CN103484848B - 一种铁系彩膜磷化液 - Google Patents
一种铁系彩膜磷化液 Download PDFInfo
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- CN103484848B CN103484848B CN201310434489.9A CN201310434489A CN103484848B CN 103484848 B CN103484848 B CN 103484848B CN 201310434489 A CN201310434489 A CN 201310434489A CN 103484848 B CN103484848 B CN 103484848B
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- color film
- phosphoric acid
- iron system
- phosphating liquid
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 15
- 239000007788 liquid Substances 0.000 title claims abstract description 15
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 24
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 16
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 8
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 claims abstract description 8
- 150000003014 phosphoric acid esters Chemical class 0.000 claims abstract description 8
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 8
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims abstract description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011787 zinc oxide Substances 0.000 claims abstract description 8
- 230000035939 shock Effects 0.000 abstract description 4
- 229910019142 PO4 Inorganic materials 0.000 abstract description 3
- 238000005452 bending Methods 0.000 abstract description 3
- 150000002505 iron Chemical class 0.000 abstract description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 3
- 239000010452 phosphate Substances 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Abstract
本发明公开了一种铁系彩膜磷化液，各组分按重量份计，氧化锌2-5份、环己六醇六磷酸脂20-25份、柠檬酸12-17份、磷酸5-8份、钼酸钠3-5份、碳酸钠或硅酸钠1-3份、浸润剂0.2-0.5份、水100份。本发明所提供的铁系彩膜磷化液，不仅保持了现有技术中铁系磷化液的抗弯曲、抗冲击性，磷化膜不易断裂的特点，而且具有很强的耐腐蚀性能。
Description
技术领域
本发明涉及一种磷化液，具体涉及一种铁系彩膜磷化液。
背景技术
铁系磷化液应用广泛，适用于家用电器、仪器仪表、钢门窗、车辆汽配、灯饰家具等五金零件喷漆或喷塑前处理磷化，尤其作为变形大的零件涂装打底。磷化膜以非结晶状存在，膜层薄，呈现彩虹色。具有以下特点：
1、抗弯曲、抗冲击性能好，膜层不易变型；
2、单组分，不需要表面调整，对基材适用性强；
3、稳定性好，即使零件污染不太干净也不会影响使用效果；
4、槽液易于维护，操作方便。
正由于铁系彩膜磷化液具有上述特点，被广泛应用。但是，因其耐腐蚀性较差，又使得其在很多领域受到限制。
发明内容
本发明要解决的技术问题是克服现有的缺陷，提供了一种耐腐蚀性强、抗弯性、抗冲击性强的铁系彩膜磷化液。
本发明的目的通过以下技术方案来具体实现：
一种铁系彩膜磷化液，各组分按重量份计，氧化锌2-5份、环己六醇六磷酸脂20-25份、柠檬酸12-17份、磷酸5-8份、钼酸钠3-5份、碳酸钠或硅酸钠1-3份、浸润剂0.2-0.5份、水100份。
作为优选方案，上述的铁系彩膜磷化液，各组分按重量份计，氧化锌2-5份、环己六醇六磷酸脂20-25份、柠檬酸12-17份、磷酸5-8份、钼酸钠3-5份、碳酸钠或硅酸钠1-3份、浸润剂0.2-0.5份、水100份。
本发明的有益效果：
本发明所提供的铁系彩膜磷化液，不仅保持了现有技术中铁系磷化液的抗弯曲、抗冲击性，磷化膜不易断裂的特点，而且具有很强的耐腐蚀性能。
具体实施方式
以下对本发明的优选实施例进行说明，应当理解，此处所描述的优选实施例仅用于说明和解释本发明，并不用于限定本发明。
实施例1：
一种铁系彩膜磷化液，各组分按重量份计，氧化锌2-5份、环己六醇六磷酸脂20-25份、柠檬酸12-17份、磷酸5-8份、钼酸钠3-5份、碳酸钠或硅酸钠1-3份、浸润剂0.2-0.5份、水100份。
实施例2：
一种铁系彩膜磷化液，各组分按重量份计，氧化锌2份、环己六醇六磷酸脂25份、柠檬酸12份、磷酸8份、钼酸钠3份、碳酸钠或硅酸钠3份、浸润剂0.2份、水100份。
实施例3：
一种铁系彩膜磷化液，各组分按重量份计，氧化锌5份、环己六醇六磷酸脂20份、柠檬酸17份、磷酸5份、钼酸钠5份、碳酸钠或硅酸钠1份、浸润剂0.5份、水100份。
以上所述仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照前述实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
Claims (2)
1.一种铁系彩膜磷化液，其特征在于：各组分按重量份计，氧化锌2-5份、环己六醇六磷酸脂20-25份、柠檬酸12-17份、磷酸5-8份、钼酸钠3-5份、碳酸钠或硅酸钠1-3份、浸润剂0.2-0.5份、水100份。
2.根据权利要求1所述的铁系彩膜磷化液，其特征在于：各组分按重量份计，氧化锌2份、环己六醇六磷酸脂25份、柠檬酸12份、磷酸8份、钼酸钠3份、碳酸钠或硅酸钠3份、浸润剂0.2份、水100份。
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| CN104498925B (zh) * | 2015-01-19 | 2017-07-21 | 山东大学 | 一种基于多官能团烷基磷酸酯的金属表面处理液及应用 |
| CN107502884A (zh) * | 2017-09-27 | 2017-12-22 | 荆门市拓达科技有限公司 | 一种用于铝及铝合金的耐磨型锰系磷化液及其制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1075176A (zh) * | 1993-03-29 | 1993-08-11 | 冶金工业部钢铁研究总院 | 带锈钢材表面处理液 |
| CN1195713A (zh) * | 1998-02-07 | 1998-10-14 | 杨妙清 | 激光淬火前处理常温磷化新工艺 |
| CN1865503A (zh) * | 2006-06-12 | 2006-11-22 | 张清学 | 汽车用磷化液、配制方法及其磷化处理工艺 |
| CN101386980A (zh) * | 2008-11-07 | 2009-03-18 | 沈阳帕卡濑精有限总公司 | 一种用于钢板处理的无镍离子磷化剂 |
| CN101935832A (zh) * | 2010-10-22 | 2011-01-05 | 南京有为化工有限公司 | 一种常温下可循环使用的锌铁系金属表面磷化液 |
-
2013
- 2013-09-23 CN CN201310434489.9A patent/CN103484848B/zh not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1075176A (zh) * | 1993-03-29 | 1993-08-11 | 冶金工业部钢铁研究总院 | 带锈钢材表面处理液 |
| CN1195713A (zh) * | 1998-02-07 | 1998-10-14 | 杨妙清 | 激光淬火前处理常温磷化新工艺 |
| CN1865503A (zh) * | 2006-06-12 | 2006-11-22 | 张清学 | 汽车用磷化液、配制方法及其磷化处理工艺 |
| CN101386980A (zh) * | 2008-11-07 | 2009-03-18 | 沈阳帕卡濑精有限总公司 | 一种用于钢板处理的无镍离子磷化剂 |
| CN101935832A (zh) * | 2010-10-22 | 2011-01-05 | 南京有为化工有限公司 | 一种常温下可循环使用的锌铁系金属表面磷化液 |
Non-Patent Citations (2)
| Title |
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| 常温铁系彩色磷化工艺研究;肖鑫等;《电镀与涂饰》;19991231;第18卷(第4期);全文 * |
| 肌醇六磷酸脂在低温磷化中的应用;陈洪希;《电镀与精饰》;20001231;第22卷(第6期);第23、24页 * |
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