthorrhynchusassimilis), alfalfa weevil (Hyperapostica), khapra beetle belongs to, spot khapra beetle belongs to, Anthrenus, hair is moth-eaten to be belonged to, moth belongs to powder, pollen beetle (Meligethesaeneus), Ptinus, golden yellow ptinid (Niptushololeucus), wheat ptinid (Gibbiumpsylloides), Tribolium, Cabot's Tragopan (Tenebriomolitor), click beetle belongs to, acupuncture needle Eimeria, angle cockchafer (Melolonthamelolontha), chafer in June (Amphimallonsolstitialis), brown New Zealand's rib wing angle cockchafer (Costelytrazealandica) and rice water resemble (Lissorhoptrusoryzophilus).

From Hymenoptera, such as Neodiprion spp belongs to, tenthredinidae, and field ant belongs to, MonomoriumMayr (Monomoriumpharaonis) and Vespa.

From diptera, such as Aedes, spot Anopheles, Culex, drosophila yellow gorilla (Drosophilamelanogaster), Musca, male servant fly belongs to, calliphora erythrocephala (Calliphoraerythrocephala), lucilia sericata belongs to, Carysomyia, cuterbrid belongs to, Gasterophilus, Hippobosca, chela fly belongs to, nose fly belongs to, Hypoderma, Pituophis, Tannia belongs to, Bibiohortulanus, Sweden's wheat stem chloropid fly (Oscinellafrit), wheat fly belongs to, spinach leaf miner (Pegomyiahyoscyami), Mediterranean fruitfly (Ceratitiscapitata), dacus oleae (Dacusoleae) and European daddy-longlegs (Tipulapaludosa), Hylemyia, and Hippelates.

From Siphonaptera, such as Xenopsyllacheopis (Xenopsyllacheopis) and angle leaf lice mouse.

From arachnids, such as scorpion (Scorpiomaurus), black widow (Latrodectusmactans), Acarus siro (Acarussiro), Dermanyssus gallinae (Dermanyssysgallinae), tea deer goitre mite (Eriophyesribis), citrus rust mite (Phyllocoptrutaoleivora), Boophilus, carrapato belongs to, Amblyomma, glass eye tick belongs to, hard tick belongs to, Acarus tritici belongs to, ginger mite belongs to, itch mite belongs to, the compacted genus of line, Bryobia praetiosa (Bryobiapraetiosa), two spotted spider mite belongs to, the compacted genus of red autumnal leaves, point tenthredinidae, short whisker Acarapis.

Parasitic plant nematode comprises such as Pratylenchidae and belongs to, Radopholus similis Throne (Radopholussimilis), fuller's teasel stem eelworm (Ditylenchusdipsaci), Tylenchulus Semipenetrans (Tylenchulussemipenetrans), Heterodera, ball Heterodera, Meloidogyne, Aphelenchoides, minute hand Turbatrix, Xiphinema, and burr Turbatrix, remote spring dragonfly genus.

A kind of Pesticidal combination containing cycloxaprid and capillary of the present invention is specially adapted to prevent and treat " biting " insect, and these insects specifically comprise following insect:

From Lepidoptera, such as pink bollworm (Pectinophoragossypiella), loose looper (Bupaluspiniarius), winter geometrid moth (Cheimatobiabrumata), Lithocolletisblancardel1a, cherry ermine moth (Hyponomeutapadella), diamond-back moth (Plutellaxylostella), tent caterpillar (Malacosomaneustria), pornography and drug moth (Euproctischrysorrhoea), Euproctis, cotton shot hole of leaf lyonetid (Bucculatrixthurberlella), tangerine leaf miner (Phyllocnistiscitrella), Agrotis, root eating insect belongs to, brown Noctua, Egyptian complete just brill (Eariasinsulana), Noctua, tomato moth (Mamestrabrassicae), small noctuid (Panolisflammea), Noctua, powder pattern moth (Trichoplusiani), codling moth (Carpocapsapomonella), Pier, snout moth's larva belongs to, Pyraustanubilalis, Anagasta kuehniella (Ephestiakuehniella), rheum officinale snout moth's larva (Gal1eriamellonella), bag casemaking clothes moth (Tineolabisselliella), etting moth (Tineapellionella), brown oecophorid (Hofmannophilapseudospretella), yellow tail leaf roller (Cacoeciapodana), Capuareticulana, choristoneura fumigerana (Choristoneurafumiferana), moth-eaten moth (Clysiaambiguella) stayed by grape, tea yellow leaf curl moth (Homonamagnanima), the green leaf roller of oak (Tortrixviridana), volume snout moth's larva belongs to, Oulema oryzae (Oulemaoryzae).

From coleoptera, such as furniture death watch beetle (Anobiumpunctatum), lesser grain borer (Rhizoperthadominica), Bruchidiusobtectus, common bean weevil (Acanthoscelidesobtectus), house longhorn beetle (Hylotrupesbajulus), the purple flea beetle (Agelasticaalni) of alder, colorado potato beetle (Leptinotarsadecemlineata), horseradish ape chrysomelid (Phaedoncochleariae), chrysomelid genus, the blue flea beetle (Psylliodeschrysocephala) of rape, mexican bean ladybird (Epilachnavarivestis), hidden wing first belongs to, saw chest ostomatid (Oryzaephilussurinamensis), weevil belongs to, Sitophilus, during vine black ear beak (Otiorrhynchussulcatus), banana spider base weevil (Cosmopolitessordidus), wild cabbage English weevil (Ceuthorrhynchusassimilis), alfalfa weevil (Hyperapostica), khapra beetle belongs to, spot khapra beetle belongs to, Anthrenus, hair is moth-eaten to be belonged to, moth belongs to powder, pollen beetle (Meligethesaeneus), Ptinus, golden yellow ptinid (Niptushololeucus), wheat ptinid (Gibbiumpsylloides), Tribolium, Cabot's Tragopan (Tenebriomolitor), click beetle belongs to, acupuncture needle Eimeria, angle cockchafer (Melolonthamelolontha), chafer in June (Amphimallonsolstitialis), brown New Zealand's rib wing angle cockchafer (Costelytrazealandica) and rice water resemble (Lissorhoptrusoryzophilus).

A kind of Pesticidal combination containing cycloxaprid and capillary of the present invention is also applicable to prevent and treat " sucking " insect, and these insects specifically comprise following insect:

From Homoptera, such as wild cabbage aleyrodid (Aleurodesbrassicae), Bemisia tabaci (Bemisiatabaci), Trialeurodes vaporariorum Westwood (Trialeurodesvaporariorum), cotten aphid (Aphisgossypii), cabbage aphid (Brevicorynebrassicae), tea deer hidden knurl volume aphid (Cryptomyzusribis), black bean aphid (Aphisfabae), apple aphid (Aphispomi), apple aphid (Eriosomalanigerum), mealy plum aphid (Hyalopterusarundinis), grape phylloxera (Phylloxeravastatrix), goitre cotten aphid belongs to, English grain aphid (Macrosiphumavenae), knurl volume Aphis, hops knurl volume aphid (Phorodonhumuli), grain Rhopalosiphum spp (Rhopalosiphumpadi), leafhopper belongs to, Euscelisbilobatus, rice leafhopper (Nephotettixcincticeps), brown apricot scale (Lecaniumcorni), olive helmet (Saissetiaoleae), rice small brown rice planthopper (Laodelphaxstriatellus), brown back rice plant hopper (Nilaparvatalugens), California red scale (Aonidiellaaurantii), sweet-scented oleander circle a red-spotted lizard (Aspidiotushederae), mealybug belongs to and Psylla spp.

On the other hand, present invention also offers a kind of prevention or control the method for animal pest, a kind of agricultural insecticide composition containing cycloxaprid and capillary being acted on the propagating materials of target useful plant, target animal insect or its environment, target useful plant.Described plant propagation material is seedling, rhizome, garden seedling, cutting or seed.

Described usual processing method as by pouring (dipping), drip irrigation, spraying, evaporation, be atomized, broadcast sowing, dusting, foaming, the mode such as coating; Or as being used for solvable pulvis, liquid agent, the slurry of seed or rice shoot process; And by dry treatment, slurry process, liquid handling.Also use described compound by ultra low volume method, or described compound or composition itself are injected soil.

Method of the present invention additionally provides with separately, successively or reactive compound described in simultaneous system combined administration.

It is common with favourable that Pesticidal combination of the present invention is used with following dosage usually:

-leaf portion is processed: 0.1-10000g/ha, preferred 10-1000g/ha, more preferably 50-300g/ha; For dipping or instillation are used, described dosage even also can reduce, particularly when using inert base as asbestos or perlite;

-for seed treatment: 2-200g/100kg seed, preferred 3-150g/100kg seed;

-for soil treatment: 0.1-10000g/ha, preferred 1-5000g/ha.

Above-mentioned dosage is only general exemplary dose, and actual those skilled in the art can according to actual conditions and needs when using, and especially adjusts rate of application according to the character of pending plant or crop and insect pest situation.

Pesticidal combination of the present invention has good plant compatibility, is suitable for Control pests, particularly insect, acarid, nematode, and fungi, rodent, microorganism etc., and it is preferably used for the composition of leaf process, soil treatment and seed, rice shoot process.

According to the present invention, all plants and each several part of plant can be processed.Plant is interpreted as representing all plants and plant population is as desired and undesirable wild plant or crop (comprising the crop of spontaneous growth) at this.Crop can be the plant obtained by conventional breeding and optimum seeking method; or by the plant that the combination of biotechnology and genetic engineering method or these methods obtains, comprise genetically modified plants and comprise the Plant cultivars that can or can not be protected by plant breeder's certificate.Plant parts is interpreted as representing that all grounds and under ground portion and plant organ are as seedling, leaf, Hua Hegen, and the example that can mention is leaf, pin, stem, dry, flower, fruit body, fruit and seed and root, stem tuber and rhizome.The part of plant also comprises the plant after results and vegetative propagation and case of propagation material, such as seedling, stem tuber, rhizome, transplants and seed.

As mentioned above, all plants and part thereof can be processed according to the present invention.In preferred embodiments, those plant varieties having processed wild plant species and Plant cultivars or obtained as hybridization or protoplast fusion by standard biologic breeding method and part thereof.In a more preferred embodiment, processed by genetic engineering (genetically modified plants obtained in conjunction with conventional method (GeneticallyModifiedOrganisms) if desired and Plant cultivars and part thereof.

According to the present invention, particularly preferably be the process commercially available or plant of Plant cultivars in using in all cases.

According to plant variety or Plant cultivars, its position and growth conditions (soil, weather, vegetative period, food), super adding and (" working in coordination with ") effect also can be produced according to process of the present invention.So, such as reduce consumption and/or widen activity profile and/or increase according to the activity of the spendable material of the present invention and composition, better plant growth, strengthen tolerance to high temperature or low temperature, strengthen tolerance to dry morning, water or soil salt content, increase performance of blooming, be easier to results, higher nutritive value, the better storage stability of hasting of maturity, higher harvest yield, better quality and/or results product and/or the machinability of gathering in the crops product all become possibility, that is out the effect of actual desired.

Pesticidal combination of the present invention is also applicable to prevent and treat the animal pest, particularly insect of enclosure space, spider and acarid, and described enclosure space is as house, factory floor, office, cabin etc.They can be used for preventing and treating these insects in domestic insecticide products, they to sensitivity and resistance kind and have activity to all developmental stage.These insects comprise:

Scorpionida, such as, clamp scorpion (Buthusoccitanus).

Acarina, such as adobe tick, stick up edge sharp-edged tick, Bryobia, Dermanyssus gallinae, family eat sweet mite, tampan tick, brown dog tick, trombiculid (Trombiculaalfreddugesi), Neutrombiculaautumnalis, dermatophagoides pteronyssinus, dust mite.

Araneida, such as cockle spider section, Yuan Zhu section.

Opiliones, such as, intend scorpion class (Pseudoscorpioneschelifer), Pseudoscorpionescheiridium, Opilionesphalangium.

Isopoda, such as damp worm, pillworm.

Doubly sufficient order, such as, have a zebra land, mountain cricket Eimeria.

Lip foot order, such as Scolopendra.

Zygentoma order, such as comb silverfish genus, Lepisma saccarina, Lepismodesinquilinus.

Blattaria, such as oriental cockroach, Groton bug, Blatella (Blattel1aasahinai), leucophaea maderae, angle abdomen Lian genus, wooden Lian genus, Australian cockroach, American cockroach, the large Lian of foxiness, Peroplaneta fluligginosa, long palpus blattaria.

Saltatoria, such as family Shuai.

Dermaptera, such as European earwig.

Isoptera, such as kalotermitid belongs to, Reticulitermes.

Worm order, such as Lepinatus belongs to, powder breathes heavily Eimeria.

Coleoptera, such as Anthrenus, moth belongs to fur, and khapra beetle belongs to, long head lesser grain borer, hidden instep cuckoo Eimeria, Ptinus, lesser grain borer, grain weevil, rice weevil, corn weevil, Stegobium paniceum.

Diptera, such as Aedes aegypti, aedes albopictus, Aedestaeniorhynchus, Anopheles, calliphora erythrocephala, great number sarcophagid, Culex quinquefasciatus, northern house, Culextarsalis, slow-witted fly belongs to, Fannia canicularis, housefly, Bai Ling belongs to, sarcophagid (Sarcophagacarnaria), Simulium, male servant chela fly, daddy-longlegs (Tipulapaludosa).

Lepidoptera, such as lesser wax-moth, galleria mellonella waxmoth, the ancient phycitid of India, rain moth, bag rain moth, curtain rain moth.

Siphonaptera, the first lice of such as dog comb, Ctenocephalides felis felis, humanlice, chigo, Xanthopsyllacheopis.

Hymenoptera, such as, blazon hunchbacked ant, bright hair ant, black wool ant, Lasiusumbratus, MonomoriumMayr, and Paravespula belongs to, Pavement Ant.

Anoplura, such as head louse, body louse, crab louse.

Heteroptera, such as cimex hemipterus, bed bug, phodnius prolixus, invades and harasses vertebra and hunts stinkbug.

Pesticidal combination of the present invention can be used as aerosol, the evaporator of spray product with no pressure such as pump spraying and atomizer spray, automatically mist formation system, fogger, foam, gel, the evaporator product with the evaporating plate that cellulose or polymer are made, liquid evaporator, gel and film evaporator, screw driving, do not consume energy or passive type vapo(u)rization system, catch moth paper, catch moth bag and insect-catching glue, as drawing agent or pulvis, in the bait formulation that sprays or bait formulation position.

It should be pointed out that any embodiment of the present invention or embodiment any technical characteristic can independently with other embodiment combination with one another any of the present invention.That is, one or more technical characteristics of any embodiment of the present invention all can reconfigure with other technical characteristic any.Technical characteristic reconfigures and the technical characteristic that formed is disclosed in herein thus, and it is documented in the same especially herein.

The composition synergistic effect with insecticidal activity that the present invention is active ingredient with cycloxaprid and capillary is obvious, the dosage of two compositions can be reduced, both mechanism of action is completely different, pest because of with wherein a kind of Pesticide Exposure after poisoning, to decline to the resistance of another kind of agricultural chemicals, more easily kill, thus delayed the generation of resistance.

Example of formulations

Embodiment 1:50% cycloxaprid+1% capillary suspending agent

Cycloxaprid 50%

Capillary 1%

Methyl naphthalene sulfonate formaldehyde condensate 10%

Xanthans 1%

Bentonite 1%

Glycerine 5%

Water complements to 100%

The ratio of each components such as active component, dispersant, wetting agent and water according to formula is mixed, after grinding and/or high speed shear, obtains 50% cycloxaprid+1% capillary suspending agent.

Embodiment 225% cycloxaprid+1% capillary wetting powder

Cycloxaprid 4%

Capillary 20%

Lauryl sodium sulfate 2%

Sodium lignin sulfonate 5%

White carbon 10%

Kaolin complements to 100%

By the proportional components mixing by formula such as active component, various auxiliary agent and filler, after ultra-fine pulverizer disintegrating, namely obtain 25% cycloxaprid+1% capillary wetting powder.

Embodiment 320% cycloxaprid+2% capillary aqueous emulsion

Cycloxaprid 20%

Capillary 2%

1-METHYLPYRROLIDONE 15%

Calcium dodecyl benzene sulfonate 5%

Agriculture breast 600#5%

Water complements to 100%

Former medicine, solvent, emulsifier are added together, make to be dissolved into homogeneous oil phase; By water-soluble component and the obtained aqueous phase of water mixing; Under high velocity agitation, oil phase is mixed with water, obtained 20% cycloxaprid+2% capillary aqueous emulsion.

Embodiment 41.5% cycloxaprid+3.5% acarid nitrile water dispersion granula

Cycloxaprid 1.5%

Capillary 3.5%

Sodium lignin sulfonate 4%

Lauryl sodium sulfate 5%

Urea 5%

Kaolin complements to 100%

Active component, dispersant, wetting agent, disintegrant and the filler ratio in formula is mixed, becomes wetting powder through air-flow crushing, then add a certain amount of water mixing extruding and make material.1.5% cycloxaprid+3.5% acarid nitrile water dispersion granula is obtained after drying screening.

Embodiment 510% cycloxaprid+20% capillary suspending agent

Cycloxaprid 10%

Capillary 20%

Methyl naphthalene sulfonate formaldehyde condensate 10%

Xanthans 1%

Bentonite 1%

Glycerine 5%

Water complements to 100%

The ratio of each components such as active component, dispersant, wetting agent and water according to formula is mixed, after grinding and/or high speed shear, obtains 10% cycloxaprid+20% capillary suspending agent.

Embodiment 62.5% cycloxaprid+7.5% capillary suspending agent

Cycloxaprid 2.5%

Capillary 7.5%

Methyl naphthalene sulfonate formaldehyde condensate 5%

Xanthans 1%

Bentonite 1%

Glycerine 5%

Water complements to 100%

The ratio of each components such as active component, dispersant, wetting agent and water according to formula is mixed, after grinding and/or high speed shear, obtains 2.5% cycloxaprid+7.5% capillary suspending agent.

Embodiment 71% cycloxaprid+10% capillary wetting powder

Cycloxaprid 1%

Capillary 10%

Lauryl sodium sulfate 10%

Sodium lignin sulfonate 5%

White carbon 10%

Kaolin complements to 100%

Said components is mixed in proportion, and grinds, pulverize, be prepared into wetting powder.

Embodiment 81% cycloxaprid+50% capillary suspending agent

Cycloxaprid 1%

Capillary 50%

Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%

MODIFIED LIGNOSULPHONATE 5%

Xanthans 1%

Bentonite 1%

Glycerine 5%

Water complements to 100%

The ratio of each components such as active component, dispersant, wetting agent and water according to formula is mixed, after grinding and/or high speed shear, obtains 1% cycloxaprid+50% capillary suspending agent.

Embodiment 915% cycloxaprid+5% capillary aqueous emulsion

Oil phase:

Cycloxaprid 15%

Capillary 5%

Methyl oleate 38%

Polystyrene 3.7%

Aqueous phase:

Xanthans 0.07%

The sodium salt 1% of the naphthalene sulfonic acids-formaldehyde condensation products of sulfonation

Bactericide 0.2%

Water complements to 100%

Cycloxaprid and capillary are dissolved in methyl oleate, add polystyrene and obtain oil phase; Mix according to the component in formula and obtain aqueous phase; Under agitation oil phase is added aqueous phase and obtain aqueous emulsion.

Embodiment 1020% cycloxaprid+30% capillary wetting powder

Cycloxaprid 20%

Capillary 30%

Sodium lignin sulfonate 4%

NaLS 2%

The silicic acid 1% of high degree of dispersion

Kaolin complements to 100%

Said components is mixed in proportion, and grinds, pulverize, be prepared into wetting powder.

Embodiment 111% cycloxaprid+25% capillary coated granule

Cycloxaprid 1%

Capillary 25%

Polyethylene glycol 3%

The silicic acid 1% of high degree of dispersion

Calcium carbonate complements to 100%

In a mixer, by levigate active component even spread on the carrier soaked by polyethylene glycol.Dust-free coated granules agent can be obtained in this way.

Embodiment 1230% cycloxaprid+60% capillary wetting powder

Cycloxaprid 30%

Capillary 60%

Lauryl sodium sulfate 1%

Sodium lignin sulfonate 1%

White carbon 1%

Kaolin complements to 100%

Said components is mixed in proportion, and grinds, pulverize, be prepared into wetting powder.

Embodiment 1320% cycloxaprid+60% capillary extrudes granule

Cycloxaprid 20%

Capillary 60%

Sodium lignin sulfonate 4%

Carboxymethyl cellulose 2%

Kaolin complements to 100%

Active component is mixed with auxiliary agent and grinds, mixture water-wet.This mixture is extruded, then dry in the air stream.

Embodiment 1450% cycloxaprid+10% capillary suspending agent

Cycloxaprid 50%

Capillary 10%

Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%

MODIFIED LIGNOSULPHONATE 5%

Xanthans 1%

Bentonite 1%

Glycerine 5%

Water complements to 100%

The ratio of each components such as active component, dispersant, wetting agent and water according to formula is mixed, after grinding and/or high speed shear, obtains 50% cycloxaprid+10% capillary suspending agent.

Embodiment 155% cycloxaprid+15% capillary ZC

Atlox49134%

Citric acid 0.05%

Catalyzer 0.1%

Water 13%

Cycloxaprid 5%

PAPI1.35%

Solvesso20010%

Atlox491316%

Dispersant LFH0.3%

Defoamer 0.16%

Urea 8.4%

Capillary 15%

Water complements to 100%

By PAPI, the oil phase that capillary and Solvesso100 are formed adds in the aqueous solution containing Atlox4913, forms emulsion.Then heat and be incubated 50 ^ocatalyst reaction is added 2 hours under C.The microcapsules of capillary is obtained after cooling.

Atlox4913, dispersant LFH, defoamer, urea, cycloxaprid and water mix in proportion, and through sand milling, are prepared into suspending agent.

The microcapsules of the capillary obtained is added in the aqueous suspension agent of cycloxaprid, stirs and obtain 5% cycloxaprid+15% capillary ZC.

Embodiment 1610% cycloxaprid+50% capillary suspended emulsion

Cycloxaprid 10%

Capillary 50%

Solvesso20010%

Ethoxylated castor oil 4%

Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%

MODIFIED LIGNOSULPHONATE 5%

Xanthans 1%

Bentonite 1%

Glycerine 5%

Water complements to 100%

Cycloxaprid is dissolved in Solvesso200, adds ethoxylated castor oil, obtain the missible oil of cycloxaprid;

By capillary, fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium, above-mentioned each component mixes in proportion, and through sand milling, is prepared into suspending agent.

Oil phase containing cycloxaprid is joined in the suspending agent containing capillary, obtains suspended emulsion.

Embodiment 1710% cycloxaprid+10% capillary missible oil

Cycloxaprid 10%

Capillary 10%

Ethoxylated castor oil 5%

Calcium dodecyl benzene sulfonate 3%

Solvesso100 complements to 100%

By above-mentioned each component mixing, be stirred to and obtain transparent homogeneous phase.

Embodiment 185% cycloxaprid+10% capillary suspension seed-coating agent

Cycloxaprid 5%

Capillary 10%

Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%

MODIFIED LIGNOSULPHONATE 5%

Xanthans 1%

Bentonite 1%

Glycerine 5%

PVP-K301%

Water complements to 100%

Above-mentioned each component is mixed in proportion, and through sand milling, is prepared into suspension seed-coating agent.

Biological test example

When the effect of active compound combinations exceedes the summation of the effect when each reactive compound is used separately, there is collaborative desinsection and acaricidal action.The predictive role of the particular combination of two kinds of reactive compounds can use so-called " Colby formula " (see S.R.Colby, " CalculatingSynergisticandAntagonisticResponsesofHerbicid eCombinations ", Weeds1967,15,20-22) calculate as follows: if

X is the kill ratio when using the reactive compound A that consumption is mppm for mg/ha or concentration, is expressed as the percentage accounting for untreated control,

Y is the kill ratio when using the reactive compound B that consumption is nppm for ng/ha or concentration, is expressed as the percentage accounting for untreated control,

E is when using consumption for kill ratio during m and ng/ha or the concentration reactive compound A and B that is m and nppm, being expressed as the percentage accounting for untreated control,

So

If the desinsection lethality rate of reality exceedes calculated value, then the lethal effect of composition be super add and, namely there is synergy.In this case, the kill ratio actually observed must be over the value of the expection kill ratio value (E) using above-mentioned formulae discovery.

Biological test example 1 rice fulgorid is tested

Solvent: the dimethyl formamide of 7 weight portions

Emulsifier: the alkylaryl polyglycol ether of 2 weight portions

For preparing suitable active agent preparations, the solvent of the reactive compound of 1 weight portion and described amount and emulsifier being mixed, and described dope is diluted with water to desired concn.

The rice leaf seriously infected by rice fulgorid (riceplanthopper) is processed by the reactive compound immersing desired concn.

After required time, determine the lethality in %.100% represents that whole rice fulgorid is killed; 0% represents do not have rice fulgorid to be killed.The lethality determined is substituted into Colby formula.

In this experiment, such as, the following active compound combinations of the application, compared with the reactive compound used separately, shows the collaborative activity improved:

Rice fulgorid is tested

Biological test example 2 tea lesser leafhopper is tested

Solvent: the dimethyl formamide of 7 weight portions

Emulsifier: the alkylaryl polyglycol ether of 2 weight portions

For preparing suitable active agent preparations, the solvent of the reactive compound of 1 weight portion and described amount and emulsifier being mixed, and described dope is diluted with water to desired concn.

The blade seriously infected by smaller green leaf hopper is processed by the active agent preparations immersing desired concn.

After required time, determine the lethality in %.100% represents that whole smaller green leaf hopper kills; 0% represents do not have smaller green leaf hopper to be killed.The lethality determined is substituted into Colby formula.

In this experiment, such as, the following active agent combinations of the application, compared with the reactive compound used separately, shows the collaborative activity improved:

Smaller green leaf hopper is tested

Biological test 3 beet armyworm is tested

Solvent: the dimethyl formamide of 7 weight portions

Emulsifier: the alkylaryl polyglycol ether of 2 weight portions

For preparing suitable active agent preparations, the solvent of the reactive compound of 1 weight portion and described amount and emulsifier being mixed, and described dope is diluted with water to desired concn.

The active agent preparations of cabbage leaves by desired concn of spraying is processed, and garden beet noctuid inoculates when blade is still moist.

After required time, determine the lethality in %.100% represents that whole beet armyworm is killed; 0% represents do not have beet armyworm to be killed.The lethality determined is substituted into Colby formula calculate.

In this experiment, such as, the following active agent combinations of the application, compared with the reactive compound used separately, shows the collaborative activity improved:

Biological test example 4 cotten aphid is tested

Solvent: the dimethyl formamide of 7 weight portions

Emulsifier: the alkylaryl polyglycol ether of 2 weight portions

For preparing suitable active agent preparations, the solvent of the reactive compound of 1 weight portion and described amount and emulsifier being mixed, and described dope is diluted with water to desired concn.

By the described active agent preparations spraying desired concn, cotton leaf is processed, and with cotten aphid, cotton leaf is inoculated when blade is still wetting.

After required time, determine the Death Level represented with %.100% refer to that all cotten aphids are killed all herein; 0% refers to do not have cotten aphid to be killed.The lethality recorded is substituted into Colby formula calculate.

Biological test example 5 panonychus citri is tested

Solvent: the dimethyl formamide of 7 weight portions

Emulsifier: the alkylaryl polyglycol ether of 2 weight portions

For preparing suitable active agent preparations, the solvent of the reactive compound of 1 weight portion and described amount and emulsifier being mixed, and described dope is diluted with water to desired concn.

By the described active agent preparations spraying desired concn, oranges and tangerines leaf is processed, and with panonychus citri, oranges and tangerines leaf is inoculated when blade is still wetting.

After required time, determine the Death Level represented with %.100% refer to that all panonychus citris are killed all herein; 0% refers to do not have panonychus citri to be killed.The lethality recorded is substituted into Colby formula calculate.

By finding out in above-mentioned experimental data that Insecticidal combinations that the present invention contains cycloxaprid and capillary achieves the effect of cooperative gain on insecticidal effect.

Claims (10)

1. the method for a prevention or control panonychus citri, it is characterized in that, a kind of Pesticidal combination is used for the propagating materials of target useful plant, object noxious livings or its environment, target useful plant, described Pesticidal combination comprises cycloxaprid and capillary as active component, and the weight ratio of described cycloxaprid and capillary is 5:1 to 1:5.

2. method according to claim 1, described plant propagation material is seedling, rhizome, garden seedling, cutting or seed.

3. method according to claim 1, comprises separately, uses cycloxaprid and capillary successively or simultaneously.

4. method according to claim 1, wherein cycloxaprid and capillary are respectively naturally through the form of compositions formulated.

5. method according to claim 1, is characterized in that, the weight of described cycloxaprid and capillary accounts for described Pesticidal combination 5%-90% by weight altogether.

6. method according to claim 1, is characterized in that, the weight of described cycloxaprid and capillary accounts for described Pesticidal combination 10%-80% by weight altogether.

7. method according to claim 1, is characterized in that, the weight of described cycloxaprid and capillary accounts for described Pesticidal combination 20%-60% by weight altogether.

8. method according to claim 1, is characterized in that, described Pesticidal combination also comprises surfactant and/or extender.

9. method according to claim 1, it is characterized in that, described Pesticidal combination, formulation is missible oil, suspending agent, seed coat agent, water dispersible granules, wetting powder, suspension emulsion, extrude granule, coated granule, aerosol, aqueous emulsion, microcapsule suspending agent, microemulsion, microcapsule suspension-suspendinagent agent, microemulsion.

10. method according to claim 1, comprises and plant is contacted with described Pesticidal combination.